Lithium battery composite electrode pole piece and preparation method and application thereof

An electrode sheet, lithium battery technology, applied in battery electrodes, non-aqueous electrolyte battery electrodes, electrolyte battery manufacturing, etc., can solve the problems of brittleness, difficult to achieve uniform and continuous coating, ion and electron transmission obstruction, and inability to obtain satisfaction, etc. Achieve the effect of avoiding adverse reactions, improving cycle performance and rate performance, and uniform interaction

Active Publication Date: 2020-11-13
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] 2) From the perspective of electrochemical reactivity, traditional polymer additives are inactive components, which are reflected in the hindrance to ion and electron transport
[0005] 3) With the development of high-capacity active materials, people hope to build functional coatings on their surfaces to protect electrode particles, thereby greatly extending their service life; these requirements cannot be met by existing commonly used polymer additives
[0007] 5) From the perspective of

Method used

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  • Lithium battery composite electrode pole piece and preparation method and application thereof
  • Lithium battery composite electrode pole piece and preparation method and application thereof
  • Lithium battery composite electrode pole piece and preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0052] (1) Preparation of polylactic acid solution: dry and weighed polylactic acid (PLA) is dissolved in dichloromethane, accompanied by magnetic stirring, to obtain a uniform polylactic acid solution with a mass fraction of 1%; the molecular weight of polylactic acid is 120,000 , and dried in a vacuum oven at 40-140°C for 4-48 hours;

[0053] (2) Preparation of composite slurry (functional slurry): a certain amount of the above-mentioned solution is added to weighed lithium iron phosphate (LFP) and conductive carbon black, and the mass ratio of active material / conducting agent / polymer is 80:10:10, adding the raw materials into a planetary ball mill and mixing for 1 hour at a speed of 350 rpm to obtain a uniformly mixed slurry;

[0054] (3) Preparation of composite electrode: Coat the uniformly mixed slurry obtained above with a certain thickness (about 100um) on the surface of aluminum foil, dry at 40°C for 1h (to ensure that the solvent is completely removed), and the solve...

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PUM

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Abstract

The invention provides a lithium battery composite electrode pole piece with high rate capability and high cycle performance, and belongs to the technical field of secondary ion lithium batteries. Theinvention provides a positive electrode pole piece or a negative electrode pole piece of a lithium battery. The positive electrode pole piece or the negative electrode pole piece comprises a currentcollector and functional slurry coated on the surface of the current collector, wherein the functional slurry is obtained by uniformly mixing a positive electrode active material or a negative electrode active material, a conductive agent and a polymer solution, and a polymer in the polymer solution is degradable bio-based polyester. The composite electrode obtained by the invention can realize anefficient and uniform electron transmission network and ion transmission channel, and effective coating and protection of active particles, thereby having excellent cycle performance and rate capability.

Description

technical field [0001] The invention provides a lithium battery composite electrode pole piece with high rate performance and high cycle performance, and belongs to the technical field of secondary ion lithium batteries. Background technique [0002] High energy density, high power density, and long cycle life make secondary ion batteries (such as Li-ion, Na-ion batteries) the most attractive energy storage devices for industry and academia. The development of advanced energy storage technologies not only depends on the development of high-capacity active materials (such as high-nickel ternary cathode materials), but also largely depends on the effective adjustment of electrode microstructure and interface, as well as the surface protection of active materials. Electrode microstructures and interfaces are key factors governing the ion / electron transport network, and thus, their design regulation is crucial to the improvement of battery performance. A small amount of polymer...

Claims

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Application Information

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IPC IPC(8): H01M4/62H01M4/13H01M4/139H01M4/60H01M10/0525H01M10/058H01M10/42
CPCH01M4/62H01M4/604H01M4/13H01M4/139H01M10/058H01M10/0525H01M10/4235Y02E60/10Y02P70/50
Inventor 杨伟孙小蓉喻鹏包睿莹王宇杨鸣波
Owner SICHUAN UNIV
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