Method for preparing ozone heterogeneous oxidation solid catalysts

Abstract

The invention relates to a method for preparing ozone heterogeneous oxidation solid catalysts, and belongs to the technical field of environmental protection and chemical catalysts. The method includes carrying out pore expansion and modification on carriers which are attapulgite, diopside, sepiolite, baryta feldspar, perlite and albite porous materials by the aid of lithium hypochlorite and bis (acetylacetone) beryllium; adding chlorinated bis-eicosyl dimethyl ammonium into the carriers and carrying surface activation treatment on the carriers under the effects of ultrasonic waves; carrying out hydrothermal reaction on the carriers which are subjected to ultrasonic surface activation, borax, potassium sulfate, tetra-(2, 2, 6, 6-tetramethyl-3, 5-heptadione acid) cerium (IV), tri-[4, 4, 4-trifluoro-1-(2-thiophene)-1, 3-butanedione] europium, tri-(6, 6, 7, 7, 8, 8, 8-heptafluoro-2, 2-dimethyl-3, 5-octene diketone) dysprosium (III), tri-[N, N-bis (trimethylsilane) amine] erbium rare earth metal organic compounds, manganese lysine, ammonium zirconium carbonate, dichlorotetraaminopalladium and tetrachloro iridium dihydrate in hydrothermal reaction kettles under the effect of nitrophenol benzyldimethyl ammonium bromide which is an emulsifier; drying reaction products to remove moisture; burning the reaction products in muffle furnaces at the certain temperatures to obtain the ozone heterogeneous oxidation solid catalysts. The chlorinated bis-eicosyl dimethyl ammonium is used as a catalyst. The borax and the potassium sulfate are used as composite mineralizers, the tetra-(2, 2, 6, 6-tetramethyl-3, 5-heptadione acid) cerium (IV), the tri-[4, 4, 4-trifluoro-1-(2-thiophene)-1, 3-butanedione] europium, the tri-(6, 6, 7, 7, 8, 8, 8-heptafluoro-2, 2-dimethyl-3, 5-octene diketone) dysprosium (III) and the tri-[N, N-bis (trimethylsilane) amine] erbium rare earth metal organic compounds are used as catalytic active auxiliary precursors, the manganese lysine, the ammonium zirconium carbonate, the dichlorotetraaminopalladium and the tetrachloro iridium dihydrate are used as catalytic active central components, the manganese lysine is a common transition metal organic compound, and the dichlorotetraaminopalladium and tetrachloro iridium dihydrate are precious metal compounds.

Description

technical field [0001] The invention relates to a preparation method of a solid catalyst for ozone heterogeneous oxidation, which belongs to the technical fields of environmental protection and chemical catalysts. Background technique [0002] Ozone oxidation technology utilizes the strong oxidation ability of ozone, which can oxidize and decompose many organic pollutants, and is widely used in wastewater treatment. Ozone catalytic oxidation technology is divided into ozone homogeneous catalytic oxidation and ozone heterogeneous catalytic oxidation. Ozone homogeneous catalytic oxidation has catalysts that are difficult to separate, recycle and reuse, and the low utilization rate of ozone leads to high water treatment operation costs. Ozone heterogeneous catalytic oxidation technology has the advantages of easy separation and recovery of catalysts and reusable use, high ozone utilization rate, and high removal rate of organic pollutants, which reduces water treatment. The ad...