The invention relates to manganese department positive electrode material of a lithium secondary battery, which can combine with electrolyte solution or solid electrolyte, and negative electrode active material to form lithium secondary battery. Its characteristics are: the positive electrode material of lithium secondary battery is LiMn1-x-y NixMyO2(x is not less than 0.2 and not larger than 0.8, y is not less than 0 and not larger than 0.6, and x+y is not larger than 1.), M is chosen from Li, Mg, Co, Ni, Fe, Al, Cr. The manufacturing method for manganese department positive electrode material of the lithium secondary battery, includes preparation of usher containing Mn; decorate to the covering of usher particle containing Mn; mix with lithium salt and prepare particle; sintering and other steps. By decoration of the surface of particle to usher 6 of positive electrode containing Mn or active material itself, state of material or apparent condition of material can be changed and its capacity of powerful charge and discharge, cycle performance and thermal stability can be raised. The invention has notable advantages including low cost, capacity of powerful charge and discharge, super-long cycle performance, excellent safety, super-long circulation property and resistance to overcharge .