The application relates to the technical field of heat-curable crosslinking agents, in particular to vinylbenzyl
fluorene containing a
benzocyclobutene group and a preparation method and application thereof, wherein the preparation method of the vinylbenzyl
fluorene containing the
benzocyclobutene group comprises the following reaction steps: S1. adding
fluorene, a
solvent, a strong base and a
phase transfer catalyst into a reaction container, adding 4-bromobenzocyclobutene dropwise into the reaction container under
inert atmosphere, continuous stirring and constant temperature conditions, sequentially performing treatment of
solvent removal under reduced pressure, extraction, washing,
solvent removal under reduced pressure in the organic phase, and obtaining a target
intermediate product; S2. adding the target
intermediate product, 4-vinylbenzyl
chloride, a solvent, a
weak base and a
phase transfer catalyst into a reaction container, performing reaction under
inert atmosphere, continuous stirring and constant temperature conditions, sequentially performing treatment of solvent removal under reduced pressure, extraction, washing, solvent removal under reduced pressure in the organic phase and recrystallization, and obtaining the vinylbenzyl fluorene containing the
benzocyclobutene group.