3970 results about "Silicon rubber" patented technology

The invention relates to the technical field of cables, and discloses a multi-layer composite wrapped high-temperature-resistant anti-aging cable which sequentially comprises a conductor, an insulating cable core, a shielding layer, an outer insulating layer, a fireproof layer, a heat insulation layer, a buffer cushion layer, an armor layer, an anti-aging layer and an outer sheath layer from inside to outside. The fireproof layer is formed by alternately laminating synthetic mica tapes and ceramic boron silicone rubber tapes, a reliable fireproof barrier is formed, and the heat insulation layer is arranged to achieve efficient heat insulation and stable structure through cooperation of gradient pore nano aerogel, ceramic silicone rubber round rods and phase change capsules. The buffering cushion layer is combined with the composite layer, the aluminum oxide hollow ball array and the composite capsule, so that the mechanical buffering and auxiliary heat insulation functions are achieved; the armor layer is woven by stainless steel fibers, the mechanical protection capability is improved, and the anti-aging layer is of a double-layer structure composed of montmorillonite composite fluororubber and an anti-oxidation layer, so that thermal oxidation aging is delayed.

The invention discloses a high-temperature-resistant epoxy resin composite material and a preparation method thereof, and relates to the technical field of composite materials. The high-temperature-resistant epoxy resin composite material is prepared from the following raw materials in parts by weight: 70 to 80 parts of modified epoxy resin, 8 to 15 parts of high-temperature-resistant modifier, 15 to 30 parts of curing agent, 3 to 8 parts of nano reinforcing filler, 1 to 3 parts of coupling agent, 3 to 6 parts of carbon fiber, 2 to 5 parts of nano titanium dioxide, 5 to 10 parts of organic silicon rubber, 1 to 3 parts of conductive agent, 3 to 7 parts of flame retardant and 2 to 4 parts of zinc borate. The high-temperature-resistant epoxy resin composite material has outstanding advantages and strong thermal stability, and can bear high temperature; mechanical performance is excellent, and firmness and durability are achieved; the self-repairing capability is achieved, and the service cycle can be prolonged; the anti-permeability is good, and gas and liquid can be effectively blocked; the surface is smooth, the friction coefficient is low and the application prospect is wide.

The invention relates to the technical field of power transmission, in particular to a moisture-proof cable which sequentially comprises a conductive wire core, a gradient buffer layer, a dynamic sealing layer, a flexible supporting layer and a self-repairing sheath from inside to outside. A gradient buffer layer; the dynamic sealing layer is of a split type sealing structure formed by an outer ring surface sealing lip and an inner ring surface static sealing belt, the outer ring surface sealing lip is formed by embedding a polytetrafluoroethylene fiber reinforcing layer in a silicone rubber matrix, and the surface of the outer ring surface sealing lip is coated with a humidity response type graphene coating; the flexible supporting layer is formed by spirally winding a nickel-titanium alloy belt, and bionic fish scales are welded to the surface of the nickel-titanium alloy belt; the self-repairing sheath is characterized in that a hexagonal honeycomb structure is molded on the outer layer, hydroxyl-terminated polysiloxane and a platinum catalyst are contained in an A-type microcapsule, and modified epoxy resin is contained in a B-type microcapsule. The moisture-proof cable shows excellent corrosion resistance, moisture resistance and self-repairing capability in a humid environment, and can maintain good performance when subjected to external physical impact.

The invention discloses spherical aluminum oxide and a silicone rubber heat conduction composite material thereof, and belongs to the technical field of functional polymer materials. The spherical aluminum oxide is subjected to surface modification through an amphiphilic fluorosilicone heat conduction interface synergist; comprising the following raw materials in parts by weight: 100-200 parts of vinyl silicone oil, 1-6 parts of side hydrogen-containing silicone oil, 1-6 parts of end hydrogen-containing silicone oil, 0.2-2 parts of a platinum catalyst, 0.01-0.1 part of an inhibitor and 2500-6000 parts of amphiphilic fluorine-silicon heat-conducting interface synergistic spherical aluminum oxide powder. Through surface modification of spherical aluminum oxide, the prepared silicone rubber heat-conducting composite material realizes synergistic gain of heat conduction, insulation and flexibility, and can meet the requirements of multiple fields such as power battery pack heat dissipation gaskets, high-frequency circuit packaging and wearable equipment.

The invention relates to the technical field of low-dielectric heat-conducting functional materials, in particular to a nano silicone rubber composite material as well as a preparation method and application thereof. According to the preparation method, a modified vinyl silsesquioxane coupling agent is taken as a bridge, and boron nitride nanosheets, silicon carbide nanowires and the modified vinyl silsesquioxane coupling agent are covalently connected through hydrolysis reaction, so that a heterostructure is constructed, and the nano heat-conducting filler is obtained; the preparation method comprises the following steps: dispersing a nano heat-conducting filler in vinyl silicone oil, and constructing a covalent cross-linked network through addition cross-linking reaction and curing treatment to obtain the nano composite silicone rubber material. According to the processing method, the filling amount, the dielectric constant and the dielectric loss can be reduced, meanwhile, the heat conduction capacity is improved, and the problems that in the prior art, the dielectric constant and the dielectric loss are low due to simple mixing of the boron nitride nanosheets and the silicon carbide nanowires are solved.

The invention discloses a low-smoke halogen-free cross-linked polyethylene insulated power cable, and relates to the technical field of power cables, the low-smoke halogen-free cross-linked polyethylene insulated power cable comprises a central conductor, the outer side of the central conductor is tightly coated with a rubber insulation sleeve, and the outer sides of a plurality of rubber insulation sleeves are jointly coated with a limiting silicon rubber sleeve; the outer side of the limiting silicon rubber sleeve is evenly coated with axial supporting inner rings at equal intervals, the outer rings of the axial supporting inner rings are tightly coated with axial protection outer rings, the outer sides of the axial protection outer rings and the filling soft rubber sleeve are jointly coated with an isolation protection rubber sleeve, and the outer ring of the isolation protection rubber sleeve is tightly coated with an installation outer rubber sleeve. According to the cable, the situation that rain and snow are attached to the outer side of the cable, and consequently the overall weight of the cable is increased is effectively prevented, the transverse traction force of the connecting position of the ends of the cable during working is reduced, the fatigue aging rate of the connecting position of the cable is reduced, and the actual service life of the cable is prolonged.

The invention discloses ceramic fluorinated silicone rubber and a preparation method thereof. The ceramizable fluorosilicone rubber comprises the following raw materials in parts by weight: 100 parts of fluorosilicone raw rubber, 10-30 parts of fumed silica, 4-8 parts of a structure control agent, 10-20 parts of an organic-inorganic compound fire-resistant filler, 4-10 parts of reinforced fibers, 20-30 parts of a carbon-based ceramic additive and 1-2 parts of a vulcanizing agent. The preparation method comprises the following steps: S1, adding the fluorosilicone raw rubber into a kneading machine, and then adding the fumed silica and the structure control agent to start mixing; s2, adding an organic-inorganic compound refractory filler, reinforced fibers and a carbon-based ceramic additive into the mixed material obtained after mixing in the step S1, and continuously mixing; s3, carrying out vacuum treatment on the material mixed in the S2, cooling the material to room temperature, adding a vulcanizing agent into a double-roller open mill, and uniformly mixing; and S4, performing tabletting vulcanization on the material mixed in the step S3 on a plate vulcanizing machine, and then performing secondary vulcanization in a drying oven to obtain the ceramization fluorinated silicone rubber.

The invention discloses a composite rubber material with wear resistance and high tear strength and a preparation method of the composite rubber material, and belongs to the technical field of rubber material processing. The technical problem that the enhancement effect of the filler on the wear resistance, tear resistance and mechanical strength of a rubber matrix needs to be further improved exists in the prior art. The composite material comprises the following components in parts by weight: 100-110 parts of internal mixed rubber, 1-2 parts of a vulcanization accelerator and 2-3 parts of a vulcanizing agent, modified polybutadiene is reinforced by aramid pulp, modified carbon black and modified graphene to prepare composite polybutadiene, and then styrene butadiene rubber is reinforced and modified by the prepared composite polybutadiene and silicone rubber to prepare the composite material. By improving the degree of crosslinking between material molecules and optimizing material composition, the wear resistance and tear resistance of the composite rubber material are effectively improved, and the mechanical property of the composite rubber material is also improved.

The invention relates to the technical field of silicone rubber, and discloses a preparation method of a modified silicone rubber elastomer, the modified silicone rubber elastomer comprises 100 parts by weight of methyl vinyl silicone rubber, 5-25 parts by weight of organosilicon grafted cellulose microcrystalline, 12-20 parts by weight of white carbon black, 1.7-2.4 parts by weight of a vulcanizing agent, 2.6-4.2 parts by weight of a cross-linking agent, and 1.5-2 parts by weight of an auxiliary agent, 1.2 to 1.6 parts by weight of an anti-aging agent; the organic silicon grafted cellulose microcrystal contains a siloxane structure and has good compatibility with the methyl vinyl silicone rubber, and in the high-temperature vulcanization process, alkenyl of the organic silicon grafted cellulose microcrystal can be subjected to a cross-linking reaction with the methyl vinyl silicone rubber and triallyl isocyanurate, so that the organic silicon grafted cellulose microcrystal can be used for curing the methyl vinyl silicone rubber and the triallyl isocyanurate. The interface bonding strength between the cellulose microcrystal and the methyl vinyl silicone rubber is enhanced, so that the silicone rubber elastomer shows higher tensile property, hardness and tearing strength.

The invention relates to the technical field of electrical insulating materials for power transmission lines, and discloses an alicyclic epoxy resin external insulating material with excellent hydrophobicity and a preparation method thereof, the insulating material comprises the following raw material components: alicyclic epoxy resin, a curing agent, an accelerant and silicone rubber particles; the silicone rubber particles are subjected to plasma treatment. The alicyclic epoxy resin external insulation material with excellent hydrophobicity provided by the invention can effectively improve the hydrophobicity and hydrophobicity migration of the alicyclic epoxy resin material, and also can synergistically solve the problem of waste silicone rubber decommissioning treatment.

The invention relates to the technical field of power cables, in particular to a heat-aging-resistant crosslinked polyethylene insulated power cable and a preparation method thereof. The cable comprises conductor wire cores, an insulating layer, a filling layer, a composite function layer, a steel tape armoring layer and a sheath layer from inside to outside. The insulating layer is composed of semi-conductive crosslinked polyethylene, silicone resin, nano montmorillonite and an HALS light stabilizer; the filling layer is composed of plasticized glass fabric, polyphenylene sulfide and rare earth oxide; the composite functional layer sequentially comprises a heat-conducting inner layer, a flame-retardant middle layer and an anti-UV outer layer from inside to outside; the sheath layer is composed of polyolefin, white carbon black, ceramic silicone rubber, a flame retardant, polyethylene wax and an initiator. According to the cable, cross-linked polyethylene and silicone resin are preferably selected as heat-resistant materials, heat conduction / flame retardance / UV resistance / armored multi-layer synergistic protection is achieved, the mechanical barrier performance is improved, meanwhile, damage of thermal stress to internal materials is reduced, comprehensive improvement of thermal aging resistance is achieved, and the cable is suitable for high-temperature, high-humidity and frequent thermal cycle harsh environments.

The invention relates to the technical field of wire and cable manufacturing, in particular to a high-flexibility low-smoke fire-fighting power cable and a preparation method thereof. The cable sequentially comprises a cable core, a shielding layer and an outer sheath layer from inside to outside, the outer sheath layer is prepared from the following preparation raw materials: 60 to 65 parts of methyl vinyl silicone rubber, 12 to 15 parts of ethylene propylene diene monomer, 8 to 10 parts of linear low-density polyethylene, 5 to 6 parts of cross-linking agent, 20 to 22 parts of flame retardant, 6 to 8 parts of reinforced flame-retardant filler, 20 to 25 parts of modified heat-conducting filler, 1.2 to 1.5 parts of coupling agent, 1.3 to 1.5 parts of antioxidant, 3 to 3.5 parts of lubricant, 2 to 2.5 parts of vulcanizing agent and 0.6 to 0.8 part of accelerant. The outer sheath layer of the high-flexibility low-smoke fire-fighting power cable prepared by the invention has excellent mechanical strength, toughness, heat-conducting property, high temperature resistance and flame retardant property, so that the high-flexibility low-smoke fire-fighting power cable has higher reliability and safety in fire-fighting power supply occasions.

The invention discloses a hollow skeleton type drug-loading rod core as well as a preparation method and application thereof. The raw material composition comprises the following components in parts by weight: 1-1000 parts of active pharmaceutical ingredients; 100 parts of R-vinyl silicone rubber; 0.45 to 20 parts of hydrogen-containing silicone oil; more than or equal to 0.000002 parts of a catalyst; the content of vinyl in the R-vinyl silicone rubber is 0.1-0.5 mol%; the content of Si-H groups in the hydrogen-containing silicone oil is 0.18 to 1.6 mol%; the molar ratio of the Si-H group to the vinyl group is (0.5-20): 1. According to the invention, methyl vinyl silicone rubber, hydrogen-containing silicone oil, a platinum catalyst and other components are taken as a basic prescription of silicone rubber, and a model drug and the silicone rubber are mixed by using an extrusion technology to prepare the hollow skeleton type drug-loaded rod core. Advantages of traditional storage type implants and skeleton type implants are integrated, the production process is simple, the medicine application range is wide, the release amount is stable, and the release amount is large.

The invention discloses a high-pressure sleeve sheath aging evaluation method and system based on feature unevenness, and belongs to the technical field of high-pressure sleeve operation and maintaining.The method comprises the steps that a to-be-tested high-pressure sleeve sheath is sampled, the interior of a sheath body is selected as a reference area, and meanwhile multiple aging feature areas on the surface of the sheath are selected as aging areas; repairing the sampled insulated damaged area, injecting a nano silicon dioxide modified silicone rubber filler, and performing ultraviolet curing; performing group degradation characteristic test and thermal stability characteristic test on the sampled sample to obtain aging characteristic parameters including characteristic peak absorptivity of each group and thermogravimetric residual rate parameters of different temperature points; taking the aging characteristic parameter of the reference area as a reference value, respectively calculating a single parameter deviation degree of each aging area, and calculating a comprehensive aging non-uniformity value; and according to a comparison result of the comprehensive aging non-uniformity value and a preset grading threshold value, outputting an aging grade of the high-voltage sleeve sheath and a corresponding operation and maintenance strategy.

The invention discloses a high-adaptability variable-rigidity flexible manipulator and a grabbing method thereof, and relates to the technical field of robot end execution. Comprising a plurality of rope-driven flexible grabbing fingers connected to the high-adaptability attaching transmission structure. The rope-driven flexible grabbing finger comprises a multi-joint movable rigid phalanx, a flexible adaptive contact layer and a special-shaped channel air bag. The high-adaptability attaching transmission structure comprises a transmission cavity formed by connecting a flexible attaching silicon rubber sleeve and a fixed bottom plate seat, and a plurality of connecting rods and a plurality of soft springs are arranged in the transmission cavity. The contact face of the mechanical arm and an object is made of a flexible material, flexible contact can be achieved, the high-adaptability attaching transmission structure can be well attached to the grabbed object, the grabbing attaching degree is increased, the grabbing adaptability is improved, meanwhile, under the influence of the air bag and the variable-rigidity structure, rigidity change can be achieved in the bearing process, and the mechanical arm is more flexible. And the bearing capacity of the manipulator is improved.

The invention provides an embedded insulator coating structure and a preparation method and application thereof, and relates to the technical field of insulating materials. The invention provides an embedded insulator coating structure. The embedded insulator coating structure comprises an insulator, a plurality of grooves formed in the surface of the insulator, and room temperature vulcanized silicone rubber anti-pollution flashover coatings filled in the grooves and coated on the surface of the insulator, and the insulator is made of a hydrophilic material. According to the embedded insulator coating structure provided by the invention, the RTV coating (namely the room temperature vulcanized silicone rubber anti-pollution flashover coating) in the groove and the RTV coating on the surface are integrated, and meanwhile, the RTV coating in the groove is embedded into the insulator substrate, so that a mechanical interlocking structure is successfully formed, and the overall adhesive force and durability of the RTV coating are improved. According to the embedded insulator coating structure provided by the invention, the technical problem that a traditional coating type RTV coating structure of an insulator is insufficient in adhesive force and durability is solved.

The invention discloses a silicone rubber foam material and a preparation method thereof. The silicone rubber foam material is prepared by mixing a component A and a component B in equal mass. The base rubber of the silicone rubber foam material takes vinyl hydroxyl silicone oil as a main body, 110 raw rubber is compounded and added, the mechanical property of silicone rubber foam can be effectively improved, the dispersity of the base rubber in a rubber material can be improved by adding modified aluminum hydroxide powder, the embrittlement degree of the material is reduced, and the flame retardant rating can reach V0; therefore, the material has a good application prospect in new energy battery materials.

The invention relates to the technical field of heat insulation pads for battery cells, in particular to a novel battery cell large-area buffer heat insulation pad and a preparation method thereof.The novel battery cell large-area buffer heat insulation pad is prepared by using surface modified boron nitride nanosheets (BNSS) as nanofiller, silica-coated magnesium hydroxide (MH-coated SiO2) of a core-shell structure as a flame retardant and polysilsesquioxane (POSS) as a high-temperature-resistant auxiliary. A ternary flame-retardant system is formed in the organic foamed silicone rubber layer through the nano filler, the flame retardant and the high-temperature-resistant additive, so that the flame-retardant property of the organic foamed silicone rubber material serving as a battery cell heat insulation pad is improved, thermal runaway propagation can be delayed, the requirements of light weight (the density is 0.3-0.6 g / cm < 3 >) and high mechanical strength are met, the manufacturing cost is reduced, the mass production cost is only increased by 15%, and the product quality is improved. However, the premium price space of the product can reach 50%, and the requirement of a high-end power battery is met.

The invention discloses a multi-dimensional force tactile perception electronic skin and a preparation method thereof. In the method, a plurality of TMR elements are distributed on a flexible printed circuit board in an array; the silicone rubber substrate is adhered to the flexible printed circuit board on which a plurality of TMR elements are arrayed; preparing a neodymium iron boron-PDMS magnet block, wherein the neodymium iron boron-PDMS magnet block is formed by mixing neodymium iron boron magnetic particles and polydimethylsiloxane; a PDMS protective layer is prepared, a PDMS main agent and a curing agent are mixed and stirred according to the ratio of 5: 1, the mixture is put into an ultrasonic oscillator to be oscillated and then poured into a mold of the protective layer, then the mixture is put into a vacuum box together to be subjected to vacuum pumping treatment, ultrasonic oscillation is conducted, and finally the mixture is put into a curing box to be cured and cooled to obtain the PDMS protective layer; the PDMS protection layer and the neodymium iron boron-PDMS magnet block are bonded through the PDMS prepolymer and then laminated on the silicon rubber substrate, so that the neodymium iron boron-PDMS magnet block is located between the silicon rubber substrate and the PDMS protection layer.

The invention belongs to the technical field of organic silicon damping materials, and particularly relates to a polyborosiloxane type damping additive for phenyl siloxane rubber as well as a preparation method and application of the polyborosiloxane type damping additive. The polyborosiloxane type damping additive for phenyl siloxane rubber is prepared from hydroxyl-terminated polysiloxane and a boron-containing aryl compound, and the hydroxyl ratio of the hydroxyl-terminated polysiloxane to the boron-containing aryl compound is 1: (0.2-3). From the perspective of molecular structure design, aryl groups are introduced into polyborosiloxane molecules, the obtained polyborosiloxane type damping additive has good compatibility with phenyl siloxane rubber, cannot be separated from the phenyl siloxane rubber, and can provide good damping performance for the phenyl siloxane rubber; the effective damping temperature range of the phenyl silicone rubber is greatly widened, and the requirement of the market for high-performance damping silicone rubber is met.

The invention discloses a high-sensitivity tactile sensing system based on a magnetic cilia array, a sensor comprises the magnetic cilia array and a sensor array, and the magnetic cilia array is attached to the upper surface of the sensor array; the magnetic cilia array comprises a substrate and cilia structures which are orderly arranged and fixed on the substrate; the cilia structure is made of ecological silicone rubber mixed with magnetic powder, and a plurality of groups of sensors are adopted to form a sensor array to construct a sensing system. By optimizing the magnetization process, uniform distribution of the magnetic particles in each cilium is ensured, and the output stability and sensitivity of the sensor are improved; meanwhile, the multi-sensor array layout is adopted, and high-precision sensing of multi-dimensional tactile information such as pressure, direction and vibration is achieved.

The invention provides ceramic silicone rubber as well as a preparation method and application thereof, and belongs to the technical field of functional materials. The ceramic silicone rubber provided by the invention is prepared from the following preparation raw materials in parts by mass: 90-105 parts of methyl vinyl silicone rubber; 35 to 45 parts of fumed silica; 3-10 parts of hydroxyl silicone oil; 0.1 to 8 parts of a silane coupling agent; 1-75 parts of an inorganic filler; the inorganic filler is mica powder, montmorillonite and wollastonite; 10-30 parts of low-melting-point glass powder, the melting point of the low-melting-point glass powder is 400-600 DEG C, and the low-melting-point glass powder is borate glass powder and / or phosphate glass powder; 0.1 to 0.3 part of platinum flame retardant; 0.5 to 1.5 parts of a vulcanizing agent; and 0.1-0.5 part of an internal release agent. The ceramic silicone rubber provided by the invention can maintain higher tensile strength and elongation at break on the basis of ensuring better ceramic performance.

The invention discloses a silica gel pad with high thermal conductivity and heat resistance and a preparation method thereof, and the method comprises the following steps: preparing a composite thermal conductive filler, mixing boron nitride nanosheets and graphene according to a certain mass ratio, adding a silane coupling agent, carrying out ball milling, adding spherical alumina, and mixing; preparing modified organic silicon resin, wherein methyl vinyl silicone rubber, hydrogen-containing silicone oil, a platinum catalyst and MQ silicon resin react to obtain the modified organic silicon resin; mixing and defoaming the modified organic silicon resin, the composite heat-conducting filler, the flame retardant and the antioxidant to obtain a heat-conducting silica gel mixture; preparing a reinforced base material, carrying out plasma treatment on glass fiber cloth, and then impregnating the glass fiber cloth with vinyl ester resin for pre-curing; and grinding the mixture by three rollers, coating the mixture on a reinforced base material, and heating and curing. The thermal conductivity of the obtained silica gel pad is 2.5-3.5 W / m.K, the volume resistivity is larger than 1012 omega.cm, the long-term heat-resistant temperature reaches 200 DEG C or above, the tensile strength is larger than 5 MPa, the peel strength is larger than 15 N / cm, and the silica gel pad has excellent thermal conductivity, insulativity, heat resistance and mechanical strength.

The invention relates to the technical field of conductive glue, in particular to polyurethane modified silicone rubber, sprayable conductive glue and a preparation method thereof. The polyurethane modified silicone rubber is prepared from the following components in parts by weight: 50 to 150 parts of vinyl silicone oil, 20 to 50 parts of polyurethane powder and 5 to 15 parts of compatilizer, the sprayable conductive glue comprises the following components in parts by weight: 20-40 parts of conductive particles, 5-15 parts of hydrogen-containing silicone oil, 50-150 parts of polyurethane modified silicone rubber, 1-10 parts of a coupling agent, 1-5 parts of a catalyst, 1-2 parts of an inhibitor, 40-90 parts of a diluent and 1-2 parts of a defoaming agent, compared with traditional silicone rubber, the polyurethane modified silicone rubber provided by the invention is high in mechanical strength and not easy to tear, when the polyurethane modified silicone rubber provided by the invention is used for preparing sprayable conductive glue, a conductive layer formed by the conductive glue is excellent in conductivity, and meanwhile, the mechanical property is also remarkably improved.

The invention discloses a telescopic grouting pipe-bag-electrode system and a using method, and belongs to the technical field of underground geotechnical engineering and tunnel engineering. The system comprises a grouting pipe, the grouting pipe is in a hollow cylinder shape and comprises a grouting pipe tail section, a grouting pipe middle section and a grouting pipe top section which are fixedly connected in sequence, and a grouting hole is formed in the grouting pipe middle section; the sliding mechanism is arranged on the tail section of the grouting pipe in a sleeving mode and can slide in the axis direction of the tail section of the grouting pipe; the grouting pipe is sleeved with the silicone rubber bag, one end of the silicone rubber bag is fixed to the top section of the grouting pipe, and the other end of the silicone rubber bag is fixed to the sliding mechanism to drive the silicone rubber bag to stretch out and draw back through the sliding mechanism; and the carbon fiber cloth electrode is attached to the outer side surface of the silicon rubber bag. According to the method, the bag expansion-electroosmosis method technology is combined, the reinforcing effect of the soft soil layer is improved, and foundation settlement is effectively controlled; and a sliding mechanism is further arranged, so that the installation problem caused by the fact that the diameter of a reserved grouting hole of the tunnel segment is small in the original reinforcement technology is solved.

The invention provides a composite insulator with a cooling function and an embedded microcapsule hydrophobing agent and a preparation method of the composite insulator, and relates to the technical field of electric insulating materials. The composite insulator comprises an umbrella cover base material, the surface of the umbrella cover base material is provided with a cooling coating, and a microcapsule water repellent agent is embedded in the umbrella cover base material. The umbrella cover base material is silicone rubber or modified epoxy resin; the cooling coating is prepared from Al2O3 (at) TiO2 / PDA-BN, fluorocarbon resin, isopropanol, a dispersing agent and a flatting agent; the microcapsule water repellent agent is composed of a core layer and a shell layer, the core layer is made of fluorinated modified polystyrene / nano-silica microspheres, and the shell layer is made of polymer resin. The composite insulator has cooling and hydrophobic functions, the two functions are synergistic, the weather resistance of the insulator can be remarkably improved, the service life of the insulator in a severe environment is prolonged, and the defects that in the prior art, materials are fast in aging, poor in hydrophobic durability, single in function and the like are overcome.

The invention relates to the technical field of silicone rubber, and discloses flame-retardant and heat-insulating silicone rubber and a preparation method thereof.The flame-retardant and heat-insulating silicone rubber is obtained by reacting a flame-retardant aid with hollow glass beads and then adding the reaction product, methyl vinyl silicone rubber, hydroxyl silicone oil, a reinforcing agent, a flame retardant and a vulcanizing agent into an open mill to be mixed and vulcanized. The flame-retardant auxiliary agent contains a siloxane structural unit and is grafted on the surfaces of the hollow glass beads, so that the compatibility between the flame-retardant auxiliary agent and the methyl vinyl silicone rubber is improved, the hollow glass beads are more uniformly dispersed in a silicone rubber matrix, a uniform heat insulation network is formed, the heat conductivity is reduced, and the heat insulation performance is improved. The flame-retardant auxiliary agent contains nitrogen-rich triazine groups, and generates nitrogen and other non-combustible gases during combustion, so that the oxygen concentration of the combustion atmosphere can be diluted, and the limit oxygen index, flame retardance and high-temperature resistance of the silicone rubber are improved.

The invention discloses a high-viscosity silicone rubber composite material and a preparation method thereof.The preparation method comprises the steps that a silicon-based polymerization solution and a silane raw material are mixed on the basis of a rotary dropper, and a silicon-based liquid compound containing a spiral laminated layer is obtained; the preparation method comprises the following steps: dispersing a nano-filler into a silicon-based liquid compound for synthesis treatment, carrying out crosslinking treatment on the obtained primary compound and peroxide to obtain a crosslinked compound, mixing the crosslinked compound with a fiber compound, and carrying out plasma treatment to obtain a fiber-reinforced compound; performing secondary cross-linking treatment on the fiber reinforced compound and a peroxide silicone oil solution in a vacuum high-temperature environment to obtain a secondary cross-linked compound; and immersing the secondary cross-linked compound into a turbid liquid containing nano aluminum oxide, and carrying out heating treatment to obtain a finished product of the high-viscosity silicone rubber composite material. According to the invention, the problem of compatibility between the filler and the matrix material is solved, the processability is improved, and the performance of the material in multiple aspects such as high temperature resistance and aging resistance is further improved.

The invention belongs to the technical field of flexible sensing, and particularly relates to a preparation method of an implantable flexible sensor and a bladder urine content wireless monitoring system based on the sensor and a radio frequency mechanism. Wherein the performance of the sensor is improved by utilizing a microporous structure, n-octane is added into TPU to form a porous dielectric layer through a method of different temperatures and different liquid solubility, and the second dielectric layer is added into TPU by using a core-shell structure of silver nanowires and titanium dioxide, so that the anti-interference performance of the pressure-volume sensor is remarkably improved. In addition, the overall structure of the sensor is designed into a semi-bent snake-shaped structure, and the sensor has good pressure-volume performance, sensitivity, restorability and anti-interference performance. The elastic silicone rubber is used for packaging, so that the biocompatibility and practicability of the material are improved, and unstable factors such as body fluid invasion are eliminated. Meanwhile, a wireless sensing system based on a radio frequency mechanism is designed and manufactured, the urine content of the bladder can be wirelessly known from the outside, and related work such as medical care can be helped.