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Solid stable chlorinedioxide antiseptics and preparation thereof

A chlorine dioxide, solid-stabilized technology, applied in the fields of botanical equipment and methods, biocides, animal repellants, etc., can solve the problems of short storage time of disinfectants, poor water solubility of coating agents, and high ineffective components, and achieve the realization of Material isolation and passivation, increased storage time, high effective components

Inactive Publication Date: 2003-09-03
HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the process of producing solid chlorine dioxide release agent is mostly acidified sodium chlorite method. In view of the fact that sodium chlorite is very easy to react with solid acidifying agent and release chlorine dioxide immediately, the currently used chlorine dioxide disinfectant Most of them pack sodium chlorite and solid acidifier separately, and this kind of binary packaging is cumbersome to operate in use
[0004] Chinese patent CN1104610A discloses a production method of stable chlorine dioxide, melts white wax or stearic acid or beeswax as a coating agent, adds sodium chlorite to make microcapsule particles, and then mixes them with dry tartaric acid or oxalic acid particles Mixed bagging, the disadvantage of this production method is that the coating agent has poor water solubility. When the product is put into water for use, the coating agent melts and floats on the water surface, polluting the water quality
[0005] Chinese patent CN1238130A discloses a powdery chlorine dioxide disinfectant and its preparation method. The disinfectant prepared by the production method is a one-pack, and it uses alkali metal or alkaline earth metal chloride as a passivating agent to act as a coating drying agent. , so that sodium chlorite and solid acid do not react before use. The disadvantage is that a large amount of desiccant is used as a passivating agent in the production process of the disinfectant, resulting in high ineffective components, and because the passivating agent used absorbs water Strong, the storage time of the disinfectant is short, especially once the bag is opened, it will expire soon

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] After fully mixing 35 parts by weight of polyvinyl alcohol, 15 parts by weight of polyvinyl arsenone, 8 parts by weight of cobalt chloride, and 42 parts by weight of water, a composite coating agent is prepared for use.

[0027] Put 25 parts by weight of sodium chlorite and 2 parts by weight of sodium percarbonate into the mixer, then continuously spray 18 parts by weight of the composite coating agent in a stirring state to stir and mix, and dry the particles after coating Treated to obtain 37 parts by weight of the coating matrix.

[0028] Crush trichloroisocyanuric acid into 200-400 mesh powder, take 11 parts by weight of the above-mentioned trichloroisocyanuric acid powder and mix evenly with 42 parts by weight of citric acid to prepare 53 parts by weight of a composite activator.

[0029] The magnesium sulfate is crushed, sieved and dried so that the particle size of the powder is not less than 50 mesh and the water content is not more than 3%. Take 10 parts by we...

Embodiment 2

[0031] After fully mixing 30 parts by weight of polyvinyl alcohol, 12 parts by weight of polyvinyl arsenone, 10 parts by weight of cobalt chloride, and 48 parts by weight of water, a composite coating agent is prepared for use.

[0032] Put 27 parts by weight of sodium chlorite and 3 parts by weight of sodium percarbonate into a mixer, then continuously spray 25 parts by weight of a composite coating agent for stirring and mixing, and dry the coated particles to obtain 43 parts by weight of coating matrix.

[0033] Crush trichloroisocyanuric acid into 200-400 mesh powder, take 5 parts by weight of the above-mentioned trichloroisocyanuric acid powder, mix evenly with 12 parts by weight of citric acid, and 29 parts by weight of sulfamic acid to prepare 46 parts by weight of Compound stimulant.

[0034] The magnesium sulfate and the calcium chloride are respectively pulverized, sieved and dried so that the particle size of the powder is not less than 50 mesh and the water conten...

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PUM

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Abstract

A stable solid ClO2 disinfectant is prepared from sodium chlorite, solid acid, composite coating agent and composite trigger through compounding and passivating. Its advantages are high stability and safety, and long storage period.

Description

technical field [0001] The invention belongs to the technical field of antibacterial disinfectants and relates to an improved production method of chlorine dioxide disinfectants. Background technique [0002] Chlorine dioxide is an excellent high-efficiency, broad-spectrum, non-toxic, and non-residual disinfectant. Because it does not produce carcinogenic, suffocating, and mutagenic effects, it has been widely studied and used worldwide in recent years. [0003] At present, the process of producing solid chlorine dioxide release agent is mostly acidified sodium chlorite method. In view of the fact that sodium chlorite is very easy to react with solid acidifying agent and release chlorine dioxide immediately, the currently used chlorine dioxide disinfectant Most of the sodium chlorite and the solid acidifier are packaged separately, and this binary package is cumbersome to operate in use. [0004] Chinese patent CN1104610A discloses a production method of stable chlorine dio...

Claims

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Application Information

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IPC IPC(8): A01N25/26A01N59/00
Inventor 张炳烛王奎涛
Owner HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY
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