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239 results about "Preferential adsorption" patented technology

Removal of ethane from natural gas at high pressure

ETS-10 type materials preferentially adsorb ethane and, if present, C3+ paraffins from mixtures comprising methane, ethane and optionally C3+ paraffins at pressures above 200 psia. A process in which ETS-10 type materials are used to separate ethane and C3+ paraffins from natural gas streams at over 200 psia is provided.
Owner:THE GOVERNORS OF THE UNIV OF ALBERTA

Selective sorbents for purification of hydrocartons

A method for removing thiophene and thiophene compounds from liquid fuel includes contacting the liquid fuel with an adsorbent which preferentially adsorbs the thiophene and thiophene compounds. The adsorption takes place at a selected temperature and pressure, thereby producing a non-adsorbed component and a thiophene / thiophene compound-rich adsorbed component. The adsorbent includes either a metal or a metal ion that is adapted to form π-complexation bonds with the thiophene and / or thiophene compounds, and the preferential adsorption occurs by π-complexation. A further method includes selective removal of aromatic compounds from a mixture of aromatic and aliphatic compounds.
Owner:RGT UNIV OF MICHIGAN

Regulation of a PSA process

A PSA process for the separation of a gas flow containing essentially oxygen and nitrogen by preferential adsorption of the nitrogen, at a high adsorption pressure, on at least one bed of adsorbent material inserted in at least one separation zone. The material preferentially adsorbs nitrogen. Each bed of adsorbing material is subjected to successive separation cycles. Each separation cycle comprises at least: a purge phase comprising a desorption of the nitrogen adsorbed on the adsorbing material at a low desorption pressure below the high adsorption pressure, and a supply phase comprising introduction of the gaseous flow at a supply temperature (Tsup) into the separation zone with passage from the low desorption pressure to the high adsorption pressure. The supply temperature (Tsup) of the gaseous flow to be separated is regulated and the high adsorption pressure is adjusted.
Owner:LAIR LIQUIDE SA POUR LETUDE & LEXPLOITATION DES PROCEDES GEORGES CLAUDE

Beneficiation method for copper sulfide ore containing easily-sliming gangue minerals

ActiveCN105435966AHigh selective adsorptionIncrease buoyancyFlotationEthylenediamineSlurry
The invention relates to a beneficiation method for copper sulfide ore containing easily-sliming gangue minerals. According to the method, lime is adopted as pH regulator and pyrite depressant of flotation pulp of the copper sulfide ore containing the easily-sliming gangue minerals; sodium sulfide serves as activator of a small number of copper oxide minerals in the ore; sodium hexametaphosphate, sodium silicate or ethylenediamine serves as gangue slurry dispersant; a combination of butyl xanthate and other collectors serves as a collector of copper sulfide minerals; terpernic oil serves as foaming agent. The ore is subjected to primary grinding, primary roughing, primary scavenging and three-time concentration; the ore pulp is subjected to strong stirring and pulp mixing before starting to be subjected to primary roughing, primary scavenging and primary concentration, so that copper contained in the ore is efficiently recovered. According to the method, through reasonable combination and addition of chemicals, the ore grinding and pulp mixing process is strengthened, the adverse influence of gangue slurry on copper sulfide mineral floatation is eliminated, the surface characteristics of copper sulfide minerals are improved, the preferential adsorption of the collector on the surfaces of the copper sulfide minerals is enhanced, and accordingly, compared with a conventional method, the copper grade and the copper recovery rate of copper concentrate are substantially increased.
Owner:NORTHWEST RES INST OF MINING & METALLURGY INST

Carboxylated MCM-41 mesoporous molecular sieve for adsorbing heavy metal ions, and preparation method thereof

The invention aims at providing a carboxylated MCM-41 mesoporous molecular sieve for adsorbing heavy metal ions (such as copper, chromium, lead, cadmium, cobalt, nickel, zinc, ferrum, mercury, silver, barium and the like) in waste water, and a preparation method thereof. The carboxylated MCM-41 mesoporous molecular sieve is characterized in that a mesoporous molecular sieve MCM-41 is utilized as a supporter; the surface of the carboxylated MCM-41 mesoporous molecular sieve contains organic functional groups (-COOH groups); the organic functional groups can undergo a coordination reaction or a chelation reaction with transition metal ions to produce an effective preferential adsorption effect. The carboxylated MCM-41 mesoporous molecular sieve has the advantages of extremely high specific surface area, regular pore canal structure, and uniform distribution of organic functional groups on the pore surface. The carboxylated MCM-41 mesoporous molecular sieve has a high adsorption capacity for heavy metal ions in waste water. The preparation method has the advantages of simple process, moderate reaction conditions, easy operation, good reappearance, environmentally friendly characteristics and good application prospects.
Owner:HARBIN INST OF TECH

Quality chemical sensor using functionalized mesoporous material as sensitive material and method

The invention relates to a quality chemical sensor using a functionalized mesoporous material as a sensitive material, and a manufacturing method and application thereof, and belongs to the field of micro-nano sensors. The sensor is characterized in that: an organic functionalized mesoporous material is used as the sensitive material, and a quality transducer is used as a sensitive detection platform. In the quality chemical sensor, preferential adsorption of specific target chemical molecules is realized by utilizing specific organic functional groups of the functionalized mesoporous material, the adsorption capacity of the sensitive material to the specific target chemical molecules is improved by utilizing the high specific surface area and porosity of the functionalized mesoporous material, and the adsorption of the functionalized mesoporous material to the specific target chemical molecules is converted into electrical signals to be outputted by utilizing the quality transducer so as to detect the specific target chemical molecules.
Owner:SHANGHAI INST OF MICROSYSTEM & INFORMATION TECH CHINESE ACAD OF SCI

Molecular engram polymer and preparation and application thereof

The invention relates to a molecular engram polymer, which is used for metal ion detection. The engram and elution objects are metal complex ions; engram geometric dimensioning and combination point location of the polymer are matched with the specificity of the metal complex ions; the polymer is synthesized in-situ on metal membrane surface of a quartz microbalance and a surface plasma resonance device, the metal complex ions are eluted, the metal ions to be detected are processed by complexation and then are selectively absorbed by the molecular engram polymer, and finally the type and content of the metal ions are detected. In the invention, metal ion complexation is adopted to enlarge small changes of metal ion volume by a large extent, template molecular geometric structure memory performance of the molecular engram polymer is utilized to realize high preferential adsorption to improve metal ion detection selectivity effectively, and mass increase and geometric dimensioning enlargement caused by metal ion complexation help further improve sensitivity and antijamming capability of metal ion detection.
Owner:SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI

Non-steam autoclaved high performance concrete tube pile using calcium silicate hydrate seed powder as exciting agent, and preparation method of non-steam autoclaved high performance concrete tube pile

The invention belongs to the technical field of building materials, and particularly relates to a non-steam autoclaved high performance concrete tube pile using calcium silicate hydrate seed powder as an exciting agent, and a preparation method of the non-steam autoclaved high performance concrete tube pile. The concrete tube pile is prepared from ordinary Portland cement, mineral additives, the calcium silicate hydrate seed powder, sand, stones, a water reducing agent and an antifoaming agent. According to the non-steam autoclaved high performance concrete tube pile and the preparation method thereof disclosed by the invention, the calcium silicate hydrate seed powder is used as the exciting agent, so that a nucleation potential barrier of cement hydration can be reduced, besides, preferential adsorption nucleation is performed on reactant ions, the cement hydration is promoted, the pozzolanic effect of the mineral additives can also be advanced, the early strength of the concrete is improved from many aspects, and the non-steam autoclaved purpose is realized. According to the non-steam autoclaved high performance concrete tube pile and the preparation method thereof disclosed by the invention, the defects of low early strength, complex production technology, high energy consumption and the like of a conventional high performance concrete tube pile can be overcome, the equipment purchase cost and the equipment maintenance cost can also be reduced, and good economic and social benefits can be achieved.
Owner:TONGJI UNIV

Processes and apparatuses for preparing liquified natural gas

Processes and apparatuses are provided for preparing liquified natural gas from a natural gas feed that comprises C5 to C7 hydrocarbons and C8 or greater hydrocarbons. An exemplary process includes effecting the preferential adsorption of the C8 or greater hydrocarbons from the natural gas feed over adsorption of hydrocarbons having less than 8 carbon atoms to provide a C8-depleted natural gas stream. The process continues with effecting the preferential adsorption of the C5 to C7 hydrocarbons from the C8-depleted natural gas stream over adsorption of hydrocarbons having less than 5 carbon atoms to form a C5 to C8-depleted natural gas stream. The C5 to C7 hydrocarbons are preferentially adsorbed with higher selectivity and capacity than adsorption of the C5 to C7 hydrocarbons during preferentially adsorbing the C8 or greater hydrocarbons. The C5 to C8-depleted natural gas stream is then liquified.
Owner:UOP LLC

Anion resin for bilirubin absorption and preparation method thereof

The invention relates to anion resin for bilirubin absorption and a preparation method thereof. According to the invention, in the anion resin for bilirubin absorption, styrene is adopted as monomers, divinyl benzene is adopted as a cross-linking agent, maleic anhydride copolymer microspheres and organic small molecules are adopted as a pore-forming agent, and oil dispersible hyperoxide is adopted as an initiating agent; porous microspheres are prepared through suspension polymerization; and the anion resin with preferential bilirubin adsorption ability is obtained through quaternary ammoniation treatment, wherein the theoretical crosslinking degree of the resin is 4-20%, the average pore size of total pores is 80-120nm, and functional groups are quaternary ammonium salt groups. Accordingto the invention, the anion resin with uniform pore sizes, good permeability, good blood compatibility, high preferential adsorption of bilirubins, is obtained, and the problems in the prior art, such as poor absorption selectivity, high prices of imports, and the like, are solved.
Owner:GUANGZHOU KONCEN BIOSCI

Ferrate/polyaniline magnetic nanometer catalytic agent and preparation method thereof

The invention adopts an in-situ oxidation polymerization method and enables the polyaniline to be wrapped on the surface of the magnetic ferrate, and a series of ferrate / polyaniline magnetic nano composite materials can be prepared by using the method and comprise cobalt ferrite / polyaniline, nickel ferrite / polyaniline, copper ferrite / polyaniline, zinc ferrite / polyaniline and manganese ferrite / polyaniline and the like. A prepared ferrate / polyaniline magnetic nanometer catalytic agent has obvious preferential adsorption performance and good photoelectrical activity, and has good application prospects and economic benefits in the fields of adsorption, photocatalysis, lithium ion batteries and the like.
Owner:NANJING UNIV OF SCI & TECH

Catalyst used for preparing fluorinated alkene with chloro-fluoro alkane and preparation method thereof

The invention belongs to the field of refrigerants, and provides a catalyst used for preparing fluorinated alkene with chloro-fluoro alkane and a preparation method thereof. The general formula of the catalyst is n wt.%M / X, wherein M stands for an active component, X stands for a carrier, and n stands for the dosage of the active component; the active component is composed of alkali metal oxide, rare-earth oxide, and high valent metal oxide; the carrier adopts coal-based activated carbon or plant-based activated carbon; the dosage of the active component is less than or equals to 40% of the total mass of the catalyst. The method comprises the following steps: dipping the carrier in water solution corresponding to the active component, drying the dipped carrier at the temperature of 80-120 DEG C for more than 12 h, and finally, roasting at the temperature of 400 DEG C-550 DEG C for 6 h to obtain the catalyst. The catalyst manufactured by the method has higher preferential adsorption for chloro-fluoro alkane molecules, so as to have low purity requirement for raw materials, high selectivity for dehydrochlorination, and high yield for a target product.
Owner:XIAN MODERN CHEM RES INST

Preparation method of modified magnetic chitosan microsphere heavy metal ion adsorbent

The invention relates to a preparation method of a modified magnetic chitosan microsphere heavy metal ion adsorbent, and in particular relates to a modified magnetic chitosan material which has good selectivity and adsorptive property for heavy metal ions in food, and can be recycled, and a preparation method of the modified magnetic chitosan material. Specifically, the invention discloses the preparation method of the modified magnetic chitosan microsphere heavy metal ion adsorbent. The method comprises the steps of preparing magnetic chitosan microspheres by taking chitosan powder as a raw material, further preparing the magnetic chitosan microspheres into hydroxypropyl chlorine magnetic chitosan microspheres, and carrying out chemical grafting on the hydroxypropyl chlorine magnetic chitosan microspheres by taking the hydroxypropyl chlorine magnetic chitosan microspheres as parents and 2-aminothiazole as ligands to obtain the modified magnetic chitosan microsphere heavy metal ion adsorbent. The modified magnetic chitosan microsphere heavy metal ion adsorbent prepared by the method has preferential adsorption for Hg2+ ions.
Owner:ZHEJIANG GONGSHANG UNIVERSITY

Environment-friendly grinding solution for roller as well as preparation method and use method thereof

The invention discloses an environment-friendly grinding solution for a roller as well as a preparation method and a use method thereof. The grinding solution contains the following raw materials, such as sodium gluconate, a non-ionic emulsifier, an aqueous extreme-pressure lubricant, boric acid, glycerol, diethanol amine, a dicarboxylate-based composite anti-rusting agent, mono-butyl ether, a hard-water-resisting agent, a de-foaming agent and distilled water; and the aqueous extreme-pressure lubricant contains triethanolamine, dimer acid, macromolecular self-emulsified ester and distilled water. According to the grinding solution provided by the invention, an environment-friendly anti-sticking additive is used for dispersing lubricating components and the anti-sticking additive is preferably adsorbed on the surface of a grinding wheel, so that the lubricating components and abrasive dusts are prevented from being stuck on the surface of the grinding wheel; by utilizing the environment-friendly special extreme-pressure lubricant, the lubrication performance and the washing performance of the grinding solution can be stable in a long period; the flocculate of the grinding solution in a pipeline is reduced so that the liquid-supplying pipeline is smooth; the grinding solution has environment-friendly property and satisfies the requirements of the grinding solution on no toxin, no corrosion, good stability and good transparency; and processes for producing and using the grinding solution provided by the invention are simple.
Owner:AMER TECH CO LTD

Preparation of 2-Mercaptopyrimidine modified magnetic cotton-straw bast adsorbent

The invention discloses a preparing method of a 2-Mercaptopyrimidine modified magnetic cotton-straw bast adsorbent. The preparing method of the 2-Mercaptopyrimidine modified magnetic cotton-straw bast adsorbent is characterized in that cotton-straw bast is firstly oxidized to obtain oxidized cotton-straw bast; then the oxidized cotton-straw bast is magnetized and aminated to obtain aminated magnetic cotton-straw bast; then materials, by mass fraction, of 76-82% of tetrahydrofuran, 2-5% of 2-Mercaptopyrimidine and 10-16% of aminated magnetic cotton-straw bast are added into a reactor, then the mixture is stirred, and 2-6% of fumaryl chloride is added dropwise, the sum of all the component is one hundred percent, stirring and a refluxing reaction are conducted at the constant temperature of 90+ / -2 DEG C for four hours, after cooling, the mixture is then washed to be neutral through deionied water, and solid-liquid separation and drying are conducted to obtain the 2-Mercaptopyrimidine modified magnetic cotton-straw bast adsorbent. The 2-Mercaptopyrimidine modified magnetic cotton-straw bast adsorbent has a very high adsorption capacity on silver, is high in preferential adsorption of silver, low in cost, and high in mechanical strength; meanwhile, the 2-Mercaptopyrimidine modified magnetic cotton-straw bast adsorbent can be repeatedly used for more than eight times, and the adsorbent can be easily separated.
Owner:UNIV OF JINAN

Preparation method of metal organic framework materials for preferential adsorption of sulfide

The invention relates to a preparation method of iron based metal organic frameworks, zinc based metal organic frameworks, copper based metal organic frameworks and chromium metal organic frameworks and application in the selective adsorption of sulfide. The method comprises the following steps: dissolving a metal ion compound and an organic ligand in a solvent, stirring to dissolve completely, heating to obtain a metal organic framework crystal, filtering, and drying to obtain a metal organic framework adsorption material, the metal organic framework adsorption material can be sued for preferential adsorption of sulfide in oil, and the adsorption capacity is greater than 10mgS / g.
Owner:TIANJIN POLYTECHNIC UNIV

Metal organic framework material with CO2 preferential adsorption separation function and preparation method of metal organic framework material

The invention provides a novel metal organic framework material with a CO2 preferential adsorption separation function and a preparation method of the metal organic framework material and belongs to the technical field of chemical sciences of inorganic and organic materials. The preparation method comprises the following steps: dissolving raw materials, namely cobalt perchlorate hydrate, 4,4'-diphenyldicarboxylic acid and 3,3',5,5'-tetramethyl-1,1'-dihydro-4,4'-dipyrazol into an organic solvent; and then reacting at 130 DEG C for 72 hours to obtain the product. According to the invention, a rarely-used method for mixing pyrazol-carboxylic acid difunctional coordinating group is adopted so as to obtain the stable novel metal organic framework material. The preparation process of the material is simple, simple and convenient to operate and low in cost; and the material has high specific surface area and good stability, is especially suitable for high preferential adsorption on CO2 and can be applied to separation and capturing of the CO2 in industrial waste gas.
Owner:NORTHWEST UNIV(CN)

Method for screening antidiabetic active compounds

ActiveCN102830209AGood reproducibilityReduce steps for preparative separationsTesting medicinal preparationsProtein targetMagnetic bead
The invention discloses a method for screening antidiabetic active compounds. The method is characterized by comprising the steps of: (1) preparing bonding enzyme magnetic beads; (2) using at least two kinds of the bonding enzyme magnetic beads to conduct preferential adsorption on a traditional Chinese medicine solution or a natural extractive solution, enabling target proteins bonded on different bonding enzyme magnetic beads to be mutually different, and enabling the target proteins to be maltase, sucrase or lipase; (3) separating compounds jointly absorbed by all bonding enzyme magnetic beads to serve as a sample set; and (4) screening the antidiabetic active compounds from the sample set through inhibitory activity tests directing at the target proteins. The method for screening antidiabetic active compounds can screen the antidiabetic active compounds in a traditional Chinese medicine or a natural extractive aiming at multiple target points or enzymes, is applicable to development of anti-diabetic medicines, simultaneously reduces compound preparation and separation steps during initial screening in a traditional method, improves screening efficiency and shortens screening times.
Owner:ZHEJIANG WANBANG PHARMA

Hydrophobic silica gel composite resin-based VOC adsorbent

The invention discloses a hydrophobic silica gel composite resin-based VOC adsorbent. A synthetic method for the adsorbent comprises the following steps: (1) pretreatment of silica gel; (2) silanization of the surface of the silica gel; (3) preparation of a polymer precursor of a resin and the silica gel: a step of dissolving a divinylbenzen monomer and the initiator azobisisobutyronitrile in tetrahydrofuran in an ice water bath, carrying out mixing under stirring so as to obtain a resin polymer fluid, and adding a certain amount of the resin polymer fluid in the silane-modified silica gel drop by drop to form moist silica gel; and (4) preparation of the hydrophobic silica gel composite resin-based VOC adsorbent: a step of conveying the moist silica gel prepared in step (3) to a crystallization kettle, carrying out crystallization at a temperature of 100 to 150 DEG C for 10 to 50 h so as to obtain a sample and drying the sample at a temperature of 50 to 110 DEG C for 5 to 10 h so as to obtain the adsorbent. With the synthetic method in the invention, the surface of the silica gel presents hydrophobicity, the size of a silica gel channel can be reduced, a specific surface area of the silica gel is increased, and preferential adsorption capability of the silica gel in absorption of VOC gas is greatly improved, so the hydrophobic silica gel composite resin-based VOC adsorbent has wide application prospects.
Owner:ZHEJIANG UNIV OF TECH

Silver powder, method for producing silver powder, and conductive paste

The present invention provides a method for producing silver powder having a low chlorine content, and a conductive paste containing the resulting silver powder. When a reducing agent solution is mixed with a solution containing a silver complex, which has been obtained as a result of dissolution of silver chloride by a complexing agent, and the silver complex is thereby reduced to obtain silver powder, an organic compound having hydrophilic groups that form cations when ionized in water is added to the reducing agent solution and / or the solution containing the silver complex such that preferential adsorption of the organic compound which takes priority over chlorine on the surface of the silver particles is promoted and the adsorption of the chlorine is inhibited.
Owner:SUMITOMO METAL MINING CO LTD

Preparation method and application of Jannus dual-layered ionic imprinting composite film

InactiveCN107529450AUnique spatial structureSolve the problem of selective adsorption of target ionsOther chemical processesSolid sorbent liquid separationCelluloseComposite film
The invention provides a preparation method and application of a Jannus dual-layered ionic imprinting composite film. The preparation method comprises the following steps: step 1, preparing nano crystal cellulose (NCC) turbid liquid; step 2, synthesizing GLYMO-IDA silane; step 3, synthesizing CPTES-ACAC silane; step 4, synthesizing a dual-layered ionic composite film; and step 5, synthesizing theJannus dual-layered ionic imprinting composite film. By means of the characteristics that the nano crystal cellulose which is wide in source is taken as a matrix functional self-assembled film, and athermosensitive monomer is grafted to achieve double preferential adsorption, the problem of adsorbing target ions preferentially can be solved well by introducing an ionic imprinting technology.
Owner:JIANGSU UNIV

Sulfuric acid-boric acid-additive ternary anodizing fluid

The invention discloses a sulfuric acid-boric acid-additive ternary anodizing fluid, which is prepared by adding 1.6-7.6ml of sulfuric acid, 0.1-1.1g of boric acid and 5-100mg of additive into 100ml of deionized water. The additive is benzotriazole, 2-mercaptobenzothiazole, dithizone or 8-oxyquinoline. The anodizing fluid of the invention is the improvement of aluminium and aluminium alloy sulfuric acid-boric acid binary anodizing fluid, and cupreous efficient cathodic corrosion inhibitor is added to enable that preferential adsorption of the corrosion inhibitor is carried out on the copper-containing particle position of an aviation aluminum alloy surface, thus forming a compact reticulatepattern complexing product, providing targeted protection on copper-containing aluminum alloy phase particles, decreasing the current concentration tendency, and inhibiting excessive growth of oxidation film cavern defect at the position of the copper-containing aluminum alloy phase particles.
Owner:BEIHANG UNIV

Novel composite metal polishing fluid and preparation method thereof

A disclosed novel composite metal polishing fluid is characterized by being prepared from the following raw materials in parts by weight: 11-13 parts of cerium oxide, 2-4 parts of graphene oxide, 7-9 parts of rapeseed oil, 1-2 parts of stannous octoate, 4-6 parts of polyoxyethylene sorbitan fatty acid ester, 3-5 parts of polyoxyethylene castor oil, 4-6 parts of urea, 2-4 parts of citric acid, 4-6 parts of emulsified silicone oil, 5-7 parts of an auxiliary agent, and 300 parts of deionized water. The prepared mixed polishing fluid is safe, non-toxic and reasonable in formula. Through the cooperation of the added surfactant and the abrasive, the polishing effect is improved, preferential adsorption is realized, and a long-term easily-cleaned physical adsorption surface is formed. By adding the auxiliary agent, the polishing fluid has good dispersity, lubricity and film-forming property, and is capable of forming an air-obstructing layer on a workpiece surface to prevent air from corroding a metal surface. The polishing fluid is capable of satisfying the polishing processing requirements of various products and parts, and helps to improve the polishing efficiency, cleaning effect, surface precision and the like.
Owner:BENGBU GAOHUA ELECTRONICS

Two fluorinated metal organic framework materials and preparation and low-carbon hydrocarbon separation application thereof

The invention discloses two fluorinated metal organic framework materials, preparation and low-carbon hydrocarbon separation application thereof, and belongs to the technical field of crystalline porous material preparation and gas separation. The two microporous copper-based MOF materials are formed by a cheap and easily available multi-coordination organic ligand 3-fluoroisonicotinic acid (FINA)and copper nitrate under different solvothermal conditions. The two MOF crystal structures have high porosity and have regular one-dimensional channels, the size of the channels is slightly larger than the molecular dynamics size of low-carbon hydrocarbon, and a structural basis is provided for adsorption separation of the low-carbon hydrocarbon gas molecules. Besides, hydrogen bond interaction sites exist in the pore channels, and alkyne molecules with smaller kinetic sizes can enter the pore channels easily after the pore channels are cut by fluorine atoms, and the acting force between alkyne gas molecules and the framework is enhanced so that the effect of preferentially adsorbing acetylene gas in acetylene-ethylene mixed gas and preferentially adsorbing propyne in propyne-propylene mixed gas is achieved, ethylene and propylene components in the mixed gas are purified, and the energy consumption in the separation process is reduced.
Owner:BEIJING UNIV OF TECH

Preparation method of three-dimensional metal mesh with preferential adsorption/separation performance

A preparation method of a three-dimensional metal mesh with preferential adsorption / separation performance comprises the following steps: (1) graphene with the nanosheet thickness is coated on a metal mesh by an immersion method so as to construct nanoscale surface roughness, and then a matter with low surface energy is coated on the graphene surface layer by an immersion method so as to change chemical energy of the surface and construct a super-hydrophobic super-lipophilic two-dimension metal mesh with surface water contact angle being 150-155 degrees and oil contact angle being zero degree; and (2) the at least two two-dimension metal meshes are angled and overlapped to form a stereo three-dimensional metal mesh.
Owner:LANZHOU UNIVERSITY OF TECHNOLOGY

Selective sorbents for purification of hydrocarbons

A method for removing thiophene and thiophene compounds from liquid fuel includes contacting the liquid fuel with an adsorbent which preferentially adsorbs the thiophene and thiophene compounds. The adsorption takes place at a selected temperature and pressure, thereby producing a non-adsorbed component and a thiophene / thiophene compound-rich adsorbed component. The adsorbent includes either a metal or a metal cation that is adapted to form π-complexation bonds with the thiophene and / or thiophene compounds, and the preferential adsorption occurs by π-complexation. A further method includes selective removal of aromatic compounds from a mixture of aromatic and aliphatic compounds.
Owner:UNIV OF MICHIGAN THE

Selective sorbents for purification of hydrocarbons

A method for removing thiophene and thiophene compounds from liquid fuel includes contacting the liquid fuel with an adsorbent which preferentially adsorbs the thiophene and thiophene compounds. The adsorption takes place at a selected temperature and pressure, thereby producing a non-adsorbed component and a thiophene / thiophene compound-rich adsorbed component. The adsorbent includes either a metal or a metal ion that is adapted to form π-complexation bonds with the thiophene and / or thiophene compounds, and the preferential adsorption occurs by π-complexation. A further method includes selective removal of aromatic compounds from a mixture of aromatic and aliphatic compounds.
Owner:RGT UNIV OF MICHIGAN

Preparation method and gas separation application of copper-based microporous metal organic framework material

The invention discloses a preparation method and gas separation application of a copper-based microporous metal organic framework material, and belongs to the technical field of crystalline porous material preparation and gas separation. The material is prepared from an organic ligand 3-hydroxyisonicotinic acid (3-OH-INA) and copper acetate under a solvothermal condition, wherein the organic ligand 3-hydroxyisonicotinic acid (3-OH-INA) is simple in structure, low in price, easy to obtain and rich in coordination mode. A unique zigzag one-dimensional channel exists in the Cu-MOF structure, thesize of the channel is slightly larger than the dynamics size of a low-carbon hydrocarbon molecule, and a structural basis is provided for the adsorption process of the gas. Besides, the ligands regularly arranged in the pore channels provide multiple hydrogen bond interaction sites, and the acting force between ethane gas molecules and a framework is enhanced, so that the effect of preferentiallyadsorbing ethane gas in ethane-ethylene mixed gas is achieved, the ethylene purification task is completed in one adsorption period, and the energy consumption in the separation process is further reduced.
Owner:BEIJING UNIV OF TECH

Cigarette filter rod capable of reducing content of volatile carbonyl compounds in cigarette smoke and preparation method of cigarette filter rod

The invention discloses a cigarette filter rod capable of reducing the content of volatile carbonyl compounds in cigarette smoke and a preparation method of the cigarette filter rod. The cigarette filter rod is characterized in that mesoporous alumina particles capable of obviously reducing the content of the volatile carbonyl compounds in the cigarette smoke are added in a common cellulore filter rod to form the binary or ternary compound cellulore filter rod. The grain size of mesoporous alumina is 20-60 meshes, the average pore size of the mesoporous alumina is 10nm to 30nm, the BET surface area of the mesoporous alumina is 100-300 m<2> / g, and the crystal form of the mesoporous alumina is gamma-type alumina. The additive amount of the mesoporous alumina in the binary compound filter rod of each piece of cigarette is 10-40 mg / piece, and the additive amount of the mesoporous alumina in the ternary compound filter rod of each piece of cigarette is 70-120 mg / piece. Because of a specific acid environment of the smoke and molecular structure features of the carbonyl compounds, the mesoporous alumina can perform preferential adsorption on the volatile carbonyl compounds in the cigarette smoke by virtue of an electrostatic adsorption function and a nano-pore confinement effect, thereby achieving the purpose of alleviating the harm of the cigarette.
Owner:CHINA TOBACCO GUANGXI IND
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