105 results about "Preferential adsorption" patented technology

The invention discloses a full-automatic condensation water collection system and method in desert, and the system comprises an environment pretreatment layer: a bionic honeycomb filter screen is combined with an electrostatic adsorption technology to filter sand and dust, a spiral pre-cooling channel is used for pre-cooling, and back flushing cleaning is automatically started every 2 hours to maintain the performance of the filter screen; in the energy supply layer, the optimal combination of photovoltaic-wind energy-heat energy three-mode power generation is dynamically calculated through an AI algorithm; photovoltaic power supply is preferentially used in the daytime, and residual energy is stored in the nitrate phase change energy storage material; wind power generation is started when the wind speed is high at night, and phase-change energy storage is used for complementing when the wind speed is insufficient; condensing the core layer: when the environment humidity is relatively high, the modified MOF material preferentially adsorbs water vapor, and switching to a condensation mode every 4 hours; the thermoelectric refrigeration sheet is started to trigger phase change condensation; the intelligent control layer is used for collecting data through a sensor, predicting future environmental parameters through an LSTM neural network and adjusting condensation power in advance; and fault early warning is carried out by combining vibration analysis and temperature gradient detection.

The invention discloses a low-concentration ether electrolyte adaptive to a high-voltage high-nickel ternary lithium ion battery, a preparation method of the low-concentration ether electrolyte and the lithium ion battery, and relates to the technical field of batteries. The ether electrolyte comprises a solvent and a solute; the solvent comprises an ether solvent, and is specifically at least one of 4-cyano tetrahydropyran, 2-(tetrahydro-2H-pyran-4-yl) acetonitrile, 2-methoxyacetonitrile, 2-ethyoxyl acetonitrile, 3-methoxypropionitrile, 3-ethyoxyl propionitrile, 3-butoxyl propionitrile, ethylene glycol bis (propionitrile) ether and 3-{2-[2-(2-cyano ethyoxyl) ethyoxyl] ethyoxyl} propionitrile. The ether solvent contains cyano groups, the strong electronegativity of the cyano groups enables the cyano groups to be coordinated with transition metal ions in the ternary material, and the cyano groups are preferentially adsorbed at the interface of the positive electrode material, so that the arrangement of solvent molecules at the interface has directivity, the proportion of ether oxygen bonds and carbon hydrogen atoms in double electric layers is reduced, and the performance of the positive electrode material is improved. And the sites which are easy to generate dehydrogenation reaction in the molecules are far away from the high-voltage positive electrode interface which is easy to generate oxidation reaction.

The invention relates to the technical field of semiconductor micro-nano manufacturing, and discloses a novel semiconductor test probe manufacturing process which comprises the following steps: preparing an ionic liquid electrolyte containing a high-pressure priority adsorbent and a low-pressure priority adsorbent; a first voltage pulse is applied between the microelectrode and the conductive base, the amplitude of the first voltage pulse enables the high-voltage preferential adsorbent to preferentially adsorb on the surface of the microelectrode, and a flexible probe root and a flexible probe body are formed through deposition; then, a second voltage pulse is applied, and the amplitude of the second voltage pulse is lower than that of the first voltage pulse, so that the low-voltage preferential adsorbent preferentially adsorbs and deposits to form a superhard probe tip. The probe with the functional gradient structure is integrally manufactured by programmed voltage regulation and control in single continuous deposition, high hardness of the needle tip and high flexibility of the needle body are simultaneously realized on a single structure, the manufacturing process is remarkably simplified, and the cost is reduced.

The invention discloses an electrolyte used in a high cut-off voltage environment and a preparation method thereof, and relates to the technical field of battery electrolyte materials. According to the electrolyte, molecular components with electrochemical activity in anthocyanin can be specifically extracted by utilizing the extraction effect of a reference electrolyte solution, and the molecular components can be preferentially adsorbed on the surface of a high-cut-off-voltage positive electrode with negative electricity through electrostatic interaction, so that a chain decomposition reaction can be cut off, lattice oxygen can be directly anchored, and the electrochemical activity of anthocyanin is improved. Lattice oxygen release is inhibited from the source; the synergistic effect of a dual protection mechanism of'dynamic clearing-static anchoring 'is realized; moreover, the impedance of ion transmission is prevented from being increased by utilizing high-speed centrifugal treatment; the electrolyte can significantly inhibit a chain decomposition reaction in a high cut-off voltage environment, effectively avoids the formation of an over-thick or over-high impedance interface layer, ensures the capacity and cycle capacity retention ratio of the battery in the high cut-off voltage environment, and is suitable for large-scale application in lithium batteries in the high cut-off voltage environment.

This invention relates to the field of aqueous metal battery technology, specifically to an aqueous tin metal battery electrolyte containing metal sulfate additives, its preparation method, and its application. The electrolyte is based on an alkaline electrolyte (such as KOH) and soluble tin salts (such as SnSO4, SnCl2), with added metal sulfates such as Li2SO4, ZnSO4, K2SO4, MnSO4, or Na2SO4 as additives at a concentration of 0.01 mol / L to 0.5 mol / L. The metal cations preferentially adsorb onto the surface of the metal anode to form an electrostatic shielding layer, regulating metal ion deposition behavior, inhibiting the formation of "dead tin," and significantly improving the battery's cycle stability and coulombic efficiency.

This invention belongs to the field of acidic wastewater treatment technology, specifically disclosing a purification device for acidic wastewater using phosphogypsum filtration. The device includes a sedimentation tank with a baffle plate inside, a reinforcing frame fixedly connected to the outer wall of the sedimentation tank, and several drain pipes connected to one side of the lower end of the sedimentation tank. The key feature is that a filter assembly for adjusting the filtration sequence is provided on one side of the sedimentation tank. One end of the filter assembly is equipped with a feeding component for different filtration sequences. The filter assembly includes a drain pipe fixedly installed on one side of the sedimentation tank. A servo motor drives a transmission plate to rotate the filter cake 180 degrees. The process of "gypsum filter cake preferential neutralization" or "activated carbon filter cake preferential adsorption" can be switched simply by adjusting the filter cake sequence. This eliminates the need for two separate sets of equipment, directly reducing the initial cost of equipment purchase and installation, while also saving the factory space required for two sets of equipment, thus reducing the company's initial investment and site constraints.

The application discloses an intermediate processing liquid for an electroless nickel immersion gold (ENIG) production line and a chemical gold preparation method. The intermediate processing liquid is applied between the electroless nickel plating and immersion gold processes, and comprises (a) a pH buffer and a metal ion complexing agent: a total concentration of 50-150 g / L; (b) an adsorptive corrosion inhibitor: a concentration of 0.5-5.0 g / L; (c) a low-foam non-ionic surfactant: a concentration of 0.01-10 g / L; (d) an auxiliary antioxidant: a concentration of 0.5-30 g / L; (e) a dissolving agent: a concentration of 1-50 ml / L; (f) a pH regulator: an appropriate amount, which is added to maintain the pH value of the intermediate processing liquid at 4.0-6.5; and (g) deionized water: a balance, so that the concentrations of the above components reach the set target values; and the intermediate processing liquid has a design use temperature of 20-45 DEG C. The intermediate processing liquid removes residual nickel ions on the board surface and in micropores through strong complex cleaning, and blocks the pollution to the subsequent gold tank; meanwhile, the preferential adsorption of the corrosion inhibitor molecules at the nickel layer grain boundaries forms a controllable molecular-level protective film, effectively adjusts the immersion gold replacement reaction kinetics, and prevents the occurrence of intergranular corrosion (black plate).

The invention provides a corrosion inhibitor and a preparation method thereof, the corrosion inhibitor comprises an organic corrosion inhibitor and a metal salt corrosion inhibitor, the organic corrosion inhibitor comprises at least one of an organic amine compound and an organic acid salt compound, and the metal salt corrosion inhibitor comprises at least one of molybdate, titanate and zinc salt. The corrosion inhibitor provided by the invention is preferentially adsorbed on active sites on the metal surface through the chemical bonding effect of organic corrosion inhibitor molecules, so that corrosion is effectively blocked; meanwhile, the metal salt corrosion inhibitor acts with a metal matrix to form a compact protective film layer, and permeation of a corrosion medium is physically blocked. Due to the chemical and physical dual protection mechanism, the corrosion inhibitor has efficient, environment-friendly and long-acting corrosion inhibition performance on aluminum alloy, steel and the like in acid and salt mist environments.

The invention relates to the technical field of sewage treatment, and discloses an industrial sewage integrated treatment device which comprises a treatment tank, a motor is fixedly connected to the top of the treatment tank, a water inlet pipe fixedly communicates with the inner wall of the treatment tank, a water outlet pipe fixedly communicates with the bottom of the treatment tank, and a rotating shaft is fixedly connected to the output end of the motor. The circumferential surface of the rotating shaft is fixedly connected with a triangular frame, the inner wall of the triangular frame is fixedly connected with an adsorption plate, and the front part of the triangular frame is fixedly connected with a fixed plate I. When sewage treatment is carried out, the triangular frame rotates to drive the adsorption plate to rotate, so that impurities in water can be adsorbed; according to the device, fine impurities in water are preferentially adsorbed, heavy metal particles in sewage are treated in advance, and the situation that the heavy metal particles are accumulated in soil during discharging, and a soil ecological system and crops are damaged is avoided.

The invention discloses a glass fiber modified polypropylene material and a preparation method thereof. The glass fiber modified polypropylene material is prepared from 52.8-94.1 parts by weight of polypropylene, 5-30 parts by weight of modified glass fiber, 0.5-6 parts by weight of maleic anhydride grafted polypropylene, 0.2-0.6 part by weight of an antioxidant and 0.2-0.6 part by weight of a light stabilizer. According to the invention, the glass fiber is subjected to surface modification in advance, the ZnO nano material is deposited on the surface of the glass fiber, and due to the selected synthesis conditions, a round crystal in the shape of a spiral cover in the middle can grow on the surface of the glass fiber. Citrate can replace O < 2-> to be preferentially adsorbed on the (0001) surface and is bonded with Zn < 2 + > through-COO <-> and-OH groups, so that the lt of a ZnO crystal is inhibited; 001gt, 001gt; each layer is composed of ZnO small lamellar crystals, and the ZnO small lamellar crystals grow along the direction of the ZnO small lamellar crystals. The glass fiber is modified, the surface of the glass fiber is coated with a layer of ZnO crystals, the ZnO crystals play a role of a rivet in the later blending modification process of the glass fiber and PP, and the glass fiber reinforced polypropylene material with higher mechanical properties is obtained.

The application discloses a kind of high charge coagulant aid synergic PAC's power plant raw water processing method, belong to water treatment technical field.To solve the charge neutralization capacity of existing separate PAC process insufficient, large reagent consumption, effluent aluminum residual risk higher problem, the application simultaneously adds the organic coagulant aid with PAC reagent in raw water, and the charge density of organic coagulant aid is higher than PAC;Organic coagulant aid is preferentially adsorbed on the surface of negatively charged colloidal particles to realize rapid charge neutralization and destabilization, and then combined with PAC to form dense alum flower, significantly reducing PAC demand.The system uses "flow rate proportional feedforward + turbidity feedback" algorithm to automatically adjust the dosage, and controls the proportion by seasons, which can reduce PAC consumption by more than 60%, the turbidity of produced water is stable below 0.6NTU, significantly reducing the operation cost and aluminum residual risk, ensuring the safety of subsequent system, and the alum flower settles quickly, and the effluent water quality is stable and excellent.

The invention relates to the technical field of waste gas treatment equipment, and discloses waste gas purification equipment for a PE pipe production line, the waste gas purification equipment comprises a zeolite rotating wheel, the zeolite rotating wheel comprises a front cylinder and a rear cylinder, the front cylinder and the rear cylinder are internally and movably connected with a front rotating wheel and a rear rotating wheel which keep rotating respectively, and a separation cavity is formed between the rear rotating wheel and the front rotating wheel; a front adsorption cavity, a front desorption cavity and a front cooling cavity are arranged between the front barrel and the separation cavity, a rear adsorption cavity, a rear desorption cavity and a rear cooling cavity are arranged between the separation cavity and the rear barrel, the front adsorption cavity and the rear adsorption cavity are connected in series, and the end part of the front adsorption cavity is communicated with waste gas through an adsorption pipe. According to the waste gas purification equipment for the PE pipe production line, a tandem type double-rotating-wheel structure is adopted, high-boiling-point pollutants are preferentially adsorbed and borne through the front rotating wheel, and adjustable internal reflux and differential rotating speed design are matched, so that the problem of zeolite pore channel blockage is solved, meanwhile, the concentration multiple of low-concentration waste gas is greatly increased, and the service life of the waste gas is prolonged. And stable self-heating operation of the catalytic oxidation furnace is ensured.

The application discloses a scandium-based MOF crystal material, a preparation method and application thereof. The MOF crystal is formed by [Sc3(mu2-OH)3(CO2)4O6] n The three-dimensional porous framework structure is formed by the mutual connection of an inorganic metal chain, 2,5-thiophene dicarboxylic acid and a nitrate ion, is directly synthesized by a solvothermal reaction with a metal Sc based on the ligand 2,5-thiophene dicarboxylic acid, and has relatively mild, simple and easy reaction conditions. The MOF crystal has high crystallinity, excellent thermal stability, water stability, solvent stability and wide pH stability. Under normal temperature and pressure, C3H6 is preferentially adsorbed, then C2H6, and finally C2H4, and the MOF crystal has good C3H6 / C2H4 and C2H6 / C2H4 separation performance, thereby obtaining high-purity C2H4 and recovering C3H6, and can be applied to the effective separation of C2H4 and C3H6 in a methanol-to-olefin (MTO) mixture.

The invention relates to the technical field of food processing, and discloses fatty acid balanced and homogenized emulsified grease and a preparation method thereof.The emulsified grease is oil-in-water type nano-emulsion and comprises an oily component and a water component which are composed of DHA source grease, ALA source grease, MUFA source grease and medium chain triglyceride according to a specific proportion, the preparation method comprises the following steps: preparing an oily component and a water-based component, carrying out high-shear pre-emulsification, carrying out interface self-optimization treatment, and carrying out high-shear pre-emulsification on the oily component and the water-based component according to the trend that a system is converted to a lower interface free energy state. And the pH response type antioxidant amphiphilic molecule which is more stable in thermodynamics can replace the surfactant which is preferentially adsorbed in dynamics in the pre-emulsification stage. By combining the structure of the amphiphilic molecule with an interface self-optimization process and cooperating with other antioxidants in the oil phase and the water phase, the physical stability and oxidation stability of an emulsion system rich in unsaturated fatty acid are remarkably improved.

The present invention provides a method for preparing a PDMS-based pervaporation membrane with a continuous intermediate layer. First, a TA-APTES@ODS intermediate layer is prepared, and then a metal source is uniformly dispersed in a PDMS polymer and spin-coated onto the membrane surface. MOFs nanoparticles are formed in situ by chemical vapor deposition, and finally a hydrophobic silane coupling agent is coated on the membrane surface to improve the performance of the membrane. The prepared intermediate layer optimizes the surface structure and performance of the base membrane, prevents the pore permeation effect of PDMS, and promotes the dense formation of the PDMS selective layer. The metal source uniformly distributed in the PDMS matrix is ​​combined with a ligand by CVD and converted in situ into uniformly dispersed MOFs nanoparticles, which alleviates the aggregation of MOFs. At the same time, the surface of the composite membrane is modified, and the preferential adsorption of butanol on the PDMS surface and permeation is promoted by coating the surface with a hydrophobic silane coupling agent, thereby improving the separation performance and permeation flux of the pervaporation membrane.

The invention provides an Ag / Sr-MFI molecular sieve adsorbent as well as a preparation method and application thereof in methane purification, and belongs to the technical field of molecular sieve adsorbents. The preparation method comprises the following steps: putting MFI configuration molecular sieve raw powder into a metal cation solution, carrying out metal cation exchange to obtain Ag / Sr-MFI molecular sieve raw powder, and carrying out molding, chambering and roasting to obtain the high-nitrogen-selectivity Ag / Sr-MFI adsorbent. According to the invention, original cations (Na < + >) in the MFI molecular sieve are exchanged into Sr < 2 + > and Ag < + >, and the strong adsorption effect of the Sr < 2 + > on N2 molecules with relatively large dipole moment in a cross pore channel and a pore channel bending part and the strong complexation effect of a small amount of Ag < + > and N2 are utilized to realize the separation of methane / nitrogen and preferential adsorption of nitrogen, so that the separation efficiency of methane / nitrogen is improved. Meanwhile, the catalyst has high nitrogen adsorption capacity and high nitrogen / methane separation selectivity, and can be used for efficiently purifying methane.

This invention discloses a carbon monoxide sensor and its filter preparation method. The filter comprises an activated carbon cloth layer and a thin film layer formed by slurry printing; the slurry contains, by mass, 20-60 parts of metal oxide, 5-10 parts of binder, 8-15 parts of dispersant, 40-80 parts of carrier, and 50-80 parts of solvent. In the preparation process, the metal oxide and dispersant are first mixed in ultrapure water, dried at 135°C, and crushed. Then, the mixture is ball-milled with the binder, carrier, and solvent to obtain the slurry. Finally, the slurry is printed onto a breathable substrate using a steel mesh or screen printing process to form a film. This sensor utilizes the activated carbon cloth to preferentially adsorb most organic vapors. Simultaneously, the metal oxide, after modification with the dispersant, has increased surface active sites, which can further catalyze the oxidation or chemical adsorption of residual organic vapors, effectively suppressing their poisoning or cross-interference on the electrochemical electrode. The printed thin film is dense and uniform, and combined with the ball milling composite process, it significantly improves the resistance to organic vapor interference, ensuring the selectivity and long-term stability of CO detection.

The invention relates to the technical field of desulfurizing agents, in particular to an efficient purification fine desulfurizing agent and a preparation method thereof, and the efficient purification fine desulfurizing agent comprises the following raw materials: silver nitrate, rare earth cerium-zinc composite oxide, a copper / gamma-aluminum oxide desulfurizing agent, potassium carbonate, ammonium bicarbonate and sodium carboxymethyl cellulose. The rare earth cerium-zinc composite oxide can preferentially adsorb and concentrate various sulfides in gas through the huge specific surface area of the rare earth cerium-zinc composite oxide, and especially part of organic sulfur (such as COS) which is difficult to directly remove is preliminarily activated or converted by utilizing the excellent catalytic oxidation capacity of cerium; the copper / gamma-aluminum oxide desulfurizer fixes copper species through surface chemical coordination, and can be subjected to efficient and irreversible chemical reaction with hydrogen sulfide and activated organic sulfur to generate stable metal sulfide, so that thorough removal of sulfur is realized; the integral desulfurization precision and the sulfur capacity are remarkably improved through the functional linkage.

This application belongs to the field of batteries and discloses a secondary battery. The secondary battery includes a negative electrode and an electrolyte. The negative electrode includes a silicon-based material containing nitrogen, with a nitrogen content A% satisfying 0.05 ≤ A ≤ 4.8. The electrolyte includes a compound of formula (I), with a mass content B% satisfying 0.01 ≤ B ≤ 6. This application combines an appropriate amount of nitrogen-containing silicon-based material with an electrolyte containing the compound of formula (I). This allows for the utilization of the high specific capacity advantage of silicon-based materials while improving the electron and lithium-ion transport rate in the negative electrode, preventing negative electrode cracking and pulverization. The nitrogen-containing silicon-based material preferentially adsorbs the compound of formula (I) and promotes its reduction and ring-opening, forming a stable organic-inorganic composite SEI film with high ionic conductivity. This synergistically optimizes interfacial lithium-ion transport, suppresses interfacial side reactions and impedance increases at high rates, and thus improves the battery's rate performance and cycle stability. Formula (I)

The invention discloses a method for preparing a carbon molecular sieve by utilizing biomass waste and application of the carbon molecular sieve in realizing C4 olefin and nitrogen-oxygen separation. The method comprises the following steps: (1) adding the biomass waste into water for soaking; (2) treating the biomass carbon source in the step (1) with boric acid to obtain a boron-containing biomass precursor; and (3) carrying out pyrolysis carbonization treatment on the boron-containing biomass precursor to obtain a boron-modified carbon molecular sieve, or adding a potassium permanganate solid into distilled water, stirring, and adding the boron-modified carbon molecular sieve to obtain the carbon molecular sieve. According to the invention, efficient conversion and utilization of biomass waste are realized, and the prepared carbon molecular sieve shows the preferential adsorption characteristic to oxygen and butadiene, and has high adsorption capacity and excellent selectivity. The method has the advantages of high efficiency, low cost, environmental protection and good operability, and shows a wide application prospect in the fields of air separation and C4 olefin adsorption separation.

The invention relates to a heavy metal waste liquid electro-deposition cyclic utilization treatment method which comprises the following steps: establishing an interface charge migration model based on waste liquid ion composition and a polarization curve, and quantifying migration impedance characteristics of Cu < 2 + >, Zn < 2 + > and Ni < 2 + >. Through progressive potential scanning, ions are subjected to gradient deposition according to migration resistance, preferential adsorption and reduction are induced through pulse frequency adjustment, and a metal reduction potential window is matched. A movable electrode structure is adopted to transversely move a deposition reaction area on a microscale, and reverse high-frequency pulses are applied in a deposition intermittent period or an electrode migration period to trigger stripping and crystallization of a metal deposition layer and removal of a passivation layer. And continuously depositing the electrode to form a dynamic circulation closed loop. A micro conductivity / ion selective electrode sensor array is integrated, and the concentration and intensity distribution of residual heavy metal ions in the waste liquid are evaluated. The concentration mode is switched according to the sensing result, and the optimized concentration reaches a redeposition threshold value. The AI scheduling system controls the reflux proportion of the concentrated solution, ensures the concentration matching reflux, improves the treatment efficiency and reduces the waste.

The utility model discloses a wastewater heavy metal treatment device with a magnetic adsorption function, which comprises a main box body, a liquid inlet hopper communicated with the inner side of the main box body is fixedly connected above the main box body, and the inner side of the main box body is fixedly connected with a partition plate; according to the utility model, through the preposed design of the magnetic impurity screening mechanism, magnetic metal impurities in wastewater are preferentially adsorbed to the outer conveying belt, automatic falling and recovery of metal are realized by utilizing the non-magnetic supporting roller, the metal separation efficiency is remarkably improved, residual non-magnetic impurities are secondarily intercepted by the filter screen drawer, the impurities are staged, the effluent quality is guaranteed, and the production cost is reduced. The anti-blocking scrubbing brush is matched with the long threaded rod for linkage, the surface of the filter screen can be automatically scraped in a reciprocating mode, the filter screen blocking problem is effectively solved, the manual cleaning frequency is reduced, continuous and stable operation of the device is ensured, the filter screen drawer is of a detachable structure, and filter screens of different mesh numbers are supported to be rapidly replaced.

The present application relates to cinnamyl aldehyde selective hydrogenation technical field, specifically to a kind of Pt nanoparticle supported porous SiC catalyst and its application in cinnamyl aldehyde hydrogenation reaction.The selectivity of cinnamyl alcohol is lower in conventional cinnamyl aldehyde selective hydrogenation reaction, it is difficult to reach more than 90%.For the above technical problem, the present application provides a kind of Pt nanoparticle supported porous SiC catalyst, mainly utilizes acid etching method to carry out porous modification to polycrystalline SiC, by adjusting the Si / C ratio of its surface to enhance the hydrogen overflow concentration of the obtained catalyst Pt / SiC surface, Pt nanoparticle in the channel of catalyst can preferentially adsorb C=O bond in reaction and make it active, so as to realize the high activity of the obtained catalyst in cinnamyl aldehyde hydrogenation reaction and the high selectivity of cinnamyl alcohol product.

The present application belongs to the technical field of gas adsorption separation, and particularly relates to a cobalt-based metal organic framework material, a preparation method thereof and application thereof in propylene ethylene separation. The cobalt-based metal organic framework material provided by the present application can preferentially adsorb propylene in a propylene and ethylene mixture, and separation can be implemented at normal temperature and pressure, thereby having low energy consumption and good safety, and thus maximizing economic benefits and energy efficiency. The cobalt-based metal organic framework material provided by the present application has a high specific surface area, and can exhibit high selective separation effect on propylene ethylene mixed gas separation at normal temperature and pressure, and thus has good application prospect. The cobalt-based metal organic framework material provided by the present application can selectively adsorb propylene, and is suitable for propylene and ethylene separation.

The invention discloses a preparation method of an ultrahigh-strength steel member with fatigue impact resistance, which successfully realizes organic unification of ultralow roughness, high steady-state gradient compressive stress and high uniform surface energy on the surface of ultrahigh-strength steel through full-chain coordinated regulation and control. The constructed residual stress field is generated in situ by a self-generated heat-force coupling process induced by laser irradiation no longer depending on external plastic deformation, and is cured into a thermodynamic metastable state through a subsequent multi-field synergistic effect, so that the retention capability of the residual stress field in a service temperature change environment is remarkably improved; meanwhile, by means of oriented reconstruction of a molecular-scale surface energy field, anisotropy of surface free energy is eliminated, the preferential adsorption and electrochemical activation tendency of an environmental medium in a stress concentration area is restrained, and the component can present consistent and predictable energy dissipation behaviors when bearing impact loads for the first time; and the fatigue performance stability and the long-term service reliability are fundamentally improved.

The invention discloses an application of an anti-corrosion commercial coating as a zinc negative electrode coating in an Ah-grade zinc metal soft package battery by introducing an additive into the anti-corrosion commercial coating, and belongs to the technical field of aqueous zinc metal secondary batteries. The invention uses tallow amines as additives to be introduced into commercial coatings. Under the action of an electric field, the preferentially adsorbed tallow amine is chemically adsorbed with zinc, so that the acting force between the coating and the zinc negative electrode is enhanced, and the coating is prevented from falling off. Meanwhile, water-related side reactions are effectively inhibited through coating modification, ordered deposition of zinc ions is guided, an electric field is uniform, the effect of inhibiting dendritic crystal growth is achieved, and the electrochemical reversibility of the zinc negative electrode is improved. Therefore, the ZnZn symmetric battery assembled by using the zinc negative electrode containing the tallow amine coating circulates for 1500 hours at the current density of 2 mA cm <-2 >; the assembled ZnMnO2 button type total battery circulates for 500 circles under the current density of 1A g <-1 >; the soft package battery circulates for 15 circles under the current density of 2 mA cm <-2 >, and has the capacity of 1.0 Ah. The preparation process is simple, the effect is remarkable, the cost is low, and the requirements of environmental economic benefits are met.

The invention discloses catalyst slurry for a high-temperature proton exchange membrane fuel cell (HT-PEMFC) as well as a preparation method and application thereof, and aims to solve the problem that phosphoric acid (PA) in the conventional HT-PEMFC is separated out from a proton exchange membrane and poisons Pt active sites of a catalyst layer, so that the performance of the cell is reduced. The catalyst comprises a carbon carrier, Pt nanoparticles loaded on the carbon carrier and a metal oxide coating the surfaces of the Pt nanoparticles, the catalyst slurry is composed of the catalyst, water, an alcohol dispersant and a long-chain polybenzimidazole (OPBI) binder with the EW greater than or equal to 106, and the catalyst slurry is prepared by compounding the components according to a specific mass ratio and carrying out multi-step ultrasonic dispersion. The slurry is sprayed on carbon paper, the slurry and a high-temperature proton exchange membrane are subjected to hot-pressing assembly to form a membrane electrode assembly (MEA), Lewis acid sites on the surface of the metal oxide can preferentially adsorb phosphate ions and protect Pt active sites, the oxygen reduction reaction (ORR) activity of a cathode is remarkably improved, proton impedance (1.06-1.15 ohm cm < 2 >) is reduced, the electrochemical active area (87-96 m < 2 > / g) is increased, the service life of a battery is prolonged, and the service life of the battery is prolonged. And the preparation process is simple and easy for industrial production.

The invention provides a catalyst for electrooxidation of chlorine-containing electrolyte and a preparation method and application thereof, the catalyst comprises a layered double hydroxide-rare earth basic carbonate heterojunction grown on a nickel substrate in situ, and the nickel substrate is foamed nickel with the surface modified by nickel. On the basis of a strategy for constructing selective adsorption sites capable of distinguishing Cl <-> and OH <->, preferential adsorption of OH <-> is realized by introducing rare earth basic carbonate (RE (OH) CO3), so that the chloride ion corrosion resistance of the material in seawater electrolysis is remarkably enhanced. The heterostructure not only has oxygen evolution reaction activity superior to that of traditional LDH, but also shows excellent structural stability and continuous corrosion resistance under the industrial-grade current density, and a feasible material solution is provided for promoting industrial application of a seawater electrolysis technology.

Methods and systems directed to the separation of a heavy hydrogen isotope, e.g., tritium, from an aqueous stream are described. The methods and systems incorporate a separation media that includes a proton conducting ceramic that at low temperatures preferentially adsorbs heavy hydrogen isotopes and at high temperature preferentially adsorbs lighter heavy hydrogen isotopes. The methods can be temperature controlled to sequentially purify a contaminated stream and regenerate the separation media. The separation media can be free of traditional hydrogen isotope exchange catalyst materials.

The invention provides a method for separating ethylene and ethane, a CHA type molecular sieve adsorbent for separating ethylene and ethane and a preparation method of the CHA type molecular sieve adsorbent, and relates to the technical field of gas separation materials. Compared with the prior art, the method for separating ethylene and ethane provided by the invention can directly utilize waste heat of pyrolysis gas for separation, so that a cooling step is omitted, and the energy consumption is reduced; the adopted adsorbent is low in cost, the performance degradation rate is less than or equal to 5% after three times of circulation, and the method is suitable for industrial popularization; and the operation process is simple, complex equipment is not needed, and large-scale application is easy. The CHA type molecular sieve adsorbent for separating ethylene and ethane provided by the invention has the advantage of preferential adsorption on ethylene, can realize efficient separation of ethylene and ethane, and has good adsorption stability and long adsorption life under medium and high temperature conditions. The problems that the thermodynamic stability of an existing molecular sieve adsorbent is suddenly reduced under the medium-high temperature condition, and efficient separation of ethylene and ethane cannot be achieved under the medium-high temperature condition are solved.