The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. The preparation method is to use attapulgite, diopside, sepiolite, feldspar, perlite and albite porous materials as carriers, and the carrier is modified by lithium hypochlorite and bis(acetylacetonate) beryllium for pore expansion. , adding the surfactant dieicosyldimethylammonium chloride to carry out surface activation treatment under the action of ultrasonic waves, and then the ultrasonic surface activation carrier is mixed with the composite mineralizer borax and potassium sulfate in the hydrothermal reaction kettle, and the catalytic activity assistant Precursors tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionate)cerium(IV), tris(4,4,4-trifluoro-1-(2-thiophene)-1 ,3-butanedione) europium, tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octenedione) dysprosium(III), Tris[N,N-bis(trimethylsilane)amine]erbium rare earth organometallic compound, catalytic active center component precursor common transition metal organic compound manganese lysine, ammonium zirconium carbonate and noble metal compound palladium dichlorotetraammine , iridium tetrachloride dihydrate, under the action of emulsifier m-nitrobenzyl dimethyl ammonium bromide, carry out hydrothermal reaction, after the reaction product is dried to remove moisture, it is burned in a muffle furnace at a certain temperature to obtain ozone Homogeneous oxidation of solid catalysts.