456 results about "Cellulose nanocrystals" patented technology

The invention relates to the technical field of high-barrier composite packaging films, and discloses a high-barrier composite packaging film with an antibacterial function, which sequentially comprises a base layer, a nano composite barrier layer, an antibacterial functional layer and an outer protective layer from bottom to top, and the layers are tightly attached through a coated starch-based adhesive. According to the high-barrier composite packaging film with the antibacterial function, the cellulose nanowhiskers have the characteristics of high strength and high modulus and are mixed with the bio-based polylactic acid, so that the tensile strength and tear resistance of the bio-based polylactic acid can be remarkably improved, and the structural stability of the packaging film in the using process is guaranteed; nano titanium dioxide and nano cellulose aerogel are arranged in the nano composite barrier layer, so that the barrier property of the packaging film on oxygen and ultraviolet rays can be enhanced, and the packaging film also has a certain antibacterial effect; in addition, the nanocellulose aerogel has a loose porous structure, so that gas molecules can be effectively prevented from passing through, and the barrier property is further improved.

The invention relates to the technical field of material science and engineering, and discloses a nanocellulose-based oil-water separation and adsorption composite material, which is prepared from the following raw materials in parts by mass: 35 to 45 parts of nanocellulose; 8 to 11 parts of bagasse cellulose; 10 to 15 parts of sodium lignin sulfonate; 4 to 8 parts of chitosan; 5-10 parts of oxidized starch; 5 to 8 parts of cellulose nanowhiskers; 2-5 parts of silicon dioxide nanoparticles; 0.5 to 1 part of calcium carbonate nanoparticles; 1-2 parts of a citric acid cross-linking agent; 1-2 parts of graphene oxide; 0.3 to 0.6 part of ethylene diamine tetraacetic acid; 2-5 parts of glycerol; 0.4 to 1 part of stearoyl chloride; 2-4 parts of nano iron oxide; the preparation method comprises the following steps: pretreating the raw materials, mixing the pretreated raw materials into slurry, carrying out crosslinking and ultrasonic dispersion, standing to obtain a basic mixture, injecting the basic mixture into a mold, carrying out freeze drying to form a photocatalytic layer, carrying out centrifugal dewatering, carrying out chelation reaction, spraying a composite solution, and carrying out vacuum drying to obtain the photocatalytic material. The obtained composite material has the advantages of efficient adsorption capacity, good mechanical properties, environmental friendliness, degradability and low preparation cost.

The invention is applicable to the technical field of daily cleaning chemicals, and provides a double-shell probiotic microcapsule which comprises probiotics, a fat-soluble plant extract, cellulose nanocrystals, a polyacrylic acid-chitosan compound, a surfactant, diisocyanate, polyethylene glycol and ethyl acetate. A wall material of the microcapsule is formed by compounding a polyacrylic acid-chitosan compound and a fat-soluble plant extract, the particle size D50 is smaller than or equal to 5 microns, the microcapsule is stable in an environment with the pH being 8-10, and the microcapsule is broken to release probiotics when the pH is smaller than or equal to 6. The outer layer is polyacrylic acid / chitosan compound / polyurethane crosslinking (pH response), the inner layer is coconut oil and soybean oil (fat-soluble core), meanwhile, the material preparation process is simple, the controllable degree is high, and the material is suitable for batch preparation.

The invention relates to the technical field of lithium ion batteries, in particular to a diaphragm material for a lithium battery and a preparation method of the diaphragm material. Comprising a base film and a modified nano TiO2 coating, the modified nano TiO2 coating is arranged on at least one side surface of the base film, and the modified nano TiO2 coating comprises the following raw materials in parts by weight: 55-80 parts of a modified nano TiO2 composite material, 8-24 parts of a binder and 2.5-7.5 parts of a dispersant; the modified nano TiO2 composite material is prepared by taking cellulose nanocrystals, lanthanum zirconate and rare earth praseodymium as modifiers and nano TiO2 as a raw material, the mass ratio of the cellulose nanocrystal to the lanthanum zirconate to the rare earth praseodymium is (1-5): (2-3): 1. By adding the modified nano TiO2 composite material and introducing nano particles into the diaphragm, a three-dimensional network structure is formed, the liquid absorption property and the ionic conductivity of the diaphragm are improved, and meanwhile, the diaphragm is high in air permeability and relatively good in mechanical property and ionic conductivity.

The invention belongs to the technical field of stem cell biological preparations, and particularly relates to an anti-aging compound preparation based on stem cells and application of the anti-aging compound preparation in delaying skin aging. The composition is composed of an inner water phase, a middle oil phase and an outer water phase, wherein the inner water phase is prepared from the following components: stem cell exosomes, hyaluronic acid, nicotinamide ribose, trehalose, mannitol, glycine and a citric acid buffer solution; the medium oil phase is prepared from the following components: medium chain triglyceride, shea butter, vitamin E succinate, PEG (Polyethylene Glycol) modified ceramide NP and cholesterol succinic acid monoester; the external water phase is prepared from the following components: polydatin, cellulose nanocrystals and an emulsifying agent. On the basis of a W / O / W emulsion system, a multi-layer anti-aging mechanism is constructed by utilizing a three-dimensional delivery framework of an inner water phase, an oil phase and an outer water phase and space-time synergy of active ingredients, the exosome permeation efficiency is improved through microneedle introduction, and the anti-oxidation and barrier repair effects are achieved by using multiple ingredients.

The invention relates to a high-strength and high-toughness polylactic acid composite material and a preparation method thereof, and belongs to the technical field of biodegradable high polymer materials. The formula of the polylactic acid composite material comprises the following components in parts by weight: 70-80 parts of polylactic acid, 5-10 parts of modified cellulose nanocrystals, 3-5 parts of modified montmorillonite, 1-2 parts of a plasticizer and 0.5-1.5 parts of an antioxidant. A preparation method of the modified cellulose nanocrystals comprises the following steps: adding cellulose nanocrystals into deionized water, and carrying out ultrasonic treatment to obtain a dispersion liquid A; and sequentially adding 0.5-1 M tannic acid solution at the temperature of 60 DEG C into the dispersion liquid A, cooling to room temperature, dropwise adding 3 M octadecylamine-ethanol solution, washing with ethanol and deionized water, and carrying out step-by-step freeze-drying treatment to obtain the modified cellulose nanocrystal, the polylactic acid composite material prepared by the preparation method has high strength, high toughness and good high temperature resistance.

The invention provides a microbial agent compound fertilizer for sandy land and a preparation method thereof, and relates to the technical field of compound fertilizers. The invention relates to a microbial inoculum compound fertilizer for sandy land. The soil conditioner is prepared from the following raw materials in parts by mass: 40 to 60 parts of compost, 0.3 to 0.8 part of nitrogen-fixing bacteria, 0.3 to 0.8 part of phosphate solubilizing bacteria, 0.3 to 0.8 part of potassium bacteria, 8 to 12 parts of charcoal, 8 to 12 parts of zeolite, 9 to 13 parts of perlite, 4 to 6 parts of vermiculite, 1 to 3 parts of seaweed extract, 2 to 4 parts of humic acid, 1 to 7 parts of waste cellulose nanocrystals, 30 to 40 parts of insect debris, 0.3 to 3 parts of nano carbon dots, 3 to 9 parts of lime and 8 to 15 parts of wood fiber. The compound fertilizer disclosed by the invention not only is rich in various necessary nutrient elements, but also has a good slow release effect and a good soil improvement function, can effectively improve soil fertility and promote plant growth through the action of various biological strains, and also has the characteristics of environmental protection and no pollution by utilizing the waste cellulose nanocrystals and the insect remains.

The invention discloses a controllable degradation antibacterial filament fiber and a preparation method thereof, a calcium alginate filament fiber is prepared by using a wet spinning technology, and the calcium alginate filament fiber is strongly modified by physical and chemical methods respectively. The chemical modification adopts a cross-linking agent for modification, and the physical modification adopts cellulose nanocrystal (CNC) as a reinforcing material. The tensile breaking strength is improved to 43.25 cN / dtex from 16.35 cN / dtex which is not modified, the tensile breaking strength is improved by 2.6 times, and the degradation period is prolonged to 7 days from 2 days. On the basis, berberine is introduced into the fiber, so that the mechanical enhancement effect can be further achieved by means of the electrostatic attraction effect between materials, the antibacterial performance is obtained, and the antibacterial rate can reach 95.28%.

The present invention relates to the field of plastic films, and in particular to an agricultural plastic film and a preparation method thereof. The agricultural plastic film is composed of the following components in parts by mass: 95-105 parts of film particles, 2-4 parts of modified nano-titanium dioxide emulsion, 6-10 parts of lignin nanoparticles, 2-4 parts of tannic acid, 6-10 parts of glycerol, 4-6 parts of maleic anhydride-grafted polycaprolactone as a co-solvent, and 4-6 parts of cellulose nanocrystals. Compared with the prior art, the present invention achieves comprehensive improvement in material degradability, anti-aging performance and processing efficiency, while taking into account production cost optimization and process adaptability. The agricultural plastic film can be widely used in agricultural scenarios such as greenhouse covering and soil moisture retention, has significant advantages in reducing environmental pollution and improving the comprehensive performance of agricultural films, and has broad application prospects.

The invention relates to a pegylated cellulose nanocrystal and a preparation method and application thereof, in particular to the technical field of nanomaterials, the preparation method comprises the following steps: modifying polyethylene glycol into chlorinated polyethylene glycol; carrying out alkaline treatment on the cellulose nanocrystal to enhance the activity of the cellulose nanocrystal; then mixing and reacting the polyethylene glycol cellulose nanocrystal and the polyethylene glycol cellulose nanocrystal to obtain a polyethylene glycol cellulose nanocrystal; according to the invention, polyethylene glycol is grafted on the surface of the cellulose nanocrystal through chemical reaction, so that the action mechanism of the cellulose nanocrystal is changed and enhanced, on one hand, the grafting of polyethylene glycol not only exerts the steric hindrance effect, but also enhances the characteristics (crystallinity, thermal stability and dispersity) of the cellulose nanocrystal; on the other hand, due to the existence of polyethylene glycol, the short-circuit diffusion effect and the nucleation effect can be enhanced, so that the cement hydration degree is improved; and polyethylene glycol has an internal curing effect, so that the self-constriction of the cement-based material can be reduced.

The invention provides a stabilizer for Pickering emulsion and application of the stabilizer, and relates to the technical field of Pickering emulsion preparation. The stabilizing agent for the Pickering emulsion is obtained by compounding 6 '-O-caffeoyl arbutin and cellulose nanocrystals. In specific application, the 6'-O-caffeoyl arbutin and the cellulose nanocrystals are prepared into a water phase, and then the water phase is mixed with an oil phase to prepare the Pickering emulsion. According to the preparation method, the defects in the prior art are overcome, the stability of the Pickering emulsion is effectively improved, meanwhile, the oxidation resistance effect of the Pickering emulsion is further enhanced, and the application value of the Pickering emulsion is improved.

The invention relates to the technical field of liquid crystal thin films, and discloses a polymer dispersed liquid crystal thin film based on cellulose nanocrystal doping and a preparation method of the polymer dispersed liquid crystal thin film. The photoinitiator comprises the following components in parts by weight: 50-70 parts of a liquid crystal material, 20-35 parts of a matrix polymer, 0.5-2 parts of a photoinitiator, 1-5 parts of a cellulose nanocrystal composite material and 5-15 parts of a solvent. The invention further provides a preparation method of the polymer dispersed liquid crystal film based on cellulose nanocrystal doping. The method comprises the following steps: S1, preparing a cellulose nanocrystal composite solution; taking the cellulose nanocrystal composite material, and dispersing the cellulose nanocrystal composite material in a solvent; by introducing the surface-modified cellulose nanocrystal and nitrogen-doped titanium dioxide composite material into a polymer matrix, the effect of optimizing liquid crystal microdroplet distribution is achieved. Compared with a liquid crystal film which does not use the composite material, the liquid crystal film solves the problems of non-uniform liquid crystal dispersion and unstable photoelectric switching performance, and ensures more uniform optical regulation and higher light transmittance.

The invention discloses a grouting material based on coal gangue and a preparation method of the grouting material. The preparation method comprises the following steps: pretreating the coal gangue; uniformly stirring the pretreated coal gangue, cement and a novel magnesium expanding agent to obtain a first dry mixture; adding a polycarboxylic acid high-performance water reducing agent and cellulose nanocrystals into the first dry mixture, and uniformly stirring to obtain a second dry mixture; adding latex powder and a coupling agent into the second dry mixed material, and uniformly stirring to obtain a third dry mixed material; adding polyacrylonitrile fibers into the third dry blend, and uniformly stirring at a low speed to obtain a fourth dry blend; and mixing and stirring the fourth dry mixture and water to obtain the grouting material based on coal gangue. The pretreated coal gangue is used as the raw material, and the overall performance of the grouting material can be improved.

The invention belongs to the technical field of self-repairing materials, and particularly relates to a double-microcapsule self-repairing waterborne polyurethane material and a preparation method thereof. Comprising the following steps: ultrasonically dispersing cellulose nanocrystals in deionized water to form a water phase, adding drying oil and lauryl sodium sulfate, and stirring to obtain the drying oil microcapsule taking Pickering emulsion as a template. Preparing a polyvinylpyrrolidone aqueous solution, a non-polar solvent solution of thiophene monomers and an ammonium persulfate aqueous solution; and mixing and ultrasonically dispersing the two, mixing with an ammonium persulfate aqueous solution, stirring and polymerizing to obtain a polythiophene microcapsule suspension after the reaction is completed, centrifuging until the supernatant is colorless, and washing and drying the solid to obtain the polythiophene microcapsule. And finally, adding the two microcapsules into waterborne polyurethane, uniformly mixing, and drying at room temperature to form the double-microcapsule self-repairing waterborne polyurethane material. According to the invention, the self-repairing and mechanical property improvement of the double-microcapsule self-repairing waterborne polyurethane material under room-temperature natural light are realized.

A method of adsorbing a dye from an aqueous solution including contacting a composition with the aqueous solution. At least a portion of the dye adsorbs to the composition. The composition includes biochar, cellulose nanocrystals, and a layered double hydroxide (LDH). The LDH includes Cu and Fe. Particles of the LDH and the biochar at least partially cover an outer surface of the cellulose nanocrystals.

The invention discloses a hydrogel-based helicobacter pylori killing medicine and a preparation method thereof in the technical field of biomedical materials, and the hydrogel medicine adopts a shell-core layered structure and comprises an outer layer and an inner layer; the outer layer is a high-density cross-linked polyethylene glycol diacrylate network, and cellulose nanocrystals modified by silane are dispersed in the polyethylene glycol diacrylate network; pH-sensitive Schiff base bonds and / or boric acid ester bonds are embedded in the inner layer, and an antibacterial agent is loaded on the inner layer. Structural expansion and breaking of the hydrogel are controlled through a multi-layer structure, multiple loaded antibacterial agents are released according to pH response, the influence of drug resistance is avoided through sterilization of multiple mechanisms, the preparation process and device of the hydrogel drug are integrated, the production cost is reduced, and the clinical conversion efficiency is guaranteed.

The invention aims to provide bio-based modified CNC-Pickering emulsified asphalt and a preparation method thereof, and belongs to the technical field of modified emulsified asphalt. Comprising the following components in parts by mass: 45 to 55 parts of matrix asphalt, 45 to 55 parts of deionized water, 1 to 5 parts of cellulose nanocrystal, 0.5 to 1 part of gamma-aminopropyltriethoxysilane, 0.5 to 1.5 parts of sophorolipid, 0.1 to 0.3 part of sodium citrate, 0.1 to 0.3 part of sodium tripolyphosphate, 0.5 to 2 parts of polyvinyl alcohol, 0.1 to 0.3 part of xanthan gum and 0.05 to 0.1 part of butylated hydroxytoluene. The cellulose nanocrystal and Pickering emulsification technology are combined, so that the stability of the emulsified asphalt can be improved, the ageing resistance, high temperature resistance and low temperature resistance of the emulsified asphalt can be improved, and the high-performance requirement of road engineering on the emulsified asphalt can be met.

The invention relates to the technical field of conductive materials, and discloses a flexible conductive composite material and a preparation method and application thereof. The flexible conductive composite material comprises the following preparation raw materials: a thermoplastic elastomer, a conductive filler, cellulose nanocrystals, an inorganic salt, an organic solvent and water. According to the flexible conductive composite material provided by the invention, the Pickering emulsion is co-stabilized by the cellulose nanocrystal auxiliary conductive filler, the cellulose nanocrystal raw material is easy to obtain, biodegradable, environment-friendly and pollution-free, the Pickering emulsion is good in stability, the conductive filler is directionally enriched on an emulsion interface to form a continuous path, the bottleneck of filler dispersion is broken through, a conductive network structure is complete, and the stability of the Pickering emulsion is improved. The strain sensing response is sensitive, reversible circulation is achieved, the conductive interval is wide, the conductive seepage threshold value is about 1 wt%-2 wt%, when the addition amount of the conductive filler is 10 wt%, the conductivity is about 25 S / cm, and the conductivity is improved in a breakthrough mode.

The present disclosure relates to a separator for an electrochemical device and an electrochemical device including the same, and particularly, to a separator for an electrochemical device, which can reduce the weight of the separator, can improve the energy density of a battery, and can enhance stiffness because cellulose nanocrystals are included in a porous polymer base, and an electrochemical device including the same.

The invention discloses a preparation method of a heat-conducting ethylene-propylene-diene monomer rubber based on an interface crosslinking vertical penetrating network, which comprises the following steps: firstly, performing high-temperature decomposition on sodium bicarbonate (NaHCO3) to generate CO2 gas to pre-expand hexagonal boron nitride (h-BN); then sea squirt cellulose nanocrystals (TCNCs) prepared through a sulfuric acid hydrolysis method are used for assisting intercalation stripping, hydroxylated boron nitride nanosheets (BNNS-OH) are prepared through high-temperature sodium hydroxide (NaOH) treatment, liquid metal is nanocrystallized through an ultrasonic technology by means of the metal-hydroxyl coordination effect, and the BNNS-OH / liquid metal heat conduction filler is prepared. Liquid metal is uniformly programmed on the surface of a BNNS-OH sheet layer to play a role of a heat conduction bridge, and further vacuum filtration is carried out under the assistance of TCNCs to prepare the boron nitride heat conduction film. An epoxy group is grafted on an ethylene propylene diene monomer (EPDM) molecular chain through in-situ epoxidation, and on the basis of the idea of modular management of heat conduction and mechanical properties, covalent reaction of hydroxyl and the epoxy group and non-covalent bridging effect of liquid metal and the epoxy group are utilized; the EPDM heat-conducting composite material with a vertical penetrating orientation network is prepared by spreading and laminating a heat-conducting film and epoxidized EPDM and performing interface cross-linking hot pressing, so that the contact area of boron nitride and an EPDM matrix is effectively increased, the interface thermal resistance is reduced, and a high-speed channel is provided for phonon transmission. The preparation method is efficient, simple, convenient, adjustable in mechanical property and heat-conducting property and capable of being used in the field of electronic device heat management.

The invention provides a multifunctional plugging agent for oil wells with medium and high water content and a preparation method of the multifunctional plugging agent. The plugging agent is prepared from the following substances in percentage by weight: 1-10% of high-strength nano gel particles, 2-5% of nano silicon dioxide dispersion liquid, 1-5% of PPG chitosan pre-crosslinking particles, 1-5% of guanidine gum dry powder, 1-2% of active calcium magnesium aluminum silicate, 0.5-1% of active silica gel, 0.5-1% of sodium sulfonate, 0.1-1% of a crosslinking regulator and the balance of water. Chitosan and cellulose nanocrystals are compounded for use, so that the strength of PPG chitosan pre-crosslinked particles is greatly improved. Chitosan reacts with an acrylamide monomer, 2-acrylamido-2-methylpropanesulfonic acid and a cross-linking agent methylene bisacrylamide to generate a double-network polymer product, so that the gel strength is greatly improved, and higher pressure bearing capacity, plugging capacity, scouring resistance and the like are achieved. Through the synergistic effect of all the components, the plugging water control effect is improved, water is plugged, oil is not plugged, and the plugging agent has important significance on plugging water control in the extra-high water cut period and improvement of oil well productivity.

The present invention relates to improved cellulose nanocrystal fillers for rubber compositions, and more particularly to the grafting of disulfides and thioesters onto cellulose nanocrystals to improve performance as fillers in rubber compositions. At least one embodiment describes a method of grafting a thiol or disulfide on a CNC surface by, for example, esterification of 3-mercapto-propionic acid (MPA), 3-(acetylthio) propionic acid (APA), or dithiodipropionic acid (DTDPA). The reaction can be carried out on CNC that is highly dispersed in a suitable solvent and the reaction conditions are improved to achieve an advantageous degree of substitution DS. Embodiments further disclose how the surface thiol groups may then be protected in a second step as thio esters or asymmetric disulfides to modulate the hydrophobicity of CNC to improve compatibility with styrene-butadiene, SBR or natural rubber.

The invention provides a polycarbonate box dam material, a preparation method and application, and the polycarbonate box dam material is prepared from the following raw materials in parts by weight: 65 to 72 parts of polycarbonate, 4 to 5 parts of methyl methacrylate-butadiene-styrene terpolymer, 18 to 22 parts of titanium dioxide, 2 to 4 parts of cellulose nanocrystal, 0.1 to 0.3 part of antioxidant and 0.1 to 0.3 part of anti-ultraviolet agent. The flame-retardant plastic is prepared from the following components in parts by weight: 0.8-1.2 parts of a silane coupling agent, 0.3-0.5 part of a plasticizer, 0.6-0.8 part of a lubricant, 0.09-0.11 part of an anti-dripping agent and 0.25-0.35 part of a flame retardant. The polycarbonate box dam material is good in adhesion performance, adhesion of the box dam material can be completed within a short time, the next production process can be rapidly started, the production efficiency is improved, and the problem that the box dam material is low in production efficiency is solved.

The invention provides core-shell structure reinforced white carbon black / graphene oxide hybridized glass-lined porcelain glaze and a preparation method thereof. The porcelain glaze is composed of a basic glaze material and a core-shell structure hybrid reinforcement phase dispersed in the basic glaze material, the reinforcement phase takes white carbon black as a core and zirconium oxide as a shell, and a three-dimensional hybrid network formed by KH-560 grafted cellulose nanocrystals or carbon nanotubes and graphene oxide is constructed between the core and the shell. The preparation method mainly comprises the following steps: carrying out pre-dispersion and in-situ hybridization on the white carbon black, the graphene oxide and the one-dimensional nanofibers through a silane coupling agent; constructing a three-dimensional network under a catalytic condition by using a sol-gel method; a stable core-shell structure is formed through a deposition reaction of zirconium sol; finally, the obtained composite slurry is compounded with basic glaze with specific components, rapid densification is achieved through microwave sintering, and the product is particularly suitable for chemical reaction kettle glass lining with strict requirements for corrosion resistance and impact resistance.

The invention relates to a method and system for predicting the service life of a PLA-based composite mulching film based on a p-norm algorithm and a storage medium. According to the technical scheme, the preparation method comprises the following steps: grafting modified cellulose nanocrystals with citric acid, and compounding the modified cellulose nanocrystals with polylactic acid to prepare a film; respectively carrying out degradation experiments of indoor ultraviolet irradiation and outdoor planting environment; according to the method, an ultraviolet degradation prediction method based on a p-norm algorithm is constructed, change rules of indexes such as elongation at break, tensile strength, a light transmission coefficient and a reflection coefficient are analyzed by associating degradation sequences of indoor ultraviolet irradiation and an outdoor planting environment, and a quantitative relation model of degradation days and performance parameters is established. The high-degradation composite film is combined, the limitation that degradation of a traditional mulching film is uncontrollable is broken through, the crop growth cycle is dynamically matched through the prediction model, and the degradation process is precisely regulated and controlled. Wherein the determination coefficient R2 of the tensile strength prediction model is equal to 0.996, the actual application error is lower than 5%, and intelligent adaptation of the degradation rate and agricultural requirements is achieved.

The invention belongs to the technical field of fruit freeze-drying processing, and particularly relates to a comprehensive fruit freeze-drying processing method capable of reducing nutrient loss of fruits, which comprises the following steps: S1, immersing sliced fruit slices into a composite color fixative, and simultaneously applying ultrasonic and pulsed electric field treatment on the composite color fixative system containing the fruit slices under the conditions that the ultrasonic power is 200-300W, the pulsed electric field intensity is 15-25kV / cm, and the ultrasonic power is 200-300W and the pulsed electric field intensity is 15-25kV / cm; the co-processing time is 2-4 minutes, so as to obtain the color-protected and strengthened fruit slices; s2, sequentially carrying out three-stage magnetic field freezing treatment on the color-protected and strengthened fruit slices to obtain frozen fruit slices; s3, dynamically adjusting parameters of the frozen fruit slices by adopting an AI algorithm, and performing vacuum freeze-drying in stages to obtain primary freeze-dried fruit slices; s4, placing the primary freeze-dried fruit slices in a vacuum environment to obtain deeply dried fruit slices; and S5, soaking the deeply dried fruit slices in an aqueous solution containing 0.5-1% of amyloid-like protein, 0.2-0.4% of sodium alginate and 0.1-0.3% of cellulose nanocrystals for 1-2 minutes to form a composite protective film with the thickness of 1-3 microns, so as to obtain the coated fruit slices.

The invention relates to the technical field of metal surface modification, in particular to a magnesium alloy anticorrosive coating and a preparation method and application thereof. The method comprises the following steps: firstly, performing micro-arc oxidation treatment on magnesium alloy to form a substrate layer; then, the micro-arc oxidation coating is subjected to hole sealing treatment through dendritic mesoporous silica loaded with a corrosion inhibitor, and the self-repairing function is given to the micro-arc oxidation coating; then, a layered self-similar coating composed of dendritic mesoporous silica loaded with a corrosion inhibitor and a resin matrix is constructed on the surface of the hole sealing layer, and interface bonding and compactness are enhanced; finally, dendritic mesoporous silica, cellulose nanocrystals, 1H, 1H, 2H, 2H-perfluorodecyl triethoxy silane, organic resin and tetraethoxy silane are introduced, and the super-hydrophobic coating with a micro-nano composite firm structure is formed on the surface layer. The obtained magnesium alloy anti-corrosion coating integrates the characteristics of long-acting corrosion resistance, super-hydrophobicity, self-repairing, high mechanical stability and the like, and the technical problems that a traditional magnesium alloy anti-corrosion coating is prone to physical or chemical damage and insufficient in durability are effectively solved.

The invention discloses a preparation method of an electromagnetic wave absorbing material based on cellulose nanocrystals. The preparation method comprises the following steps: preparing cellulose nanocrystal aerogel; adding an aniline monomer, ammonium persulfate and hydrochloric acid into an ethanol solvent to obtain a mixed solution; adding the cellulose nanocrystal aerogel into the mixed solution, and carrying out in-situ polymerization; and washing the polymerized aerogel with ethanol, and carrying out vacuum drying. The cellulose nanocrystal aerogel with a chiral structure is prepared, polyaniline is polymerized on the aerogel in situ, the conductivity of the material is improved, the electromagnetic wave absorbing material based on the cellulose nanocrystal is prepared, the preparation method is simple, and the product has excellent electromagnetic wave absorbing performance such as light weight, wide frequency band and strong absorption.

The present invention provides a high-adhesion low-solvent coating and a preparation method thereof, belonging to the field of coatings. The present invention synergistically improves the performance of waterborne coatings through a variety of modification strategies: the phosphate groups of the phosphorylated waterborne polyurethane dispersion form coordination bonds with the substrate to enhance adhesion; the thiol groups react with unsaturated groups to construct a stable crosslinked network. Oxidation and amination of graphene quantum dots improve dispersibility and form hydrogen bonds and crosslinking points to enhance mechanical properties; quaternized cellulose nanocrystals improve compatibility, and double bonds participate in the crosslinked network to enhance structural stability; mercapto- and borate-group modified polydopamine strengthens the network strength and flexibility and improves the interfacial binding force. These mechanisms provide a solid foundation for the development of high-adhesion, low-solvent high-performance coatings.

The invention discloses a humidity response discoloration radiation refrigeration material which comprises a scattering layer and an iridescent photon film arranged on the surface of the scattering layer, the iridescent photon film is a cellulose nanocrystal / polyethylene glycol composite film, and the scattering layer is a polylactic acid-silicon dioxide-aluminum oxide composite nanofiber film. Through the composite design of the top cellulose nanocrystal / polyethylene glycol iridescent photon film and the bottom PLA / SiO2 / Al2O3 scattering layer, coupling of color mirror reflection of the color radiation refrigeration function layer constructed by CNC / PEG composite and broadband diffusion response of the electrostatic spinning film reflecting layer is achieved, and the negative effects of moisture absorption and color development on the reflectivity are reduced; color intelligent response and efficient radiation refrigeration are successfully combined; the preparation method is simple in process, the adopted raw materials are all degradable and renewable materials, the cost is low, and industrial popularization and application are easy.