The invention discloses a synthetic process for an amino
aromatic hydrocarbon compound. The process comprises the following steps: pre-preparing reaction solutions -1 and -2 by using an
aromatic hydrocarbon compound (I), concentrated sulphuric acid and concentrated
nitric acid, respectively pumping the solutions in a micro reactor, heating to react, cooling the reaction liquid, and pos-treating to obtain a
nitryl aromatic hydrocarbon compound (II); mixing the
nitryl aromatic
hydrocarbon compound (II), a catalyst and a
solvent as a reaction solution -3; respectively pumping the reaction solution -3 and
hydrogen into the micro reactor, heating to react, cooling the reaction liquid and post-treating to obtain the amino aromatic
hydrocarbon compound (III). The process disclosed by the invention is less in use level of
nitric acid, convenient to concentrate and apply waste acid; in the
nitrification reaction process, the heat release is little, and the
nitration product
nitryl aromatic
hydrocarbon compound (II) is quickly transferred. The reaction phenomenon is stable without intense heat release and even material
punching of a common kettle
nitration reaction, so that the safety of
nitration reaction is improved; the process is easy to realize industrialization, simple to operate and high in industrial safety degree and meets the environmental requirements.