The invention provides an advanced alkane purifying method for removing impurities. The method comprises the following steps: 1, alkane to be purified contacts with an alkali solution; 2, the alkane contacts with a copper adsorbent; and 3, the alkane contacts with an adsorbent for selectively adsorbing polar compounds to obtain advanced purified alkane. The advanced alkane purifying method for removing impurities can be used for advanced purification of a C3-C5 alkane fraction generated through FCC; and an alkali washing processing unit, a fine desulphurization unit and a polar compound adsorption unit are used to remove hydrogen sulfide, mercaptan, carbon oxysulfide and other sulfides, and a small content of methanol, dimethyl ether and / or acetone and other impurities, so the C3-C5 alkane fraction generated through the FCC is suitable for being converted to propylene, isobutene or pentene, so the output of olefins is improved, the life of an alkane dehydrogenation catalyst is prolonged, the unit consumption is reduced, the economic benefit is improved, and the operation of a downstream dehydrogenation method is improved.