114results about How to "Improve dephosphorization efficiency" patented technology

An oxygen-nitrogen top blowing converter process for desulfurization is carried out by blowing oxygen-nitrogen at its top while blowing nitrogen or inertial gases at its bottom to desulfurise. Its top blowpipe controls oxygen blowing to desulfurise in two modes, with mixed gases at some ratio or with pure oxygen switched with pure nitrogen, in order to inhibit sputtering and to enhance stirring in smelting pool when sputter occurs by excessive oxidation, so that balance of (P)/[P] in dynamics is improved. It desulfurises better when bottom blowing is weak, can inhibit decarbonise reaction effectively with >70% recovery of Mn in molten iron, also, strengthen blowing at top to stir strongly and shorten pre-treat time, increase rate of desulfurization, control slag elimination in procedure effectively to prevent sputtering, and increase stability and security.

The invention relates to a technological process for stainless steel smelting, in particular to a process for directly producing austenitic stainless by utilizing oxide nickel. The process has the following advantages: oxide nickel of various grades is adopted to obtain different ingredients of molten nickel iron by smelting in a blast furnace and a submerged arc furnace, an electric arc furnace is cancelled as a melting unit, the chemical heat of the molten iron is utilized to melt all or part of chromium and manganese alloy, and a bottom-blowing argon-oxygen converter is utilized to dephosphorize so as to improve the dephosphorization efficiency of molten chromium iron and the obtainment yield of chromium, thereby the following series and trademarks of products, i.e. 200 series of 201, 202, J4, and the like, 300 series of 304,304L, 316,321,329, and the like, are produced; and meanwhile, all links in the whole production flows are organically combined, and various energy sources, such as coal gas, steam, afterheat, and the like are fully utilized and recycled, thereby the energy consumption is low, the secondary waste gas discharge amount not great, the production cost and the raw material cost are low, and the investment and the occupied area are not great.

The invention discloses a method for controlling temperature of a steelmaking melting pool of a converter by blowing CO2 gas, which belongs to the filed of convertor steel making and relates to a converter dephosphorization technology. The invention sprays CO2 gas (or mixed gas of CO2-O2) into the melting pool of the converter and realizes the smooth temperature increase of the melting pool by regulating the proportion of V[CO2]/(V[O2]+V[CO2]). The proportion of V[CO2]/(V[O2]+V[CO2]) is controlled at 10%-100% at the early and middle stages of melting (3-5min), the total flow rate of the blowing gas is 100-80000Nm/h, bottom blowing and strong stirring are adopted at this time, and the temperature is controlled between 1300 DEG C and 1400 DEG C. The proportion of V[CO2]/(V[O2]+V[CO2]) is adjusted and controlled at 10%-50% at the middle stage of melting according to desilication and dephosphorization situation and the temperature of the melting pool, and the flow rate of the blowing gas is 100-80000Nm/h. The method is applicable to the converter steel making of 30-300 tons, the dephosphorization rate can achieve 85%-95% by adopting the method, and the rephosphorization rate after slag dumping is lower than 3%.

The invention relates to a dephosphorizing agent and application thereof, belonging to the technical field of ferrous metallurgy. The dephosphorizing agent solves the problems of low dephosphorizing efficiency, high residue consumption, environment pollution and difficulty in resource comprehensive utilization in the existing calcium-oxide-based molten iron pretreatment dephosphorizing agent. The dephosphorizing agent comprises the following components in percentage by mass: 25-50% of FeOt, 20-45% of CaO, 15-30% of SiO2, 2-10% of Na2O and 3-12% of Al2O3. After being molten, the molten iron dephosphorizing can form a solid-phase/liquid-phase coexistent multiphase residue system at 1300-1400 DEG C, wherein the solid phase is a 2CaO.SiO2 phase capable of providing a place for enriching oxidized phosphorus in molten iron, so that the dephosphorizing agent has the characteristics of favorable dephosphorizing effect, low slag consumption, no fluorine and small environmental pollution and is beneficial to comprehensive utilization of dephosphorizing slag.

The invention discloses an operation technology for an electric furnace converter. A furnace burden structure containing 85-95% of molten iron and 5-15% of steel scrap is adopted; after a furnace lid of an electric furnace is opened, the steel scrap is added at one time through a material basket; molten iron is continuously blended at a speed of 2.0-4.0 tons per minute by utilizing an iron blending device, and meanwhile, an oxygen flow is jetted into the furnace through three furnace-wall praxair carbon oxygen guns which are mounted on the furnace wall; the oxygen supply strength is adjusted according to a blowing condition in the furnace and the carbon content in the furnace stabilized at 0.40-0.80% is ensured; lime, return mine and limestone are added while oxygen is blown; slagging is performed and temperature of the molten steel in the furnace is adjusted; during a blowing process, the temperature of the molten steel in the electric furnace is controlled within a range of 1500 DEGC to 1560 DEG C and the stability of carbon oxygen reaction in the furnace is ensured; and the temperature of the molten steel is controlled within the range of 1600 DEG C to 1650 DEG C at end point of the electric furnace, thereby finishing electric furnace smelting. According to the operation technology provided by the invention, the problems of serious splashing and difficulty in dephosphorization of electric furnace converter production are solved, the splashing is light, the time of electric furnace smelting is short, and energy conservation and cost reduction are realized.

A production method for smelting clean steel from full-scrap steel using duplex electric arc furnaces, which belongs to the field of electric arc furnace steelmaking. This method makes electric arc furnaces located in two positions be connected in series, wherein the electric arc furnace in a first position is dephosphorization electric arc furnace, and the electric arc furnace in a second position is decarbonization electric arc furnace.

The invention discloses a smelting method of converter efficient dephosphorization and belongs to the technical field of ferrous metallurgy. The smelting method of converter efficient dephosphorization comprises the following steps that after the last time of converter steel tapping, slag splashing furnace protection is conducted, and residual slag is poured out; before converter blowing is started, pre-melted slag is added into a converter; converter blowing is conducted for 4-5 minutes, the oxygen lance position and the oxygen supply intensity are adjusted dynamically according to blowing time; slag pouring operation is conducted; and slag-forming blowing is conducted, at the converter endpoint, the slag basicity R, the mass fraction of magnesium oxide and the mass fraction of ferrous oxide are controlled, and finished steel of which the phosphorus mass fraction is required to be 0.010% or below is obtained. Through the smelting method of converter efficient dephosphorization, the converter dephosphorization efficiency can be effectively improved, the phosphorus content at the converter endpoint is lowered, and the cost is low.

The invention discloses a compound refined diatomite sewage dephosphorization agent. The compound refined diatomite sewage dephosphorization agent comprises 67-75% of modified refined diatomite, 24-32% of a polymeric diacid flucculant and 1-2% of a cationic organic polymer flocculant. The compound refined diatomite sewage dephosphorization agent has the advantages that the modified diatomite has efficient adsorption effects and the polymeric diacid flucculant and the cationic organic polymer flocculant are conducive to obvious improvement of aggregation and flocculation effects of suspended sludge blankets in a biological aeration tank or a sedimentation tank, thus the dephosphorization efficiency of sewage treatment is greatly improved; and compared with the traditional chemical dephosphorization technology only adopting an aluminium salt or a ferric salt, a technology adopting the compound refined diatomite sewage dephosphorization agent has higher treatment efficiency and a lower operation cost.

The invention relates to a converter steelmaking process for recycling converter final slag, belonging to the technical field of converter steelmaking. The converter blowing process is divided into two steps including a dephosphorizing step and a decarbonising step; before the beginning of blowing in the dephosphorizing step, 0-70 kg/t of converter final slag in a cooled state is added firstly; then, bowing in the dephosphorizing step is carried out by adding iron and waste steel; slag having low FetO content is produced in the blowing process; deslagging is carried out after blowing; then, blowing in the decarbonising step is carried out; carbon catching and steel tapping are carried out after blowing in the decarbonising step; and converter final slag is remained in the converter and used for an underfired furnace to blow in the dephosphorizing step. The converter steelmaking process for recycling converter final slag disclosed by the invention has the advantages that the best use of converter slag is ensured to the most extent; and loss of steel materials is further reduced for smelting low-TFe dephosphorization slag.

The invention relates to a molten iron pre-dephosphorization method by utilizing a top and bottom combined blown converter, belonging to the technical field of molten iron pre-dephosphorization. In the method, generally used molten iron pre-dephosphorization raw and auxiliary materials, such as lime, iron ores and fluorite, are adopted; through controlling the gun position and oxygen flow of a dephosphorization oxygen gun, the fast heating at an earlier stage of smelting is achieved, the slagging effect is improved, the dephosphorization efficiency is improved to above 80%; through the oxygengun, oxygen is supplied to a molten iron bath surface from the top, and a stirred gas is supplied to the inside of molten iron through a converter bottom gas supplying system; and through controllingthe gun position and oxygen flow of the oxygen gun, the dephosphorization efficiency is improved, and the emission load of waste slag in the steel-making process is reduced.

The invention discloses a method for smelting stainless steel containing Ni, which is characterized in that the method mainly comprises the following steps: low-grade nickel-containing chromium-containing ore is dried and then is sintered; the sintered ore is smelted into molten iron containing the Ni in a blast furnace; the molten iron is subject to pretreatment desulfurization and dephosphorization to form a stainless steel mother solution; iron alloy is melted in an electric furnace; the refining is performed in a stainless steel smelting furnace and a VOD furnace; and a stainless steel billet is obtained by continuous casting. The low-grade nickel-containing chromium-containing ore is used to substitute for chromium and nickel alloy to smelt the stainless steel, so the cost for the stainless steel is reduced greatly. At the same time, the method can fully utilize the low-grade ore, ensure that the idle scarce resource is fully utilized, and can reduce cost.

The invention relates to arc furnace deep dephosphorization technology and a deep dephosphorization agent thereof. The arc furnace deep dephosphorization technology comprises the following steps of: melting steel by using slag, performing deep dephosphorization and preparing foamed slag, and is characterized in that lime and the deep dephosphorization agent are added after the addition of scrap steel and before complete melting of the scrap steel in parts so as to enhance the deep dephosphorization effect. The deep dephosphorization agent consists of the following components in percentage by weight: 25 to 40 percent of lime, and 60 to 75 percent of ferric oxide powder. The method for preparing the dephosphorization agent comprises the following steps of: smashing the raw materials into 100 to 150 meshes and uniformly mixing; and premelting the materials at the high temperature of between 1,200 and 1,550 DEG C, cooling and processing into granules with the diameter of 3 to 50 mm. Compared with the prior art, the invention has the advantages that: the deep dephosphorization technology and the deep dephosphorization agent are adopted for deep dephosphorization, the lime is not added before charging, and the lime and the deep dephosphorization agent are added after charging and before complete melting of the materials in parts to enhance the deep dephosphorization effect, so that the tapping phosphorus is reduced to 0.0030 percent or even lower.

The invention provides a hot metal pre-dephosphorization method and belongs to the technical field of hot metal treatment in steelmaking. During loading of hot metal, the proportion of the hot metal is 92-100% and the proportion of scrap steel is within 8%; during slag formation, the slag basicity R is 1.6-2.6, feeding of lime and dolomite for slag formation is started within 40 seconds after blowing; when 7 minutes before oxygen supply, the oxygen supply flow Q is 1/4 to 1/2 of the oxygen flow of a decarburization furnace, and the later-period oxygen supply flow is 0.85-1.0 time of the early-stage oxygen supply flow Q; the maximal bottom-blowing air supply intensity is not less than 0.020Nm<3>/min.t; the final temperature of a dephosphorization furnace is not higher than 1380 DEG C, and the dephosphorization rate is higher than 80%. The method provided by the invention has the advantages that the dephosphorization efficiency of hot iron pre-dephosphorization based on an existing converter is not less than 85%; heating materials are not needed to be added for a following decarburization furnace, so that the converter production cost is greatly lowered.

The invention discloses a pre-melted dephosphorizing agent that is used for preprocessing liquid iron in the field of metallurgy of iron and steel, and is particularly applicable to the smelting techniques that have bad raw material condition of the liquid iron and large fluctuation of initial phosphorus content or are used for producing low-phosphorus steel and ultra-low phosphorus steel. The pre-melted dephosphorizing agent that is used for preprocessing liquid iron is smashed into particles after a complete pre-melting processing at the temperature of 1250 to 1400 DEG C, and consists of following raw materials and weight percentages thereof: 35 to 50 percent of activated lime, 40 to 60 percent of iron oxide and 6 to 15 percent of fluorite. The pre-melted dephosphorizing agent that is used for preprocessing liquid iron has higher content of CaO and Fe2O3, meets the requirements of high basicity and high oxidizing slag of the dephosphorizing in the liquid iron preprocessing, can quickly reduce the phosphorus content in the liquid iron below 0.01 percent; consequently by adopting the pre-melted dephosphorizing agent that is used for preprocessing liquid iron of the invention, the phosphorus content in the liquid iron which has bad raw material condition of the liquid iron, high phosphorus content in the initial liquid iron and large fluctuation of initial phosphorus content can be reduced to a lower level, and the low-phosphorus liquid iron that is required for smelting the low-phosphorus steel and the ultra-low phosphorus steel can be provided.

The invention discloses a dephosphorization method of converter oxygen tapping. The method is characterized in that after converter smelting is finished, oxygen tapping is carried out, in the tapping process, lime, fluorite and a modifier are added, and after tapping is finished, steel ladle dephosphorization is carried out through stirring. On the premise that the technology path is not changed, the dephosphorization capacity of steel ladle slag is utilized fully, the dephosphorization efficiency of a production line is improved by 2% to 4%, the dephosphorization effect of the converter-RH technology is stably improved, the converter dephosphorization pressure is reduced, the component judgment drop caused by phosphorus content standard exceeding of a steel ladle is avoided, the cost is low, and the efficiency is high.

The invention relates to a method for gasifying, dephosphorizing and steel-making in a converter steel slag furnace, and belongs to the technical field of metallurgy. The method comprises the following steps of: first furnace smelting: blowing gas, adding a slag-making material into a first furnace while starting to blow, controlling alkalinity of end-point slag until blowing is ended, adding first anthracite before tapping, splashing slag after tapping, gasifying, dephosphorizing and keeping all steel slag; second furnace smelting: reducing dosage of the slag-making material by one half, keeping one half of the slag after tapping, splashing the slag, and keeping the residual steel slag; and the rest of the steps which are the same with the first furnace smelting step; the third to the tenth furnace smelting: reducing 20-30wt% of the dosage of the slag-making material on the basis of the first furnace, keeping one half of the slag after tapping, and splashing the slag; and the rest ofthe steps which are the same with the first furnace smelting step. The method is simple, can reduce content of phosphor in steel slag, increases steel slag circulating times, reduces material consumption, improves converter dephosphorizing efficiency, relieves the problem that a semi-steel smelting heat source is insufficient, and reduces steel slag discharge amount.

The invention relates to a dephosphorization method of high-phosphorous chromium-nickel pig iron. The method comprises the following steps in order: I. EAF (electric arc furnace) preliminary desilication, adding the high-phosphorous chromium-nickel pig iron into an EAF for fusing so as to realize preliminary desilication, with silicon in the desiliconized molten iron up to 0.05-1.0% by weight; II. removing electric furnace slag and blending the molten iron into an AOD (argon oxygen decarburization) furnace or converter, with the molten iron at a temperature of 1400-1550DEG C; III. dephosphorization, adding 6-45kg/ton steel of lime and 1-34kg/ton steel of fluorite into the blended molten iron, leaving the alkalinity R being 1-5, blowing a mixed gas of oxygen and nitrogen that are in a ratio of 2:1-5:1, when the gas allocation amounts to 0.5-3Nm<3>/ton steel. min. and the content of molten steel P is less than or equal to 0.04%, removing oxidized slag, thus obtaining low-phosphorous molten iron. In another method, a ladle and molten iron dephosphorization pretreatment is conducted after removing electric furnace slag following EAF preliminary desilication in step I. The dephosphorization method of high-phosphorous chromium-nickel pig iron in the invention is characterized by low cost and short time. The dephosphorization process is shortened to 6-10min, thus enhancing the dephosphorization efficiency.

The invention belongs to the field of iron and steel, and particularly relates to a method for producing ultra-low phosphorous steel by a converter double slag process. The method comprises the following steps: 1) adopting a conventional feeding process in the early stage of blowing, and when the amount of oxygen to be blown accounts for 25 to 35% of total required blown oxygen amount, adding 1 to2 Kg/t of Al2O3 and 0.75 to 1.5kg/t of limestone into a converter; 2) when the amount of oxygen to be blown accounts for 30 to 40% of the total required blown oxygen amount, performing a deslagging operation, and then adopting the conventional feeding process; 3) when the amount of oxygen to be blown accounts for 90 to 100% of the total required blown oxygen amount, adding 0.75 to 1.5kg/t of Al2O3 and 1 to 2kg/t of limestone into the converter, thus obtaining the ultra-low phosphorous steel after the converter blowing is finished. The Al2O3 and the limestone are added to make slag during primary deslagging, so that the melting point of slag can be reduced, the fluidity of the slag is increased, the dephosphorization efficiency before deslagging is improved, and the phosphorus content is reduced to 0.025% or less during primary deslagging; the Al2O3 and the limestone are added at an end point of the converter to improve the flowability and foaming of the slag, the temperature of moltensteel is not reduced, and the slag-steel interface reaction temperature is reduced to improve the dephosphorization efficiency, so that the phosphorus content can be reduced to 0.005% at the end point of the converter.

The invention relates to a smelting method of low phosphate steel. The method comprises the steps of molten iron desulphurization, waste steel adding and molten iron adding, converter primary blowing,deslagging, converter secondary blowing, and deslagging tapping. A double slag process is used for smelting, particularly, through control over the furnace inlet molten iron ratio and adoption of a material adding method, an oxygen supply method and a bottom blowing method which are matched, smelting of high-temperature high-carbon low phosphate steel is achieved; the smelting molten iron ratio is controlled according to the molten iron temperature and the molten iron silicon content, the primary blowing time is controlled to range from 5 min to 7 min, the variable gun variable oxygen pressure oxygen blowing mode is adopted, according to the molten iron silicon content, the lime adding amount is controlled, before secondary blowing gun lowering, a certain amount of temperature rising agent is added, the tapping temperature is controlled to be above 1670 DEG C, the tapping carbon content is controlled to above 0.1%, the process structure is adopted for producing, and the content of converter end point phosphorus is stably controlled to below 0.008%.

The invention relates to a vehicle-mounted slag-raking machine for a converter, and a use method, and belongs to the field of steelmaking slag-raking technology. The vehicle-mounted slag-raking machine for the converter comprises a slag-raking plate, a walking chassis, a rotary central disk, a telescopic working arm, a cab and a power system, wherein the rotary central disk is arranged above the walking chassis, and the power system is arranged at the left side over the rotary central disk; the cab is arranged at the right side over the rotary central disk, and the power system is adjacent to the cab; and one end of the telescopic working arm is connected onto the power system, and the other end of the telescopic working arm is connected with the slag-raking plate. The slag-raking is started in 4minutes to 7minutes after the start of converting, and the slag-raking machine is driven to a converter mouth, and is rightly opposite to the converter; and in a deslagging process, the slag-raking plate is fed into the converter by the telescopic working arm to slag off. The vehicle-mounted slag-raking machine for the converter has the advantages that: the use is flexible and convenient, and one slag-raking machine can be used for multiple converters; most of converter slag can be fast and effectively racked out, the decarburization slag basicity can be effectively improved by raking out a large number of dephosphorization slag, the dephosphorization efficiency can be improved, the lime consumption of the converter can be reduced, and the consumption of iron and steel materials can be reduced.

The invention discloses a hot metal pretreatment dephosphorization agent and a preparation method thereof. In mass percent, a formula of the dephosphorization agent comprises: 30-70% of drying sintering nose electric precipitation ash, 10-30% of lime CaCO3 and 10-40% of iron oxide; binary basicity CaO/SiO2 of the hot metal pretreatment dephosphorization agent is 3-4, and alkali chloride content is 5-15%; in mass percent, the total content of four substances, namely CaO, Fe, KCl and NaCl, in the dry sintering nose electric precipitation ash is not less than 60%, wherein the content of alkali chlorides is not less than 10%; and the iron oxide is one or more of sintered ore, iron ore powder, converter dust, electric furnace dust and oxidized scale. Ingredients of the formula of the dephosphorization agent are dried and treated and then are ground until particle size is below 1mm, and uniform mixing is carried out.