A solar module polymer backsheet comprising a basement layer, tie layer on each side of the basement layer, a fourth film layer and a fifth film layer on the other side of the tie layer, the basement layer comprises at least one of the following components: polyamide polymers, polypropylene and propylene polymers, polyethylene and vinyl polymers, poly(vinylidene chloride), styrene polymers, ABS resins, liquid crystal polymers, acrylic polymers, polyphenylene oxides, polycarbonates, and polymer alloys of polycarbonates with poly(C2-6 alkylene glycol phthalates). The manufacturing process of the backsheet was provided, one polymer or a mixture of more polymers are used to form the film configuration in place of the former PET layer, thus excellent processability, material mechanical performances, barrier property and ageing resistance can be obtained; furthermore, the laminated films of the backsheet are formed via melt co-extrusion or extrusion composite process, which significantly upgraded the adhesion strength between the laminated films, and simplified manufacturing process.