This invention relates to a method for dephosphorizing waste oils. First, the
raw material is pretreated using a low-pressure
pyrolysis process, causing thermal degradation and
polymerization of the non-hydrated phospholipids that are difficult to remove. Then, an ultrasonic-assisted
acid washing process is coupled in, utilizing the
ultrasonic cavitation effect to effectively disrupt the chelate structure between
metal ions and
phospholipid groups in the non-hydrated phospholipids. Simultaneously, the displacement effect of the
ultrasound promotes relative movement and accelerated coagulation of the colloidal particles loosened by
pyrolysis and
acid washing in the
oil phase, achieving ultrasonic-assisted demulsification and enhancing the subsequent separation efficiency between the aqueous and oil phases. Based on this, an
organic acid solution is used as a complexing extractant to in-situ complex the released
metal ions into water-soluble complexes, which are then transferred to the aqueous phase for separation. Through the synergistic effect of
pyrolysis activating the structure, ultrasonic breaking of chelates, and
organic acid complexation and transfer, this invention achieves deep dephosphorization of waste oils, significantly reducing their
phosphorus content while preserving the original quality of the oils to the greatest extent possible.