The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. Use medical stone, wollastonite, dolomite, calcite, bentonite and polyhalite as the carrier. After the carrier is expanded by lithium hypochlorite and bis(acetylacetonate) beryllium, add tetradecyltributylammonium chloride After ultrasonic activation treatment, the activated carrier is mixed with the composite mineralizer borax and potassium sulfate in a hydrothermal reaction kettle, and the precursor of the catalytic activity auxiliary agent scandium(III) isopropoxide, tri(4,4,4-trifluoro-1 ‑(2‑thiophene)‑1,3‑butanedione) europium, tris(6,6,7,7,8,8,8‑heptafluoro‑2,2‑dimethyl‑3,5‑octene Diketone) dysprosium(III), tris(trifluoromethanesulfonimide)ytterbium, catalytic active center component precursor titanocene ring-substituted salicylic acid complex, zinc lactate, ammonium zirconium carbonate, dichlorotetraammine Palladium, under the action of N-dodecyldimethyl-N'-trimethyl-2-hydroxypropyl ammonium chloride, carry out hydrothermal reaction, dry to remove moisture, and burn in a muffle furnace to obtain ozone Heterogeneous Oxidation Solid Catalysts.