The invention discloses a high-initial-efficiency fast-charge
graphite composite material and a preparation method thereof, the
composite material is of a core-shell structure, the core is
graphite, and the shell is
lithium sulfonate /
lithium molybdate and an
amorphous carbon coating layer thereof; the
mass ratio of the shell is 5-15 wt% according to the
mass ratio of the
composite material being 100%. The preparation method comprises the following steps: adding a
molybdenum compound into a
solvent to prepare a solution, adding
graphite oxide, an inorganic
lithium salt and a
carbon nanotube conductive solution, reacting for 2-12 hours at the temperature of 50-120 DEG C, filtering, carbonizing filter residues to obtain a
lithium molybdate conductive agent coated graphite material, and depositing a lithium
sulfonate derivative on the surface of the
lithium molybdate conductive agent coated graphite material by an atomization method to obtain the
lithium molybdate conductive agent coated graphite material. The
electron and
ion conductivity of the material can be improved, and the rate and the first efficiency of the material can be improved.