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117results about How to "Low in phosphorus" patented technology

Smelting method of steel for raw material pure iron

The invention relates to a smelting method of steel for raw material pure iron, comprising the following steps of: I, tapping by a converter: tapping when P is less than or equal to 0.006%, S is less than or equal to 0.07% and C is 0.02-0.04% in liquid steel; and binary alkalinity of furnace slag is 3-4; II, primarily dephosphorizing: in the process of tapping by the converter, adding a liquid steel dephosphorizing agent into a steel ladle and powerfully agitating by argon; III, deeply dephosphorizing: adding lime after an LF (Low Frequency) furnace arrives, wherein the binary alkalinity of the furnace slag is 4-5; powerfully agitating by the argon and slagging off; adding the lime by the LF furnace and adjusting the slag by fluorite, wherein the alkalinity is 7-8; raising the temperature and adding aluminum powder to adjust the slag and powerfully agitating by the argon; IV, decarbonizing: conveying the steel ladle to an RH and arriving at the station and vacuumizing oxygen, wherein the vacuum degree is less than or equal to 4 mbar; and decarbonizing at the vacuum degree for 10-15 minutes; and V, desulfurizing: after decarbonizing, making the oxygen content after decarbonizing; adding aluminum according to a constant oxygen amount and adjusting; and adding a desulfurization agent, wherein the mass percentages of components in the liquid steel are as follows: the C is less than or equal to 0.002%, the S is less than or equal to 0.005%, the P is less than or equal to 0.002% and Al is less than or equal to 0.03%; and the others are Fe and unavoidable impurities. The smelting method of the steel for the raw material pure iron improves the purity of the liquid steel.
Owner:SHANXI TAIGANG STAINLESS STEEL CO LTD

Method and device for treating phosphorus wastewater by adopting multi-electrode baffling electric flocculation process

The invention belongs to the technical field of sewage treatment in environmental engineering, and particularly relates to a method and a device for treating phosphorus wastewater by adopting a multi-electrode baffling electric flocculation process. The PH value of wastewater is regulated with alkaline liquor to 7.0-8.0; the regulated wastewater is pumped into an electric flocculation tank through a peristaltic pump, is subjected to electrolytic flocculation treatment through the baffling of a multi-electrode under the condition of aeration, and then is discharged through an overflow launder, the discharged water is collected and left to stand for 30 minutes, a liquid supernatant is discharged, a floc is recycled; a power supply of the electric flocculation tank is a direct current power supply, the current density is 1.27-5.08mA/cm<2>, and the electrolysis time is 2 minutes to 48 hours. The technical characteristics are as follows: the wastewater baffles along the multi-electrode, then the short stream of the wastewater is avoided, the chance of enabling a pollutant in the wastewater to be in contact with a high-concentration flocculating agent in an electrolysis plate is increased, the flocculent precipitation is promoted, so that the pollutant treatment effect is improved. The multi-electrode baffling electric flocculation process is suitable for treating inorganic phosphorus wastewater at medium and low concentrations, needed equipment is simple, easy in operation and low in cost, and runs stably, so that the process is an electrochemistry phosphorous removal process having a high potential.
Owner:中国中化股份有限公司 +2

Method for improving by-product phosphogypsum quality during phosphoric acid production process

The invention discloses a method for improving the by-product phosphogypsum quality during a phosphoric acid production process. The method comprises the steps that: (1) phosphoric acid is subjected to a reaction with phosphate concentrate; filtering is carried out, such that a filtrate containing calcium dihydrogen phosphate, calcium hydrogen phosphate, and phosphoric acid is obtained; and the filtrate is delivered to an extraction tank; (2) the filtrate is subjected to an extraction reaction in the extraction tank by using sulfuric acid with calcium dihydrogen phosphate and calcium hydrogen phosphate, and an obtained extract liquid is dilute phosphoric acid containing phosphogypsum; during the process, through analyzing filtrate calcium content, sulfuric acid theoretical dose is calculated according to a phosphoric acid extraction reaction formula, and sulfuric acid addition amount is determined; and (3) the extraction liquid is filtered by using a filtering machine, such that dilute phosphoric acid and phosphogypsum comprising 97% of dehydrate are obtained. In the phosphogypsum provided by the invention, dihydrate gypsum content is greatly higher than that of prior art, phosphorus content is substantially reduced, and phosphogypsum quality is greatly improved. Therefore, good raw material is provided for downstream phosphogypsum construction material manufacturing, and a basis is provided for sufficient utilization of phosphogypsum. The method is suitable for wet-method phosphoric acid production enterprises intending to utilize phosphogypsum.
Owner:GUIZHOU JINLIN CHEM

Processing method for rice bran oil

The invention discloses a processing method for rice bran oil. A finished rice bran oil product is obtained by successively subjecting rice bran to puffing, leaching, pretreatment of mixed rice bran crude oil, degumming, decoloring, de-waxing and physical deacidification. In the procedure of leaching, a leaching solvent--isopropanol is added into the rice bran having undergone puffing, and oil yield of the rice bran oil is improved through optimization of the leaching procedure; in the procedure of pretreatment of the mixed rice bran crude oil, the mixed rice bran crude oil is subjected to filtration so as to control impurity content to be less than 0.2%; in the procedure of degumming, the temperature of the rice bran crude oil having undergone removal of impurities is adjusted to 42 to 45 DEG C, 20 to 25% of an aqueous oxalic acid solution is added under stirring, heating is carried out during stirring until the temperature is 62 to 64 DEG C, and the solution is stood for 1 to 2 h so as to obtain oxalic acid degummed oil; and then the oxalic acid degummed oil is subjected to water processing so as to obtain degummed oil. The processing method for the rice bran oil provided by the invention has the advantages of low energy consumption, high oil yield and a good decoloring effect.
Owner:湖南灯塔米业有限公司

Method for recovering simple-substance phosphorus from sludge phosphorus via terminal membrane microfiltration and application for same

ActiveCN103213958AHigh recovery rateShort production processPhosphorus purificationSludgePhosphorite
The invention discloses a method for recovering simple-substance phosphorus from sludge phosphorus via terminal membrane microfiltration, which is remarkably increased in the recovery rate of simple-substance phosphorus compared with the existing method. The method for recovering simple-substance phosphorus from sludge phosphorus via terminal membrane microfiltration disclosed by the invention comprises the following steps of: firstly, mixing a sludge phosphorus raw material with hot water at 60-90 DEG C, so as to melt and settle simple-substance phosphorus in the sludge phosphorus raw material under the heat insulation of the hot water; secondly, only drawing the melted and settled substances in the mixture aforementioned in a terminal membrane microfiltration device, so as to filter the melted and settled substances by a membrane component at a filter temperature of 50-85 DEG C and under a filter pressure of 0.1-0.3 MPa; and finally, conveying the product passing through the membrane component aforementioned to a phosphorus-receiving tank, and settling at the bottom of the phosphorus-receiving tank to obtain simple-substance phosphorus. A production process adopting the method aforementioned for yellow phosphorus comprises the steps of pouring the raw materials of phosphorite, coke, silica and the like in an electric furnace to react, and then performing spray-cooling on a furnace gas and obtaining crude phosphorus, wherein after that, the crude phosphorus is directly used as a raw material, and the operation is performed according to the method aforementioned for recovering simple-substance phosphorus from sludge phosphorus.
Owner:CHENGDU INTERMENT TECH

Physical concentration and phosphorus reduction method for skarn-type high-phosphorus molybdenum ore

The invention discloses a physical concentration and phosphorus reduction method for a skarn-type high-phosphorus molybdenum ore. The physical concentration and phosphorus reduction method comprises the following steps of (1) crushing, namely crushing raw ores by using a crusher, sieving, and returning a +3mm-grade raw ore to crush until the particle size of the raw ore is up to the -3mm grade; (2) grinding the ores, namely adding the crushed -3mm-grade raw ore into raw ore grinding equipment to carry out closed-circuit ore grinding operation, meanwhile, adding 500-1000g / t of water glass and 250-800g / t of a phosphate mineral inhibitor into a grinding machine, and grinding the raw ore until the particle size is up to the -0.075mm grade and the phosphorus content is up to 55-75%; (3) carrying out roughing operation; (4) carrying out scavenging operation; (5) regrinding a roughed molybdenum concentrate, namely adding 100-280g / t of a sulfur inhibitor and 150-300g / t of a phosphate mineral inhibitor to regrind the roughed molybdenum concentrate in roughed molybdenum concentrate regrinding equipment until the particle size is up to the -0.045mm grade and the phosphorus content is up to 70-95%; and (6) carrying out fine flotation operation. By using the physical concentration and phosphorus reduction method, the phosphorus content of a molybdenum concentrate product can be reduced to be lower than the standard, and a high-quality molybdenum concentrate product can be obtained.
Owner:INST OF MULTIPURPOSE UTILIZATION OF MINERAL RESOURCES CHINESE ACAD OF GEOLOGICAL SCI

Method for recovering simple-substance phosphorus from sludge phosphorus via cross-flow membrane microfiltration and application for same

The invention discloses a method for recovering simple-substance phosphorus from sludge phosphorus via cross-flow membrane microfiltration, which is remarkably increased in the recovery rate of simple-substance phosphorus compared with the existing method. The invention further discloses a production process for yellow phosphorus, which omits a two-stage refining groove and an all sludge phosphorus pool compared with the existing process, so that lots of investment, manpower, water and energy consumption can be saved. The method for recovering simple-substance phosphorus from sludge phosphorus disclosed by the invention comprises the following steps of: firstly, mixing a sludge phosphorus raw material with hot water at 60-90 DEG C, so as to melt and settle simple-substance phosphorus in the sludge phosphorus raw material under the heat insulation of the hot water; secondly, only drawing the melted and settled substances in the mixture aforementioned in a cross-flow membrane microfiltration device, so as to filter the melted and settled substances by a membrane component at a filter temperature of 50-85 DEG C and under a filter pressure of 0.1-0.3 MPa; and finally, conveying the product passing through the membrane component aforementioned to a phosphorus-receiving tank, and settling at the bottom of the phosphorus-receiving tank to obtain simple-substance phosphorus, wherein the speed of the mixture flowing along the surface of the membrane component during filtering is controlled to be 0.01-0.5 m/s.
Owner:CHENGDU INTERMENT TECH

Preparation method of scale and corrosion inhibitor

The invention discloses a preparation method of a scale and corrosion inhibitor, which belongs to the technical field of preparation of water treatment chemicals. Nano cellulose prepared by utilizingneedle wood leaves is used as an adsorption carrier of corrosion inhibitor. The parent corrosion inhibitor prepared by the invention is Mannich base, by virtue of quaternization, the parent corrosioninhibitor adopts nitrogen atoms with larger electronegativity as a center polar group, the polar group is extremely high in hydrophilic performance, the concentration of the metal ions which are easyin forming scales such as calcium and magnesium can be reduced, the surface of a chelated adsorption material is coated with oxidized nano cellulose to form a nano filter membrane, the metal ions canbe efficiently adsorbed, the corrosion of saline-alkaline water for a salt discharging concealed pipe can be reduced, and when the added graphene oxide is oxidized, the graphene lamina is swelled, sothat a gap between two layers can be enlarged, the ion exchange is likely to occur for the metal ions in the saline-alkaline water, and the scale and corrosion inhibitor provided by the invention is high in capability for adsorbing and controlling the metal ions in the saline-alkaline water, and wide in application prospect.
Owner:FOSHAN GAOMING DISTRICT ZHUAHE NEW MATERIAL TECH CO LTD

Treatment method for high-concentration phosphorus-containing wastewater

The invention discloses a treatment method for high-concentration phosphorus-containing wastewater. The treatment method comprises the steps: adding alkali liquor into the high-concentration phosphorus-containing wastewater, adjusting pH to 7.2 to 8 to enable ortho-phosphate to present in forms of monohydrogen phosphate and dihydrogen phosphate, then, adding a precipitant to enable phosphate and the precipitant to form an insoluble compound, and carrying out filtering; adding filter liquor into a supercritical water oxidation reaction device, thoroughly blending organics, oxygen gas and waterduring reaction under a supercritical state so as to form a uniform phase, rapidly oxidating organic phosphorus into inorganic phosphate, and releasing the inorganic phosphate into a liquid phase; andadding ferric polysulfate and an anionic polyacrylamide solution into supercritical treated wastewater, and carrying out condensation and flocculation processes, so as to settle and remove phosphate.According to the method, phosphorus is removed by employing a supercritical oxidation and chemical precipitation cooperated method, phosphorus removal is rapid and thorough and is relatively wide inrange, high-concentration organic phosphorus and inorganic phosphorus can be treated, and the content of total phosphorus in final wastewater is lower than 1mg/L.
Owner:石家庄新奥环保科技有限公司

Coupled sewage biological nitrogen and phosphorus removal and phosphate recovery method

The invention relates to a coupled sewage biological nitrogen and phosphorus removal and phosphate recovery method. According to the method based on a biological nitrogen and phosphorus removal mainstream process of a sewage plant, phosphorus releasing ponds which operate in a side stream sequencing batch manner and are coupled with the main stream process is arranged, the amount of sludge introduced into a secondary sedimentation tank of each of the phosphorus releasing ponds is based on the volume ratio of water inflow: sludge inflow of the phosphorus releasing pond=(0.5-2.0): 1, and the total sludge amount entering into the phosphorus releasing pond everyday is below 10% of the daily average flow rate of the sewage plant; each of the phosphorus releasing ponds operates 2-4 periods everyday, and residual sludge is discharged from the phosphorus releasing ponds. The phosphorus releasing ponds can be flexibly adjusted according to a result of pilot run of the phosphorus releasing ponds and phosphate recovery, the phosphate is recovered to the optimum extent, and the biological treatment effect of the sewage is improved. According to the method provided by the invention, not only do the sewage treatment indexes meet the national discharge standard, but also phosphorus in the sewage can be recovered. The method is a sewage treatment and resource recovery method in sustainable development and is suitable for a newly constructed municipal sewage treatment plant or a constructed sewage plant with a nitrogen and phosphorus removal function.
Owner:TONGJI UNIV

Method for extracting fluorescent carbon quantum dots from semi coke

The invention provides a method for extracting fluorescent carbon quantum dots from semi coke. The method comprises the following steps: firstly, adding semi coke powder into a 4M to 6M nitric acid solution, and carrying out stirred refluxing at the temperature of 80 DEG C to 120 DEG C; carrying out natural cooling, then, carrying out centrifugation for 30 minutes to 60 minutes at the rate of 10,000r/min to 15,000r/min, collecting supernatant, removing precipitates, and drying the obtained supernatant by distillation in a reduced-pressure distillation manner, so as to obtain black solids; dispersing the black solids in deionized water, carrying out neutralizing by ammonia water, then, carrying out centrifugation for 30 minutes to 60 minutes at the rate of 10,000r/min, and collecting supernatant; dialyzing the supernatant by dialysis bags, collecting solutions in the dialysis bags, and carrying out vacuum drying for 24 hours to 48 hours at the temperature of 60 DEG C to 80 DEG C, thereby obtaining the carbon quantum dots. According to the method, the semi coke which is low in cost and easy in raw material obtaining is adopted as a carbon source, and the carbon quantum dots can be obtained through simple chemical oxidation, evaporation, neutralization, centrifugation and dialysis treatment processes. The carbon quantum dots have the particle size of 3nm to 5nm and are uniform in dispersion, and surfaces of the carbon quantum dots have a large number of carboxyl groups and hydroxyl groups, so that a relatively good fluorescent property is shown.
Owner:XINJIANG UNIVERSITY

Method and system for processing high-calcium and high-phosphorus vanadium slag

The invention discloses a method and system for processing high-calcium and high-phosphorus vanadium slag. The method for processing the high-calcium and high-phosphorus vanadium slag comprises the following steps: mixing the high-calcium and high-phosphorus vanadium slag, silica, reducing coal and a binder, so as to obtain a mixed material; carrying out formation on the mixed material, so as to obtain mixed pellets; carrying out reducing roasting dephosphorization on the mixed pellets, so as to obtain dephosphorized metallized pellets and phosphorus-containing flue gas; carrying out melt separation on the dephosphorized and metallized pellets, so as to obtain molten iron and low-phosphorus vanadium slag; carrying out oxidation roasting with calcium on the low-phosphorus vanadium slag, so as to obtain acid-soluble calcium vanadate clinker; and carrying out acid leaching and vanadium extraction on the acid-soluble calcium vanadate clinker, so as to obtain a vanadium pentoxide product. By utilizing the method for processing the high-calcium and high-phosphorus vanadium slag, phosphorus in the high-calcium and high-phosphorus vanadium slag can be effectively removed, so that the recycling rates of iron and vanadium are remarkably increased, and the qualities of the iron and the vanadium are remarkably improved.
Owner:JIANGSU PROVINCE METALLURGICAL DESIGN INST
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