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77 results about "Mercapto Compounds" patented technology

Process for the preparation of ergothioneine and use of mercapto compounds therein

ActiveCN119432939BChemical recyclingFermentationPtru catalystThiol Reagents
The application provides a preparation method of ergothioneine and application of a mercapto compound in the method. The method comprises the following steps: in the presence of a catalyst system, a sulfur oxide is reacted to generate ergothioneine. The catalyst system comprises a first catalyst and a second catalyst. The first catalyst is ergothioneine synthase, and the second catalyst is one or more of a mercapto-containing amino acid and a mercapto-containing polypeptide. The preparation method of ergothioneine provided by the application does not need to use a large amount of a chemical mercaptan reagent with a foul smell, has the advantages of high efficiency, green environmental protection, and friendly production scene, and is beneficial to industrial production of ergothioneine.
Owner:ABIOCHEM BIOTECH CO LTD

Method for low-alkalinity flotation of lead-zinc (silver-containing) polymetallic ore based on heterocyclic sulfydryl coordination polymer

The invention discloses a method for low-alkalinity flotation of lead-zinc (silver-containing) polymetallic ore based on a heterocyclic sulfydryl coordination polymer, which comprises the following steps of: adjusting the pH value of ore pulp to 7.5 + / -0.3, and sequentially carrying out roughing, scavenging and concentration by adopting a composite collecting agent according to a gradient flotation procedure; wherein the mass concentration of the ore pulp is 20-40%; the adding amount of the composite collecting agent is 150-300g / t of ore pulp; the composite collecting agent is composed of a modified heterocyclic sulfhydryl compound, C12-C18 alkylamine polyoxyethylene ether and a star-shaped branched nonionic surfactant according to the mass ratio of 1: (1-3): (0.5-2). According to the method, the complex silver polymetallic ore is subjected to efficient flotation under the low-alkalinity condition by applying the composite collecting agent based on the heterocyclic sulfydryl coordination polymer. Through deep exploration and optimization of a flotation reagent system, process parameters and a microcosmic action mechanism, the recovery rate of metal such as silver, copper and lead is remarkably increased, and the ore dressing cost is greatly reduced.
Owner:METALLURGICAL LABORATORY BRANCH OF SHANDONG GOLD MINING TECHNOLOGY CO LTD

Surfactant with branched structure as well as preparation method and application of surfactant

The invention discloses a surfactant with a branched structure as well as a preparation method and application of the surfactant. The preparation method comprises the following steps: carrying out Michael addition reaction on an amphiphilic branched polymer and polyfluorinated organic amine in an organic solvent in the presence of a catalyst to obtain the surfactant with the branched structure, the amphiphilic branched polymer has a hydrophilic chain segment and a hydrophobic chain segment, and the tail end of a branched molecular chain has double bonds. The amphiphilic branched polymer is obtained by copolymerization of polyethylene glycol di (methyl) acrylate and polypropylene glycol di (methyl) acrylate through active free radicals, or is prepared by Michael addition polymerization of a di (methyl) acrylate compound and a dimercapto compound or a diamine compound in an organic solvent in the presence of a catalyst. The surfactant can quickly reduce the surface tension and prolong the retention time of pesticide liquid, and is green, environment-friendly and degradable.
Owner:NANJING TECH UNIV

Stabile silane modified polymer composition and method

ActiveUS12662568B2Polymer scienceOrganometallic catalysis
An alkoxysilyl-containing polyurethane polymer composition is prepared using a urethane-forming organometallic catalyst which is then stabilized to moisture exposure by the addition of a mercapto-containing compound. The stabilized moisture-curable alkoxsilyl-containing polyurethane polymer composition is activated to moisture curing by the addition of a hydrolysis and condensation catalysts. The stabilized moisture-curable alkoxsilyl-containing polyurethane polymer composition is useful as a component in the preparation of coatings, adhesives, sealants, consumer goods and industrial goods.
Owner:MOMENTIVE PERFORMANCE MATERIALS INC

Tellurium-based nano material capable of efficiently inducing copper death as well as preparation method and application of tellurium-based nano material

The invention discloses a tellurium-based nano material capable of efficiently inducing copper death as well as a preparation method and application of the tellurium-based nano material. The preparation method comprises the following steps: by taking water as a medium, mixing soluble copper salt and a sulfydryl-containing compound, and stirring to react, so as to obtain a Cu-S2 solution; dropwise adding the Cu-S2 solution into the TeO2 nano-carrier solution, and carrying out stirring reaction; and after the reaction is finished, carrying out solid-liquid separation, taking the solid, and resuspending with methanol to obtain the TeO2 coated Cu-S2 nano material. The preparation method is simple and rapid, large-scale production can be achieved, and the obtained TeO2 coated Cu-S2 nano material can efficiently induce cancer cells to generate copper death, is effective to various cancer cells and has potential clinical transformation application prospects.
Owner:JINAN UNIVERSITY

A fluorine-free organic small molecule-based ultrathin superhydrophobic coating and a preparation method thereof

The application discloses a kind of based on fluorine-free organic small molecule ultra-thin super-hydrophobic coating and preparation method thereof, specific steps are as follows: 20 portions-40 portions of amine compound, 20 portions-40 portions of epoxy compound and 20 portions-40 portions of solvent are mixed, and mixed solution is obtained.After substrate is soaked in mixed solution 1h-24h, pretreated substrate is obtained.1 portion-30 portions of olefin compound, 1 portion-25 portions of polydimethylsiloxane, 1 portion-25 portions of initiator, 1 portion-40 portions of mercapto compound, 1 portion-40 portions of solvent are mixed, and mixed coating is obtained.Mixed coating is evenly covered on the surface of pretreated substrate, and after standing 1h-7h, it is dried, and ultra-thin super-hydrophobic coating is obtained.The ultra-hydrophobic coating prepared by the method has excellent stability, durability, self-cleaning property and oil-water separation performance, and can be widely used for separating immiscible oil-water mixture.
Owner:XIAN UNIV OF TECH

Preparation method of super-hydrophobic cotton cloth with self-cleaning and oil-water separation functions

The application provides a preparation method of super-hydrophobic cotton cloth with self-cleaning and oil-water separation functions, and belongs to the technical field of functional materials. The preparation method is characterized by the following steps: modifying a commercial cotton cloth by using a silane surfactant to modify a mercapto group, in-situ grafting polybutadiene on the modified cotton cloth by using a photosensitizer in a n-hexane solution, and grafting hydrophobic particles to the cotton cloth by using a bis-mercapto compound. The super-hydrophobic cotton cloth prepared by the application has good super-hydrophobic performance and oil-water separation selectivity, and has a super-high continuous adsorption efficiency of oil in an oil-water mixture, which can reach 99.9%. The application has a simple process and is suitable for industrial production. The super-hydrophobic cotton cloth prepared by the application has high stability, can be recycled, and can be used for repairing water bodies such as marine oil spills and oil-containing industrial wastewater treatment.
Owner:QINGDAO UNIV OF SCI & TECH

A method for low temperature preparation of bis-sulfides

The application discloses a method for preparing a disulfide at low temperature, which comprises the following steps: coupling reaction of m-dihalobenzene and a mercapto compound in the presence of sodium hydride and lithium iodide to prepare the disulfide. At present, the existing methods for synthesizing a disulfide have some problems to a greater or lesser extent. Either noble metal catalysis is needed, the cost is high, and there is a risk of heavy metal residue in the product; or the reaction operation is complex and complicated, and the reaction condition is harsh. The application develops a new method, which can start from cheap and readily available raw materials, use cheap initiators, and simply and effectively synthesize a disulfide under mild reaction conditions, so as to meet the needs of research and development and actual production.
Owner:SUZHOU UNIV

Sulfur-containing gem-difluoroallyl compound as well as preparation method and application thereof

The invention discloses a sulfur-containing gem-difluoroallyl compound as well as a preparation method and application thereof. The invention provides a preparation method of a compound as shown in a formula C. The preparation method comprises the following step: in a solvent, in the presence of alkali, carrying out gem-difluoroallylation reaction on a compound as shown in a formula A and a compound as shown in a formula B to obtain the compound as shown in the formula C. According to the method, the sulfydryl in the sulfydryl-containing compound can be mildly and efficiently gem-difluoroallylated, metal catalysis is not needed, the reaction can be performed in a water phase, the operation is simple, and the method is suitable for performing rapid fluoroalkylation modification and further functional modification on polypeptide, protein, complex bioactive molecules and the like; the method has very important application prospects in the fields of medicine, life science and the like.
Owner:SHANGHAI INST OF ORGANIC CHEM CHINESE ACAD OF SCI

An electro-assisted passivation solution, its preparation method, and passivation method

This invention discloses an electro-assisted passivation solution and its preparation and passivation methods. The raw materials of the electro-assisted passivation solution include the following components: 0.1-1 wt.% alkali-soluble mercapto compound, 0.1-1 wt.% amphoteric oxide, 1-5 wt.% inorganic alkali, 0.5-1.5 wt.% nonionic surfactant, and the balance being water. The components do not contain toxic substances. The passivation solution is suitable for electro-assisted passivation processes. The film formation process on copper parts is very fast, and the formed film layer is dense and uniform, resulting in good corrosion resistance, high protection effect, and environmental friendliness for the copper parts.
Owner:ZHONGNAN TRANSMISSION MACHINERY FACTORY CHANGSHAAVIATION IND

Aromatic dipeptide functionalized mercapto compounds, methods of making and using the same

The application relates to the technical field of compound synthesis, and discloses an aromatic dipeptide functionalized mercapto compound, 3,5-di(triphenylmethylthio)benzoic acid is obtained by adding 3,5-di(methylmercapto)benzoic acid and pyridine into a solution of chloromethyl triphenylphosphonium, purifying after sufficient reaction; then the 3,5-di(triphenylmethylthio)benzoic acid is mixed with N-hydroxysuccinimide and dissolved in an organic solvent, EDC.HCl is added, purifying after sufficient reaction; then 2,5-dioxopyrrolidin-1-yl 3,5-bis(triphenylmethylthiomethyl)benzoate is obtained; then phenylalanine-tryptophan and triethylamine are added, purifying after sufficient reaction; then (3,5-bis(triphenylmethylthiomethyl)benzoyl)tryptophylphenylalanine is obtained; then trifluoroacetic acid and triethylsilane are added, purifying after sufficient reaction; and finally the aromatic dipeptide functionalized mercapto compound is obtained. The aromatic dipeptide functionalized mercapto compound can quickly and effectively identify sodium and potassium ions, and has relatively low detection limit and relatively loose detection condition.
Owner:HUANENG WUHAN POWER GENERATION CO LTD

Preparation method of ultra-thin high-strength paper-based adhesive tape body paper

The invention relates to the technical field of papermaking, in particular to a preparation method of ultrathin high-strength paper-based adhesive tape base paper. The preparation method comprises the following steps: mixing softwood pulp and hardwood pulp, forming base paper by adopting a double-net dehydration process, and forming a covalent cross-linked network in a paper sheet by adopting a cellulose reactive coupling agent with an o-benzoquinone structure and a multi-sulfydryl compound based on a sulfydryl-benzoquinone click chemistry and interface supramolecular assembly multi-bonding enhancement system; meanwhile, a dual intelligent enhancement system based on a biomacromolecule self-assembly body and a dynamic metal coordination network is established, and dynamic reversible crosslinking is constructed through a polyelectrolyte compound and a Fe < 3 + >-tannic acid coordination network; a multifunctional surface treatment technology combining a zwitterionic polymer brush and bionic in-situ mineralization is developed, a sulphobetaine methacrylate polymer brush grows through a surface-initiated atom transfer radical polymerization method, amorphous silicon dioxide is induced to be mineralized, and the adhesive tape body paper prepared through the method is high in strength.
Owner:ZHEJIANG KAIFENG NEW MATERIAL CO LTD

Photosensitive resin composition, resist ink, resist laminate, and use thereof

The application provides a photosensitive resin composition, a resist ink, a resist laminated body and application thereof. The photosensitive resin composition comprises, in parts by weight, 50-70 parts of an alkali-soluble resin, 30-50 parts of a photopolymerizable monomer and 0.1-4.0 parts of a photoinitiator; wherein the photopolymerizable monomer comprises an allyl compound and a mercapto compound, and the mass content of the mercapto compound in the photopolymerizable monomer is 7wt%-22wt%. The application introduces the allyl compound and the mercapto compound into the photosensitive resin composition, the alkyl group in the allyl compound can add polymerize with the mercapto group in the mercapto compound, which helps to make the prepared photosensitive resin have relatively uniform crosslinking after exposure, and obtain a photosensitive resin with low polymerization shrinkage stress, which shows good adhesion in the bonding process of a copper substrate.
Owner:HANGZHOU FIRST ELECTRONIC MATERIAL CO LTD

Application of phenolic anti-aging agent with thermal oxidation resistance and ozone aging resistance in diene rubber composite material

PendingCN121203242ACrazingChemical reaction
The invention discloses an application of a phenolic anti-aging agent with thermal oxidation resistance and ozone aging resistance in a diene rubber composite material. The phenolic anti-aging agent is obtained by reacting a natural antioxidant containing a phenolic hydroxyl group and unsaturated double bonds with a sulfhydryl compound. According to the invention, the natural antioxidant is modified by adopting click chemical reaction, and the obtained product has excellent performance in the aspects of thermo-oxidative aging resistance and ozone aging resistance, so that the thermo-oxidative aging process of the rubber composite material can be obviously slowed down, and cracks generated on the surface of the material due to uniform cracking of ozone can be effectively reduced.
Owner:BEIJING UNIV OF CHEM TECH

Injectable self-healing hydrogel based on thiohemiketal as well as preparation method and application of injectable self-healing hydrogel

The invention discloses an injectable self-healing hydrogel based on thiohemiketal as well as a preparation method and application thereof, and the injectable self-healing hydrogel is prepared according to the following steps: (1) preparation of a water-soluble trifluoroacetophenone monomer: adding 1-(4-(bromomethyl) phenyl)-2, 2, 4-triazole-1-yl)-1, 2, 4-triazole-1-yl)-2, 2, 4-triazole-1-yl)-2, 2, 4- The preparation method comprises the following steps: carrying out quaternization reaction on 2, 2-trifluoroethyl-1-ketone and a quaternization reagent containing double bonds to obtain a water-soluble trifluoroacetophenone monomer; (2) carrying out free radical copolymerization on a water-soluble trifluoroacetophenone monomer and a hydrophilic monomer to obtain a trifluoroacetophenone functionalized linear polymer; and (3) mixing the trifluoroacetophenone functionalized linear polymer with the aqueous solution of the multi-sulfhydryl compound to obtain the injectable self-healing hydrogel based on the thiohemiketal. According to the method, a linear polymer functionalized by trifluoroacetophenone reacts with a multi-sulfhydryl compound to form the thiohemiketal dynamic cross-linked injectable self-healing hydrogel, so that the problems that part of dynamic covalent hydrogel is insufficient in self-healing performance and limited in pH use range are solved.
Owner:SOUTHWEST UNIV

Efficient collecting agent applied to iron ore reverse flotation desulfurization and preparation method and application of efficient collecting agent

The invention discloses an efficient collecting agent applied to iron ore reverse flotation desulfurization and a preparation method and application of the efficient collecting agent, and particularly relates to the technical field of beneficiation reagents. The efficient collecting agent is a dimercapto compound, sulfur atoms in molecules of the dimercapto compound show high electron donating capacity, and when the sulfur atoms react with metal ions, the sulfur atoms in the molecules of the dimercapto compound show high electron donating capacity; sulfur atoms form coordinate bonds with metal ions by means of lone pair electrons, and the dissociation tendency of the metal ions is remarkably reduced in the process, so that the overall stability of the formed complex is improved. The disulfhydryl compound can generate insoluble black complex precipitates with Fe < 2 + > ions in ore pulp, but cannot generate precipitates with Fe < 3 + > ions, so that the disulfhydryl agent has very strong collecting capacity on pyrite and cannot react with hematite, ether bonds are introduced into the disulfhydryl compound, the solubility, surface tension and molecular activity of the disulfhydryl compound can be increased, and the disulfhydryl compound can be used for collecting the hematite. The collecting capacity is enhanced, and effective separation of pyrite and hematite can be achieved by using dimercapto ether as the collecting agent.
Owner:NANJING MEISHAN METALLURGY DEV

Method for preparing 3-mercaptopropionic acid by efficiently catalyzing acrylic acid-hydrogen sulfide addition reaction through organic phosphine

The embodiment of the invention relates to the field of catalytic synthesis of sulfhydryl compounds, in particular to a method for preparing 3-mercaptopropionic acid by efficiently catalyzing an acrylic acid-hydrogen sulfide addition reaction through organic phosphorus. Uniformly mixing acrylic acid, a polymerization inhibitor and part of a solvent, and transferring the mixture into a constant-pressure titrator; uniformly mixing an organic phosphine catalyst with the residual solvent, and transferring the mixture into a high-pressure kettle; the method comprises the following steps: connecting a constant-pressure titrator with a high-pressure kettle, firstly introducing inert gas to purge a reactor, then sequentially introducing reducing gas and hydrogen sulfide gas, and maintaining the pressure for a certain period of time; starting a constant-pressure titrator and dropwise adding a raw material mixed solution containing acrylic acid at a certain rate; and after the raw material mixed solution is dropwise added, introducing hydrogen sulfide gas again, and carrying out an acrylic acid-hydrogen sulfide addition reaction. The reaction conditions for preparing the 3-mercaptopropionic acid provided by the invention are mild, the generation amount of three wastes is small, the high reaction yield of the 3-mercaptopropionic acid can be realized under the conditions of low reaction temperature and pressure, and the 3-mercaptopropionic acid product with the purity of more than 99.8% can be obtained from the reaction liquid through a vacuum distillation process.
Owner:新疆兴发化工有限公司 +1

Catalytic synthesis of bisphenol A by modified AI ion exchange resin

The invention relates to the technical field of organic synthesis catalysis, and discloses a method for catalytically synthesizing bisphenol A by using modified Al ion exchange resin, which comprises the following steps: firstly, pretreating 732 # ion exchange resin: soaking the 732 # ion exchange resin by using a saturated salt water solution with the volume twice that of the treated resin, and rinsing by using deionized water after the salt water is completely discharged, so that discharged water is not yellow; soaking the resin by using a NaOH solution with the mass concentration of 2-4% and the same amount as that of the NaOH solution, and washing the resin by using deionized water after the alkali liquor is completely discharged until discharged water is close to neutral; and finally, soaking in an HCl solution with the mass concentration of 5% and the same amount as the above, completely discharging the acid solution, washing with deionized water until the solution is neutral, and drying for later use. The modified Al ion exchange resin is used for catalytic synthesis of bisphenol A, the modified Al ion exchange resin can be used as a catalyst, the reaction time is shortened, the recovery efficiency is high, a sulfhydryl compound is not needed as a cocatalyst, the molar ratio of phenol to acetone is 8: 1, and the cost of raw materials is greatly reduced.
Owner:天津仁爱学院

Modified carbon black, method for preparing the same, and use thereof

The application relates to the technical field of modified carbon black for rubber, and discloses a novel modified carbon black and a preparation method and application thereof. The preparation method of the novel modified carbon black comprises the following steps: dissolving cardanol glycidyl ether, a catalyst and a mercapto compound in an organic solvent, then adding carbon black, uniformly stirring, and then performing constant-temperature reaction to obtain a crude product; and the crude product is washed and vacuum-dried to obtain the novel modified carbon black. The novel modified carbon black has multiple active groups and nonpolar long side chains. The long side chain nonpolar groups make it difficult for the carbon black to agglomerate, so that the carbon black can be better dispersed in natural rubber. The double bonds on the long side chains can form crosslinking bonds with the rubber, the interaction force between the carbon black and the rubber is increased in a chemical bond mode, and then the mechanical properties and processing properties of the rubber are improved. In addition, the modified carbon black containing sulfur elements can promote vulcanization of the rubber, improve the vulcanization efficiency, and further improve the mechanical properties and processing properties of the rubber.
Owner:SOUTH CHINA UNIV OF TECH +1

Preparation method of 3-mercaptopropionic acid

The present disclosure relates to the field of synthesis of mercapto compounds, and in particular, to a preparation method of 3-mercaptopropionic acid. The preparation method provided by the present disclosure comprises the steps of: mixing sodium acrylate with sodium hydrosulfide or sodium sulfide for reacting; adding sodium sulfide (or adding sodium sulfide and sulfur powder) for further reacting; crystallizing, and acidifying with an acid to obtain a solution of 3-mercaptopropionic acid. According to the preparation method provided by the present disclosure, the raw materials are inexpensive, the product 3-mercaptopropionic acid can be obtained with a high yield and high purity, moreover, and solid waste and solvent(s) can be separated and recovered; sodium salt can be used as an industrial product after crystallization; the solvent(s) can be recovered and recycled by distillation; and disposal of three wastes is simple.
Owner:HEBEI HOFMANN NEW MATERIAL TECH CO LTD

Systems and methods of making polymeric optical layers for optical layering

The present disclosure relates to systems and methods of making polymeric optical layers for optical layering applications. In an aspect, a waveguide device for a head mounted display is provided. The waveguide device may include a waveguide die having a first refractive index range and a polymeric optical layer. The polymeric optical layer may include a second refractive index range that is different from the first refractive index range and a thiol-containing polymer. For example, the thiol-containing polymer may include thiourethane. In some embodiments, the thiol-containing polymer may be formed from a monomer mixture including a thiol-containing compound and an isocyanate. For example, the thiol-containing compound may include 4-mercaptomethyl-3,6-dithia-1,8-octanedithiol (MDTODT) and / or the isocyanate may include m-xylylene diisocyanate (XDI). In some embodiments, the monomer mixture may include a second thiol-containing compound, such as, for example, 1,3-benzene dithiol (1,3-BDT).
Owner:META PLATFORMS TECHNOLOGIES LLC

Multifunctional hydrogel for treating traumatic brain injury and preparation method and application thereof

The present application relates to a multifunctional hydrogel for treating traumatic brain injury and a preparation method and application thereof. The preparation method of the hydrogel comprises the following steps: step 1, dissolving a tetracycline drug in a buffer to prepare a tetracycline drug solution; step 2, adding a multi-arm polyethylene glycol with a double bond end group into the solution prepared in step 1 to form a solution containing the multi-arm polyethylene glycol with a double bond end group and the tetracycline drug; step 3, adding a multi-sulfhydryl compound into the solution prepared in step 1 to form a solution containing the multi-sulfhydryl compound and the tetracycline drug; and step 4, mixing the solutions prepared in steps 2 and 3 to prepare the hydrogel. In the acute phase, the active oxygen rapidly increases to make the hydrogel release more drugs to regulate the inflammatory environment and play a neuroprotective role, and in the chronic phase, the hydrogel continuously releases drugs to continuously regulate the anti-inflammatory polarization of microglia cells, enhance neural plasticity and restore nerve function.
Owner:BEIJING TSINGHUA CHANGGUNG HOSPITAL +1

Modified vegetable protein adhesive and preparation method thereof

The invention discloses a modified vegetable protein adhesive and a preparation method thereof. The adhesive comprises two core types: one core type is prepared from vegetable protein meal, alkali, urea, water and a thiolated PAE resin cross-linking agent; and the other one is prepared from vegetable protein meal, alkali, urea, water and a water-borne epoxy resin cross-linking agent. The sulfhydrylated PAE resin cross-linking agent is prepared by grafting a sulfhydryl-containing compound to a polyamide polyamine main chain, and a compact cross-linked network can be formed through the effects of disulfide bond construction and the like; the water-borne epoxy resin cross-linking agent is prepared from epoxy resin, methacrylic acid, a comonomer and other raw materials through copolymerization and neutralization, and protein hydrophilic groups can be effectively blocked. The adhesive disclosed by the invention is modified by the specific cross-linking agent, so that the bonding strength and the water resistance are remarkably improved, meanwhile, the advantages of environment friendliness and no formaldehyde are kept, and the adhesive can be widely applied to manufacturing of artificial boards such as plywood and shaving boards.
Owner:HONGNAI WOOD IND (SUQIAN) CO LTD

Polythionocarbamate resin, preparation method and application

The invention discloses polythionocarbamate resin and a preparation method and application thereof.The polythionocarbamate comprises a thioamide group, an aliphatic thioether group, an aromatic thioether group and an aromatic benzene ring skeleton, and further, the polythionocarbamate is prepared from benzyl dithiocyanate, an aromatic sulfhydryl compound, an aliphatic sulfhydryl compound and a solvent; the polythionocarbamate resin provided by the invention has good processability and high refractive index performance. The invention also provides an optical lens, an optical element and an optical device containing the polythionocarbamate resin.
Owner:ZHUHAI MOJIE TECH CO LTD

A highly flexible emulsion, its preparation method, and its application in soft porcelain.

PendingCN122080315AImprove low temperature flexibilityImprove frost resistanceIsooctyl acrylateEpoxy
This invention belongs to the field of building materials technology, specifically relating to a high-flexibility emulsion, its preparation method, and its application in flexible ceramics. The high-flexibility emulsion uses methyl methacrylate, isooctyl acrylate, hydroxyethyl acrylate, and modifier A as core monomers; and methyl methacrylate, styrene, hydroxyethyl acrylate, and modifier B as shell monomers, prepared using a monomer pre-emulsification semi-continuous seed emulsion polymerization process. Modifier A is obtained by reacting epoxidized cashew nut shell powder with a mercapto compound; modifier B is obtained by reacting carboxybenzotriazole, epoxy silane, and epoxy acrylate. This invention prepares a core-shell structured high-flexibility emulsion using a monomer pre-emulsification semi-continuous seed emulsion polymerization process. By introducing specific modifiers A and B into the core and shell monomers, the low-temperature flexibility, frost resistance, tensile properties, and weather resistance of flexible ceramics are optimized.
Owner:GUANGDONG XINRUN STONE NEW MATERIALS CO LTD

A method for detecting dichromate based on surface-enhanced Raman spectroscopy

This invention provides a method for detecting dichromate ions based on surface-enhanced Raman spectroscopy, belonging to the field of analytical chemistry. The method includes: mixing the sample to be tested with a solution containing a thiol compound, adjusting to acidic conditions to allow dichromate ions (Cr(VI)) to undergo a redox reaction with the thiol-containing compound; constructing a SERS substrate, i.e., preparing a ZnO / Ag heterostructure substrate; mixing a suspension of the ZnO / Ag heterostructure substrate with the reaction system to obtain a mixed solution, allowing the ZnO / Ag heterostructure substrate to adsorb the thiol-containing compound and enhance the Raman signal; dropping the mixed solution onto the surface of a solid support, acquiring the Raman spectral signal using a Raman spectrometer, and quantifying the Cr(VI) concentration by the change in signal intensity. This invention achieves rapid and highly sensitive detection of Cr(VI), exhibiting strong selectivity and anti-interference capabilities, and is suitable for detection in fields such as environmental monitoring, food safety, and pharmaceutical analysis.
Owner:GANNAN MEDICAL UNIV

Photocurable material and aqueous humor drainage device and method of manufacturing the same

ActiveCN119185668BSurgeryPolymer scienceMeth-
The application provides a photocuring material and an aqueous humor drainage device and a preparation method thereof, and relates to the technical field of medical devices; the photocuring material is composed of an A component, a B component and a photoinitiator I; the A component comprises A1 raw materials and A2 raw materials; the A1 raw materials simultaneously contain an antimetabolite structure, an F element and a mercapto group; the A2 raw materials are mercapto group-containing compounds; the B component comprises B1 raw materials and B2 raw materials; the B1 raw materials are selected from at least one of triallyl isocyanurate, trimethylolpropane triacrylate, ethyl acrylate and 2-phenylethyl methacrylate; and the B2 raw materials are modified gelatin. The mercapto-ene material with good biocompatibility is adopted, the antimetabolite structure and the F element are combined, the postoperative scar formation of a surgical site can be effectively reduced, the photocuring material has good cell adsorption resistance, and the drainage efficiency is improved.
Owner:MINGCHE BIOTECHNOLOGY CO LTD

A bio-based hyperbranched epoxy resin / bisphenol a epoxy resin composite resin containing imide structure

ActiveCN119751906BFuranPolymer science
The application discloses a kind of bio-based hyperbranched epoxy resin / Bisphenol A type epoxy resin composite resin containing imide structure.Preparation process: (1) the reaction of hydroxyl amine, aldehyde compound and mercapto carboxylic acid obtains mercapto compound A3) ;(2) N-phenyl maleimide, 2,5-furan dimethylamine and mercaptan are synthesized by thiol-olefin click reaction Diamino compound, again with maleic anhydride and carry out imidization reaction, synthesis bio-based maleimide (B2) ;(3) A3 and B2 are synthesized by click reaction end mercapto hyperbranched polymer, again with alkenyl epoxy compound and generate bio-based hyperbranched epoxy resin by click reaction;(4) Bisphenol A type epoxy resin is blended with it and cured, and bio-based hyperbranched epoxy resin / Bisphenol A type epoxy resin composite resin containing imide structure is obtained.The material prepared in the application is environment-friendly and sustainable production, and can be applied to aerospace, turbine technology and other frontier fields.
Owner:SOUTH CENTRAL UNIVERSITY FOR NATIONALITIES

Heavy metal wastewater treatment agent and application thereof

The application discloses a heavy metal wastewater treatment agent and a use method thereof, and relates to the technical field of sewage treatment. The heavy metal treatment agent mainly comprises an agent A, an agent B and an agent C, wherein the agent A is a liquid agent and contains the following raw materials in parts by weight: 40-45 parts of a strong oxidant, 2-5 parts of a chelating agent and 2-5 parts of a catalyst; the agent B is a solid agent and is mainly a heavy metal adsorbent; the nano zero-valent iron is modified twice by a mercapto compound and a porphyrin compound, so that the adsorption capacity for heavy metals is increased, the electron transfer efficiency is improved, and the reduction performance of the nano zero-valent iron is enhanced; and the agent C is a liquid agent and mainly contains 1-5% of a flocculant and 0.1-0.2% of a coagulant aid. The heavy metal ion-containing wastewater treatment agent provided by the application has a removal efficiency of more than 95% for heavy metal wastewater with low pH value and complex components, and the effluent is stable and reaches the discharge standard.
Owner:GEJIU HONGRUN DRAINAGE CO LTD