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677results about How to "Improve hydrolytic stability" patented technology

Cation water polyurethane/acrylic ester composite emulsion and preparation method thereof

The invention relates to cationic water-based polyurethane/acrylic ester composite emulsion and the preparation process, belonging to the chemical product and preparation technology field. Raw materials comprise diisocyanate mixture, polyhydric alcohol, organotin catalyst, chain extender, thinner, neutralizing agent and initiating agent. The preparation process comprises adding polyhydric alcohol into a reactor to dehydrate in vacuum, adding into diisocyanate mixture and organotin catalyst, conducting prepolymerization reaction to synthesize prepolymer with isocyanate-termi-nated, coldly adding thinner to dilute and to condense and reflow, adding chain extender to obtain mixture through chain extending reaction, cooling down, adding neutralizing agent to finish salt-forming reaction, regulating pH value, adding deionized water to conduct dispersed emulsification to obtain cationic water-based polyurethane elusion, and heating up and adding initiating agent to initiate free radical polymerization reaction to prepare composite elusion. The cationic water-based polyurethane/acrylic ester composite emulsion is synthesized through adopting non solvent process with low pollution and environment-friendly, increases solvent resistance, water resistance and tensile strength of glue film through introducing micro-cross-linked structure, increases hydrolytic stability of the glue film through introducing carbodiimide structure, and increases elongation at break and elasticity property through of glue film through introducing 2, 4-MDI.
Owner:WANHUA CHEM GRP CO LTD

Method for preparing polyol ester lubricating oil by using composite solid acid catalyst

The invention relates to a method for preparing polyol ester lubricating oil by using a composite solid acid catalyst. The method comprises the following steps of: adding a water carrying agent into polyol ester and monobasic fatty acid, performing esterification reaction under the action of the composite solid acid catalyst, and dehydrating and esterfying to obtain raw ester; performing filter pressing on the raw ester to separate the raw ester from the solid acid catalyst, wherein the catalyst can be recycled; and performing reduced pressure distillation on the raw ester to remove the residual fatty acid, and then deacidifying and decolorizing to refine with heating by using a refining adsorption bed layer respectively to obtain low-acid value polyol ester lubricating oil. The method has the advantages that the catalyst can be recycled, the esterification rate is high, an aftertreatment process is simple, and a product is low in acid value, high in purity, environment-friendly and suitable to be produced industrially. The reaction esterification rate can reach over 99 percent, and the acid value of the ester product obtained through refining can be controlled to be less than 0.01mg KOH/g. The product is excellent in visco-temperature performance, high in lubricity and thermal stability, strong in hydrolytic stability, low in volatility and excellent in electrical insulation property.
Owner:SHAANXI RES DESIGN INST OF PETROLEUM CHEM IND

Impact-modified polycarbonate compositions having a good combination of natural color, hydrolytic stability and melt stability

The present invention relates to polycarbonate compositions comprising
    • A) from 10 to 99 parts by weight, in each ease based on the sum of components A+B+C, of aromatic polycarbonate and/or aromatic polyester carbonate,
    • B) from 1 to 35 parts by weight, in each case based on the sum of components A+B+C, of rubber-modified graft polymer of
      • B.1 from 5 to 95 wt. % of at least one vinyl monomer on
      • B.2 from 95 to 5 wt. % of one or more graft bases having a glass transition temperature <10° C.,
    • C) from 0 to 40 parts by weight, in each case based on the sum of components A+B+C, of vinyl (co)polymer and/or polyalkylene terephthalate,
    • D) from 0 to 50 parts by weight, in each case based on the sum of components A+B+C, of phosphorus-containing flameproofing agent,
    • E) from 0 to 1.0 part by weight, in each case based on the sum of components A+B+C, of acidic additives, and
    • F) from 0 to 50 parts by weight, in each case based on the sum of components A+B+C, of additives,
    • wherein component B is obtainable by reacting component B.1 with the graft base B.2 by means of emulsion polymerization, with the proviso that in those compositions that are free of components D) and E), the graft polymer dispersion in the spray drying or in the precipitation has a pH value of less than 7,
    • characterized in that there are used in the graft reaction from 0.1 to 5 parts by weight (based on the sum of the parts by weight of the monomers B.1 and of the graft base B.2 that are used=100 parts by weight) of at least one emulsifier selected from the group consisting of alkali, alkaline earth, ammonium and phosphonium salts of a saturated fatty acid having from 10 to 50 carbon atoms, wherein the emulsifier or emulsifiers remains or remain in component B,
and also to a process for the preparation of these polycarbonate compositions and to the use of the polycarbonate compositions in the production of molded bodies, and to the molded bodies themselves.
Owner:BAYER MATERIALSCIENCE AG

Method for producing phosphorus copolymerized flame-retarding terylene high-strength industrial yarns

The invention discloses a method for producing phosphorus copolymerized flame-retarding terylene high-strength industrial yarns, which is characterized by comprising the following steps: pumping ethylene glycol (EG) and purified terephthalic acid (PTA) into a pulping kettle according to a molar ratio of 1.15 for pulping; after uniform pulping, transferring the uniform pulp into an esterification kettle for esterification; after the esterification is accomplished, adding blended liquid of a flame retardant, uniformly mixing, and adding the mixture into a polymerization kettle; after the polymerization is accomplished, discharging and cutting to obtain flame-retarding polyester chips with a viscosity of 0.61; feeding the prepared flame-retarding polyester chips into a solid-phase polymerization system, and improving the viscosity to 0.90 to 1.10; and melting at a high temperature into molten spinning solution in a screw extruder, spinning by a spinning component, drawing, and thermally setting to obtain phosphorus copolymerized flame-retarding terylene high-strength industrial yarns. In the invention, a copolymerized flame-retarding modification process is used for flame-retarding modification of the polyester, and the obtained terylene industrial yarns have high strength and a permanent flame-retarding property.
Owner:ZHEJIANG GUXIANDAO POLYESTER DOPE DYED YARN CO LTD
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