992 results about "Mineral acid" patented technology

The invention provides a metal organic sulfonic acid-based solid acid catalyst applied to nylon 6 recovery and depolymerization and a preparation method thereof, and realizes upgrading and recovery of waste nylon 6. The main contents are as follows: (1) a structural design and a preparation method of the metal organic framework sulfonic acid-based solid acid catalyst; and (2) the solid acid is used for catalytic depolymerization of nylon 6. The problems that equipment corrosion is aggravated by inorganic acid in the nylon 6 recovery process and a liquid-phase catalyst is difficult to separate and recover are solved, and the application prospect is good.

The invention belongs to the field of waste artificial graphite regeneration, and particularly relates to a waste artificial graphite regeneration method, a regenerated material and application thereof, the regeneration method comprises the following steps: carrying out normal pressure liquid phase modification on waste artificial graphite in an organic acid solution in advance, and then putting the modified waste artificial graphite in an inorganic acid solution for positive pressure liquid phase modification to prepare a modified material; mixing the modified material with a Mn source, a metal N source, a first carbon source and a binder to obtain a mixture, then performing heat treatment on the mixture in a hydrogen-containing atmosphere, and then performing negative-pressure annealing treatment to obtain a heat-treated material; the metal N source comprises a compound of at least one of iron, cobalt and nickel; and mixing the heat-treated material with lithium salt and a second carbon source, and carrying out roasting treatment to obtain the graphite regenerated material. The regeneration method disclosed by the invention is particularly suitable for repairing the artificial graphite waste which is difficult to treat, so that the artificial graphite waste can be repaired to obtain a material with excellent capacity, long circulation and particularly low-temperature stability.

The invention relates to a composite reverse osmosis membrane acidic cleaning agent, a preparation method and a cleaning process thereof, and belongs to the technical field of environment-friendly water treatment. The cleaning agent comprises the following components in percentage by mass: 4-8% of inorganic acid, 20-40% of organic acid, 1-3% of a surfactant, 0.5-1% of a chelating agent, 0.5-1% of a compound corrosion inhibitor and the balance of deionized water. The composite corrosion inhibitor is formed by compounding 2-mercaptobenzothiazole and the like according to a specific mass ratio, the molecular weight of polyaspartic acid is 5000, and the molar ratio of Zn to Mo in the zinc-molybdate compound is 2: 1. The preparation method comprises the following four steps: firstly preparing a compound corrosion inhibitor premix, then preparing an acidic base solution, and then sequentially adding the components to finally obtain the cleaning solution. According to the cleaning process, a cleaning agent and deionized water are mixed, the membrane flux recovery rate is larger than or equal to 85% through cleaning of a specific process, the reverse osmosis membrane can be effectively cleaned, and the performance of the reverse osmosis membrane can be recovered.

The invention relates to a low-cost high-stability urease inhibitor and a preparation method and application thereof.The preparation method includes the steps that montmorillonite is modified with inorganic acid to obtain inorganic acid modified montmorillonite, then hydrogen ions in the inorganic acid modified montmorillonite are exchanged with a cationic surface active agent to obtain quaternary ammonium salt surface active agent modified organic montmorillonite, and the quaternary ammonium salt surface active agent modified organic montmorillonite is used for preparing the urease inhibitor. After montmorillonite is subjected to organic modification, the hydrophobicity is greatly improved, and the organic modified montmorillonite has hydrophilicity and hydrophobicity. The organic modified montmorillonite interacts with amino acid residues in a urease flap region due to the hydrophobic effect, so that the amino acid residues are gathered in the organic modified montmorillonite due to the hydrophobic effect, urease conformational change is caused, catalytic activity on urea is lost, and the organic modified montmorillonite has a remarkable urease inhibition effect, is stable in chemical property and non-toxic in material, and can be used for preparing a novel urease inhibitor. The fertilizer is easy to disperse in fertilizer and soil and low in price.

The invention relates to the technical field of pendimethalin wastewater treatment, in particular to a pendimethalin wastewater treatment method which comprises the following steps: step 1, adding ferrous oxide or ferrous hydroxide into wastewater, and adjusting the pH value of the wastewater to be neutral; 2, adjusting the pH value of the primary filtrate to 2-5 by using an inorganic acid, and adding an iron-carbon mixture with the mass ratio of 1: (0.5-2) to carry out an oxidation-reduction reaction; and step 3, introducing the secondary filtrate into 2-5 reaction kettles which are connected in series, and adding hydrogen peroxide for 1-3 times according to the mass ratio of hydrogen peroxide to COD (Chemical Oxygen Demand) of (15-25): 1. According to the pendimethalin wastewater treatment method provided by the invention, the iron-carbon mixture generates a primary battery effect in the solution, nitrate radicals can be quickly reduced into nitrogen oxides or ammonia gas, the nitrate radicals are efficiently and quickly treated, and meanwhile, iron ions and ferrous ions can finally generate corresponding hydroxides to be separated out.

The invention discloses an aluminum-based circuit acidic etching solution, which relates to the technical field of etching, and comprises the following components by mass concentration: 30-60 g / L of composite inorganic acid, 10-20 g / L of a wetting agent, 5-15 g / L of a stabilizer, 5-15 g / L of an accelerator, 6-15 g / L of a brightener, 0.5-2.5 g / L of a composite anti-lateral corrosion agent, and 2-4 g / L of a complexing agent. According to the acid etching solution for the aluminum-based circuit, the lateral etching rate of a 50-75-micron thin circuit can be lower than 30%, the etching rate is stable, the etched appearance is bright and uniform, and the circuit does not have a burr phenomenon; the wetting agent is added, so that the etching uniformity can be improved, the burr phenomenon can be prevented, the adsorption rate of inorganic acid can be increased for the burr part which is difficult to treat, and the corrosion efficiency of the burr part can be improved; by adding the brightener, the phenomena of uneven partial etching and blackening of the surface after etching can be solved.

The invention discloses a process for producing oligosaccharide from lignocellulose and performing acid circulation, which comprises the following steps of: (1) performing swelling reaction on the lignocellulose by using more than 70wt% of inorganic acid solution to obtain high-acid biomass candy pomace; (2) extracting the high-acid biomass candy pomace with an organic solvent to obtain low-acid biomass candy pomace and an acid-containing organic phase; (3) removing insoluble substances of the low-acid biomass candy pomace to obtain an oligosaccharide solution; and (4) adding water into the acid-containing liquid obtained in the step (2) for reverse extraction, standing and layering to obtain an acid solution and an organic phase. According to the method, the acid in the high-acid and solid biomass candy pomace is effectively recycled, the process is efficient and mild, energy does not need to be additionally provided, and all used reagents can be recycled and reused.

The invention discloses stable silicon dioxide microspheres as well as a preparation method and application thereof. Mixing a sodium silicate diluent and an organic acid aqueous solution to form colloidal particles, and carrying out a sol-gel reaction to obtain silica sol; the preparation method comprises the following steps: in an air environment, throwing silica sol into water under stirring to form microspheres, injecting inorganic acid into the water at the same time, then injecting a sodium silicate diluent for reaction, and then adjusting the pH value of the system to 6-7; and aging, washing, drying and roasting to obtain the silicon dioxide microspheres. The preparation method comprises the following steps: mixing a sodium silicate diluent and an organic acid aqueous solution by an acid mixing method, granulating by air to form microspheres, and finally injecting inorganic acid to quickly remove heat, reduce pressure drop and maintain the state of the microspheres, thereby obtaining the stable silicon dioxide microspheres. The porous silicon dioxide microsphere with larger surface area and pore volume is obtained, has better catalytic performance when being used as a catalytic oxidation carrier, and has the advantages of high conversion rate and high stability.

The invention relates to the technical field of etching liquid, in particular to a copper metal etching liquid composition. Comprising the following components in percentage by weight: 5-10% of hydrogen peroxide, 0.1-0.3% of a first fluorine source, 1-5% of first inorganic acid, 1-5% of alkali, 0.01-0.8% of a first metal corrosion inhibitor and the balance of deionized water; and the auxiliary agent comprises 2-8% of a second fluorine source, 10-55% of second inorganic acid, 0.1-2% of a second metal corrosion inhibitor and the balance of deionized water. The etching liquid is excellent in etching effect, CD-loss reaches 0.6-0.8 [mu] m, the slope angle reaches 40-50 degrees, the highest copper load reaches 20000 ppm, and meanwhile the problem that when copper is high, due to the fact that the nitric acid concentration is too high, metal etching is abnormal is solved.

The invention relates to the technical field of inorganic compound preparation, and particularly discloses a method for preparing high-purity iron phosphate through low-temperature acidolysis of phosphated residues, which comprises the following steps: washing, drying and crushing the phosphated residues to obtain phosphated residue powder; carrying out low-temperature acidolysis reaction on the phosphated residue powder and inorganic acid in an aqueous medium at 60-90 DEG C to obtain an acidolysis solution; adding an oxidizing agent into the acidolysis solution, adjusting the pH value of the system to 2.5-4.5 at 65-85 DEG C, carrying out oxidation impurity removal, and filtering to obtain an iron-containing phosphate solution; and selectively supplementing an iron source according to the molar ratio of iron to phosphorus in the solution, adjusting the pH value to 1.0-3.0, and carrying out precipitation reaction at 65-75 DEG C to generate iron phosphate. According to the method, low-energy-consumption resource utilization of the phosphated residues is achieved by combining low-temperature acidolysis with oxidation impurity removal and component regulation and control, the product purity meets the battery-grade requirement, and the method is suitable for preparing the lithium battery positive electrode material precursor.

A brazing-sheet manufacturing method includes superposing a core-material slab on or adjacent to at least one surface of a filler-material slab to form a clad slab, the core-material slab being composed of an aluminum material and the filler-material slab being composed of an Al—Si—Mg series alloy. Then, the clad slab is hot rolled to form a clad sheet having a core material layer composed of the aluminum material of the core-material slab and a filler material layer composed of the Al—Si—Mg series alloy of the filler-material slab. Then, the clad sheet is subjected to one or more passes of cold rolling. Either between cold-rolling passes or after the completion of the cold rolling, a surface of the clad sheet is etched using a liquid etchant that includes one or more inorganic acids. The liquid etchant does not contain fluorine atoms.

The invention discloses a solar cell and a preparation method thereof, electric equipment and power generation equipment, the solar cell comprises a passivation material, and the passivation material comprises cations and anions; the cations comprise ammonium ions, and the anions comprise acid radical ions; the ammonium ions comprise substituted or unsubstituted alkyl ammonium ions, and the acid radical ions comprise any one of organic acid radical ions and inorganic acid radical ions. The positive ions in the passivation material can enter perovskite crystal lattices to form two-dimensional perovskite to play a role in protecting a light absorption layer, and the electron cloud density on the negative ions is relatively high and can act with excessive lead iodide in the perovskite to stabilize a lead-iodine octahedral framework, so that the passivation material can passivate the defects of a perovskite layer, and the light absorption performance of the light absorption layer is improved. And the photoelectric conversion efficiency and the stability of the solar cell device are improved.

The invention discloses a method for catalyzing and photo-initiating nitro reduction through ferric trichloride, and belongs to the field of pharmaceutical compound synthesis. According to the method, transition metal salt is mainly used as a catalyst for reaction, inorganic acid and organic acid are used as additives, nitryl is reduced into amino under the condition of air or nitrogen, the catalytic efficiency is high, the yield of reduction products is high, the production cost is greatly reduced, and the method is suitable for synthesis and amplification of later compounds and has good application prospects. The method has the advantages of no expensive metal catalyst or reducing agent, simple preparation process, high efficiency, environmental protection, safety and cost saving.

The invention relates to the technical field of etching liquid, in particular to a double-dosage-form etching liquid composition. Comprising a main agent and an auxiliary agent, and the main agent comprises the following components in percentage by weight: 8-20% of hydrogen peroxide, 1-10% of a first etching agent, 1-10% of a first inhibitor, 0.1-5% of a first stabilizer and the balance of deionized water; the auxiliary agent comprises 5-30% of a second etching agent, 0.1-5% of a second inhibitor, 1-10% of a chelating agent, 10-40% of a second stabilizer and the balance of deionized water; the first etching agent comprises organic acid and inorganic acid, and the organic acid comprises succinic acid. The etching solution disclosed by the invention shows excellent etching performance, and has good compatibility performance for three-layer film (MTD / Cu / MoNb) and two-layer film (Cu / MoNb) and for different copper thicknesses (3500 / 6000 / 8000).

Disclosed in the present disclosure is a method for selectively leaching scandium from red mud. The red mud contains scandium, and the method comprises: using an inorganic acid solution to pretreat red mud to obtain pretreated red mud slurry; and using a leaching agent to carry out selective leaching on the pretreated red mud slurry to obtain leached slurry, the leaching agent containing organic acid and metal inorganic salt, and the mass ratio of the organic acid to the metal inorganic salt being 0.00015-0.0500.

The invention relates to the technical field of modified biochar, in particular to wood vinegar modified biochar, a saline-alkali soil modifier containing the wood vinegar modified biochar and a preparation method of the wood vinegar modified biochar. The invention provides a preparation method of wood vinegar modified biochar, which comprises the following steps: cleaning and drying biochar, adding the biochar into wood vinegar, stirring at room temperature for 0.5-1 hour, adding a potassium permanganate solution, continuously stirring for 2.5-4 hours, carrying out solid-liquid separation, and collecting solids to obtain the wood vinegar modified biochar. The invention further provides the wood vinegar modified biochar, a saline-alkali soil modifier containing the wood vinegar modified biochar and a preparation method of the wood vinegar modified biochar. The saline-alkali soil improver has excellent sodium ion adsorption capacity and plant growth promoting capacity, inorganic acid, organic acid or various microbial strains do not need to be used in the preparation process, the preparation method is simple and feasible, and the saline-alkali soil improver can be widely applied to development and utilization of saline-alkali soil.

The invention discloses a method for in-situ synthesis of a hydrogen type hierarchical pore ZSM-5 molecular sieve from binary ash, which comprises the following steps: firstly, mixing aluminum ash, water and fly ash according to a certain proportion, and desalting to obtain binary ash; mixing the binary ash, a pore-enlarging agent and inorganic acid to prepare silicon-aluminum sol; then, mixing the silica-alumina sol with a structure-directing agent, aging, crystallizing, washing, drying and roasting to obtain sodium type hierarchical pore ZSM-5; and finally, mixing the sodium-type hierarchical pore ZSM-5 molecular sieve with ammonium salt, washing and drying to obtain the hydrogen-type hierarchical pore ZSM-5 molecular sieve. The performance of the prepared hydrogen-type hierarchical pore ZSM-5 molecular sieve is equivalent to that of a molecular sieve prepared from a traditional aluminum-silicon source, the external specific surface area reaches up to 650 m < 2 > / g, the mesoporous volume reaches 0.65 m < 3 > / g or above, resource utilization of solid waste and hazardous waste is achieved, environmental pollution is reduced, and the synthesis cost of the hydrogen-type hierarchical pore ZSM-5 molecular sieve is reduced.

The present disclosure relates to a procedure for the synthesis of polymers (homo and copolymers) of the poly (ionic liquid) (PIL) type. The homopolymers are derived from polyvinylimidazolium, polyvinylpyrrolidone or polyvinylpyridine and the copolymers from monomers of vinyl ionic liquids (ILs) are derived from imidazole and N-vinylpyrrolidone. The structural modification of these homopolymers and copolymers occurs by using strong inorganic acids such as sulfuric, chlorosulfonic and bromosulfonic, among others, and halide metallic salts such as AlCl3, FeCl3, CuCl, ZnCl2, and SnCl2. Also, these PILs are employed as catalysts in alkylation reactions between isoparaffins and olefins for producing alkylate gasoline.

The present invention performs: a step in which an anion-exchange resin before being packed into an ion-exchange device is brought into contact with an aqueous mineral-acid solution; and a step in which the anion-exchange resin that has been in contact with the aqueous mineral-acid solution is brought into contact with an alkali metal hydroxide solution having a metal concentration not higher than a given threshold.

The invention provides a double-dosage-form copper acid etching solution as well as a preparation method and application thereof. The double-dosage-form copper acid etching solution comprises an agent A and an agent B, the agent A comprises the following components in parts by weight: 15-20 parts of an oxidizing agent, 4-7 parts of an organic acid chelating agent, 0.1-0.5 part of inorganic acid, 0.5-2 parts of alkali, 1-2 parts of a surfactant and 0.01-0.1 part of a metal corrosion inhibitor; the agent B is prepared from the following components in parts by weight: 25 to 30 parts of organic acid chelating agent, 0.2 to 0.5 part of inorganic acid, 15 to 20 parts of alkali, 1 to 2 parts of surfactant and 0.1 to 0.3 part of metal corrosion inhibitor. The double-agent copper acid etching solution provided by the invention can be compatible with etching of Cu / Mo and Cu / MTD film layers, can be compatible with etching of film layers with different thicknesses, and is long in service life, low in CD Bias, free of chamfer cracks, good in residue, small in taper variation and short in etching time.

This invention provides a method and application for the comprehensive utilization of chlor-alkali salt mud solid waste to prepare a composite de-icing agent, belonging to the field of comprehensive utilization of solid waste resources and composite material synthesis technology. The invention first prepares a slurry by mixing chlor-alkali salt mud with water. Then, under the action of an acidification aid and an ionic liquid, organic and inorganic acids are added in a single step, followed by precipitation of the composite de-icing agent in an alcohol precipitation solution. The method of this invention achieves a salt mud utilization rate of 86.55-88.85% and an effective component extraction rate of 96.70-99.27%, especially for Ca... 2+ Na + K + Mg 2+ Al 3+ The extraction rates reached 95-99.99%, 99.9%, 99.9%, 85.5-95.0%, and 80.5-90.0%, respectively, and also improved the extraction efficiency of Ca in the solution. 2+ Na + K + Mg 2+ Al 3+ The precipitation rates reached 95.5-99.5%, 75.5-80.5%, 72.5-75.5%, 95.5-99.5%, and 71.5-75.5%, respectively, and the product yield reached 90.80-95.08%. It has broad prospects for snow melting and ice removal in low-temperature environments of -15℃ to -20℃.

The application belongs to the technical field of etching liquid, and particularly relates to an anti-crystallization copper etching liquid and a preparation method and application thereof. The copper etching liquid is obtained by mixing hydrogen peroxide, inorganic acid, organic acid, fluorine compound, hydrogen peroxide stabilizer, organic sulfonic acid sodium salt, pyrazine polycarboxylic acid, amino acid ionic liquid and water. The components in the copper etching liquid jointly act, so that the phase stability of the copper etching liquid is significantly improved, the copper etching liquid can avoid crystallization in long-time work, and is suitable for industrial application.

The invention relates to a salt form of a pyrrole sulfonamide acid inhibitor as well as a preparation method and application of the salt form. Specifically, the invention discloses a compound shown as a formula (I), n = 0.1-2.0, and HA is an organic acid or an inorganic acid. The compound has the characteristics of convenience in storage, long-term stability of the product and simple preparation method, meets the industrial production requirements, and meets the development requirements of clinical pharmaceutical preparations. The compound disclosed by the invention can be used for preparing a potassium ion competitive acid blocker and preparing a medicine for treating gastric acid related diseases. # imgabs0 #

The invention relates to a method for recycling high-purity graphite from a negative electrode of a waste lithium battery by using a fine washing agent. The method comprises the following steps: preliminarily disassembling the waste lithium battery negative electrode to separate out a negative electrode plate; crushing and screening the negative plate by adopting a machine crusher, and collecting screened fine powder; carrying out heat treatment to remove the binder and other organic matters; stirring and soaking the graphite powder subjected to heat treatment, inorganic acid, sodium carbonate and a fine washing agent; filtering, washing a filter cake with deionized water, and drying to obtain high-purity graphite; the fine cleaning agent is prepared by the following steps: continuously irradiating acrylamide-beta-cyclodextrin, tetramercapto porphyrin, 1-butylene-2, 3, 4-tricarboxylic acid, dimethyl sulfoxide and a photoinitiator at room temperature for 30-80 minutes by keeping ultraviolet light of 365 nm and 10 mW / cm < 2 >, and distilling to remove dimethyl sulfoxide. The fixed carbon content of the recovered graphite can reach 99.98%.

The invention relates to the technical field of etching solutions, in particular to a Cu-MTD alloy etching solution composition and application thereof. The composition comprises a main agent and an auxiliary agent, and the main agent comprises the following components in percentage by weight: 12-20% of hydrogen peroxide, 6-15% of first organic acid, 0.001-0.08% of a first pH regulator, 2-8% of organic alkali and the balance of deionized water; and the auxiliary agent comprises 20-55% of second organic acid, 2-10% of inorganic acid, 0.05-0.5% of a second pH regulator, 10-30% of an alkaline compound and the balance of deionized water. According to the etching solution, the main agent and the auxiliary agent are compounded, the taper angle of a Cu layer can be larger than 42 degrees, and the service life cycle can reach that the Cu concentration is larger than or equal to 10000 ppm.

The invention provides a preparation method of ultrahigh-purity copper. The preparation method comprises the following steps: providing a first anode, a first cathode and an electrolyte; the electrolyte comprises the following components: a purified copper salt solution, inorganic acid, an oxidizing agent and an additive, the purified copper salt solution comprises purified copper salt and water, the purified copper salt comprises copper sulfate and copper nitrate, and the molar ratio of nitrate to sulfate in the purified copper salt solution is (1.5-9): 1; the additive comprises any one or a combination of at least two of an alcohol compound, polyacrylamide or a tetrazole compound; and the first cathode and the first anode are immersed in the electrolyte for electrochemical deposition, and the ultra-high-purity copper is obtained. The electrolyte composed of the purified copper salt solution, the inorganic acid, the oxidizing agent and the additive is adopted, the proportion of nitrate radicals to sulfate radicals in the purified copper salt solution is controlled, the impurity content of the sulfur element and the silver element in the electrolyte can be controlled, and preparation of the ultra-pure electrolytic copper is achieved.

The invention discloses a preparation method of a bifunctional heterojunction catalyst for AEM electrolyzed water. The method comprises the following steps: step 1, mixing multi-walled carbon nanotubes, deionized water, absolute ethyl alcohol and inorganic acid; step 2, putting the mixed solution in the step 1 into an ultrasonic machine to form a porous structure and more active adsorption sites; step 3, carrying out freeze drying treatment on the mixed solution treated in the step 2; step 4, mixing the dried multi-walled carbon nanotubes with acetylacetone salt, and uniformly grinding the mixed powder; and step 5, putting the powder obtained in the step 4 into a tubular furnace, and carrying out heat treatment in the atmosphere of H2 / Ar to obtain the PtFeCoNiMoZr / ZrO heterojunction catalyst. The catalyst has a remarkable catalytic effect on HER and OER reactions, and meanwhile, stable electrolysis which stably runs for 200 hours in an AEM electrolytic cell under the current density of 1200 mA / cm < 2 > is successfully realized.

The invention discloses a method for leaching waste lithium battery positive electrode powder by using intestinal flora in a neutral environment, and belongs to the technical field of resource recycling, the method comprises the following steps: step 1, a pretreatment link, the pretreatment link comprises the following process links, and each link has no sequence: (1) preparation of battery powder, (2) acquisition of intestinal flora, and (3) preparation of a culture medium; 2, domesticating the flora; and 3, valuable metal in the waste battery powder is leached out. According to the method, the intestinal flora is applied to the biological leaching of the waste LIBs positive electrode powder, so that the dependence of traditional strong acidophilic bacteria on an extremely low pH condition is broken through, and the environmental harm is greatly reduced; according to the method, inorganic acid does not need to be added, the pH value of a reaction system is stabilized within the nearly neutral range of 7.8-8.2, equipment loss caused by acid etching is reduced, reagent consumption for subsequent metal recovery and neutralization treatment is reduced, and remarkable economic benefits and environmental benefits are achieved.

The invention belongs to the technical field of coatings, and discloses a room-temperature curing water-based Dacromet coating as well as a preparation method and application thereof. The room temperature curing water-based Dacromet coating is prepared from 10 to 15 parts of silica sol, 20 to 40 parts of water, 0.1 to 0.5 part of inorganic acid, 5 to 15 parts of silane monomer, 2 to 10 parts of aluminum silver paste, 30 to 50 parts of flaky zinc powder, 0.5 to 2 parts of corrosion inhibitor, 0.5 to 5 parts of dispersing agent, 0.5 to 2 parts of multiwalled carbon nanotube, 0.5 to 2 parts of graphene, 0.05 to 0.5 part of defoaming agent and 0.05 to 0.5 part of wetting agent. According to the invention, through accurate screening and proportion optimization of all the components, the synergistic interaction among all the components is realized, so that the prepared coating can be cured only at room temperature. After being cured, the prepared coating shows excellent adhesive force and can be firmly attached to the surface of a base material; and in the aspect of corrosion resistance, by virtue of the shielding effect of the sheet zinc and the graphene and the synergistic effect of multiple protection mechanisms of cathode protection of the zinc-aluminum and the carbon nanotubes, the coating has excellent corrosion resistance, and an energy-saving, low-carbon and efficient protection solution is provided for a fastener of an electric power system.

The invention provides a copper etching solution and application thereof. The copper etching liquid comprises an inorganic acid, hydrogen peroxide, an azole compound, a halogen ion source and an amine compound, wherein the amine compound is selected from a compound shown in a formula 1 or an ammonium salt with a structural fragment shown in a formula 2. When the copper etching solution is applied to etching treatment on a chemical copper plating seed layer by a semi-additive method, the copper etching solution shows excellent differential etching capability, and has no obvious etching on the side wall of electroplating copper and the seed layer at the bottom of a copper circuit on the basis of effectively removing the seed layer between the copper circuits, so that the etching quality of the copper plating seed layer is improved. The undercut phenomenon can be prevented, the line width reduction amount is small, and the reliability degree of micronized line wiring can be obviously improved.