1479results about "Zinc organic compounds" patented technology

The thin film-forming material of the present invention comprises a bis(β-diketonato)zinc compound that is liquid at 25° C. and is suitable for forming a zinc-containing thin film. By using the thin film-forming material, a thin film can be produced with stable film-forming rate or stable film composition control without suffering from problems of raw material gas suppliability and in-line raw material transport. Preferred (β-diketonato)zinc compounds include, for example, bis(octane-2,4-dionato)zinc and bis(2,2-dimethyl-6-ethyldecane-3,5-dionato)zinc.

An isoreticular metal-organic framework (IRMOF) and method for systematically forming the same. The method comprises the steps of dissolving at least one source of metal cations and at least one organic linking compound in a solvent to form a solution; and crystallizing the solution under predetermined conditions to form a predetermined IRMOF. At least one of functionality, dimension, pore size and free volume of the IRMOF is substantially determined by the organic linking compound.

The invention relates to a nanometer hole metal-organic frame material in a single-level or multilevel pore canal structure as well as a preparation method and the application thereof. The preparation method comprises the following steps: at least one metal salt and at least one polyfunctional group organic ligand reacts with at least one template agent in at least one solvent under the condition that no hole aid agent exists or only one hole aid agent exist, and single-level or multilevel nanometer holes or channels with the size of 0.5-100 nm exist in at least one direction in the internal space of the obtained metal-organic frame solid. The nanometer hole metal-organic frame material with large hole size and the nanometer hole metal-organic frame material in the layered multilevel pore canal structure can be obtained without the synthesis of the large-size organic ligand and have wide applications.

Provided is a colored photosensitive curing composition useful for color filters in primary colors, including blue, green, and red, having a high molar absorption coefficient and allowing a reduction in film thickness and superior color purity and fastness.

A colored photosensitive curing composition, comprising, as its colorant, a dipyrromethene-based metal complex compound obtained from a metal or metal compound and a dipyrromethene-based compound represented by the following Formula (I):

• • wherein in Formula (I), R¹ to R⁶ each independently represent a hydrogen atom or a substituent group; and R⁷ represents a hydrogen or halogen atom, or an alkyl, aryl or heterocyclic group.

Organometallic compounds of Group IIB and IIIA metals that are substantially pure and contain low levels of oxygenated impurities are provided. Also provided are methods of preparing such organometallic compounds.

A chelate comprised of creatine bonded to an essential mineral selected from the group consisting of Mg, Ca, Cu, Zn, Fe, Cr, Co, Mo, Se and Mn to form a heterocyclic ring. Preferably, the metal is Mg, but Ca, Zn, Fe, Cr and Mn are also preferred. The creatine chelates of the present invention are capable of being absorbed in the stomach or intestines via active transport without substantial metabolism of the chelate. In other words, the creatine ligand is protected by the metal from undergoing cyclization in the acidic environment of the stomach and the metal is made more bioavailable due to the presence of the creatine ligand.

The invention relates to a preparation method of a thermal conduction enhanced metal organic framework gas storage material and belongs to the field of nanocomposites. The preparation method comprises the following steps: firstly selectively preparing a metal organic framework material with a large surface area and a high micropore proportion; performing synthesis post-modification on the metal organic framework material by a 'one-pot' method, regulating the polarity and contained functional groups of pores, immobilizing metal nanoparticles inside the pores to enhance the thermal conduction property of the metal organic framework material; adsorbing industrial gas by utilizing the ultra-large specific surface area and the nano duct structure of the metal organic framework material, wherein the thermal conduction enhanced adsorption material can be used for quickly transmitting the heat generated in the adsorption and desorption process of the industrial gas. The metal organic framework industrial gas adsorber prepared by the invention can be used for efficiently adsorbing and desorbing the industrial gas and effectively improving the thermal conduction property of the adsorber, and avoiding the influence of the heat effect on the adsorption quantity in the adsorption and desorption process. The preparation method provided by the invention has the advantages of use of readily available and inexpensive raw materials, simple process, and mild reaction conditions and is suitable for large-scale production.

A zinc amino acid chelate formulation is disclosed comprising zinc ions being chelated by an amino acid ligand mixture comprising glycine and a sulfur-containing amino acid wherein the ligand to zinc molar ratio is from about 1:1 to 2:1 and wherein the glycine to sulfur-containing amino acid molar ratio is between about 1:6 to 6:1.

The present invention provides a metal-organic framework (“MOF”) comprising a plurality of metal clusters and a plurality of multidentate linking ligands. Each metal of the plurality of metal clusters comprises one or more metal ions. Each ligand of the plurality of multidentate linking ligands connects adjacent metal clusters. The present invention also provides a method of forming the metal-organic framework. The method of the invention comprises combining a solution comprising one or metal ions with a multidentate linking ligand having a sufficient number of accessible sites for atomic or molecular adsorption that the surface area of the resulting metal-organic framework is greater than 2,900 m²/g.

Metal complexes that exhibit multiple radiative decay mechanisms, together with methods for the preparation and use thereof.

The invention belongs to the technical field of nanocomposite materials and in particular relates to a preparation method of a metal-organic framework compound with a hierarchical pore structure. The preparation method comprises the following steps: firstly, self-assembling a diblock copolymer in a solvent to form a flexible polymer nanowire with a core-shell structure, and cross-linking cores to obtain a polymer nanowire with a stable solvent; adding metal ions and organic ligands into a nanowire solution to form a mixed solution; crystallizing at the room temperature to obtain a metal-organic framework/core-shell structure polymer nanowire compound; calcining to remove the polymer nanowire to obtain a hierarchical pore material with MOFs (metal-organic frameworks) micropores, small mesopores formed after calcination of a shell layer of the polymer nanowire and large mesopores formed after calcinations of a core layer. According to the MOFs material with the hierarchical pore structure, the advantages of the micropores and the micropores are combined, the mass transfer speed of the MOFs material is improved, relatively large molecules can conveniently enter the MOFs material, and the application potential of the MOFs material in the field of catalysis, adsorption and the like is improved.

The invention discloses a method for rapidly synthesizing a BTC (1,3,5-benzenetricarboxylic acid)-based nanoscale organometallic framework material at room temperature. The nanomaterial is prepared by the following steps: mixing metal acetate aqueous solution with BTC solution at room temperature, and reacting to obtain BTC-based organometallic framework nanoparticles. The method is rapid, simple and energy-saving; the yield is high; the used raw materials and solvents are inexpensive and easily available; the safety problem of commonly used nitrate is not caused; the method is favorable to the industrial production and has wide application prospects in the fields of catalysis, adsorption, drug carriers, building of nano devices and the like.

In a method for functionalizing a carbon nanotube surface, the nanotube surface is exposed to at least one vapor including at least one functionalization species that non-covalently bonds to the nanotube surface, providing chemically functional groups at the nanotube surface, producing a functionalized nanotube surface. A functionalized nanotube surface can be exposed to at least one vapor stabilization species that reacts with the functionalization layer to form a stabilization layer that stabilizes the functionalization layer against desorption from the nanotube surface while providing chemically functional groups at the nanotube surface, producing a stabilized nanotube surface. The stabilized nanotube surface can be exposed to at least one material layer precursor species that deposits a material layer on the stabilized nanotube surface.

The invention discloses a method for hydrothermally synthesizing a porous metal-organic framework under low temperature and normal pressure, which comprises the following steps: 1) bivalent transition metal salt is put into proper amount of distilled water to be dissolved; 2) a multidentate organic ligand is put into proper amount of distilled water, and ammonia (30 percent, W/W) is added into the solution until the organic ligand is dissolved; 3) solutions obtained in step 1) and step 2) are mixed, and diluted by the distilled water; 4) the solution obtained in step 3) reacts for 4 to 24h at a temperature of between 80 and 100 DEG C, and is naturally cooled to room temperature at an environmental temperature to obtain an MOF crystal product; and 5) the MOF crystal product obtained in step 4) is filtered, MOF crystals are colleted and washed by the distilled water and absolute ethyl alcohol respectively, and the product is obtained after the natural drying. By performing a hydrothermal reaction in an ammonia solution, the method has mild conditions needed by the synthesis, less energy consumption and time consumption, and does not need a voltage resistant reactor. Therefore, the method is simpler and has lower cost; and a porous crystal material obtained by the synthesis has potential application value in the fields of gas separation, gas storage and heterogeneous catalysis.

A system and method for systematically generating potential metal-organic framework (MOFs) structures given an input library of building blocks is provided herein. One or more material properties of the potential MOFs are evaluated using computational simulations. A range of material properties (surface area, pore volume, pore size distribution, powder x-ray diffraction pattern, methane adsorption capability, and the like) can be estimated, and in doing so, illuminate unidentified structure-property relationships that may only have been recognized by taking a global view of MOF structures. In addition to identifying structure-property relationships, this systematic approach to identify the MOFs of interest is used to identify one or more MOFs that may be useful for high pressure methane storage.

The invention which belongs to the technical field of new materials relates to a synthetic method of ZIFs, and concretely discloses a method for synthesizing nanometer/micrometer scale ZIFs based on imidazole and its derivatives at room temperature in a concise, efficient and green manner. The method comprises the following steps: dissolving a single imidazole ligand or a mixture of two imidazole ligands in water or an organic liquid to form a solution, adding an alkaline substance to adjust the pH value of the solution, adding a metal salt to form a reaction system, and reacting to obtain the nanometer or micrometer scale ZIFs. The method which allows routine reactants to be utilized and the alkaline substance to be added to adjust the pH value of the system has the advantages of ligand application amount reduction, controllable product size, and high purity of the nanometer/micrometer scale ZIFs. The synthetic method has the characteristics of cheap and easily available raw materials and solvent, and no pollution, and has important meanings to the production and the application of the ZIFs.

Metal L-seleno-alpha-amino acids salts and their use as a bioavailable feed and water ration supplement for domesticated animals such as cattle, pigs and poultry.