The invention discloses an aqueous organic-inorganic composite coating, comprising the base materials of water-soluble film-forming material, pigment, filler, additive and water. The aqueous organic-inorganic composite coating is specifically composed of the following component, by weight: 15-25 parts of potassium silicate, 10-20 parts of styrene-acrylic emulsion, 0.2-0.5 part of stabilizer, 0.2-0.5 part of dispersing agent, 0.3-0.6 part of defoaming agent, 0.2-0.5 part of film-forming additive, 0.2-0.5 part of antifreeze, 0.1-0.3 part of thickening agent, 14-20 parts of titanium dioxide, 15-25 parts of heavy calcium, 5-10 parts of talcum powder and 20-25 parts of water. The invention has the following advantages: high film hardness, no cracking, excellent weather fastness, lasting replenished film, no addition of preservatives, excellent environmental protection performance, long recoating period of film and resource saving. In addition, the product has minimal construction resistance, and is easy for painting, promotion and application. The aqueous organic-inorganic composite coating has wide application range, and can be applied to coating of basement, underground parking, inner wall and outer wall.