1343 results about "Zinc salts" patented technology

The invention relates to the technical field of adsorbents, and particularly discloses an aluminum oxide type adsorbent and a preparation method thereof.The preparation method comprises the following steps that lanthanum salt, cerium salt and a polyethylene glycol aqueous solution are mixed to be uniform, then the mixture is mixed with gamma-Al2O3 to be uniform, pH is adjusted, standing is conducted, solid-liquid separation is conducted, drying and roasting are conducted, and a double-doped carrier is obtained; dispersing the double-doped carrier in a mixed solution containing 2-methylimidazole, ferric salt and zinc salt, adjusting the pH value, carrying out heating reaction, solid-liquid separation and drying in an inert atmosphere, grinding to obtain powder, and carrying out molding treatment on the powder to obtain a composite carrier; uniformly mixing the Ag modified molecular sieve with silica sol, coating the surface of the composite carrier with the mixture, and drying to obtain an adsorbent precursor; dipping an adsorbent precursor in the dispersion liquid, and after dipping, solid-liquid separation and drying, reactivating to obtain the aluminum oxide type adsorbent; the prepared adsorbent can synergistically and efficiently remove multiple impurities and is excellent in corrosion resistance.

The invention belongs to the technical field of pharmaceutical chemical processes, and particularly relates to a preparation method of a penem antibiotic intermediate 4-BMA, which comprises the following steps: adding Zn powder, chlorosilane, aliphatic tertiary amine, zinc salt and 4-AA in a formula (I) into THF (tetrahydrofuran), uniformly stirring, dropwise adding a THF solution of alpha-haloamide with an induction group in a formula (II) for reaction, filtering the reaction solution, removing the zinc powder, and drying to obtain the penem antibiotic intermediate 4-BMA. Extracting the filtrate to obtain a THF phase, washing with an aqueous solution of potassium oxalate, and recovering THF to obtain a formula (III); and carrying out oxidative hydrolysis, sulfur dioxide quenching, sulfur dioxide acid regulation crystallization and recrystallization on the formula (III) to obtain the intermediate 4-BMA. According to the preparation method disclosed by the invention, a zinc salt is used as a catalyst during preparation of the formula (III), potassium oxalate is used for removing residual Zn (II) in a THF phase, SO2 is used for quenching hydrogen peroxide and acid regulation and crystallization of 4-BMA, the oxygenolysis problem of 4-BMA is solved, and the preparation method has the characteristics of greenness, safety and high efficiency, is strong in product competitive advantage and is suitable for industrial production.

The invention relates to an aqueous zinc-iodine battery electrolyte containing a phenolic additive, and a preparation method and application thereof, and belongs to the technical field of aqueous zinc-iodine batteries. The invention aims to solve the technical problems of serious multi-iodide shuttling and negative electrode by-products of the existing aqueous zinc-iodine battery. The preparation method of the aqueous zinc-iodine battery electrolyte containing the phenolic additive comprises the following steps: dissolving zinc salt and the phenolic additive in deionized water, and fully stirring and mixing to obtain the aqueous zinc-iodine battery electrolyte containing the phenolic additive. The phenolic additive used in the application can accelerate conversion from I3-to I-, accelerate iodine conversion reaction kinetics and reduce generation of polyiodide, so that shuttling of the polyiodide is effectively inhibited, a phenolic additive monomer is adsorbed on the surface of a zinc negative electrode, contact between Zn < 2 + > and water molecules is reduced, and generation of zinc negative electrode by-products is inhibited; the zinc-iodine battery also has the advantages of being easy to manufacture and low in cost.

The invention provides a method for preparing ultra-small molecular zinc hyaluronate, and relates to the field of hyaluronate. The method comprises the following steps: carrying out enzymolysis on macromolecular sodium hyaluronate by using leech hyaluronidase to obtain ultra-small molecular sodium hyaluronate; the method comprises the following steps: adsorbing ultra-small molecular sodium hyaluronate by using anion exchange resin, eluting by using a zinc salt solution, and reacting the obtained eluent to obtain ultra-small molecular zinc hyaluronate; the average molecular weight of the ultra-small molecular sodium hyaluronate is 600 Da to 1000 Da. The whole process is simple, the obtained ultra-small molecular zinc hyaluronate is high in zinc content, free of sodium ion residues and high in preparation yield, an organic solvent is not needed in the whole production process, and the method is suitable for industrial production.

The invention discloses a high-modulus leather / eutectic gel composite electrolyte and a preparation method and application thereof, and belongs to the technical field of energy storage. The preparation method comprises the following steps: 1) preparing a eutectic gel solution containing polyvinyl alcohol, zinc salt, small molecular polyol and water; 2) carrying out vacuum impregnation to obtain leather fibers containing a eutectic gel solution; and (3) obtaining the leather / eutectic gel composite electrolyte with the imitated reinforcing steel bar-concrete structure through freeze-thaw circulation.The composite electrolyte effectively solves the problem that an existing gel electrolyte is low in modulus and difficult to effectively deal with extreme mechanical deformation, and the cycle life of the water-based zinc ion battery is remarkably prolonged.

The invention belongs to the technical field of electrochemical energy storage, and particularly relates to a low-temperature aqueous electrolyte for anchoring I < + > ions based on a double-coordination structure and a low-temperature four-electron aqueous zinc-iodine battery. The low-temperature aqueous electrolyte is a mixed solution of a zinc salt, an electrolyte additive and water, and the low-temperature aqueous electrolyte comprises 2-5 mol / L of the zinc salt and 0.3-0.6 mol / L of the electrolyte additive; the zinc salt is zinc perchlorate or zinc tetrafluoroborate. The low-temperature four-electron aqueous zinc-iodine battery comprises the low-temperature aqueous electrolyte. Compared with the prior art, the invention at least has the following beneficial effects: (1) the corrosion risk caused by chloride ion concentration is reduced; (2) efficient four-electron iodine positive electrode reaction is realized; and (3) obtaining the low-temperature four-electron aqueous zinc-iodine battery.

The invention provides an asphalt-based hard carbon negative electrode material as well as a preparation method and application thereof, belongs to the technical field of battery materials, and is used for solving the technical problems that a template is non-uniformly distributed in a carbon source and the size is difficult to control in hard carbon preparation. The preparation method of the asphalt-based hard carbon negative electrode material comprises the following steps: mixing asphalt and organic zinc salt, and then carrying out heat treatment to obtain high-softening-point asphalt; and pre-oxidizing and carbonizing the high-softening-point asphalt to obtain the asphalt-based hard carbon negative electrode material. Organic zinc salt and asphalt form a metal template in situ at a high temperature, the metal template can be uniformly distributed in the asphalt, meanwhile, the particle size of the template is controlled through process change, and the prepared asphalt-based hard carbon negative electrode material has high reversible specific capacity, high initial coulombic efficiency and good rate capability.

The invention discloses a preparation method and application of a bio-based zinc adenine salt environment-friendly PVC heat stabilizer, and belongs to the field of fine chemical synthesis and plastic additive application. The nitrogen-containing organic metal heat stabilizer adenine zinc complex is prepared by taking adenine and zinc acetate as main raw materials through a one-step method. The method is simple and environment-friendly in preparation process, easily available in raw materials and suitable for industrial production. The prepared heat stabilizer zinc adenine is used as a heat stabilizer, can effectively absorb hydrogen chloride generated by PVC thermal decomposition, and can replace allyl chlorine atoms, so that the heat stability of a PVC product is improved, PVC has more excellent heat stability, and the heat stabilizer is expected to replace a traditional commercially available heat stabilizer.

The invention relates to the technical field of coating preparation, and discloses a high-adhesion quick-drying inorganic zinc silicate shop primer and a preparation method thereof.The high-adhesion quick-drying inorganic zinc silicate shop primer is prepared from modified zinc powder, modified graphite powder, a sodium silicate solution, alpha-phase nanometer AlO, a quick-drying agent, an adhesion promoter, heat-resistant filler, a dispersing agent, a defoaming agent and a diluting solvent; the quick-drying agent is prepared by compounding zinc naphthenate, EDTA and titanium isopropylate according to the mass ratio of 1: (0.2-0.3): (0.4-0.6), the quick-drying agent accelerates the reaction by catalyzing hydrolysis of silicate through zinc salt, chelating of EDTA and metal ions, titanium isopropylate provides titanium ions to synergistically form a film and improve the quick-drying efficiency, the adhesion promoter is prepared by compounding KH-560 and E-44 epoxy resin according to the mass ratio of 3: 1, and the adhesion promoter is prepared by compounding epoxy resin and epoxy resin. The adhesion promoter enhances interface mechanical occlusion and adhesion through silane bonding base materials and epoxy resin, other raw materials are matched with the adhesion promoter to accelerate the drying speed of the primer, and a coating coated with the primer is not prone to stripping and peeling. The application has the effects of improving the adhesive force and drying speed of the inorganic zinc silicate shop primer.

The invention belongs to the technical field of hot melt adhesives, and discloses a polyurethane hot melt adhesive as well as a preparation method and application thereof. The polyurethane hot melt adhesive is prepared from the following raw materials: polyester polyol, polyether polyol, fluorine-containing dihydric alcohol, isocyanate, a chain extender, a catalyst and a modified montmorillonite antibacterial filler, the preparation method of the modified montmorillonite antibacterial filler comprises the following steps: modifying montmorillonite through sulfur-containing amino acid, increasing the interlayer spacing of the montmorillonite through an intercalator, entering the interlayer spacing of the montmorillonite through a metal organic framework synthesized by imidazole or an imidazole derivative and zinc salt, and carrying out surface modification to obtain the modified montmorillonite antibacterial filler. A silver-ammonia solution is treated by a reducing agent, so that the nano-silver is loaded on the montmorillonite and in the surface, the skeleton and the pores of the MOFs material. The polyurethane hot melt adhesive disclosed by the invention not only has high peel strength, but also has excellent waterproofness and lasting antibacterial property.

The invention relates to a composite hydroxypropyl methylcellulose skeleton sustained-release material and a preparation method thereof, and belongs to the technical field of drug sustained release. The sustained-release material is prepared from 70 to 90 parts of hydroxypropyl methylcellulose (HPMC), 10 to 20 parts of sodium alginate, 8 to 15 parts of chitosan, 0.1 to 0.2 part of Omega-3 fatty acid, 0.05 to 0.06 part of vitamin D, 2.5 to 5 parts of soluble calcium salt-zinc salt composite cross-linking agent, 0.5 to 1.5 parts of hydrolyzable cross-linking agent, 3 to 10 parts of enzyme sensitive auxiliary material, 1 to 5 parts of pore-foaming agent and 2 to 8 parts of hydrophobic blocking agent. The preparation method comprises the steps of raw material pretreatment and dry mixing, active component dispersion liquid preparation, wet granulation and primary cross-linking, secondary cross-linking and drying, vacuum drying and size stabilization, curing and packaging and the like. The sustained-release material provided by the invention has the advantages of controllable drug release rate, good mechanical strength and biodegradability, is suitable for sustained-release delivery of Omega-3 fatty acid, vitamin D and other active components, and can improve the bioavailability and stability of drugs.

The invention relates to the technical field of water-based energy storage batteries, in particular to a two-phase electrolyte for a water-based zinc ion battery and a preparation method of the two-phase electrolyte, and the two-phase electrolyte comprises soluble zinc salt, water and quaternary ammonium nitrate; the soluble zinc salt comprises one of zinc trifluoromethanesulfonate, zinc bis (trifluoromethylsulfonyl) imide, zinc acetate, zinc sulfate and zinc chloride, and the molar concentration of the soluble zinc salt is 1-5 mol / L; the quaternary ammonium nitrate is one or more than two of tetramethylammonium nitrate, tetraethyl ammonium nitrate, tetrabutyl ammonium nitrate, hexadecyl trimethyl ammonium nitrate and octadecyl trimethyl ammonium nitrate, and the molar concentration of the quaternary ammonium nitrate is 1-3 mol / L. The preparation method is simple, convenient and efficient, the reversibility of the zinc anode is optimized, the method is crucial for promoting the design of a practical water-based zinc ion battery, and the application of the zinc-based battery in the field of energy storage is further accelerated.

The invention discloses a corrosion and scale inhibitor suitable for high-salinity water quality and a preparation method and application thereof.The corrosion and scale inhibitor comprises nano SiO2 at NH2, organic phosphonate, zinc salt, polycarboxylic acid and nano SiO2, a corrosion inhibition component is composed of the nano SiO2 at NH2, the organic phosphonate and the zinc salt according to the mass ratio of (0.8-1.2): 0.5: (0.3-0.4), a scale inhibition component is composed of the polycarboxylic acid and the nano SiO2 according to the total solid content mass ratio of 3: 1, and the scale inhibition component is composed of the nano SiO2 at NH2, the organic phosphonate and the zinc salt. The polycarboxylic acid grafting rate in the scale inhibition component is greater than or equal to 80%, and the corrosion inhibition component and the scale inhibition component are compounded according to the ratio of 1: 1 to prepare a finished product agent; the preparation method comprises the following steps: preparing the corrosion inhibition component, adjusting the pH value to 3-4, preparing the scale inhibition component, and compounding the corrosion inhibition component and the scale inhibition component to prepare the finished product agent. According to the invention, nano SiO2 and NH2 are added to prepare a corrosion inhibition component, nano SiO2 is added to prepare a scale inhibition component, and the components are strictly mixed step by step, so that the components form a chemical and physical multi-synergistic corrosion and scale inhibition effect, and the finished agent has the characteristics of corrosion inhibition rate, CaCO3 resistance rate higher than 95%, MgSiO3 resistance rate higher than 80%, high-salt environment tolerance, high high-temperature stability, low biotoxicity and the like.

The invention belongs to the technical field of redox flow batteries, and particularly discloses a high-performance hierarchical pore carbon felt electrode for a flow battery and a preparation method of the high-performance hierarchical pore carbon felt electrode for the flow battery. Zinc salt or bismuth salt is dissolved in a solvent, and a precursor solution is obtained through stirring and ultrasonic treatment; dipping the pre-oxidized felt into the precursor solution, performing ultrasonic treatment, taking out and drying; and carbonizing the dried carbon felt at a high temperature in a protective atmosphere, treating with nitric acid, cleaning with deionized water, and drying to obtain the hierarchical porous carbon felt electrode with high activity and high specific surface area. The prepared high-performance hierarchical pore carbon felt electrode has a multi-scale pore structure and rich active sites, the specific surface area, the conductivity and the catalytic activity are remarkably improved, meanwhile, the hydrophilicity is optimized, and the electrolyte wettability is enhanced. The method is short in technological process, high in efficiency, low in cost and suitable for large-scale production and industrial application of the high-performance carbon felt electrode.

The present invention relates to the technical field of ORR catalyst preparation, and in particular to an iron-nitrogen-carbon catalyst and its preparation method and application. The present invention provides a method for preparing an iron-nitrogen-carbon catalyst, characterized in that it comprises: dispersing a zinc salt and a ferrous salt in methanol to obtain a mixed solution A; under heating conditions, dispersing 2-methylimidazole and 1,4-terephthalonitrile in methanol to obtain a mixed solution B; stirring and mixing the mixed solution A and the mixed solution B to obtain a precursor powder, and calcining the precursor powder under an inert atmosphere to obtain an iron-nitrogen-carbon catalyst with a hierarchical porous structure. The present invention provides a new preparation method for preparing an iron-nitrogen-carbon catalyst with a hierarchical pore structure, which prepares the iron-nitrogen-carbon catalyst with a hierarchical pore structure by introducing a 1,4-terephthalonitrile molecular template.

The application discloses a preparation method of a catalyst for liquid-phase refining of crude octanol, and the preparation method comprises the following steps: (1) mixing pretreated fly ash and pseudo-boehmite, adding deionized water and nitric acid, stirring until a colloid is formed, drying the colloid, mixing the dried colloid with kaolin, and obtaining a carrier through kneading, extrusion molding, drying and calcination; (2) taking a nickel salt, a manganese salt and a zinc salt as active components, taking a calcium salt as an auxiliary component, dissolving the active components and the auxiliary component in deionized water to obtain a salt solution, adding n-hexane into the salt solution and stirring uniformly to prepare an impregnation solution, immersing the carrier in the impregnation solution, and obtaining the catalyst through washing, drying and calcination. The catalyst prepared by the method is mainly used in a liquid-phase refining reaction process of crude octanol, and has high activity stability and selectivity.

The invention discloses cobalt molybdenum nitride / cobalt modified nitrogen-doped hollow carbon microspheres as well as preparation and application thereof, and relates to the technical field of electrochemical energy storage devices. Carboxylated polystyrene microspheres, soluble zinc salt and cobalt salt, phosphomolybdic acid and 2-methylimidazole are dispersed in methanol, a PMA (at) ZnCo-ZIFs / PS precursor of a spherical structure is obtained, then the PMA (at) ZnCo-ZIFs / PS precursor is placed in an inert atmosphere for carbonization treatment, and the cobalt molybdenum nitride / cobalt modified nitrogen-doped hollow carbon microsphere material is obtained. According to the structure and the preparation method, the nitride / metal cobalt component and the nitrogen-doped sodium affinity sites are introduced at the same time, uniform transportation and nucleation of sodium ions are effectively induced, sodium metal is guided to deposit in a specific three-dimensional structure, growth of sodium dendrites is effectively inhibited, volume expansion of metal sodium in the reaction process is relieved, the preparation method is simple and convenient, and the preparation method is suitable for industrial production. The cost is low, the electrochemical performance of the sodium metal battery assembled by using the composite material can be remarkably improved, and the composite material has a good large-scale application prospect.

The invention discloses a method for preparing biomass-based hard carbon through in-situ continuous catalytic carbonization and application, and belongs to the technical field of biomass-based carbon material preparation and energy storage. The method comprises the following steps: mixing a biomass raw material with a zinc salt aqueous solution; performing low-temperature pyrolysis and carbonization on the mixed material in an inert atmosphere; performing high-temperature carbonization on the low-temperature pyrolysis carbonization intermediate in an inert atmosphere; and after high-temperature carbonization is finished, naturally cooling to room temperature, washing and drying to obtain the hard carbon material. By utilizing the differentiated existence forms of the zinc salt at different temperatures and the characteristics of in-situ continuous catalysis and high-temperature volatilization, special rapid heating equipment is not needed, and the catalyst does not need to be washed off after low-temperature pyrolysis carbonization, so that the cooperative regulation and control of the interlayer spacing and the closed-pore structure of the biomass-based hard carbon microcrystalline are realized; the biomass-based hard carbon with wide microcrystalline interlayer spacing and rich closed pore structures is obtained. The obtained hard carbon has large reversible specific capacitance, high platform capacity and high rate performance when being applied to a sodium / lithium ion battery negative electrode material.

The invention relates to the field of water treatment, and discloses a scale and corrosion inhibitor for seawater circulating cooling water, which is prepared from phosphonic acid grafted maleic anhydride-acrylic acid copolymer, hydroxyethylidene diphosphonic acid, amino trimethylene phosphonic acid, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N- The anti-corrosion coating is prepared from the following raw materials: N, N-diethylaminomethyl-benzotriazole, gamma-aminopropyltriethoxysilane, zinc salt and a polyoxyethylene-polyoxypropylene block copolymer. The core of the invention is that all the raw material components form the thermo-sensitive polyelectrolyte compound through a self-assembly process. The compound is stably dispersed at low temperature by utilizing the cloud point effect of the block copolymer, and is subjected to phase change and preferential deposition on a high-temperature heat exchange surface, so that targeted and efficient delivery of various active components is realized. According to the invention, the problems of incompatibility of components and poor stability of a traditional compound agent are solved, the product has excellent storage stability, and efficient and synergistic corrosion and scaling control can be realized under high-temperature and high-salinity working conditions.

The invention discloses an electrolyte for regulating interface reaction based on an organic anion mediated gradient ion pump, and belongs to the field of zinc metal batteries. The electrolyte for regulating and controlling the interface reaction based on the organic anion mediated gradient ion pump comprises a mixed aqueous solution of zinc salt electrolyte and organic anion salt, the zinc salt electrolyte is selected from any one of zinc sulfate, zinc chloride, zinc acetate or zinc trifluoromethanesulfonate; an organic chain in the organic anion salt is of a Janus structure, the organic chain contains hydroxyl and alkyl with hydrophobic end chain parts, the problems that an interfacial film of an existing aqueous zinc metal battery solid electrolyte is prone to failure, a zinc negative electrode is poor in stability, and side reaction is serious are solved, the high-reversibility and long-life zinc deposition / stripping process is achieved through multiple effects of the organic salt additive, and the service life of the solid electrolyte is prolonged. The overall performance of the zinc metal battery is improved.

The invention discloses a preparation method for regulating the morphology of zinc oxide, and belongs to the technical field of metal oxides, and the preparation method comprises the following steps: (1) preparing a zinc salt solution and an alkaline solution; (2) respectively inputting the zinc salt solution and the alkaline solution into an ultrasonic microreactor, enabling the zinc salt solution and the alkaline solution to be in contact in the conveying process in the ultrasonic microreactor, and reacting under the ultrasonic action to form zinc oxide slurry; and (3) outputting the zinc oxide slurry from the ultrasonic microreactor, filtering, washing, drying, crushing, and screening to obtain the zinc oxide powder. Controllable synthesis of nano-zinc oxide with different morphologies is realized by utilizing the super-strong mixing capacity of the ultrasonic pipeline reactor.

The invention belongs to the technical field of preparation of a solid electrolyte in a high-specific-capacity battery, and particularly discloses a preparation method and application of a composite solid electrolyte of a high-specific-capacity battery, and the method comprises the following steps: adding natural ore powder into a zinc salt electrolyte or a lithium salt electrolyte, stirring and replacing, and then adding a lithium salt electrolyte or a zinc salt electrolyte; centrifugally washing and drying to obtain ore powder; weighing ore powder and mixing with a polymer to obtain mixed powder; and pressing the mixed powder by using a tablet press to obtain the composite solid electrolyte. According to the preparation method and the application of the high-specific-volume battery composite solid electrolyte, the composite solid electrolyte prepared by the method can be used for an aqueous zinc-iodine battery, so that side reaction caused by free water is effectively reduced; the dissolution of active iodine and the shuttling of polyiodide can be inhibited, the capacity fading of the battery is relieved, and the cycling stability is improved; meanwhile, the composite solid electrolyte can also be used for a lithium ion battery, and the cycling stability and safety can be improved.

The invention belongs to the technical field of daily chemical products, and particularly relates to a hidroschesis, cooling and deodorization composition as well as a preparation method and application thereof. The hidroschesis, cooling and deodorization composition comprises the following components in parts by weight: 10-55 parts of zinc ricinoleate, 1-11 parts of a cooling agent and 10-55 parts of a plant extract, the plant extract is at least one of lemon fruit extract, equisetum arvense extract, mangnolia officinalis bark extract and phellinus linteus extract. The cooling, antiperspirant and deodorant composition provided by the invention takes the zinc ricinoleate, the menthol and the menthol oxypropylene glycol as main cooling and antiperspirant components, and is matched with various plant extracts to exert the auxiliary bacteriostatic, astringing, anti-allergy and anti-allergy effects; the effective synergistic effect is achieved in the aspects of hidroschesis, deodorization, bacteriostasis, astringency, allergy relieving and resisting and the like.

The invention discloses a metal-doped hard carbon negative electrode material and a preparation method thereof, and relates to the technical field of sodium ion batteries. The method comprises the following steps: 1) mixing a zinc salt activator and a carbon source according to a certain proportion, and stirring to obtain a zinc-doped hard carbon precursor; and 2) performing high-temperature carbonization on the mixture in an inert gas environment to obtain the negative electrode material. The preparation method disclosed by the invention is simple to operate and relatively low in cost, the obtained zinc-doped hard carbon negative electrode material contains rich microporous and mesoporous structures, more sodium storage sites are provided, the diffusion rate of sodium ions is increased by zinc ions through interlayer spacing regulation and control, a charge shielding effect and improvement of interface dynamics, and the performance of the zinc-doped hard carbon negative electrode material is improved. The first-circle coulombic efficiency and the circulation rate capability are promoted to be obviously improved.

The invention discloses a water-based poly-ceramic coating material as well as a preparation method and application thereof. The formula comprises a composite base material (40-45 parts of modified waterborne polyurethane resin and 15-20 parts of a waterborne acrylic emulsion), a synergistic curing system (10-12 parts of a blocked isocyanate curing agent and 0.8-1.2 parts of a latent organic zinc salt accelerant), an organic-inorganic reinforced phase (10-15 parts of nano silicon dioxide and 8-10 parts of polysilazane) and a functional aid. The base material and the cosolvent cooperate to make VOCs less than or equal to 30 g / L, a curing system cooperates to realize low-temperature rapid curing, organic-inorganic components cooperate to form a poly-ceramic structure, the coating is adaptive to an existing roll aluminum production line, and the problems of environmental protection, energy conservation and performance of a traditional coating are solved.

The present application provides a kind of variable color 3D printing material based on inulin complex, the variable color 3D printing material includes inulin, calcium salt, magnesium salt and zinc salt.The variable color 3D printing material of the present application significantly improves the gelation performance of pure inulin, greatly shortens its gelation time, significantly improves the 3D printing formability, printing precision and water holding capacity of pure inulin gel, has rich variable color and color stability.

The invention relates to the technical field of gel electrolyte, in particular to a method for constructing gel electrolyte on the surface of an electrode through in-situ self-initiation and application of the method. The method comprises the following steps: (1) dissolving a zinc salt in water to obtain a liquid electrolyte; (2) uniformly mixing a gel monomer, an initiator, a cross-linking agent and a liquid electrolyte to obtain a precursor solution; and (3) pouring the precursor solution on the surface of the negative electrode of the battery, covering the precursor solution with the positive electrode of the battery, and standing to realize in-situ construction of the gel electrolyte on the surface of the electrode. The solution is gelatinized through reducibility self-initiation of the metal electrode and is constructed on the surface of the electrode in situ, the electrochemical performance of the aqueous zinc metal is remarkably improved, meanwhile, the process steps are reduced, and the cost is reduced.

The invention relates to the field of battery materials, and discloses a preparation method of a porous hard carbon material and application of the porous hard carbon material in a sodium-ion battery, the preparation method of the material comprises the following steps: S1, preparing a sucrose solution by taking sucrose as a carbon source, carrying out hydrothermal reaction treatment on the sucrose solution, and then filtering and separating to obtain a hard carbon precursor; s2, dissolving zinc salt with distilled water to prepare a solution, adding the hard carbon precursor obtained in S1 into the solution, then adding absolute ethyl alcohol into the solution, mixing and stirring at normal temperature, finally heating to evaporate the solvent to dryness, and fully grinding to obtain a uniformly mixed material containing the zinc salt; and S3, putting the material obtained in the S2 into a furnace body, heating to 600 DEG C under a protective atmosphere, carrying out primary carbonization, then heating to 1300 DEG C, carrying out high-temperature carbonization, cooling, taking out, and uniformly grinding, so as to obtain the porous hard carbon material. The material provided by the invention has the characteristics of convenient preparation method, high first-week coulombic efficiency and high specific capacity.

The invention discloses an electrolyte for improving the cycling stability of a zinc-sulfur battery and application of the electrolyte in a photoelectric storage integrated battery. The electrolyte comprises a solvent, an additive and zinc salt, the additive is iodide, and the iodide comprises iodine negative ions and positive ions or polar functional groups. The functional additive is added into the electrolyte, positive ions inhibit dendritic crystals and side reactions of zinc, and iodine negative ions accelerate reversible change between sulfur and zinc sulfide, so that the cycling stability of the zinc-sulfur battery is improved. A zinc-sulfur battery with high specific capacity and long cycle life is integrated with a solar battery, so that the photoelectric storage integrated battery with high overall conversion efficiency, high specific capacity and long cycle life is prepared.

The present invention discloses a method for preparing a high-capacity asphalt-based hard carbon negative electrode material for sodium ion batteries. The asphalt-based hard carbon material is prepared by adopting a combined pre-oxidation-precarbonization process and a zinc salt catalysis method. The present invention further pre-carbonizes the pre-oxidized asphalt raw material to reduce surface defects of the final hard carbon product, thereby improving the initial efficiency and capacity of the sodium ion battery. The preparation method is simple, the process is controllable, the cost is low, and it is easy to promote and implement industrially.