The invention provides a protective
coating for a
fuel storage and transportation cabin and a preparation method thereof, the protective
coating comprises a primer layer, and the primer layer comprises a component A and a component B, the component A is prepared from the following raw materials in parts by weight: 20 to 40 parts of phosphorylated-
sulfur heterocyclic modified
epoxy resin, 0.1 to 1 part of dispersing agent, 0.1 to 1 part of flatting agent, 0.1 to 1 part of defoaming agent, 0 to 10 parts of n-butyl
alcohol, 0 to 10 parts of
xylene, 10 to 15 parts of
zinc phosphate, 0.5 to 1.0 part of thixotropic agent, 10 to 15 parts of flaky filler, 20 to 35 parts of talcum
powder, 5 to 10 parts of barite
powder and 3 to 10 parts of
titanium dioxide; the component B is prepared from the following raw materials in parts by weight: 99 to 100 parts of amino resin and 0.3 to 0.8 part of a catalyst.
Phosphorylation-
sulfur heterocycle is utilized to modify
epoxy resin, a phosphating group (P-O-C) is generated, the
lipophobicity is increased, an intrinsic anti-swelling network is constructed based on a
sulfur /
phosphorus atom covalent bonding
epoxy skeleton, and by utilizing the three-dimensional
shielding effect of
phosphorus atoms and the high-density cross-linking characteristic of
thioether bonds, the anti-swelling performance of the epoxy resin is improved.
Fuel oil permeation channels are blocked from the
molecular level,
pollutant dissolution is inhibited, and it is ensured that the
coating has good soaking resistance to
fuel oil.