55results about How to "Burning at high temperature makes the organic matter completely carbonized and strong adsorption" patented technology

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment protection and chemical catalysts. The preparation method includes: using a diatom purifier, kyanite, aluminum hydroxide, celestite, fly ash and coal gangue as the carriers, using lithium hypochlorite and bis(acetylacetone) beryllium to perform pore expansion on the carriers, adding chlorinated dodecyl dimethyl hydroxyethyl ammonium to activate the carriers under ultrasonic action, allowing the carriers to have hydrothermal reaction with compound mineralizer including borax and potassium sulfate, catalytic activity promoter precursors including tri(hexafluoroacetylacetone) yttrium(III) dihydrate, acetylacetone samarium, tri(4, 4, 4-trifluoro-1-(2-thiophene)-1, 3-butanedione) europium and tri(6, 6, 7, 7, 8, 8, 8-heptafluoro-2, 2-dimethyl-3, 5-octene diketone) dysprosium(III), and catalytic activity central precursors including pyruvic acid isonicotinoyl hydrazone vanadium, nickel citrate, cupric glutamate and dipotassium hexachloroosmate in a hydrothermal reaction kettle under the effect of N-dodecyl dimethyl-N'-dodecyl-dimethyl-2-hydroxypropyl ammonium dichloride, drying to remove moisture, and burning in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidized solid catalyst, and belongs to the technical field of environmental protection and chemical catalyst. The preparation method comprises the following steps: taking maifanite, wollastonite, potassium feldspar, szaibelyite, illite and raphite as carriers, performing lithium hypochlorite and bis(acetylacetonato) beryllium reaming, adding octadecyl trimethyl ammonium chloride to perform activating treatment under an ultrasonic effect; and then enabling the active carriers to perform hydrothermal reaction with the compound mineralizing agent borax and potassium sulfate, catalytic active promoter precursors scandium isopropoxide (III), thulium trifluoromethane sulfonate (III), tri(trifluoromethane sulfimide)ytterbium, lutetium carbonate hydrate, catalytic active center precursors titanocene ring substituted salicylic complex, L-aspartic acid molybdenum, gold potassium tetrachloride and iridium tetrachloride dihydrate under the effect of the emulsifier N-decyl dimethyl-N -trimethyl-2-hydroxypropyl ammonium dichloride, drying to remove the moisture, firing in a muffle furnace to obtain the ozone heterogeneous oxidized solid catalyst.

The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. Use diatomite, kyanite, illite, sodium borate, hydrotalcite and alunite as carriers to expand the pores through lithium hypochlorite and bis(acetylacetonate) beryllium, then add surfactant monoalkyl ether trimethyl Ammonium chloride is activated under the action of ultrasonic waves, and then the carrier is mixed with the composite mineralizer borax and potassium sulfate in a hydrothermal reactor, and the precursor of the catalytic activity assistant tris(hexafluoroacetylacetonate) yttrium (III) dihydrate , 1,1,1‑trifluoroacetylacetonate neodymium, tris(trifluoromethanesulfonylimide) ytterbium, lutetium carbonate hydrate, catalytic active center precursor isonicotinoyl hydrazone vanadium pyruvate, cobalt gluconate, ammonium zirconium carbonate And Potassium tetrachloride, carry out hydrothermal reaction under the effect of emulsifier N-decyldimethyl-N'-trimethyl-2-hydroxypropyl dichloride, after drying to remove moisture, in muffle Ignition in a furnace to obtain a solid catalyst for ozone heterogeneous oxidation.

The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. The preparation method is to use γ-alumina, barite, basalt, magnesite, brucite and serpentine porous materials as carriers, and the carrier is modified by lithium hypochlorite and bis(acetylacetonate) beryllium to expand pores , adding the surfactant dimethyl dioctadecyl ammonium chloride to carry out surface activation treatment under the action of ultrasonic waves, and then the ultrasonic surface activation carrier is mixed with the composite mineralizer borax and potassium sulfate in the hydrothermal reaction kettle, and the catalytic activity assistant Precursors tetrakis(2,2,6,6‑tetramethyl‑3,5‑heptanedionate) cerium(IV), samarium acetylacetonate, tris(6,6,7,7,8,8,8‑ Heptafluoro‑2,2‑dimethyl‑3,5‑octenedione) dysprosium(III), thulium(III) trifluoromethanesulfonate rare earth organometallic compounds, precursors of catalytic active center components common transition metalorganic Compound manganese lysine, ammonium zirconium carbonate, catechol ethylenediamine tungsten complex and noble metal compound palladium dichlorotetraammine, in emulsifier 2,6‑bis(diethylaminomethyl)‑4‑nonyl The hydrothermal reaction is carried out under the action of phenol-epichlorohydrin quaternary ammonium salt. After the reaction product is dried to remove moisture, it is burned in a muffle furnace at a certain temperature to obtain a solid catalyst for ozone heterogeneous oxidation.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environmental-friendly and chemical engineering catalysts. The preparation method comprises the following steps: by taking erionite, garnet, diatom pure, kyanite, potassium feldspar and szaibelyite as a carrier, after chambering and modifying the carrier through lithium hypochlorite and di(acetylacetone) beryllium, adding a surfactant dodecyl trimethyl ammonium chloride for surface activating treatment under the action of ultrasonic waves; then performing a reaction on the ultrasonic surface activated carrier in a hydrothermal reaction kettle and a compound mineralizer borax and potassium sulfate and catalytic active auxiliary agent precursors isoproscandium oxide (III), a tri(hexafluoroacetyl acetone) yttrium (III) dihydrate, tri(3-trifluoro acetyl-D-camphor) praseodymium (III) and tri(trifluoromethane sulfimide) ytterbium; and performing a hydrothermal reaction with catalytic active central compound precursors a titanocene ring substituted salicylic acid complex, vanadium isonicotinoyl hydrazone pyruvate, cupric glutamate and dipotassium hexachloroosmate under the action of an emulsifier N-dodecyl dimethyl-N'-dodecyl-2-hydroxypropyl ammonium dichloride, drying a reaction product to remove water, and firing the reaction product in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment protection and chemical engineering catalysts. The preparation method includes using perlite, albite, potassium feldspar, ascharite, illite and ulexite as carriers; subjecting the carriers to pore expanding through lithium hypochlorite and bis(acetylacetone)beryllium, and adding a surfactant 2, 6-bis(diethylamino methyl)-4-nonyl phenol-chlorinated benzene quaternary ammonium salt, activating under ultrasonic action; enabling the activated carriers to be in hydrothermal reaction with composite mineralizing agent borax and potassium sulfate, catalytic active auxiliary precursor 1, 1, 1-trifluoroacetylacetone neodymium, holmium oxalate decahydrate, trifluoromethane thulium sulfonate (III) and tri(trifluoromethane sulfimide)ytterbium and catalytic activity central precursor cobalt gluconate, nickel citrate, terpyridyl ruthenium chloride hexahydrate and potassium tetrachloroaurate in a hydrothermal reaction kettle under action of an emulsifier octadecyl dimethyl ethoxy ammonium laurate; drying for removing water; firing in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidized solid catalyst, and belongs to the technical field of environmental protection and chemical catalyst. The preparation method comprises the following steps: taking perlite, albite, nitratine, dolomite, coal ash and coal gangue as carriers, performing lithium hypochlorite and bis(acetylacetonato) beryllium reaming, adding a surfactant N-decyl dimethyl-N'-trimethyl-2-hydroxypropyl ammonium dichloride to perform activating treatment under an ultrasonic effect; and then enabling the active carriers to perform hydrothermal reaction with the compound mineralizing agent borax and potassium sulfate, catalytic active promoter precursors tri(cyclopentadienyl) promethium, tris(4,4,4-trifluoro-1-(2-thienyl)-1,3-butanediono)europium (III), holmium oxalate decahydrate, lutetium carbonate hydrate, catalytic active center precursors cobalt gluconate, cupric glutamate, terpyridyl ruthenium chloride hexahydrate, dipotassium hexachloroosmium under the emulsifier N-oleyl-N'N'-diethyl ethylenediamine dihydrochloride, drying to remove the moisture, firing in a muffle furnace to obtain the ozone heterogeneous oxidized solid catalyst.

The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. The preparation method uses porous materials such as perlite, albite, bentonite, polyhalite, basalt and kabeinite as carriers, and after the carrier is modified by lithium hypochlorite and bis(acetylacetonate) beryllium to expand the pores, it is added to the surface The active agent nonylphenol-based diquaternary ammonium salt is subjected to surface activation treatment under the action of ultrasonic waves, and then the ultrasonic surface activation carrier is combined with the composite mineralizer borax and potassium sulfate in a hydrothermal reaction kettle, and the catalytic activity auxiliary agent precursor 1,1, Neodymium 1‑trifluoroacetylacetonate, tris(6,6,7,7,8,8,8‑heptafluoro‑2,2‑dimethyl‑3,5‑octenedione) dysprosium(III), tris [N,N‑bis(trimethylsilyl)amine]erbium, tris(trifluoromethanesulfonimide)ytterbium rare earth organometallic compound, catalytic active center component precursor common transition metal organocompound cobalt gluconate, citric acid Nickel and precious metal compounds potassium dithiocyanato silver (I) and palladium dichlorotetraammine are subjected to hydrothermal reaction under the action of emulsifier trimethylaminoethanol palmitate ammonium iodide, and the reaction product is dried to remove moisture , in a muffle furnace, burning at a certain temperature to obtain a solid catalyst for ozone heterogeneous oxidation.

The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. The preparation method is to use perlite, albite, montmorillonite, potassium halite, sodium nitrate and dolomite porous materials as carriers, and after the carrier is modified by lithium hypochlorite and bis(acetylacetonate) beryllium, adding The surface active agent nonylphenol-based diquaternary ammonium salt is subjected to surface activation treatment under the action of ultrasonic waves, and then the ultrasonic surface activation carrier is combined with the composite mineralizer borax and potassium sulfate in a hydrothermal reaction kettle, and the catalytic activity auxiliary agent precursor 1,1 , Neodymium 1-trifluoroacetylacetonate, terbium triacetate hydrate, thulium(III) trifluoromethanesulfonate, lutetium carbonate hydrate rare earth metal organic compound, catalytic active center component precursor common transition metal organic compound cobalt gluconate, lemon Nickel, catechol ethylenediamine tungsten complex and noble metal compound dichlorotetraammine palladium, under the action of emulsifier lauryl amidopropyl dimethyl dihydroxypropyl ammonium chloride, carry out hydrothermal reaction, the reaction product After drying to remove moisture, burn in a muffle furnace at a certain temperature to obtain a solid catalyst for ozone heterogeneous oxidation.

The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. The preparation method is to use perlite, albite, montmorillonite, potash salt, brucite and serpentine porous materials as carriers, and after the carrier is modified by lithium hypochlorite and bis(acetylacetonate) beryllium to expand pores, Add surfactant nonylphenol-based diquaternary ammonium salt to carry out surface activation treatment under the action of ultrasonic waves, and then ultrasonic surface activation carrier is mixed with composite mineralizer borax and potassium sulfate in a hydrothermal reaction kettle, catalytic activity auxiliary agent precursor 1, Neodymium 1,1‑trifluoroacetylacetonate, terbium triacetate hydrate, tris[N,N‑bis(trimethylsilyl)amine]erbium, tris(trifluoromethanesulfonylimide)ytterbium rare earth organometallic compound, catalytic activity Central component precursor common transition metal organic compound cobalt gluconate, nickel citrate, catechol ethylenediamine tungsten complex and noble metal compound potassium tetrachloride, in emulsifier oleamidopropyl dimethyl hydroxyethyl chloride The hydrothermal reaction is carried out under the action of ammonium chloride, and the reaction product is dried to remove moisture, and then burned at a certain temperature in a muffle furnace to obtain a solid catalyst for ozone heterogeneous oxidation.

The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. The preparation method is to use perlite, albite, aluminum metahydroxide, phosphorite, hydrotalcite and alunite porous materials as carriers, and after the carrier is modified by lithium hypochlorite and bis(acetylacetonate) beryllium to expand pores, Add surfactant nonylphenol-based diquaternary ammonium salt to carry out surface activation treatment under the action of ultrasonic waves, and then ultrasonic surface activation carrier is mixed with composite mineralizer borax and potassium sulfate in a hydrothermal reaction kettle, catalytic activity auxiliary agent precursor 1, Neodymium 1,1‑trifluoroacetylacetonate, gadolinium tris(2,2,6,6-tetramethyl‑3,5‑heptanedionate), tris[N,N‑bis(trimethylsilyl)amine] Erbium, lutetium carbonate hydrate (III) rare earth metal organic compound, catalytic active center component precursor common transition metal organic compound cobalt gluconate, nickel citrate, molybdenum L-aspartate and noble metal compound hexanitroso rhodium trisodium Pt, under the action of emulsifier N-decyldimethyl-N'-trimethyl-2-hydroxypropyl diammonium chloride, carry out hydrothermal reaction, after the reaction product is dried to remove moisture, in the muffle furnace , burning at a certain temperature to obtain a solid catalyst for ozone heterogeneous oxidation.

The invention relates to a preparation method for a solid catalyst for ozone heterogeneous oxidization and belongs to the technical field of an environment-friendly and chemical catalyst. The preparation method comprises the following steps: by taking medical stone, wollastonite, dolomite, calcite, illite and ulexite as carriers, modifying the carriers by broaching with lithium hypochlorite and bis(acetylacetone) beryllium, and then adding a surfactant, tetradecyl tributyl ammonium chloride, and performing surface activating treatment under the effect of ultrasonic wave; performing hydrothermal reaction on an activated carrier, compound mineralizers including borax and potassium sulphate, catalytic activated assistant precursors including isopropoxy scandium (III), tri(4,4,4-trifluoro-1-(2-thiophene)-1,3-butanedione) europium, holmium oxalate hydrate and tri[N,N-bi(trimethyl silane) amine] erbium, and catalytic active core component precursors including dicyclopentadienyl titanium substituted salicylic acid complex, zinc lactate, diphenol ethylene diamine tungsten compound and iridium tetrachloride in a hydrothermal reaction kettle under the effect of N-octadecyl dimethyl-N'-trimethyl-propyl ammonium dichloride used as an emulsifier; drying and dewatering the reaction product; burning in a muffle furnace under a certain temperature, thereby acquiring the solid catalyst for ozone heterogeneous oxidization.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst, and belongs to the technical fields of environment protection and catalysts for chemical industry. The preparation method comprises the following steps of using diatomite, kyanite, talcum, trona, brucite and serpentinite as carriers, expanding pores of the carriers by lithium hypochlorite and bis(acetylacetone)beryllium, and adding a surfactant (monoalkyl ether trimethyl ammonium chloride) for activating treatment under the action of ultrasonic wave; then, performing hydrothermal reaction on the carriers, composite mineralizing agents (borax and potassium sulfate), catalytic activity additive precursors (yttrium tri(hexafluoroacetylacetone) (III) dihydrate, tri(cyclopentadienyl) promethium, tris(4,4,4-trifluoro-1-(2-thienyl)-1,3-butanediono)europium (III), and tris(2,2,6,6-tetramethyl-3,5-heptanedionato)gadolinium), and catalytic activity center precursors (pyruvic acid isonicotinyl hydrazone vanadium, cobalt gluconate, catechol ethylenediamine tungsten complex and sodium hexanitrorhodate(III)) in a hydrothermal reaction kettle under the action of an emulsifier (hexadecyl dimethylamine ethyl sulfate), drying to remove water, and firing in a muffle furnace, so as to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. The preparation method is to use attapulgite, diopside, basalt, magnesite, brucite and serpentine porous materials as carriers, and after the carrier is modified by lithium hypochlorite and bis(acetylacetonate) beryllium to expand pores, Add surfactant trilauryl ammonium chloride to carry out surface activation treatment under the action of ultrasonic waves, then ultrasonic surface activation carrier is mixed with composite mineralizer borax and potassium sulfate in hydrothermal reaction kettle, catalytic activity auxiliary agent precursor three (3‑ Trifluoroacetyl‑D‑camphor) praseodymium (III), promethium tricyclopentadienyl, holmium oxalate decahydrate, lutetium carbonate hydrate rare earth metal organic compound, catalytic active center component precursor common transition metal organic compound fumaric acid Ferrous, nickel citrate and noble metal compound terpyridine ruthenium chloride hexahydrate, tetraammine palladium dichloride, in emulsifier 2,6-bis(diethylaminomethyl)-4-nonylphenol-epoxychloro Hydrothermal reaction is carried out under the action of propane quaternary ammonium salt. After the reaction product is dried to remove water, it is burned in a muffle furnace at a certain temperature to obtain a solid catalyst for ozone heterogeneous oxidation.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment protection and chemical engineering catalysts. The preparation method includes using perlite, albite, bentonite, polyhalite, magnesium spinel and olivinite as carriers; subjecting the carriers to pore expanding through lithium hypochlorite and bis(acetylacetone)beryllium, and adding a surfactant 2, 6-di(diethylamino methyl)-4-nonyl phenol-chlorobenzene quaternary ammonium salt, activating under ultrasonic action; enabling the activated carriers to be in hydrothermal reaction with composite mineralizing agent borax and potassium sulfate, catalytic active auxiliary precursor 1, 1, 1-trifluoroacetylacetone neodymium, tri(6, 6, 7, 7, 8, 8, 8-heptafluoro-2, 2-dimethyl-3, 5-octene diketone)dysprosium (III), trifluoromethane thulium sulfonate (III) and lutenium carbonate hydrate and catalytic activity central precursor cobalt gluconate, nickel citrate, silver dithiocyanate (I) acid potassium and cis-dichlorodiamineplatinum in a hydrothermal reaction kettle under action of an emulsifier N-decaalkyl dimethyl-N'-trimethyl-2-hydroxypropyl ammonium dichloride; drying for removing water; firing in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. The preparation method is to use perlite, albite, montmorillonite, sylvite, amazonite and lithium limestone porous materials as carriers, and after the carrier is modified by lithium hypochlorite and bis(acetylacetonate) beryllium, adding Surfactant nonylphenol-based diquaternary ammonium salt is subjected to surface activation treatment under the action of ultrasonic waves, and then the ultrasonic surface activation carrier is combined with the composite mineralizer borax and potassium sulfate in a hydrothermal reaction kettle, and the catalytic activity auxiliary agent precursor 1,1 , Neodymium 1‑trifluoroacetylacetonate, terbium triacetate hydrate, ytterbium tris(trifluoromethanesulfonimide) ytterbium, lutetium carbonate hydrate rare earth metal organic compound, catalytic active center component precursor common transition metal organic compound cobalt gluconate , nickel citrate, catechol ethylenediamine tungsten complex and noble metal compound hexachloroosmium dipotassium, under the action of emulsifier N-oleoyl-N', N'-diethylethylenediamine hydrochloride Hydrothermal reaction, after the reaction product is dried to remove moisture, it is burned in a muffle furnace at a certain temperature to obtain a solid catalyst for ozone heterogeneous oxidation.

The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. The preparation method is to use perlite, albite, montmorillonite, potassium halite, bentonite and polyhalite porous materials as carriers, and after the carrier is modified by lithium hypochlorite and bis(acetylacetonate) beryllium, adding The surface active agent nonylphenol-based diquaternary ammonium salt is subjected to surface activation treatment under the action of ultrasonic waves, and then the ultrasonic surface activation carrier is combined with the composite mineralizer borax and potassium sulfate in a hydrothermal reaction kettle, and the catalytic activity auxiliary agent precursor 1,1 ,1-Neodymium trifluoroacetylacetonate, Terbium triacetate hydrate, Tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octenedione) Dysprosium(III), tris(trifluoromethanesulfonimide)ytterbium rare earth organometallic compound, catalytic active center component precursor common transition metal organic compound cobalt gluconate, nickel citrate, ammonium zirconium carbonate and noble metal compound terpyridine chloride Ruthenium hexahydrate is hydrothermally reacted under the action of emulsifier octadecyl dihydroxyethylammonium methyl sulfate, and the reaction product is dried to remove moisture, and burned at a certain temperature in a muffle furnace to obtain ozone Heterogeneous Oxidation Solid Catalysts.

The invention relates to a preparation method for a solid catalyst for ozone heterogeneous oxidization and belongs to the technical field of an environment-friendly and chemical catalyst. The preparation method comprises the following steps: by taking medical stone, wollastonite, dolomite, calcite, basalt and blodite as carriers, modifying the carriers by broaching with lithium hypochlorite and bis(acetylacetone) beryllium, and then adding a surfactant, tetradecyl tributyl ammonium chloride, and performing surface activating treatment under the effect of ultrasonic wave; performing hydrothermal reaction on the carriers, compound mineralizers including borax and potassium sulphate, catalytic activated assistant precursors including isopropoxy scandium (III), tri(4,4,4-trifluoro-1-(2-thiophene)-1,3-butanedione) europium, holmium oxalate hydrate and lutetium carbonate hydrate, and catalytic active core component precursors including dicyclopentadienyl titanium substituted salicylic acid complex, zinc lactate, diphenol ethylene diamine tungsten compound and gold potassium chloride in a hydrothermal reaction kettle under the effect of 2,6-bi(diethylamine)-4-nonyl phenol-epoxy chloropropane hyamine used as an emulsifier; drying and dewatering the reaction product; burning in a muffle furnace under a certain temperature, thereby acquiring the solid catalyst for ozone heterogeneous oxidization.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environmental-friendly and chemical engineering catalysts. The preparation method comprises the following steps: by taking perlite, albite, metaaluminum hydroxide, phosphorite, potassium feldspar and camsellite as a carrier, after chambering and modifying the carrier through lithium hypochlorite and di(acetylacetone) beryllium, adding a surfactant N-octadecyl dimethyl-N'-trimethyl-propyl ammonium dichloride for surface activating treatment under the action of ultrasonic waves; then performing a reaction on the ultrasonic surface activated carrier in a hydrothermal reaction kettle and a compound mineralizer borax and potassium sulfate and catalytic active auxiliary agent precursors 1,1,1-trifluoroacetyl acetone neodymium, tri(2,2,6,6-tetramethyl-3,5-heptylic diketone acid) gadolinium, holmium oxalate decahydrate and thulium trifluoromethanesulfonate (III); and performing a hydrothermal reaction on catalytic active central compound precursors cobalt gluconate, nickel citrate, zinc lactate and iridic tetrachloride dehydrate under the action of an emulsifier ethyl trimethylamine stearate ammonium chloride, drying a reaction product to remove water, and firing the reaction product in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment-friendly and chemical engineering catalysts. The preparation method comprises the following steps: by taking medical stones, wollastonite, bentonite, polyhalite, coal ash and gangue as carriers, after chambering and modifying the carriers through lithium hypochlorite and di(acetylacetone) beryllium, adding a surfactant, octadecyl trimethyl ammonium chloride, for surface activating treatment under the action of ultrasonic waves; then causing the carriers to generate hydrothermal reaction with borax and potassium sulfate which serve as compound mineralizers, isoproscandium oxide (III), tri[N,N-bis(trimethyl silyl)amide erbium, tri(trifluoromethane sulfimide) ytterbium and a lutetium carbonate hydrate which serve as catalytic active auxiliary agent precursors, and a titanocene ring substituted salicylic acid complex, molybdenum L-aspartate, gold potassium tetrachloride and dipotassium hexachloroosmate which serve as catalytic active central compound precursors in a hydrothermal reaction kettle under the action of an emulsifier, 2,6-di(diethylamino methyl)-4-nonyl phenol-epichlorohydrin quaternary ammonium salt, drying a reaction product to remove water, and firing the reaction product in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment protection and chemical engineering catalysts. The preparation method includes using perlite, albite, bentonite, polyhalite, nitratine and dolomite as carriers; subjecting the carriers to pore expanding through lithium hypochlorite and bis(acetylacetone)beryllium, and adding a surfactant 2, 6-di(diethylamino methyl)-4-nonyl phenol-chlorobenzene quaternary ammonium salt, activating under ultrasonic action; enabling the activated carriers to be in hydrothermal reaction with composite mineralizing agent borax and potassium sulfate, catalytic active auxiliary precursor 1, 1, 1-trifluoroacetylacetone neodymium, holmium oxalate decahydrate, tri[N, N-bis(trimethylsilane)amine]erbium, andtrifluoromethane thulium sulfonate (III) and catalytic activity central precursor cobalt gluconate, nickel citrate, potassium tetrachloroaurate and hexanitroso rhodium trisodium in a hydrothermal reaction kettle under action of an emulsifier diethyl maleate bis(chlorinated dodecyl dimethyl ammonium); drying for removing water; firing in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment protection and chemical engineering catalysts. The preparation method includes using perlite, albite, montmorillonite, sylvinite, magnesium spinel and olivinite as carriers; subjecting the carriers to pore expanding through lithium hypochlorite and bis(acetylacetone)beryllium, and adding a surfactant nonyl phenol diquaternary ammonium salt, activating under ultrasonic action; enabling the activated carriers to be in hydrothermal reaction with composite mineralizing agent borax and potassium sulfate, catalytic active auxiliary precursor 1, 1, 1-trifluoroacetylacetone neodymium, terbium triacetate hydrate, tri[N, N-bis(trimethyl silane)amine]erbium and lutenium carbonate hydrate and catalytic activity central precursor cobalt gluconate, nickel citrate, catechol ethanediamine tungsten complex and terpyridyl ruthenium chloride hexahydrate in a hydrothermal reaction kettle under action of an emulsifier oleamide propyl trimethyl ammonium methyl sulfate; drying for removing water; firing in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. Use perlite, albite, kaolin, red gold, aluminum hydroxide and lapis lazuli as carriers to expand the pores through lithium hypochlorite and bis(acetylacetonate) beryllium, and then add surfactant N-octadecyldimethyl ‑N'‑trimethyl‑propyl ammonium dichloride is activated by ultrasonic waves, and the carrier is mixed with the compound mineralizer borax and potassium sulfate in a hydrothermal reaction kettle, and the catalytic activity auxiliary agent precursor 1,1,1 ‑Neodymium trifluoroacetylacetonate, tris(2,2,6,6‑tetramethyl‑3,5‑heptanedionate) gadolinium, tris(6,6,7,7,8,8,8‑heptafluoro ‑2,2‑Dimethyl‑3,5‑octenedione)dysprosium(III), holmium oxalate decahydrate, catalytically active site precursors cobalt gluconate, nickel citrate, zinc lactate and silver dithiocyanate (I) Potassium acid, hydrothermal reaction under the action of emulsifier lauryl amidopropyl dimethyl dihydroxypropyl ammonium chloride, drying to remove water, burning in a muffle furnace to obtain ozone heterogeneous oxidation solid catalyst.