The invention relates to the technical field of artificial fibers, and provides a
bamboo charcoal surface modification method for
spinning, a modification device and a nylon 6 preparation method, and the method comprises the following steps: putting dry
bamboo charcoal powder into a closed reaction cavity, and introducing
ozone;
ozone is decomposed into
oxygen and
oxygen atoms in the reaction cavity; reacting the
oxygen atoms with carbon atoms in the
bamboo charcoal to generate an intermediate-COO <->; capturing a
hydrogen atom from the surface of the bamboo
charcoal by the intermediate to generate carboxyl-COOH, so as to obtain carboxyl modified bamboo
charcoal powder. Therefore, the strong oxidizing property of oxygen atoms is utilized, carboxyl is introduced to the surface of the bamboo
charcoal, and the modified bamboo charcoal is prepared. Carboxyl of the modified bamboo charcoal
powder is grafted to short-chain nylon 6, so that the compatibility of bamboo charcoal particles and a nylon 6 matrix is improved. Meanwhile, agglomeration of the bamboo charcoal particles is reduced, and dispersion of the bamboo charcoal particles in a nylon 6 matrix is facilitated. The notch
impact strength of the prepared nylon 6 is remarkably improved, the
yarn breaking probability is reduced, and the problems that a spinneret plate is blocked in the
spinning process and the like are solved.