3127 results about "Di-isocyanate" patented technology

The invention discloses an embolism part for peripheral arteriovenous vessels, the embolism part comprises an anchoring part and a blocking part fixedly connected with the anchoring part, the blocking part adopts polyurethane shape memory foam, the expansion rate of the polyurethane shape memory foam is 50-100 times, and a preparation method of the polyurethane shape memory foam comprises the following steps: step 1, preparing a polyurethane shape memory foam material; the preparation method comprises the following steps: preparing a polyurethane acrylate prepolymer from macromolecular polyol, diisocyanate, a chain extender containing disulfide bonds, other micromolecular chain extenders and an acrylate end-capping reagent; and 2, uniformly mixing the polyurethane acrylate prepolymer, a foaming agent, a foaming promoter and a photoinitiator to obtain a foaming solution, and sequentially carrying out light curing and foaming on the foaming solution to obtain the polyurethane shape memory foam. According to the embolism part, the polyurethane shape memory foam is adopted as the blocking part, the blocking part applies radial acting force to the wall of the blood vessel all the time based on the expansion trend of the blocking part, and the blocking part and the anchoring part jointly act and can be stably maintained in the blood vessel.

The invention discloses a scratch repair coating and a preparation method thereof, and relates to the technical field of high polymer materials. When the scratch repair coating is prepared, hydroxylated boron nitride reacts with 1-(3-triethoxysilylpropyl)-2-imidazoline to prepare pre-modified boron nitride, and then the pre-modified boron nitride and 4-chloro-1-butene are subjected to quaternization to prepare modified boron nitride; the preparation method comprises the following steps: reacting styryl phosphonic dichloride with 4, 4, 5, 5, 6, 6, 7, 7, 7-nonafluoro-1, 2-heptanediol to prepare a hydroxyl-terminated phosphorus-fluorine-containing polymer; the preparation method comprises the following steps: reacting isophorone diisocyanate with a hydroxyl-terminated phosphorus and fluorine-containing polymer to prepare a polyurethane prepolymer; reacting the polyurethane prepolymer with hydroxyl-terminated coumarin to generate modified polyurethane; and uniformly mixing the modified polyurethane, the modified boron nitride and a photoinitiator to prepare the scratch repair coating. The scratch repairing coating prepared by the invention has good self-repairing performance, flame retardant property, corrosion resistance and mechanical property.

The invention belongs to antibacterial materials, and particularly relates to antibacterial modified waterborne polyurethane and a preparation method and application thereof.The preparation method of the antibacterial modified waterborne polyurethane comprises the following steps that polyol and diisocyanate are mixed and subjected to a prepolymerization reaction, and a polyurethane prepolymer is obtained; mixing the polyurethane prepolymer and a chain extender, and carrying out chain extension reaction; in the chain extension reaction, adding the graft and carrying out esterification reaction to obtain a first intermediate; mixing the first intermediate with triethylamine and carrying out neutralization reaction to obtain a second intermediate; and emulsifying the second intermediate in deionized water to obtain the antibacterial modified waterborne polyurethane. Compared with the prior art, the antibacterial waterborne polyurethane has the advantages that the problems of poor intermiscibility, low durability and the like in physical addition and the problems of limited binding objects and weak antibacterial effect in covalent binding in the antibacterial waterborne polyurethane in the prior art are solved. According to the scheme, arginine and chitosan are grafted to a molecular chain of waterborne polyurethane, so that the waterborne polyurethane is endowed with a synergistic antibacterial property.

The invention relates to the technical field of polyurethane films, in particular to a long-acting, stable, flexible, impact-resistant and resistance-reducing protective film and a preparation process thereof. According to the invention, the raw materials such as polyethylene glycol, a modified fluorosilicone monomer, isophorone diisocyanate, hydroxyethyl acrylate, an acrylic antifouling monomer, dodecafluoroheptyl methacrylate and the like are added to prepare the anti-drag coating. Mixing a polyurethane thermoplastic elastomer, aminopropyl polydimethylsiloxane, an antioxidant and an ultraviolet light absorber, and carrying out melt extrusion and blow molding to form a film, so as to obtain a flexible impact-resistant base film; and uniformly coating the surface of the flexible anti-impact base film with the anti-drag coating, and carrying out ultraviolet curing to obtain a finished product. The finished product prepared by the invention has good impact resistance, and can effectively reduce frictional resistance, so that the finished product has wide application prospects in the technical field of polyurethane films.

The invention discloses a water-based multi-layer degradable self-polishing ship antifouling coating system and a preparation method thereof, and belongs to the field of marine anticorrosion and antifouling materials. The system is composed of a zinc-rich primer, a modified epoxy intermediate paint and a functionalized finish paint. The finish paint takes polyhydroxyalkanoate as a matrix, and integrates a self-stratification modifier capable of forming a silicon-rich top layer during curing and a latent dual-curing system capable of realizing normal-temperature curing through a synergistic effect. According to the present invention, the mixing mechanism of dynamic self-polishing and static fouling release is adopted, and the innovative curing technology is combined, such that the long working life, the excellent mechanical property and the long-acting antifouling ability are achieved. The drawing adhesive force of the system is not lower than 7.9 MPa, and the environment-friendly requirements that the content of volatile organic compounds is smaller than or equal to 50 g / L, and the content of free diisocyanate monomers is smaller than or equal to 0.1 wt% are met.

The invention relates to the technical field of films, in particular to a flexible film special for a handwriting board and a preparation method of the flexible film. The flexible film is obtained by coating a release film with coating slurry and carrying out thermocuring, wherein the coating slurry contains modified polyurethane, a flatting agent, a defoaming agent and ethyl acetate. According to the modified polyurethane, polycarbonate diol, isophorone diisocyanate and other raw materials are subjected to a reaction, and a nano particle chain extender containing disulfide bonds is added. The nano particle chain extender containing disulfide bonds is prepared by modifying nano silicon dioxide and grafting cystamine dihydrochloride and diamino polyethylene glycol. Through nanoparticle surface modification and dynamic disulfide bond network construction, molecular-level coupling of a rigid reinforced phase and a flexible substrate, inhibition of nanoparticle aggregation and balance of strength and toughness are realized, the dynamic disulfide bond network can self-repair microcracks, and a high-quality special flexible film solution is provided for a high-performance handwriting board.

The invention provides a hydrophilic modified HDPE composition and application thereof, and relates to the technical field of composite materials. The hydrophilic modified HDPE composition is prepared from the following raw material components in parts by weight: 100 parts of HDPE and 1 to 10 parts of a hydrophilic anthraquinone compound. Preferably, the raw material component also can comprise 0.1-2 parts of a carbon-based material. The hydrophilic anthraquinone compound is obtained by reacting an anthraquinone compound with a diisocyanate compound and then reacting with a hydrophilic compound. According to the hydrophilic modified HDPE composition disclosed by the invention, the hydrophilicity of HDPE is improved, and an anthraquinone structure is introduced, so that the denitrification effect on nitrogen-containing sewage can be improved.

The invention is applicable to the technical field of daily cleaning chemicals, and provides a double-shell probiotic microcapsule which comprises probiotics, a fat-soluble plant extract, cellulose nanocrystals, a polyacrylic acid-chitosan compound, a surfactant, diisocyanate, polyethylene glycol and ethyl acetate. A wall material of the microcapsule is formed by compounding a polyacrylic acid-chitosan compound and a fat-soluble plant extract, the particle size D50 is smaller than or equal to 5 microns, the microcapsule is stable in an environment with the pH being 8-10, and the microcapsule is broken to release probiotics when the pH is smaller than or equal to 6. The outer layer is polyacrylic acid / chitosan compound / polyurethane crosslinking (pH response), the inner layer is coconut oil and soybean oil (fat-soluble core), meanwhile, the material preparation process is simple, the controllable degree is high, and the material is suitable for batch preparation.

The invention relates to the technical field of fibers, and discloses a high-elasticity polyurethane flame-retardant fiber, a preparation method and application of the high-elasticity polyurethane flame-retardant fiber to a telescopic electric wire. The preparation method comprises the following steps: by using 1, 1, 3, 3-tetramethyldisiloxane as a bridging agent through hydrosilylation reaction, connecting allyl modified DOPO with allyl phenoxy cyclotriphosphazene to prepare a flame retardant with three flame-retardant elements of phosphorus, nitrogen and silicon at the same time; the preparation method comprises the following steps: preparing a polyurethane urea solution by a method of adding 4, 4-diphenylmethane diisocyanate in batches, introducing a flame retardant, mixing the polyurethane urea solution with an antioxidant, a dyeing assistant and a delustering agent, and carrying out dry spinning to obtain the high-elasticity polyurethane flame-retardant fiber. The polyurethane fiber has excellent flame retardant property and heat resistance, and good mechanical property and resilience, and can be applied to telescopic electric wires.

The invention discloses a polyurethane protective adhesive tape for aviation and a preparation method thereof, and relates to the technical field of adhesives. When the polyurethane protective adhesive tape for aviation is prepared, polyester glycol, an ultraviolet absorption monomer, 3-(4-pyridyl) pentane-1, 5-diol, 1, 4-butanediol and isophorone diisocyanate are polymerized to prepare polyurethane; the preparation method comprises the following steps: carrying out a reaction on polyurethane and 2-bromoethyl acrylate to prepare modified polyurethane; enabling the pretreated magnesium hydroxide to react with 3-epoxypropoxy-1, 1, 3, 3-tetramethyldisiloxane and ammonia water in sequence, so as to obtain modified magnesium hydroxide; the modified polyurethane and the modified magnesium hydroxide are mixed and then subjected to compression molding to prepare a polyurethane film; and coating a polyurethane film with the polyacrylate glue solution, and drying to obtain the polyurethane protective adhesive tape for aviation. The polyurethane protective adhesive tape for aviation prepared by the invention has excellent flame-retardant, anti-aging, antibacterial and self-repairing properties.

The invention relates to an automobile paint surface protective film agent and a preparation method thereof, and belongs to the technical field of automobile beauty. The automobile paint surface protective film agent is prepared from the following raw materials: amino functional polysiloxane, fluorine modified acrylic resin, epoxy modified organic silicon emulsion, functional filler, a surfactant, hydrophobic modified silicone oil, a brightening agent, a penetrating agent, a cosolvent and deionized water, and the raw materials are blended to prepare the automobile paint surface protective film agent. The functional filler is prepared by firstly carrying out surface modification on a polymer and then carrying out click chemistry on dodecanethiol on hydroxylated nano silicon dioxide, and the polymer is prepared by carrying out nucleophilic addition on poly (ethylene glycol) methacrylate Mn360, poly (ethylene glycol) methacrylate Mn500 and isophorone diisocyanate. The automobile paint surface protective film agent is high in film forming speed, a formed film layer has the characteristic of multiple effects, and meanwhile, the wear resistance is also very good.

The invention discloses a silk protein-MXene composite film and a preparation method thereof. The silk protein-MXene composite film sequentially comprises a conductive surface layer, a porous response layer and a supporting bottom layer from top to bottom, the invention relates to the technical field of composite films. According to the fibroin-MXene composite film and the preparation method thereof, a three-layer gradient structure is formed by the conductive surface layer, the porous response layer and the supporting bottom layer, good conductivity and electromagnetic shielding effectiveness are ensured by utilizing oriented arrangement of MXene of the conductive surface layer, gallic acid and MXene form a hydrogen bond network, and nitrogen-doped carbon quantum dots coat the surface of MXene to form a physical barrier, so that the electromagnetic shielding effect is improved, and the electromagnetic shielding effect is improved. Through double oxidation resistance of gallic acid and nitrogen-doped carbon quantum dots, a sponge body structure formed by the porous response layer is matched to endow the composite film with high-sensitivity response to external stimulation, the supporting bottom layer is crosslinked by hexamethylene diisocyanate and enhanced by nanocellulose, the tensile strength is improved, and the tensile strength of the composite film is improved. And the contradiction between the mechanical property and the conductivity of the traditional composite film is effectively solved.

The invention relates to the technical field of polyurethane acrylate, and particularly discloses dual-curing polyurethane acrylate resin and a preparation method thereof. Wherein the dual-curing polyurethane acrylate resin is prepared from the following raw materials: polyester polyol, polyether polyol, diisocyanate, hydroxyl acrylate, a chain extender, a photoinitiator, cardanol glycidyl ether, a polymerization inhibitor and modified nanoparticles. Wherein the citric acid and the polyethyleneimine are adopted to carry out synergistic modification on the nano particles, the dispersion stability of the nano particles is improved, so that the mechanical property of the resin is improved, the cardanol glycidyl ether and the photoinitiator generate a synergistic effect, and the resin can be quickly shaped through photocuring promoted by the photoinitiator; the cardanol glycidyl ether participates in the subsequent thermocuring reaction, so that the curing effect is improved, and the adhesive force between the film layer and the base material is enhanced.

The invention discloses a wear-resistant vehicle body film and a preparation method thereof, and relates to the technical field of films. The wear-resistant automobile body film prepared by the invention is prepared from polytetrahydrofuran ether glycol, isophorone diisocyanate, a catalyst, dihydric alcohol quaternary ammonium salt, a functional aid, modified silicon dioxide and a chain extender. The dihydric alcohol quaternary ammonium salt is obtained by reacting N, N '-dihexyl-N, N'-dimethyl propane-1, 3-diamine with monochloroacetone and then condensing with glycerol; the functional additive is obtained by reacting 2-boric acid thiophene-4-methyl acetate with 2, 7-dibromofluorene and then carrying out bromination hydrolysis; the modified silicon dioxide is obtained by reacting pretreated silicon dioxide with melamine and then reacting with sodium hypophosphite. The wear-resistant vehicle body film prepared by the invention has good anti-aging, wear-resistant, antibacterial and flame-retardant properties.

The invention relates to the technical field of wastewater treatment, in particular to a multistage composite adsorbent for treating petrochemical wastewater and a preparation method thereof.The preparation method comprises the steps that S1, plant straw powder and 3-aminopropyltriethoxysilane are subjected to a constant-temperature reaction, and aminated plant straw is obtained; s2, carrying out hydrothermal reaction on the aminated plant straw and a cerium nitrate solution to obtain functionalized plant straw; s3, the halloysite nanotubes, glutaraldehyde and the functionalized plant straw are stirred for a reaction, high-temperature carbonization is conducted after the reaction is completed, and composite biochar is obtained; s4, carrying out a reaction on the composite biochar and an amino silane coupling agent to obtain aminated composite biochar; s5, calixarene, toluene diisocynate and the aminated composite biochar are subjected to a reaction, and the multi-stage composite adsorbent is obtained. According to the technical scheme, the comprehensive adsorption capacity and removal efficiency of various organic pollutants in the petrochemical wastewater are improved, and the defect that a traditional adsorbent is poor in selectivity is overcome.

The invention discloses a quick-curing polyurethane seamless expansion joint material for roads and a preparation method, and belongs to the technical field of road engineering materials. The material is prepared from polyether polyol, polycaprolactone glycol, a bisphenol A epoxy-polyether block isocyanate terminated prepolymer, a methyl phenyl silicon-boron hybrid hydroxyl chain extender, diphenylmethane diisocyanate, calcium carbonate, wollastonite, a hindered amine anti-aging agent and dioctyl phthalate. Wherein the bisphenol A epoxy-polyether block isocyanate terminated prepolymer is prepared by the following steps: reacting bisphenol A with epoxy chloropropane to generate epoxy resin, reacting with polytetramethylene ether glycol, and introducing isophorone diisocyanate; the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation and ethylene glycol reaction on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester; and the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester. The material has the advantages of quick curing property, weather resistance and high-temperature stability, and is suitable for road seamless expansion joint scenes.

The invention relates to a hyaluronic acid-polyurethane composite material based on a double dynamic network and a preparation method and application thereof, and the preparation method comprises the following steps: carrying out hydrophobic modification reaction on hyaluronic acid and aminophenylboronic acid to obtain aminophenylboronic acid modified hyaluronic acid; the preparation method comprises the following steps: mixing polytetrahydrofuran ether glycol, polyethylene glycol and isophorone diisocyanate, carrying out a primary reaction, adding trimethylolpropane tri (3-mercaptopropionic acid) ester, carrying out a secondary reaction, adding tannic acid, and carrying out a third reaction to obtain tannic acid-terminated dynamic thionocarbamate polyurethane; and mixing the amino phenylboronic acid modified hyaluronic acid with the tannic acid terminated dynamic thionocarbamate polyurethane for reaction to obtain the hyaluronic acid-polyurethane composite material with the double dynamic networks. Compared with the prior art, by introducing a'thionocarbamate-borate 'double-dynamic network, high toughness, high strength, good self-repairability and repeatable processability in an extreme environment are realized, and the material is particularly suitable for manufacturing and repairing of key components in an LNG ship body and a heat insulation system thereof.

Disclosed in the present invention are a reinforced polyurethane rigid foam material and a preparation method therefor, belonging to the technical field of high polymer materials. The material comprises: 5-10 parts of glass fiber yarn, 40-60 parts of an aromatic polyether polyol, 30-50 parts of an aromatic polyester polyol, 30-50 parts of toluene diisocyanate, 40-60 parts of polymethylene polyphenyl polyisocyanate, 5-10 parts of a flame retardant, 5-15 parts of a foaming agent, 1-5 parts of a catalyst and 1-5 parts of a surfactant. The present invention can achieve continuous production of the reinforced polyurethane rigid foam material and can improve the tensile property of the material by 20% or above and increase the utilization rate of glass fibers by 5% or above. The reinforced polyurethane rigid foam material can be widely applied to the field of liquefied gas storage and transportation.

The present invention discloses a high-gloss environmentally friendly UV-curable luminous ink and a preparation method thereof, which belongs to the technical field of UV-curable luminous ink. The ink comprises the following raw materials in parts by weight: 78 to 84 parts of bio-based polyurethane prepolymer, 38 to 45 parts of bio-based acrylate monomer, 10 to 15 parts of modified 2,4,6-trimethylbenzoylphenylphosphonic acid ethyl ester as UV curing initiator, 11 to 16 parts of luminous powder, 7 to 10 parts of micro powder filler, and 4 to 8 parts of auxiliary agent; the bio-based polyurethane prepolymer is obtained by reacting castor oil, resorcinol, fructose and 1,5-pentamethylene diisocyanate in a weight ratio of 8 to 12:2 to 3:13 to 17:4 to 9. In the above manner, the prepared high-gloss environmentally friendly UV-curable luminous ink is coated on a substrate and then subjected to UV light curing treatment (curing energy 2800mJ / cm 2 ), the thickness of the cured film can be controlled more loosely, and the cured film thickness can be controlled at 8-12μm. The cured film has good coating appearance, friction resistance, stain resistance and gloss.

This invention discloses a visible-light-responsive dynamically covalently cross-linked self-healing polyurethane and its preparation method, belonging to the field of self-healing materials technology. The material is prepared by reacting diisocyanate, long-chain diol, butanediol, trimethylolpropane, and a monool containing an azophenylboronic acid structure in a certain proportion at 60°C. This invention achieves visible-light-responsive self-healing of the polyurethane material by introducing a visible-light-responsive azophenylboronic acid structure into the polyurethane and utilizing the photoresponsive cis-trans isomerization of the azo structure to regulate the reversible breakage and recombination of the boron-oxygen hexacyclic ring. The visible-light-responsive dynamically covalently cross-linked self-healing polyurethane material prepared by this invention maintains high mechanical strength (16.47 MPa) while exhibiting a strength self-healing efficiency of 95.8% after 8 hours of visible light irradiation, showing broad application prospects in smart materials, anti-corrosion coatings, and other fields.

The invention belongs to the technical field of high polymer materials, and particularly relates to bio-based light-cured polyurethane acrylate resin as well as a preparation method and application thereof. The preparation method of the bio-based light-cured polyurethane acrylate resin comprises the following steps: (1) mixing a catalyst, a first polymerization inhibitor, first hydroxyl acrylate and itaconic acid, stirring and reacting at 90-120 DEG C for 6-9 hours to obtain a reaction product, then adding epoxidized soybean oil, and stirring at 90-120 DEG C for 3-5 hours to obtain a prepolymer; and (2) cooling the prepolymer obtained in the step (1) to room temperature, dropwise adding second acrylic hydroxyl ester and diisocyanate, and then stirring and reacting at 30-60 DEG C for 1.5-4 hours until an NCO infrared peak value disappears, thereby obtaining the polyurethane acrylate. The resin is high in bio-based content, moderate in viscosity, good in flexibility, high in hardness, strong in adhesive force, high in glossiness, small in smell and good in storage stability, and is suitable for being applied to preparation of UV curing coatings, UV curing printing ink, UV curing adhesives, 3D printing materials and nail polish glue.

The invention relates to the technical field of marine antifouling materials, in particular to a modified polyurethane marine antifouling coating based on a metal pyridine structure and a preparation method. According to the modified polyurethane marine antifouling paint based on the metal pyridine structure, polyhydric alcohols and diisocyanate monomers with different molecular weights are subjected to condensation polymerization to obtain a polyurethane prepolymer; then reacting a diaminopyridine monomer or a dihydroxypyridine monomer with a metal ion compound to obtain a chain extender with a metal pyridine structure; finally, the marine antifouling paint is prepared through the reaction between the terminal amino or hydroxyl of the metal pyridine structure chain extender and the terminal isocyanate group of the polyurethane prepolymer, the metal pyridine structure is introduced into polyurethane, the mechanical performance of the marine antifouling paint is enhanced, the marine antifouling paint is endowed with the antibacterial effect through metal ion release, and the service life of the marine antifouling paint is prolonged. Adhesion and growth of marine fouling organisms can be effectively inhibited, and an efficient and durable solution is provided for development of a polyurethane marine antifouling coating.

The present invention relates to the technical field of coatings and discloses a method for preparing an EVA waterproof coating. Activated montmorillonite reacts with toluene diisocyanate to obtain isocyanate-modified montmorillonite. EVA is hydrolyzed under the catalysis of potassium hydroxide to obtain hydroxylated EVA. An epoxy trisiloxane intermediate reacts with terephthalic acid under ring-opening esterification with benzyltriethylammonium chloride to obtain p-hydroxytrisiloxane benzoate. P-hydroxytrisiloxane benzoate, hydroxylated EVA, and isocyanate-modified montmorillonite are cross-linked with toluene diisocyanate under the catalysis of stannous octoate, and a defoamer and a dispersant are added thereto and stirred uniformly to obtain an EVA waterproof coating. The EVA waterproof coating prepared by the present invention has good mechanical properties and waterproof properties.

The invention relates to the technical field of layered composite fabrics, in particular to a bio-based antibacterial fiber fabric and a preparation method thereof. The preparation method comprises the following steps: carrying out a reaction on diisocyanate, polyether polyol, bio-based polyester polyol and hexamidine dihydroxyethyl sulfonate in N, N-dimethylacetamide, so as to obtain a polyurethane prepolymer solution; 2-(4-aminophenyl)-5-aminobenzimidazole and amino-modified nano-zinc oxide are sequentially added into the polyurethane prepolymer solution for a reaction, a prepared polyurethane spinning solution is subjected to dry spinning to prepare polyurethane fibers, and then the polyurethane fibers are sequentially spun into yarn and fabric; the bio-based nylon is subjected to melt spinning to obtain bio-based nylon fibers, and the bio-based nylon fibers are sequentially spun into yarns and fabrics; the bio-based antibacterial fiber fabric is prepared by taking a polyurethane fabric as an inner-layer fabric and taking a bio-based chinlon fabric as an outer-layer fabric, and the fabric is good in antibacterial performance and moisture absorption performance.

The invention relates to the technical field of high polymer materials, in particular to high-strength and high-toughness modified plastic particles as well as a preparation method and application thereof. The preparation method of the high-strength and high-toughness modified plastic particles comprises the following steps: carrying out a reaction on MMT / CNTs and diisocyanate to prepare isocyanate-based MMT / CNTs; the preparation method comprises the following steps: reacting isocyanate-based MMT / CNTs with glycerol 1, 3-diglycerol alkyd diacrylate to prepare MMT / CNTs containing alkenyl groups; the preparation method comprises the following steps: carrying out grafting reaction on maleic anhydride, alkenyl-containing MMT / CNTs and POE (Polyolefin Elastomer) to prepare a modifier; and carrying out melt blending, extrusion, cooling and pelletizing on the modifier, the auxiliary agent and PA6 to obtain the high-strength and high-toughness modified plastic particles. The nano filler MMT / CNTs and the polyolefin elastomer POE are introduced, so that the modified plastic particles taking the PA6 as the matrix have high strength and high toughness.

The invention discloses a large-current-carrying-capacity flexible power cable, which belongs to the technical field of cable preparation, is used for solving the technical problem that the flame retardant property and the mechanical property of the power cable need to be further improved in the prior art, and specifically comprises a cable core, a wrapping layer, an insulating layer and a sheath layer which are sequentially arranged from inside to outside. The preparation method comprises the following steps: preparing alkoxy silane containing a benzocyclobutene group, preparing flame-retardant particles by using a sol-gel method, preparing modified polyurethane by using modified polysiloxane and 2, 5-furandimethanol as soft segments, naphthalene diisocyanate as a hard segment and trimethylolpropane as a chain extender, and preparing the flame-retardant flame-retardant polyurethane. The linear low-density polyethylene, the MAH-g-PE, the modified polyurethane, the flame-retardant particles and the auxiliary additive are melted and extruded outside the wire core to form the insulating layer, so that the power cable is obtained, the flame-retardant property of the power cable is effectively improved, and the mechanical property and the current-carrying stability of the power cable are also improved.

The invention belongs to the technical field of polyurethane waterproof coatings, and particularly relates to a single-component fluorine-free high-hydrophobicity polyurethane waterproof coating and a preparation method thereof, and the single-component fluorine-free high-hydrophobicity polyurethane waterproof coating comprises the following raw materials by weight: 60-80 parts of composite polyether polyol; 20 to 40 parts of silane modified polyether polyol; 11 to 17 parts of diisocyanate; 2-5 parts of a chain extender; 50 to 70 parts of a plasticizer; 50 to 70 parts of filler; 0.15 to 0.2 part of a catalyst; and 3-5 parts of an auxiliary agent. A polyoxypentene ether chain segment, a castor oil-based structure and a silane group are introduced into the molecular structure of the waterproof coating through chemical modification, the intrinsic hydrophobic and mechanical properties of the material are improved, the migration defect caused by addition of a hydrophobic agent and silicone oil in a traditional preparation method is overcome, and the invention further provides a preparation method of the waterproof coating.

The invention relates to the technical field of polyurethane impermeable materials, and particularly discloses a high-molecular impermeable material with oil resistance and impermeability as well as a preparation method and application thereof, and the high-molecular impermeable material comprises the following components in parts by weight: 120 parts of a polyurethane prepolymer, 20-45 parts of a diluent, 10-30 parts of an auxiliary agent, 15-20 parts of a micro-powder filler, 10-15 parts of carboxymethyl cellulose and 3-8 parts of dibasic hydrogen phosphate; wherein the polyurethane prepolymer is prepared from a diisocyanate compound and polyether polyol through a reaction; wherein the micro powder filler is a mixture of sodium acrylate hydrogel micro powder and sodium alginate hydrogel micro powder; wherein the dibasic hydrogen phosphate is monovalent ion salt. The high-molecular anti-seepage material has excellent anti-seepage performance in an oil storage environment, has relatively high adhesive force, and can be suitable for grouting in a humid environment; and water resistance and oil resistance of an underground water-sealed stone cavern oil depot environment can be better realized.

The invention discloses high-resistance self-extinction waterborne polyurethane resin as well as a preparation method and application thereof, the preparation method comprises the following steps: S1, uniformly mixing polymeric polyol, a catalyst, a carboxylate hydrophilic chain extender and a micromolecule chain extender to obtain a mixed system; s2, diisocyanate is added into the mixed system in the step S1 for a reaction, and an addition product is obtained; s3, after the addition product obtained in the step S2 is cooled to the room temperature, adding an organic solvent, and then adding a neutralizer for neutralization to obtain a waterborne polyurethane prepolymer; s4, a sulfonate chain extender is added into the waterborne polyurethane prepolymer prepared in the step S3 for reaction, water is added for emulsification, and waterborne polyurethane emulsion is obtained; and S5, dispersing an amine chain extender with water, adding the dispersed amine chain extender into the waterborne polyurethane emulsion obtained in the step S4, and carrying out a reaction so as to obtain the high-resistance self-extinction waterborne polyurethane resin. According to the preparation method, function integration is realized, the production process is simplified, and the production efficiency is improved.

The invention discloses a flame-retardant thermoplastic polyurethane elastomer material and a preparation method thereof, and belongs to the technical field of modified nano materials. The preparation method comprises the following steps: dissolving melamine, phytic acid and boron nitride in deionized water, carrying out oil bath, adding a coupling agent, stirring, carrying out vacuum filtration, washing with water, and drying to obtain a layered nano flame retardant; the preparation method comprises the following steps: dispersing a flame retardant in deionized water containing a nonionic dispersant, and carrying out ultrasonic treatment; the preparation method comprises the following steps: reacting polyether polyol with diisocyanate to obtain a primary prepolymer; adding other auxiliary agents, stirring, and carrying out gradient heating polymerization; and injecting into a mold, curing for 6-12 hours at 105-125 DEG C, and drying for 12-24 hours at 80-90 DEG C. A phosphorus-nitrogen-silicon ternary synergistic flame-retardant system is introduced, the boron nitride nanosheet surface grafting and dynamic pre-polymerization-gradient heating process is optimized, the dispersity is improved, and smoke suppression and thermal stability are achieved. Compared with the prior art, the flame retardant efficiency is high, the mechanical property is excellent, and environmental friendliness is achieved.