The application relates to a composite positive
electrode material, a preparation method and a full-
solid-state
lithium selenium battery, which comprises the following steps: under the condition that the ball milling speed is 300 rpm-700 rpm and the ball milling time is 15 h-25 h, raw materials are subjected to ball milling treatment, so that the raw materials react in situ to generate an
interface layer, and a composite positive
electrode material is obtained; the raw materials comprise a positive
electrode active substance, a Se-containing
argyrodite solid-state
electrolyte and a conductive agent; the positive electrode active substance comprises at least one of Se
single substance and
porous carbon loaded Se
single substance, and the
interface layer comprises a LiPSe compound. The application can solve the problems of poor interface stability and insufficient
ion and
electron conduction performance caused by
solid-solid interface contact in the positive
electrode material in the related art, and improves the
energy density, rate, cycle life and other performances of the battery.