420 results about "Polypropylene glycol" patented technology

The invention relates to the technical field of proton exchange membranes, and provides a covalent grafted heteropoly acid modified perfluorosulfonic acid membrane as well as a preparation method and application thereof. According to the invention, polypropylene glycol monoalkyl ether and Keggin type vacancy heteropoly acid are subjected to covalent grafting, and then the obtained covalent grafted heteropoly acid is used as an additive to modify the perfluorosulfonic acid membrane, so that the leakage problem of heteropoly acid in the proton exchange membrane can be effectively relieved, and meanwhile, the excellent proton conduction performance of heteropoly acid is also retained; moreover, the polypropylene glycol monoalkyl ether has relatively large molecular weight, so that the heteropoly acid can be anchored more firmly in the perfluorosulfonic acid membrane, and the proton conduction capability of the heteropoly acid is fully exerted. The result of the embodiment shows that the covalent grafted heteropoly acid modified perfluorosulfonic acid membrane provided by the invention shows excellent proton conduction performance and chemical stability, and has a wide application prospect.

The invention discloses a low-staining low-viscosity waterborne polyurethane macromolecular coloring agent and a preparation method of the low-staining low-viscosity waterborne polyurethane macromolecular coloring agent. Comprising the following components in parts by weight: 15 to 30 parts of aliphatic diisocyanate, 15 to 30 parts of micromolecular dye, 10 to 30 parts of polypropylene glycol and / or dihydroxy silicone oil, 25 to 50 parts of polyethylene glycol, 1 to 3 parts of micromolecular dihydroxy compound chain extender, 0.05 to 0.3 part of catalyst, 90 to 140 parts of acetone and 50 to 300 parts of water. By designing the hydrophilicity and proportion of the soft and hard segments of the polyurethane coloring agent, the waterborne polyurethane macromolecular coloring agent color paste which is low in staining, easy to clean, less than 1000mpas in product viscosity, more than 5% in color concentration and more than 5% in dye equivalent and good in compatibility is finally obtained, and the waterborne polyurethane macromolecular coloring agent color paste can meet the requirements of liquid product coloring agents such as clothing care and household cleaning agents. The cleaning agent can also be used for liquid cleaning agent products for body care and catering.

The present invention discloses an infrared-shielding polyurethane glass film and a preparation method thereof, relating to the field of polymer materials technology. When preparing the infrared-shielding polyurethane glass film, the present invention comprises reacting an organic nickel complex and 3-imidazole-1-propionic acid to produce a functionalized crosslinker; sequentially reacting 4-aminophenylacetonitrile with 3-hydroxypropyl acrylate and quinoline-4-carboxaldehyde to produce a UV-absorbing monomer; reacting polypropylene glycol, a UV-absorbing monomer, 1,4-butanediol, and 4-chloromethyl-1,3-phenylenediisocyanate to polymerize to produce polyurethane; reacting tungsten-doped titanium dioxide and chloropropyltriethoxysilane to produce modified titanium dioxide; and uniformly mixing the polyurethane, modified titanium dioxide, the functionalized crosslinker, and acetone, followed by coating and curing to produce the infrared-shielding polyurethane glass film. The infrared-shielding polyurethane glass film prepared by the present invention has excellent infrared shielding, anti-aging, antibacterial, and mechanical properties.

The invention relates to hot baking type selective ink and a preparation method thereof. The hot baking type selective ink comprises the following components in parts by mass: 10-20 parts of acrylic resin, 10-20 parts of fluorine-containing polyacrylate, 20-40 parts of an active monomer, 3-10 parts of a photoinitiator, 5-20 parts of modified boron nitride and 1-10 parts of an auxiliary agent, wherein the modified boron nitride is obtained by reacting boron nitride with a silane coupling agent and polypropylene glycol diglycidyl ether. The fluorine-containing polyacrylate is obtained by reacting fluorine-containing acrylate, acrylate and maleic anhydride. According to the invention, not only are the film-forming property and the stability of the ink improved, but also the corrosion resistance, the strength and other properties are enhanced, the protective effect can be more effectively exerted, the stable operation of the PCB is ensured, the problems in the prior art are solved, the requirements of the industry on multiple properties of products are met, and the application prospect is good.

The invention provides a water-in-oil adjuvant for animal vaccines and a preparation method and application thereof, and relates to the technical field of biology, the water-in-oil adjuvant comprises 73%-75% of oil for injection, 20%-23% of an emulsifier and 2%-7% of a stabilizer; the emulsifying agent is prepared from 4.5 percent to 5 percent of polyoxyethylene fatty alcohol ether, 3.0 percent to 3.5 percent of glycerol monoisostearate, 7.0 percent to 8.0 percent of span 80, 4.5 percent to 5 percent of Tween 80 and 1 percent to 1.5 percent of vitamin E; the vaccine prepared from the water-in-oil adjuvant has the advantages that the viscosity is reduced, and the injection is easy. The technical problems that in the prior art, a vaccine prepared from an oil-in-water adjuvant is large in viscosity, so that resistance is large during injection, the occurrence rate of side reactions is high, an injection part swells, and granuloma is formed are solved.

The invention relates to the field of inorganic material preparation, and particularly discloses pseudo-boehmite and a preparation method thereof. A preparation method of pseudo-boehmite comprises the following steps: (1) mixing an aluminum salt solution and an aluminate solution, adding a crystal form regulating agent, and stirring for reaction to obtain a sol system; the crystal form regulating agent is ZnS quantum dots modified by thiohydracrylic acid; (2) adding a pore diameter guiding agent into the sol system, and aging for 6-8 hours; the pore diameter guiding agent is a compound of a polyethylene glycol-polypropylene glycol-polyethylene glycol triblock copolymer and sodium citrate; and (3) carrying out solid-liquid separation on the aged sol system, and washing and drying the obtained solid to obtain the pseudo-boehmite. The proportion of 5-10nm pores of the pseudo-boehmite prepared by the preparation method disclosed by the invention reaches 90% or above, so that the pore distribution requirement of a fine catalytic reaction on the pseudo-boehmite can be met, and the efficient catalytic reaction is favorably realized.

The invention belongs to the technical field of 3D printing photocuring, and particularly relates to photocuring organic silicon modified polyurethane acrylate resin as well as preparation and application thereof. According to the invention, isophorone diisocyanate is used as a hard segment, polypropylene glycol-1000, dimethylolpropionic acid and dihydroxy-terminated silicone oil are used as soft segments, and the light-cured organic silicon modified polyurethane acrylic resin is synthesized with pentaerythritol triacrylate. By controlling the hydroxyl content in the double-terminal hydroxyl silicone oil and the proportion of the double-terminal hydroxyl silicone oil in a soft segment, the prepared organic silicon modified polyurethane acrylic resin has better flowability and light transmittance and higher double bond content; the organic silicon modified polyurethane acrylic resin, the acryloyl morpholine and the photoinitiator are cured according to a specific proportion, and the obtained elastomer has good mechanical properties and thermal stability and has high printing precision. The synthesized organic silicon modified polyurethane acrylate resin has the potential of replacing a traditional polyurethane acrylate material.

The invention discloses a two-component epoxy pouring sealant as well as a preparation method and application thereof, and belongs to the technical field of high polymer materials. The bi-component epoxy pouring sealant comprises a component A and a component B. The component A comprises the following raw materials: 60-100 parts of modified epoxy resin; 5-25 parts of a reactive diluent; 1 to 10 parts of nano silicon dioxide; the component B comprises the following raw materials in parts by mass: 50-60 parts of an alicyclic amine curing agent; 20-30 parts of a polyether amine curing agent; 10 to 15 parts of methyl tetrahydrophthalic anhydride; 3-5 parts of a silane modifier; 0.1 to 0.5 part of a defoaming agent; the modified epoxy resin is prepared by carrying out esterification reaction on bisphenol A type epoxy resin and long-chain fatty acid for modification and then carrying out graft modification with polypropylene glycol diglycidyl ether. In addition, the invention also provides a preparation method of the two-component epoxy pouring sealant. The epoxy pouring sealant provided by the invention has excellent bonding performance on non-polar plastics such as PP / PE and the like.

The present invention provides an epoxy resin adhesive and a preparation method thereof, and relates to the technical field of building structure adhesives, the epoxy resin adhesive is prepared from a component A and a component B, the component A comprises the following raw materials by weight: 90-110 parts of epoxy resin, 15-25 parts of a toughening agent, 40-50 parts of a filler I and 15-20 parts of benzyl alcohol, and the toughening agent comprises polycarbonate, polyamide and polypropylene glycol diglycidyl ether; the component B is prepared from the following raw materials in parts by weight: 40 to 60 parts of curing agent, 10 to 20 parts of filler II, 1.5 to 3 parts of polyvinylpyrrolidone and 5 to 10 parts of benzyl alcohol. The preparation method comprises the following steps: S1, preparing A glue; s2, preparing B glue; and S3, mixing glue. The toughening agent is added in the component A, polycarbonate, polyamide and polypropylene glycol diglycidyl ether are selected as the toughening agent, the three raw materials are compounded and cooperated, the processability and flowing property of the epoxy resin adhesive can be effectively improved, and the problems that a cured finished product is high in brittleness and poor in impact resistance are solved.

The invention relates to a liquid detergent composition comprising a first surfactant selected from fatty alcohol ether sulfates, a second surfactant selected from betaines, optionally at least one solvent selected from ethanol, propanol, isopropanol, ethylene glycol, butyl glycol, propylene glycol, polypropylene glycol, alcoholamine, monoethanolamine, glycerol and mixtures thereof, wherein the salt concentration in the composition is about 0.2 to about 10 wt.-% and wherein the salt is selected from the group consisting of sodium salts such as sodium chloride, sodium sulfate, sodium formate, sodium acetate or sodium propionate, potassium salts such as potassium chloride, potassium sulfate, potassium formate, potassium acetate or potassium propionate, magnesium salts such as magnesium chloride, magnesium sulfate, magnesium formate, magnesium acetate or magnesium propionate, and calcium salts such as calcium chloride, calcium sulfate, calcium formate, calcium acetate or calcium propionate, and mixtures thereof, and wherein the composition is a concentrate that can be diluted with water while maintaining or increasing the viscosity.The present invention further relates to the use of such a cleaning composition for cleaning hard surfaces, in particular dishes, and to a process for preparing a cleaning composition, the process comprising diluting the concentrated liquid cleaning composition with water.

The invention belongs to the technical field of waterborne polyurethane dispersions, and particularly discloses a bio-based waterborne polyurethane printing adhesive and a preparation method thereof. The bio-based waterborne polyurethane printing adhesive is prepared from the following raw materials in parts by mass: # imgabs0. The bio-based waterborne polyurethane printing adhesive is prepared from bio-based polymer polyols, such as polytetrahydrofuran ether glycol and polypropylene glycol with 100% bio-based content, polycarbonate diol with 50-70% bio-based content, polyethylene glycol with 50-70% bio-based content, polyethylene glycol with 50-70% bio-based content and polyethylene glycol with 50-70% bio-based content, wherein the bio-based polymer polyols are similar to or completely identical to a petroleum-based structure; the characteristics of the traditional petroleum-based waterborne polyurethane printing adhesive are maintained; the prepared bio-based waterborne polyurethane printing adhesive has high bio-based content and is unique in the field of waterborne printing.

The invention relates to the technical field of low-zinc composite active agents, in particular to a low-zinc efficient composite active agent for blended rubber and a preparation method thereof.The preparation method comprises the following steps that zinc acetate, zinc nitrate, zinc sulfate and urea are mixed to prepare nano-zinc oxide, and the nano-zinc oxide is modified with polypropylene glycol to obtain modified nano-zinc oxide; mixing and stirring a dispersing agent, stearic acid, modified nano zinc oxide, multi-walled carbon nanotubes and magnesium oxide under the protection of inert gas to prepare a blend, and curing and molding the blend through a condensation granulation process to obtain the low-zinc high-efficiency composite activator for blended rubber. The prepared low-zinc efficient composite active agent for the blended rubber shortens the vulcanization time of the blended rubber, is excellent in dispersity and enhances the mechanical properties, including tensile strength and elongation at break, of the blended rubber, and in addition, the preparation method is simple and convenient to operate and low in cost and has a good industrial application prospect.

The invention relates to the technical field of composite coating preparation materials for battery diaphragms, in particular to a composite coating for a battery diaphragm as well as a preparation method and application. The invention discloses a graphene quantum dot / carbon nanotube composite material, which is prepared from the following components in percentage by weight: 3 to 8 percent of aminated graphene oxide-polydopamine graft, 10 to 18 percent of polyimide-polyetheretherketone-nano SiO2 hybrid, 2 to 5 percent of hydroxyapatite-montmorillonite core-shell particles, 0.5 to 3 percent of zinc borate-melamine cyanurate compound, 1 to 3 percent of graphene quantum dot-carbon nanotube hybrid, 2 to 6 percent of sodium carboxymethyl cellulose and 50 to 70 percent of deionized water. 0.5 to 2 percent of barium strontium titanate nanocrystalline or 1 to 3 percent of polyethylene glycol-polypropylene glycol segmented copolymer can also be added. All the components are combined through molecular-level reaction to construct a high-performance protection network. The composite coating is good in high temperature resistance and mechanical strength, high in ionic conduction efficiency, excellent in flame retardant effect and good in interfacial compatibility, the preparation process is environmentally friendly and easy to industrialize, the composite coating is suitable for various batteries, and the comprehensive performance of the composite coating is superior to that of a traditional coating.

The invention discloses an infrared shielding polyurethane glass film and a preparation method thereof, and relates to the technical field of high polymer materials. When the infrared shielding polyurethane glass film is prepared, an organic nickel complex and 3-imidazole-1-propionic acid react to prepare a functional cross-linking agent; the preparation method comprises the following steps: reacting 4-aminophenylacetonitrile with 3-hydroxypropyl acrylate and quinoline-4-formaldehyde in sequence to prepare an ultraviolet absorption monomer; the preparation method comprises the following steps: carrying out reaction polymerization on polypropylene glycol, an ultraviolet absorption monomer, 1, 4-butanediol and 4-chloromethyl-1, 3-phenyl diisocyanate to prepare polyurethane; the tungsten-doped titanium dioxide and chloropropyltriethoxysilane are subjected to a reaction, and modified titanium dioxide is prepared; uniformly mixing polyurethane, modified titanium dioxide, a functional cross-linking agent and acetone, and coating and curing to obtain the infrared shielding polyurethane glass film. The infrared shielding polyurethane glass film prepared by the invention has excellent infrared shielding, anti-aging, antibacterial and mechanical properties.

The invention provides bio-based MS base resin, bio-based MS glue and a preparation method of the bio-based MS base resin and the bio-based MS glue, and belongs to the technical field of high polymer materials. The MS base resin is isocyanate group silane terminated bio-based polyether polyol or polyether polyol subjected to chain extension. The polyether polyol is selected from one or more of bio-based polyethylene glycol, bio-based polypropylene glycol, bio-based poly (trimethylene ether glycol) and bio-based polytetrahydrofuran ether glycol. And mixing the bio-based MS base resin, the plasticizer, the filler, the catalyst III, the coupling agent and the auxiliary agent, and stirring under a vacuum condition to obtain the bio-based MS adhesive. The bio-based MS adhesive prepared by the invention is high in bio-based material content, uncomplicated in preparation process and low in energy consumption, and meanwhile, an adhesive body is good in mechanical property, high in stability and good in high temperature resistance and humidity and heat resistance.

The present invention provides: a packaging material which is excellent in terms of breaking resistance and easy tearability; a polyisocyanate composition which is suitable for the manufacturing of this packaging material; and an adhesive.　The present invention specifically provides a polyisocyanate composition (X) which contains a polyisocyanate compound (A), wherein: the polyisocyanate compound (A) contains 60 mass% or more of a bifunctional polyisocyanate compound (A1) that is derived from a non-aromatic diisocyanate; a polyol mixture contains 70 ± 1 mass% of a polypropylene diol that has a hydroxyl value-based number average molecular weight of 415 ± 20 and 30 ± 1 mass% of a polypropylene triol that has a number average molecular weight of 415 ± 35; a coating film, which is obtained by curing with the molar ratio [NCO] / [OH] of the isocyanate groups of the polyisocyanate compound (A) to the hydroxyl groups of the polyol mixture being 1.3 ± 0.1, has an elongation at break of 30% or more as determined at a tensile rate of 200 mm / minute at 25°C and a humidity of 40%.

The invention discloses a high-strength energetic compound based on a polydopamine and thiourea polymer and a preparation method of the high-strength energetic compound, and the energetic compound is composed of energetic crystal 1, 3, 5-triamino-2, 4, 6-trinitrobenzene, the polydopamine and the thiourea polymer. The preparation method comprises the following steps: modifying an energetic crystal 1, 3, 5-triamino-2, 4, 6-trinitrobenzene through polydopamine in advance; the polythiourea is obtained through reaction of 2, 2 '-(ethylene dioxygen) diethylamine, carbon disulfide and trimethylolpropane tripolypropylene glycol ether, and the addition amount is 2.5 wt.%-10 wt.%; and mixing the two components by a kneading method, and drying to obtain the energetic compound. The obtained compound has the characteristics of strengthening and toughening, the Brazil mechanical strength reaches 14.76 MPa, and the fracture strain reaches 0.474%. By introducing polyphenol polydopamine and polythiourea to achieve a synergistic effect, the mechanical property of the explosive is greatly improved, and a technical support can be provided for the application of the explosive; meanwhile, the preparation method is simple, mild in reaction condition and easy for large-scale production.

The invention relates to a composition for a suspension chain modified PSE elastomer, the suspension chain modified PSE elastomer and a preparation method of the suspension chain modified PSE elastomer, and belongs to the technical field of high polymer material science and engineering. The composition is prepared from 55 to 75 weight percent of PUSH resin, 14 to 25 weight percent of bisphenol A epoxy resin, 0.3 to 1 weight percent of accelerant and 10 to 25 weight percent of draping chain compound, the drape chain compound is selected from at least one of phenyl glycidyl ether, C12 to C14 glycidyl ether and cardanol glycidyl ether; wherein the PUSH resin is obtained by polymerizing isocyanate, a combination A and 2, 2 '-(1, 2-ethanedioxy) diethanethiol according to a molar ratio of 1: (0.4-0.6): (0.9-1.1), and the combination A is prepared from polypropylene glycol and polyether triol according to a molar ratio of 1: (0.3-4). The overhanging chain modified PSE elastomer provided by the invention has excellent comprehensive damping performance and especially has a wider damping temperature range.

Hyaluronic acid and silk fibroin or silk fibroin fragments tissue fillers and methods of making and using the same are provided herein. In some embodiments, the disclosure relates to a biocompatible tissue filler comprising silk fibroin or silk fibroin fragments, hyaluronic acid (HA), and polyethylene glycol (PEG) and / or polypropylene glycol (PPG), wherein a portion of the HA is modified or crosslinked by one or more linker moieties comprising one or more of polyethylene glycol (PEG), polypropylene glycol (PPG), and a secondary alcohol, wherein the linker moieties are attached to the HA at one end of the linker.

The invention relates to a preparation method of a stretchable easily-processed and recycled polyimine elastomer, and belongs to the technical field of functional materials. The invention aims to solve the problems that the existing bio-based polymer is complex in preparation process, relatively low in elongation at break and difficult to apply to flexible stretchable materials. The method comprises the following steps: 1, preparing a multi-site prepolymer; 2, adding trimethylolpropane tripolypropylene glycol ether (amino-terminated); and 3, vacuum drying. The preparation method is used for preparing the stretchable easily-processed and recycled polyimine elastomer.

The invention discloses a synthesis method of an M-N-C zinc metal catalyst, which belongs to the field of catalyst synthesis, and comprises the following specific steps: adding a certain amount of zinc nitrate hexahydrate into a mixed solution of ethanol and water, dissolving the zinc nitrate hexahydrate in methanol, adding an addition polymer of polypropylene glycol and ethylene oxide, and carrying out ultrasonic dissolution on the mixture based on ultrasonic equipment, so as to obtain the M-N-C zinc metal catalyst. The preparation method comprises the following steps: dissolving 2-methylimidazole in methanol to obtain a solution A, dissolving 2-methylimidazole in methanol, and stirring to clarify the solution to obtain a solution B; through cooperative use of the devices, the M-N-C zinc metal catalyst with constructed mesopores is obtained, pore channels are graded on the basis of etching and regulation and control of mesoporous pore channels, the half-wave potential of the M-N-C zinc metal catalyst is improved on the basis of pore channel grading, mass transfer of reactants and products is accelerated, pore channel blockage is avoided, and the service life of the M-N-C zinc metal catalyst is prolonged. And through the porous synergistic effect, the transmission path of protons and electrons is shortened, the polarization loss is reduced, and thus the current density is improved.

The invention relates to the technical field of photoluminescent materials, and discloses a migration-resistant benzotriazole photoluminescent material and a preparation method thereof, and the photoluminescent material is a polyether chain segment substituted benzotriazole luminescent material. A polyethylene glycol or polypropylene glycol unit substituent group is introduced into a 4, 7-diphenyl benzotriazole luminescent material, so that the problem that a traditional small-molecular 4, 7-diphenyl benzotriazole luminescent material is easy to migrate and aggregate in an adhesive film is effectively solved. Due to existence of the polyethylene glycol or polypropylene glycol unit, the polyethylene glycol or polypropylene glycol unit can be interwoven and wound with a macromolecular chain of the adhesive film, migration of light conversion agent molecules in a macromolecular material is remarkably reduced, and it is guaranteed that the light conversion function takes effect for a long time; amorphous polyethylene glycol or polypropylene glycol and derivatives thereof are adopted, so that the flexibility of molecules is increased, the compound is in an amorphous state, the stability and processing performance of the material are improved, and meanwhile, the material is more easily and uniformly dispersed in a macromolecular medium.

The invention belongs to the technical field of metal material plating, and particularly relates to a connector surface composite coating and a preparation process thereof, and the preparation process comprises the following steps: adding modified carbon black and sodium molybdate into deionized water, stirring to obtain a corrosion inhibition material, and mixing with modified zinc oxide to obtain a mixed filler; the preparation method comprises the following steps: adding dibutyltin dilaurate and toluene diisocynate into polypropylene glycol to obtain a core material; adding hexadecyl trimethyl ammonium bromide and the mixed filler into a 93-96 wt% ethanol solution, adding the core material for emulsification, adding an isophorone diisocyanate solution, and stirring to obtain a microcapsule; nickel sulfate hexahydrate, nickel chloride hexahydrate, sodium citrate, boric acid, a surface dispersant, a sodium hydroxide solution and microcapsules are added into deionized water to be mixed, and an electroplating solution is obtained; and putting the connector into the electroplating solution for electroplating to obtain the composite coating. The expansion of pitting corrosion can be inhibited, and the long-term use reliability and stability of the connector in a marine environment are improved.

The invention relates to a polyurethane-based composite solid polymer electrolyte film and a preparation method and application thereof, and belongs to the field of organic polymer solid electrolyte preparation. Polyethylene glycol-polypropylene glycol triblock copolymer and hydroxyl-terminated polybutadiene are used as soft segments, isophorone diisocyanate is used as a hard segment, and under the action of a catalyst, the polyurethane-based composite solid polymer electrolyte film is prepared. A chain extender containing disulfide bonds is utilized, and a polyurethane elastomer is prepared through gradual addition polymerization reaction; a polyurethane elastomer and a mixed solution of a lithium salt and a polyvinylidene fluoride-hexafluoropropylene copolymer are uniformly mixed, the polyurethane elastomer accounts for 10%-30% of the mass of the polyvinylidene fluoride-hexafluoropropylene copolymer, a precursor solution is obtained, the precursor solution is prepared into a film, and the polyurethane-based composite solid polymer electrolyte film is obtained. The polymer solid electrolyte membrane with excellent mechanical property and excellent lithium ion conductivity is constructed, and the development requirement of a high-performance lithium metal battery is met.

The invention discloses a paper-plastic composite reactive polyurethane hot melt adhesive for low-temperature coating, and belongs to the technical field of polyurethane adhesives, the paper-plastic composite reactive polyurethane hot melt adhesive for low-temperature coating comprises the following components by weight: 50-70 parts of modified polyester polyol, 30-50 parts of modified polyether polyol, 15-24 parts of diisocyanate, and 5-30 parts of tackifying resin, 0.1-1 part of a catalyst, 5-35 parts of a filler, 0.05-2 parts of a polymerization inhibitor and 0.1-0.5 part of an antioxidant; the modified polyester polyol is modified poly (butylene succinate); the modified polyether polyol is modified polypropylene glycol; the polyurethane hot melt adhesive prepared by modifying 5-norbornene-2-methylamine with a strong polar bond-NH and 3, 7-dimethyl octyl-6-ene-1-alcohol containing an insect-proof and mildew-proof functional component with polyhydric alcohol has relatively low melting temperature and viscosity, has initial viscous force of more than 1N and final viscous force of more than 5N at the same time, and has the characteristics of high temperature resistance, high temperature resistance, high temperature resistance and the like. The method can be well applied to paper-plastic compounding for low-temperature coating.

The invention discloses a high-toughness long-acting steel structure anticorrosive coating material, and relates to the technical field of anticorrosive paint. The anti-rust paint is prepared from the following components in parts by mass: 15 to 20 parts of epoxy resin, 10 to 15 parts of organic silicon polyurethane modified epoxy resin, 5 to 10 parts of organic silicon oligomer containing multiple epoxy groups, 10 to 15 parts of polypropylene glycol diglycidyl ether, 4 to 6 parts of titanium dioxide, 5 to 10 parts of anti-rust pigment, 10 to 20 parts of micaceous iron oxide gray, 2 to 3 parts of auxiliaries, 30 to 40 parts of polyamide 650 and 10 to 15 parts of triethanolamine. The flexibility, the ultraviolet resistance and the corrosion resistance of the anti-corrosion coating material are remarkably improved, and the service life is effectively prolonged.

The application relates to the technical field of solar energy, in particular to a self-cleaning solar photovoltaic panel and a preparation process thereof. The application adds anhydrous ethanol, ammonia water, deionized water, methyl triethoxysilane, tetraethyl orthosilicate and octadecyl trimethoxysilane to prepare silica sol. Then, tetra(2-hydroxyethoxy)silane, polypropylene glycol, toluene diisocyanate, betulin, 3,4-diamino furazan, silica sol and a catalyst stannous octoate are added to prepare a polymer. Glass, ethylene-vinyl acetate copolymer, a cell piece and ethylene-vinyl acetate copolymer are sequentially laid in layers; the laminated assembly is assembled with a frame to obtain a solar photovoltaic panel. Finally, a coating is prepared by taking the polymer as a raw material, and the coating is coated on the solar photovoltaic panel to obtain a finished product. The finished product has good hydrophobicity and antibacterial property, and therefore has a wide application prospect.

The present invention relates to the technical field of polyurethane hydrophobic materials, and discloses a preparation method and application of a hydrophobically modified polyurethane nanocomposite material, comprising the following steps: (1) mixing polytetrahydrofuran, polypropylene glycol, and isophorone diisocyanate for reaction; (2) adding dihydroxy-terminated polydimethylsiloxane or glycerol monostearate to the reaction solution for reaction, then adding a chain extender for reaction, and adding triethylamine for neutralization to obtain a modified waterborne polyurethane emulsion; (3) adding SiO2 powder to octadecyltrichlorosilane for reaction to obtain hydrophobic SiO2 powder; (4) adding the hydrophobic SiO2 powder to ethyl acetate to obtain a first mixed solution; adding the modified waterborne polyurethane emulsion to ethyl acetate to obtain a second mixed solution; and adding the first mixed solution to the second mixed solution to obtain a hydrophobically modified polyurethane nanocomposite material. The present invention combines modified waterborne polyurethane with nano-SiO2 to achieve good hydrophobicity and durability.

The invention relates to the technical field of lubricating oil, and particularly discloses graphene water-based rapier loom gear oil and a preparation method thereof. The graphene water-based rapier loom gear oil provided by the invention is prepared from the following components in parts by weight: 967 to 992 parts of water-soluble polyether polyol, 10 to 15 parts of silicon dioxide, 5 to 8 parts of phosphorus-containing modified graphene oxide, 1 to 5 parts of an anti-wear agent, 1 to 5 parts of an antioxidant and anti-gum agent and 1 to 3 parts of an anti-rust agent, the water-soluble polyether polyol is selected from one or more of polyethylene glycol, polypropylene glycol, an ethylene oxide-propylene oxide copolymer and allyl alcohol polyoxyalkyl ether; furthermore, the silicon dioxide is a mixture of silicon dioxide with the particle size of 10-15 microns, silicon dioxide with the particle size of 300-500 nm and silicon dioxide with the particle size of 50-100 nm. The graphene water-based rapier loom gear oil provided by the invention has very good viscosity-temperature characteristics and extreme pressure wear resistance, and can ensure the operation stability of rapier loom equipment under an extreme pressure condition.

The invention discloses a preparation method of a water-resistant and melting-resistant sodium silicate-based fireproof coating, and belongs to the technical field of preparation of fireproof materials and inorganic-organic hybrid coatings. The method comprises the following steps: (1) reacting isophorone diisocyanate with polypropylene glycol to prepare an isocyanate-terminated polyurethane prepolymer; (2) mixing the polyurethane prepolymer with piperazine pyrophosphate to obtain a component A; (3) mixing a sodium silicate aqueous solution with melamine to obtain a component B; and (4) mixing and curing the component A and the component B in proportion to obtain the coating. According to the invention, an isocyanate group in a polyurethane prepolymer and a sodium silicate aqueous solution are subjected to an in-situ chemical reaction, an organic hydrophobic network is constructed on the surface of an inorganic phase, and the water resistance of the coating is remarkably improved. Meanwhile, piperazine pyrophosphate and melamine form an intumescent flame-retardant system, the intumescent flame-retardant system and sodium silicate are synergistically promoted to form a compact and stable intumescent layer at high temperature, and the problems that a traditional water glass coating easily absorbs moisture and melts and flows at high temperature are effectively solved. The method is simple and controllable in process, and the prepared coating has excellent water resistance, fire resistance and heat insulation performance.