The invention discloses a preparation process of vegetable insulating oil with high
oxidation stability, and belongs to the technical field of
vegetable oil refining. The core of the process is as follows: firstly, taking
palladium and
nickel salts in a specific
molar ratio as precursors, and combining with
polyethylene glycol to prepare a
palladium-
nickel bimetallic catalyst loaded on alkaline carclazyte; then,
vegetable oil is mixed with the catalyst and
activated carbon, and
hydrogen is introduced under mild vacuum and heating conditions for selective hydrogenation refining; and finally, adding an
antioxidant and a
pour point depressant into the refined oil to obtain a final product. Through the synergistic effect of the catalyst, extremely unstable
linolenic acid in hydrogenated
oil can be efficiently and selectively hydrogenated, by means of an integrated process and blending, the
oxidation stability is remarkably improved, meanwhile, the excellent low-temperature fluidity of the product is kept, the refining yield is high, the process is simple and convenient, and the method is suitable for large-scale production of the environment-friendly high-performance vegetable insulating oil.