The invention discloses a double-wall structured hollow ultrafine
polymer fiber and a preparation method thereof. The preparation method includes a first step of enabling 100-300 parts of polymers A and 300-1000 parts of
solvent A to be added in a dissolving kettle provided with a stirrer and a
thermometer, stirring and dissolving the polymers A and the
solvent A under temperature of 30-100 DEG C, carrying out defoaming and curing for 10-12 hours at vacuum degree of 0.03-0.05 MPa, and obtaining
polymer shell layer
spinning solution, a second step of enabling 0.5-100 parts of polymers B and 10-1000 parts of
solvent B to be added into the dissolving kettle provided with the stirrer and the
thermometer, stirring and dissolving the polymers B and the solvent B under temperature of 30-100 DEG C, carrying out defoaming and curing for 10-12 hours at vacuum degree of 0.03-0.05 MPa, and obtaining
polymer core layer
spinning solution, a third step of enabling the polymer shell layer
spinning solution and the polymer core layer spinning solution to pass through a core layer spinning
nozzle and a shell layer spinning
nozzle, wherein the inner
diameter of the core layer spinning
nozzle is 0.3-0.6 mm, and flow rate is 1-8 mm / h, the inner
diameter of the shell layer spinning nozzle is 0.8-1.2 mm, and the flow rate is 5-10 mm / h, spinning
voltage is 15-25 kilovolts, and finally manufacturing the double-wall structured hollow ultrafine polymer
fiber through electrostatic spinning. The polymers A can form the outer layer of a hollow polymer
fiber wall, and the polymers B can form the inner layer of the hollow polymer fiber wall.