933 results about "Silver nanoparticle" patented technology

The invention discloses a preparation method of PEDOT: PSS (poly (3, 4-ethylenedioxythiophene): poly (styrenesulfonate))-based composite fiber with silver nanoparticles loaded on the surface. The method comprises the following steps: uniformly mixing a silver nanowire solution with a PEDOT: PSS solution, or uniformly mixing the silver nanowire solution, the PEDOT: PSS solution and a polymer solution to obtain a spinning solution; extruding the spinning solution into a coagulating bath through a wet spinning process and soaking to obtain nascent composite fibers; and drying the nascent composite fiber to obtain the PEDOT: PSS-based composite fiber of which the surface is loaded with silver nanoparticles and the interior contains silver nanowires. The interior and surface structures of the PEDOT: PSS fiber are simultaneously modified, the interior of the fiber contains a silver nanowire structure, and the surface of the fiber has a silver nanoparticle structure. The composite fiber has the characteristics of ultra-sensitive SERS sensing capability, high conductivity, electric heating, molten drop resistance and antibacterial property.

The invention relates to the field of super-hydrophobic materials, in particular to a basalt fiber composite material as well as a preparation method and application thereof. According to the composite fabric material provided by the invention, a multistage micro-nano rough surface of the MoS2 nanoflowers and the silver nanoparticles is constructed on the fiber substrate, so that not only is super-hydrophobic self-cleaning realized, but also the anti-icing performance is relatively high, and particularly, rapid heating is realized by combining broadband absorption of the MoS2 nanoflowers and a local surface plasma resonance effect of the silver nanoparticles; and meanwhile, the silver nanoparticles accelerate heat conduction, so that excellent ice melting capability is obtained. The high conductivity of the silver nanoparticles constructs a conductive path, and the layered structure of MoS2 triggers interface polarization, so that the electromagnetic shielding effectiveness of the X wave band is improved. The dual antibacterial mechanism of the MoS2 nanoflowers and the silver nanoparticles also realizes broad-spectrum efficient antibiosis, the preparation method is green and environment-friendly, the cost is low, and the requirements of complex scenes such as wearable electronic equipment, medical protection, polar region protection and national defense can be met.

The invention discloses a gynecological antibacterial gel containing a carbomer component, and belongs to the technical field of gynecological nursing materials. The gel is prepared from 0.5 to 5 percent of plant extract microcapsules, 0.5 to 3 percent of carbomer, 2 to 10 percent of glycerol, 0.1 to 1.5 percent of triethanol and the balance of purified water. The plant extract microcapsule is prepared by compounding methacrylated silk fibroin and a caffeic acid hyaluronic acid graft, has temperature responsiveness, can improve the adhesive force on the surface of vaginal mucosa, and realizes slow release of the plant extract; the caffeic acid catechol hydroxyl is chelated with silver ions, a nano-silver monodisperse layer is formed on the surface of the microcapsule, and the antibacterial activity is improved. The composite plant extract can inhibit bacteria, repair mucous membranes and maintain the acidic microenvironment of the vagina. When the gel is prepared, the problem that the swelling efficiency of carbomer is low is solved through glycerol pre-grinding, and triethanolamine is added in three times to form a gradient cross-linked network. The problems that traditional gel is unstable in viscosity, poor in mucous membrane adhesiveness and prone to damaging vagina micro-ecology are solved, the antibacterial effect is good, and preservation is stable.

The invention discloses a paclitaxel drug resistance SERS (Surface Enhanced Raman Scattering) substrate and a detection method. Belongs to the technical field of drug resistance detection. The SERS substrate is mixed with ultrapure water after centrifuging a silver nanoparticle-sodium citrate suspension, and the mixture is dropwise added to a silicon wafer and dried to form a coffee ring structure. During detection, cancer tissue crushing liquid is dropwise added to the center of the substrate, SERS signals are collected through a Raman spectrometer and compared with a pre-established drug resistance / sensitivity spectrum database, and drug resistance is judged according to characteristic peaks at 820 cm <-1 >, 1180 cm <-1 >, 1270 cm <-1 > and 1450 cm <-1 >. The method is easy and convenient to operate, short in detection time (within 10 minutes), high in sensitivity and suitable for rapid screening of paclitaxel drug resistance of breast cancer patients.

The invention relates to the technical field of surface coating materials, in particular to a multifunctional surface coating which comprises the following raw materials: organic silicon modified acrylic resin, an intumescent flame retardant, hollow glass beads, nano titanium dioxide, an auxiliary agent, graphene, silver nanoparticles and flaky zinc powder. The intumescent flame retardant is formed by compounding melamine polyphosphate and pentaerythritol, and the auxiliary agent comprises a dispersing agent, a flatting agent and a plasticizer. By integrating multiple functions of fire prevention, water prevention, heat insulation, self-cleaning and the like into a whole, the complex requirements of different fields of buildings, industry, traffic and the like on material performance can be comprehensively met. In the application of building exterior walls, the fireproof safety, the waterproof sealing performance and the heat insulation performance of buildings can be effectively improved, and energy consumption is reduced; in the aspect of industrial equipment protection, equipment can be protected from being damaged by environmental factors such as high temperature, moisture and corrosion, and the service life of the equipment is prolonged.

The invention provides a polyvinylidene fluoride-based nanofiber yarn wave-absorbing fabric as well as a preparation method and application thereof, and belongs to the technical field of preparation of wave-absorbing composite materials. The preparation method comprises the following steps: preparing nanofiber yarns or nanofiber core-spun yarns by adopting a conjugate electrostatic spinning technology, directly adding a conductive substance into a spinning solution to form conductive nanofibers, and further coating the nanofiber yarns or the nanofiber core-spun yarns with a PDA shell layer to improve the wear resistance and reduce silver nanoparticles in situ; finally, the yarns are woven into fabric through a weaving or knitting technology, and the fabric is applied to the fields of buildings, electromagnetic protective clothing, flexible electronics and the like. Compared with an existing microwave absorbing material, the fabric-based material is light in weight and good in mechanical flexibility and processability. Fabrics formed of nanofiber yarns or nanofiber core spun yarns facilitate the induction of interfacial polarization and multiple reflections, and can deeply design material properties. The material provided by the invention has better wear resistance, wearability and microwave absorption performance, and is suitable for actual production and application.

The invention relates to double-layer integrated asymmetric viscous hydrogel as well as a preparation method and application thereof, and belongs to the technical field of hydrogel. The invention relates to a preparation method of double-layer integrated asymmetric viscous hydrogel, which comprises the following steps: adding natural macromolecular polysaccharide and a polymeric monomer into a salt solution, stirring at room temperature, then adding an initiator and a cross-linking agent, stirring and polymerizing to obtain the double-layer integrated asymmetric viscous hydrogel. Through a one-pot method, a salt component is introduced into a hydrogel system, and the hydrogel has a double-layer structure with asymmetric viscosity under the salting-out action; in addition, the hydrogel is doped with a carbon nanotube with the surface modified by polydopamine and silver nanoparticles, so that the mechanical property and the conductivity of the hydrogel are remarkably improved. The preparation method provided by the invention is simple, is suitable for various hydrogel systems, has good universality and is easy to popularize and apply.

The invention discloses composite conductive powder for preparing conductive silver paste and the conductive silver paste, and particularly relates to the technical field of electronic materials.The composite conductive powder is of a double-shell core-shell structure composed of a silver metal inner core, a silicon dioxide middle coating layer and a silver nanoparticle self-assembled outer layer and is subjected to ultraviolet irradiation treatment; the conductive silver paste is based on the composite conductive powder and is matched with cerium oxide modified glass powder, graphene nanosheets, thermoplastic polyurethane resin and a dibasic acid ester solvent to form a low-temperature environment-friendly formula. The volume resistivity of the conductive silver paste is as low as 1.2 * 10 <-6 > omega.cm, the curing temperature is reduced to 120 DEG C, the content of volatile organic compounds meets the environmental protection standard, meanwhile, the tensile strength is improved by 50%, the conductive silver paste can bear 500 times of bending circulation without breakage, the adhesive force reaches the level 0 of a cross-cut method, the strict requirement of a high-performance electronic device for the conductive silver paste is effectively met, and the conductive silver paste has wide application prospects.

The invention discloses a complex sample detection method based on surface enhanced Raman spectroscopy and application, and relates to the field of biomolecular detection.The method comprises the following steps that silver nanoparticles are prepared and serve as a surface enhanced Raman substrate; preparing a concentrated silver particle solution by using the silver nanoparticles; detecting surface enhanced Raman spectrum signals of the complex sample under excitation of different wavelengths; removing a background signal and noise from the obtained surface enhanced Raman spectrum signal; and averaging the surface enhanced Raman spectra obtained by processing each wavelength, and carrying out maximum and minimum normalization processing on the obtained average spectrum intensity. According to the method, richer and more comprehensive chemical information and component information of the complex samples can be obtained, more accurate recognition and classification of the complex samples can be achieved, the recognition accuracy is greatly improved, the method is convenient and rapid to operate, low in cost and high in generalization ability and practicability, and large-scale commercial application can be achieved.

The invention discloses a flexible hydrogen sensor and a manufacturing method thereof, and the flexible hydrogen sensor comprises a flexible substrate which is made of a polyimide material; the gas sensitive layer is printed on the flexible substrate, and the gas sensitive layer is a graphene layer loaded with palladium nanoparticles and silver nanoparticles; the electrode layer is deposited on the gas sensitive layer; and the protective layer is formed on one side, deviating from the flexible substrate, of the electrode layer and the gas sensitive layer. The flexible hydrogen sensor can be flexibly installed in a new energy power battery pack, and hydrogen generated when the battery fails is sensitively detected.

The invention provides a micro-nano optical fiber probe for biochemical component detection based on infrared spectroscopy and detection equipment, and a preparation method of the micro-nano optical fiber probe comprises the following steps: S1, selecting one section of a multimode quartz optical fiber as a sensing area, and then removing a cladding layer and a coating layer of the sensing area to expose a bare fiber; s2, dripping a mixed acid solution prepared from hydrofluoric acid and citric acid to the bare fiber to corrode the bare fiber, and then cleaning and blow-drying; immersing the treated multimode quartz optical fiber into a silane coupling agent solution, reacting for 0.5-1 hour, and then drying; s3, immersing the multimode quartz optical fiber treated in the step S2 into a solution containing silver nanoparticles, and reacting for 10-20 minutes to obtain an optical fiber modified by the silver nanoparticles; and S4, sputtering a gold layer on the surface of the silver-modified optical fiber by adopting a vacuum magnetron sputtering technology to obtain the micro-nano optical fiber probe with the silver-gold film layer. After the surface of the silver nanostructure is covered with the gold film, oxygen, water, corrosive molecules and the like are effectively prevented from making direct contact with silver. In addition, both the gold and the silver can support a surface plasmon resonance (SPR) effect, and particularly, the prepared detection equipment can ensure the sensitivity of the SPR.

The invention belongs to the technical field of biomedical high-molecular polymer materials, and discloses a pH and temperature dual-response lignin-based amphiphilic polymer and micelle as well as a preparation method and an application of the pH and temperature dual-response lignin-based amphiphilic polymer and micelle. The preparation method of the polymer comprises the following steps: purifying the alkali lignin, preparing a macroinitiator AL-Br based on the alkali lignin, and then preparing the lignin-based amphiphilic polymer with double responses of pH and temperature. The polymerization process is controllable, and the usage amount of copper is lower than 500 ppm. The lignin polymer disclosed by the invention can be self-assembled into nano-scale micelles in a water medium, the structure is stable, and AgNPs and an entrapped hydrophobic anticancer drug CPT can be simultaneously prepared in situ. The obtained single nano-carrier system has good silver nanoparticle stabilizing capacity, in-vitro pH and temperature double-response drug release capacity and excellent cytotoxicity and antibacterial capacity, can achieve the anti-tumor and antibacterial purposes at the same time, and is well applied to preparation of drugs with anti-tumor and antibacterial effects at the same time.

The invention relates to a PPR antibacterial pipeline and a preparation method thereof, and belongs to the technical field of pipeline processing. The sea-buckthorn extract is used as an auxiliary medium, green synthesis of the silver nanoparticles can be promoted, use of traditional toxic reducing agents and stabilizing agents is avoided, natural active ingredients contained in the sea-buckthorn extract and the silver nanoparticles generate a synergistic effect, the antibacterial efficiency is remarkably enhanced, and the dosage and biotoxicity of the silver nanoparticles are reduced. Meanwhile, the nano silicon dioxide is added, so that the coating can be kept stable in a high-temperature environment. The carboxymethyl chitosan endows the pipeline with excellent antibacterial performance, and forms a synergistic effect with the silver nanoparticles, so that the antibacterial ability of the pipeline is further enhanced. Through the modification of the silane coupling agent KH560, the interface bonding force between the nano silicon dioxide and carboxymethyl chitosan and the interface bonding force between the nano silicon dioxide and the main component PPR of the pipeline are enhanced, so that the reinforcing agent can be more uniformly and stably dispersed in a PPR matrix, and the overall performance of the pipeline is improved.

The invention discloses a preparation method of a sandwich structure immunosensor based on surface enhanced Raman scattering and application of the sandwich structure immunosensor to detection of an anti-phospholipase A2 receptor antibody, and is characterized by comprising the following steps: sputtering silver ions on a cotton swab / ZIF-67 prepared by an in-situ growth method by adopting an ion sputtering method to obtain a cotton swab / ZIF-67 / Ag NPs composite material; the preparation method comprises the following steps: preparing an antigen solution, then adding the antigen solution into the antigen solution to obtain an immune substrate, adding a methylene blue aqueous solution into a silver nanoparticle solution for reaction, then connecting an anti-human PLA2R IgG antibody to obtain an immune probe, and finally dropwise adding a phosphate buffer solution containing an antibody to be detected onto the immune substrate, and dropwise adding the immune probe solution to the immune substrate adsorbed with the antibody to be detected to obtain the sandwich structure immunosensor based on surface enhanced Raman scattering. The method has the advantages of high sensitivity, good selectivity and strong stability.

The invention discloses a preparation method of a heat conduction and electromagnetic shielding self-healing polyurethane composite material, which comprises the following steps: modifying nano cellulose CNF (denoted as CNF-coated PPA) by using polyphenol amine PPA, and depositing silver nanoparticles on the surface of the CNF-coated PPA in situ to obtain a deposited material; the preparation method comprises the following steps: preparing a polyamide epichlorohydrin PAE solution, modifying graphene nanosheets GNP by using the PAE solution, and recording the modified graphene nanosheets GNP as PAE-GNP suspension liquid; cNF (at) PPA (at) Ag is dispersed into the PAE-GNP suspension liquid, and the CNF (at) PPA (at) Ag suspension liquid is marked as CNF-GNP suspension liquid; and preparing waterborne polyurethane WPU, dispersing the CNF-GNP suspension into the WPU, and carrying out vacuum filtration, drying and hot pressing on the mixed solution to obtain the polyurethane composite material. The method is simple in preparation process, mild in reaction condition and stable in product quality, and the polyurethane composite material prepared according to the method has excellent heat conduction, electromagnetic shielding and self-healing performance.

The present invention deals with a heat and moisture exchange filter with biocidal activity for medical ventilation equipment that comprises polymeric cellulose fibers impregnated with silver nanoparticles (AgNPs). The heat and moisture exchanger filter can be used in intubated patients under artificial ventilation in anesthesiology and intensive care and allows robust replacement, a fundamental utility for protection against nosocomial cross-contamination infections caused by microorganisms, such as bacteria, fungi, yeasts and viruses.The invention also deals with the method of preparing the heat and moisture exchange filter with biocidal activity and the use of silver nanoparticles.

The invention belongs to the field of biomedical materials, and discloses a composite hydrogel dressing and application. The composite hydrogel dressing is prepared by the following steps: blending 4-aminophenylboronic acid grafted hyaluronic acid and gallic acid grafted collagen, adjusting the pH value, carrying out a cross-linking reaction to obtain a cross-linking product, and stirring and mixing the cross-linking product with a gallic acid reduced silver nanoparticle solution. The antibacterial and self-healing composite hydrogel dressing for promoting wound repair has proper adhesion, mechanical properties and free radical scavenging ability, and excellent antibacterial property, biocompatibility and self-healing ability.

The invention discloses a preparation method of an environment-friendly degradable single-sided perspective sticker, and belongs to the technical field of modified nano materials. The method comprises the following steps: (1) preparation of a multi-layer composite structure: mixing polylactic acid and poly (butylene succinate), adding nano-montmorillonite and a surface modifier, and carrying out melt blending to form a first-layer melt; stirring poly (butylene adipate-co-terephthalate) and fluorescent carbon nanodots to form a second layer of melt; the first layer, the pressure-sensitive adhesive layer and the second layer are co-extruded and compounded to form a film blank. And (2) construction of the nano-film: biaxially stretching the film blank, imprinting a micropore array, dipping in the silver nanoparticle suspension, and drying to obtain the nano-film. And (3) coating functionalization treatment: immersing into a fluorine-containing nano coating solution, and curing. And (4) post-treatment: carrying out secondary curing. The obtained single-sided perspective sticker is suitable for the fields of buildings, vehicle privacy films and the like, and solves the problems of serious pollution and slow degradation of a traditional sticker.

The invention belongs to the field of flexible electronic devices, and discloses a preparation method of a high-performance strain sensor based on a nano-silver nano-cellulose seepage network. According to the hydrogel, polyvinyl alcohol is used as a matrix, a seepage network formed by polydopamine anchored nano-silver / nano-cellulose PCNF is used as a conductive phase, glycerin is used as an anti-freezing humectant, and through the synergistic effect of a three-dimensional seepage conductive network and a dynamic hydrogen bond network, the defects that traditional hydrogel is poor in sensing stability, poor in environmental stability and low in mechanical strength are overcome. The preparation process is simple, the conductive hydrogel is high in tensile strength, high in sensitivity and good in cycling stability and has an antibacterial function, and an assembled strain sensor can monitor a human motion signal in real time and is suitable for the fields of wearable equipment, electronic skin and medical monitoring in an extreme environment. Through material system and process innovation, integration of high performance and multiple functions is achieved, and wide application prospects are achieved.

A membrane includes a polysulfone-based support, a polydopamine (PDA) layer disposed on a surface of the polysulfone-based support, and a silver / polydopamine (Ag / PDA) composite layer disposed on a surface of the polydopamine layer. The polysulfone-based support has a pore size of up to 600 nanometers (nm). The Ag / PDA composite layer contains core-shell structure particles and spherical particles. The core-shell structure particles have a silver nanoparticle core and a polydopamine shell. The spherical particles are silver-decorated polydopamine particles. The membrane can at least partially separate an Erichrome Black T (EBT) dye from an EBT dye / salt containing mixture by rejecting the EBT dye and allowing the EBT dye / salt containing mixture to pass through the membrane.

The application discloses a bimetallic optical fiber SPR sensor based on silver core-gold shell nanoparticles, comprising: an optical fiber, the outer surface of which is provided with a sensing area; and the metal functional layer is arranged on the sensing area, the metal functional layer comprises dispersedly stacked silver nanoparticles, and the outer surfaces of the silver nanoparticles are coated with gold films. The metal functional layer of the sensor is composed of the metal nanoparticles, and compared with a traditional metal film SPR sensor, the specific surface area and porosity of metal are remarkably improved, and the detection sensitivity of the SPR sensor can be improved; silver nanoparticles are adopted as a main metal material, SPR sensing is greatly promoted, the silver nanoparticles are coated with a gold film to form isolated bimetal nanoparticles, the chemical stability of the silver nanoparticles is improved, the sensor is endowed with common characteristics of gold and silver, and the detection performance is remarkably improved.

The invention provides a method for detecting an external vesicle marker through high-flux nano plasma exciting light immune color development, and belongs to the technical field of human extracellular vesicles. After a serum sample is subjected to centrifugal treatment, the serum sample and a CD81 capture antibody substrate are incubated, and the particle size distribution of the vesicles is monitored in real time; a zwitterionic polymer modified gold nanoparticle LAM detection probe and a polyethylene glycol modified silver nanoparticle LprG detection probe are prepared to be specifically combined with a vesicle surface antigen, a chromogenic enhancement solution is adopted to induce a plasma resonance signal, and full-hole scanning imaging is carried out; and constructing a double-layer game optimization model to cooperatively optimize the detection sensitivity and the signal stability, carrying out weighted summation on normalized signals of the particle size subgroups to obtain comprehensive detection signal intensity, comparing the comprehensive detection signal intensity with a threshold value, and outputting a final judgment result. The technical problem that quantitative accuracy is affected by signal intensity deviation caused by vesicle particle size difference in outer vesicle marker detection is solved.

The invention provides a graphene-based capacitive sensor for detecting the moisture content in lubricating oil, a preparation method of the graphene-based capacitive sensor and a method for detecting the moisture content in the lubricating oil, and belongs to the technical field of moisture content detection. The graphene-based capacitive sensor for detecting the moisture content in the lubricating oil comprises a graphene-based electrode and a gold nanoparticle layer which are arranged in a laminated manner, the graphene-based electrode comprises a laser-induced graphene film and doped nanoparticles loaded on the surface and in pores of the laser-induced graphene film, and the doped nanoparticles are silver nanoparticles and copper oxide particle clusters; array holes are formed in the gold nanoparticle layer, the diameter of holes in the array holes is larger than the diameter of water molecules and smaller than the diameter of lubricating oil molecules, and the depth of the holes in the array holes is consistent with the thickness of the gold nanoparticle layer. The graphene-based capacitive sensor can realize real-time online detection of the moisture content in the lubricating oil, and is high in detection sensitivity and simple to operate.

The invention relates to an SERS (Surface Enhanced Raman Scattering) substrate based on a silver-covalent organic framework heterojunction as well as a preparation method and application of the SERS substrate, and belongs to the technical field of analysis and detection. The SERS substrate based on the silver-covalent organic framework heterojunction comprises an amidoxime group modified covalent organic framework material and silver nanoparticles adsorbed on the amidoxime group modified covalent organic framework material. The COF-TpDb-AO with semiconductor characteristics can improve the Raman signal intensity through a chemical enhancement effect, the silver nanocluster generates a strong electromagnetic enhancement effect, the SERS substrate significantly improves the detection sensitivity (the detection limit is as low as 7.4 * 10 <-9 > mol / L) through the cooperation of electromagnetism and the chemical enhancement effect, and the enhancement factor (EF) is 1.26 * 10 < 6 >.

The invention relates to the field of biomedical textile materials, and discloses a partially absorbable sports medicine orthopedic suture line and a preparation method thereof.The suture line is prepared from, by mass, 50%-90% of polylactic acid and 10%-20% of polyglycolic acid. The mass content of polyglycolic acid is 10%-50%, the composite material further comprises a bioactive component, the mass content of the bioactive component is 0.1%-10%, the bioactive component comprises bone morphogenetic protein, silver nanoparticles and hydroxyapatite, the tensile strength of the suture line is 30-120 MPa, and under different physiological conditions, the suture line is not prone to fracture, and the suture line is not prone to fracture. And the degradation product can be compatible with surrounding tissues. The shape of the suture line can be automatically adjusted at the physiological temperature by embedding the shape memory alloy, and the suture line can adapt to dynamic changes of the tissue and provide uniform tension and support when interacting with the biological tissue due to the intelligent response capability, so that the tissue healing is effectively promoted.

The invention discloses an antibacterial stainless steel band with high surface quality and a preparation method thereof, and relates to the technical field of antibacterial stainless steel bands, and the preparation method comprises the following steps: smelting an iron alloy raw material, introducing argon into a steel ladle after tapping, stirring molten steel, uniformly mixing, and continuously casting the molten steel into a blank; the casting blank is sequentially subjected to cogging, hot rolling, cold rolling, annealing, solid solution treatment and aging treatment, and a stainless steel band base material is obtained; the method comprises the following steps: by taking a stainless steel band as a working electrode, a platinum plate as a counter electrode and a saturated calomel electrode as a reference electrode, carrying out silver nanoparticle deposition in an aqueous electrolyte through a three-electrode deposition system, taking out and drying to obtain an electro-deposition modified stainless steel band; and the electrodeposition modified stainless steel band is soaked in a dopamine-octadecylamine mixed solution, heating reaction is conducted, ultrasonic washing is conducted through ethyl alcohol, room-temperature drying is conducted, then the electrodeposition modified stainless steel band is soaked in a chitosan coupling heterojunction solution, room-temperature maintaining, deionized water washing and vacuum drying are conducted, and the antibacterial stainless steel band is obtained.

The invention relates to the field of solder materials, and provides a non-ferrous metal solder for low-temperature brazing and application, the solder is composed of carbon-coated copper nanorods, tin-bismuth alloy-coated silver nanoparticles, 2-mercaptobenzimidazole, rosin resin, an organic active agent, a dispersing agent, ionic liquid, hydroxyethyl cellulose, indium nitrate and citric acid. The silver particles are of a core-shell structure and are coated with tin-bismuth alloy layers, and continuous carbon layers are formed on the surfaces of the copper nanorods, so that the conductivity and the interface stability of the solder are effectively improved. The non-ferrous metal solder with excellent conductivity, low melting point and good wettability is prepared through step-by-step mixing, hot press molding and low-temperature heat treatment processes, and is suitable for electronic device packaging, power device connection and flexible circuit interconnection, and the defects of existing solder in the aspects of low-temperature welding and high conductivity are overcome.

The invention discloses application of biological silver nanoparticles synthesized based on bacillus velezensis in prevention and treatment of tomato gray mold, and relates to the technical field of prevention and treatment of tomato gray mold. Researches find that the biological silver nanoparticles Bio-AgNPs have a relatively strong inhibition effect on the growth of botrytis cinerea hyphae, and when the concentration of the biological silver nanoparticles Bio-AgNPs is 100 mu g / mL, the growth inhibition rate of the botrytis cinerea hyphae is 100%. The Bio-AgNPs shows a good prevention and treatment effect on the tomato gray mold, after 40 [mu] g / mL of Bio-AgNPs is used for treating tomato fruits and leaves, the scab of the tomato fruits is obviously reduced by 52.21%, and the prevention and treatment effect on the tomato leaf gray mold is 40.19%.

The invention relates to the technical field of functional coatings of medical instruments, in particular to a temperature-sensitive response type sodium polyacrylate catheter leakage-proof coating, a preparation method and application thereof, and the coating is of a three-layer composite structure. And the bottom bonding layer adopts a polydopamine modified silane coupling agent system, contains silver nanoparticles, has the thickness of 5-15 microns, and ensures strong bonding and antibiosis of the substrate. The middle functional layer is a three-dimensional cross-linking degree gradient interpenetrating network polymer, is composed of a plurality of monomers and nano materials, and is 50-100 [mu] m in thickness, the cross-linking degree of the middle functional layer is gradually increased from inside to outside, gradient transition of mechanical properties is achieved, the outer protective layer is composed of a copolymer, is 3-8 [mu] m in thickness, and provides excellent anti-fouling and biocompatibility. The coating is endowed with strong adhesive force, gradient mechanical property and surface stability, the sodium polyacrylate component absorbs water and expands in urine to form sealing, and the expansion degree of the sodium polyacrylate component is regulated and controlled by the pH value and ionic strength of the urine.

The invention discloses a hybrid Ag / MXene / Fe-Co MOF surface enhanced Raman scattering sensor and an application of the hybrid Ag / MXene / Fe-Co MOF surface enhanced Raman scattering sensor in rapid detection of bacteria. According to the sensor, silver nanoparticles are prepared through a sodium citrate reduction method, a two-dimensional material MXene and a bimetal organic framework are combined, and a surface enhanced Raman scattering spectrum detection platform with high sensitivity, stability and anti-interference performance is constructed. The conductive network of MXene and the local surface plasmon resonance effect of silver nanoparticles synergistically enhance an electromagnetic field, and the porous structure of Fe-Co MOF enriches target molecules and forms dense hot spots, so that the Raman signal intensity is remarkably improved. Experiments show that the detection limit of the sensor to 4-mercaptobenzoic acid is as low as 10 <-12 > M, and the signal stability can last for 7 days; the detection limit on common pathogenic bacteria such as escherichia coli and staphylococcus aureus reaches 10 CFU / mL, and the linear correlation coefficient is superior to 0.96. The sensor has hydrophobicity and biocompatibility, can efficiently capture bacteria through capillary force, is suitable for trace detection of complex samples, and provides a new strategy for rapid diagnosis of clinical drug-resistant bacteria.