The invention relates to the technical field of
thallium recovery and treatment, in particular to a method for efficiently recovering
thallium from a complex solution. The invention discloses a method for efficiently recovering
thallium in a complex solution. The method comprises the following steps: S1, multi-stage replacement; a
metal displacer is added into the thallium-containing feed liquid, a multi-stage displacement reaction is carried out, and the pH value during the multi-stage displacement reaction is 3-5; after the reaction is finished, separating to obtain thallium-removed feed liquid and thallium-containing
solid; s2, dissolving; dissolving the thallium-containing
solid with an inorganic acid to form a thallium-containing solution; s3, oxidizing and precipitating; and adding an
oxidizing agent into the thallium-containing solution, adjusting the pH value of the solution to 1-3 after the oxidation is finished, generating a precipitate, and separating to obtain a thallium
hydroxide solid. The method disclosed by the invention is wide in application range, can be used for treating thallium-containing
wastewater with various concentrations, is simple in process and easy to implement, and meanwhile, thallium and other valuable metals can be recycled, so that efficient
recovery and utilization of resources are realized.