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328results about "Metal recycling" patented technology

High vanadium ferroalloy smelting method

The invention discloses a high vanadium ferroalloy smelting method. The method comprises the steps of adding cold-state vanadium-rich slag and limestone to the bottom of an electric arc furnace, adding a phase-I mixture consisting of vanadium pentoxide, aluminum particles, limestone and steel cuttings and smelting; returning heat-state vanadium-enriched slag of last batch into the electric arc furnace and discharging slag when vanadium content in smelting slag is less than 0.5%; adding a phase-II mixture consisting of vanadium trioxide, aluminum particles, limestone and steel cuttings, smelting, discharging slag when vanadium content in smelting slag is less than 0.5%, and before discharging the slag, adding aluminum or aluminum-magnesium alloy for reduction treatment; adding a refining mixture consisting of vanadium pentoxide and limestone or iron scale and limestone, smelting, controlling temperature of vanadium-iron alloy liquid in the furnace to be above 1900 DEG C, discharging the vanadium-iron alloy liquid and the vanadium-enriched slag when vanadium content is 78-82% and aluminum content is less than 1.5% in the vanadium-iron alloy liquid, pouring the vanadium-iron alloy liquid into an ingot mould which is preheated to be above 500 DEG C, and cooling, demoulding and breaking to obtain high vanadium ferroalloy which contains more than 80% of vanadium.
Owner:攀钢集团西昌钒制品科技有限公司

An integrated desulfurization, denitrification and demercuration flue gas purification system and purification process

The invention relates to a smoke gas purification system with an integrated function of desulfuration, denitration and demercuration and a purification process, which are used for treating SOX, NOX and Hg in smoke gas and recycling sulphur and Hg in smoke gas. A uniform gas distribution plate and a flow guide plate are arranged at a smoke gas inlet in the middle of an adsorption tower, a contracting nozzle structure of a central flow collection pipe outlet in the lower section of the adsorption tower is connected with an NH3 inlet, and by the structure improvement, the adsorption tower has the advantages of uniform distribution and mixing of gas, and the smoke gas purification efficiency and the utilization rate of active coke are also improved. Due to a ring-shaped partition plate gas extracting structure of an active coke regeneration tower, no residue is formed in the tower when the regeneration tower desorbs gas; meanwhile, a mercury capturing device is arranged outside the active coke regeneration tower. The characteristic of low content of mercury in smoke gas is taken into account in the smoke gas purification process, active coke is designed for gathering Hg till Hg is saturated and then is regenerated by an acid washing method, and Hg is recycled or subjected to refilling. The smoke gas purification system has the advantages of simultaneous removal of various pollutants, good effect of uniformly distributing smoke gas and high utilization rates of heat energy and by-products, and complete gas exhaust of the regeneration tower is guaranteed.
Owner:SHANGHAI LONGKING ENVIRONMENTAL PROTECTION

Recovery method of vanadium potassium silicon in waste vanadium catalyst

The invention discloses a method for recovering vanadium, potassium and silicon from a waste vanadium catalyst. The method comprises the following steps: firstly, leaching the waste vanadium catalyst in water, and leaching in a reductic acid, wherein the total leaching rate of vanadium is greater than or equal to 95.0%, separating the silicon from vanadium and potassium transferred to a leaching solution in a form of a leaching slag; preparing liquid sodium silicate to recover silicon from the leaching slag by alkali dissolution; separating the vanadium from potassium in the leaching solution in an extraction manner; preparing potassium sulphate to recover potassium from a raffinate phase in an evaporative crystallization manner; and preparing vanadium pentoxide from an extract phase by the procedures of re-extraction, molybdenum precipitation, calcination and the like. Meanwhile, the vanadium in the extract phase and the raffinate phase is larger in distribution ratio, and does not react with other metal impurities such as iron and the like due to excellent selectivity of an extraction agent TOA on vanadium, other metal impurity ions such as iron and the like do not need to be removed in advance, and the vanadium can be directly extracted. Thus, a part of edulcoration procedures are reduced, the raw material consumption is saved, and a high-purity product of vanadium can be directly prepared. By adopting the method disclosed by the invention, not only can the vanadium, potassium and silicon in the waste vanadium catalyst be comprehensively recovered, but also the targets of turning the waste into treasure and protecting the environment are achieved.
Owner:KAIFENG UNIV
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