The invention in particular relates to 
passivation solution without chrome which is used for galvanized sheets and a method thereof. The technical scheme thereof comprises: firstly, dissolving inorganic salt 
corrosion inhibitor, then, adding the inorganic salt 
corrosion inhibitor into a stirred tank, adding dispersant, 
organic acid, 
sealant, 
silicone-
acrylate emulsion and water while stirring, then, using inorganic acid or alkali to regulate the pH value to be 2.0-5.0, and then stirring for 1-2 hours under the condition that the temperature is 20-30 DEG C, the content of the components of each 
liter is: the inorganic salt 
corrosion inhibitor 10-55g, additive 4-10g, the 
organic acid 5-20g, the 
sealant 5-30g, the 
silicone-
acrylate emulsion 150-300g, and the rest is the water. The method of the invention can additionally form a layer of organic resin separate layer on the basis of forming an inorganic 
metal compound 
precipitation film, additionally, since the 
silicon compound is added, not only the 
binding force between a 
passivation layer and 
zinc coating can be increased, but also the corrosion resistance, the scrubbing resistance and the 
wear resistance of the 
passivation layer can be increased, and the 
coating treatment after passivation can not be affected.