320 results about "Hexanoic acid" patented technology

The invention discloses a pure bio-based polyhydroxyalkanoate adhesive as well as preparation and application thereof, and belongs to the technical field of degradable adhesives. According to the adhesive, polyhydroxybutyrate valerate or polyhydroxybutyrate hexanoate is used as a matrix, and the acid value reaches 2-15 mg KOH / g through molten end group activation; a reactive emulsifier with a hydrophilic-lipophilic balance value of 9-12 is introduced into a water phase, and the stable aqueous dispersion is prepared through phase inversion high-shear emulsification. The Z-average particle size of the dispersion is 0.12-0.30 [mu] m, and the content of the free surfactant is not higher than 30wt%. After the tackifying resin, the plasticizer and the vegetable wax are compounded, the bio-based carbon content of the obtained adhesive is not lower than 95%, and the volatile organic compound content is not higher than 100 mg / kg. The paper / paper heat sealing strength of the adhesive is not lower than 7.0 N / 15mm, the 180-degree peel strength is not lower than 7.5 N / 25mm, and the adhesive can pass repulping evaluation.

The invention discloses a biosynthesis system for high-yield 1, 6-hexamethylenediamine and application of the biosynthesis system, and belongs to the technical field of biology. According to the method, key genes which are excavated and optimized in a 1, 6-hexamethylenediamine biosynthetic pathway are co-expressed in a single cell module or a multi-cell module, and different enzyme elements expressed by the cell module are subjected to enzyme cascade reaction, so that 1, 6-hexamethylenediamine can be efficiently synthesized by taking caprolactam or 6-aminocaproic acid as a substrate; furthermore, after the carboxylic acid reductase MaCAR is mutated, the catalytic activity of the carboxylic acid reductase MaCAR can be remarkably improved, and the yield of the 1, 6-hexamethylenediamine is further improved; in addition, the biosynthesis system disclosed by the invention directly takes the cell module as a whole-cell catalyst, and an enzyme purification step is avoided, so that the biosynthesis system has the advantage of low cost.

The application belongs to the technical field of daily chemical industry, and particularly relates to an emulsion and a preparation method thereof. The emulsion provided in the application comprises an emulsifier, glycerol, oil-phase active substance, pentaerythritol tetra(ethylhexanoate) and water; the emulsifier is a lipopeptide; the weight percentage of the lipopeptide and the glycerol is not less than 3%; the weight ratio of the oil-phase active substance and the pentaerythritol tetra(ethylhexanoate) is 1:3-10; the ratio of the sum of the weights of the lipopeptide and the glycerol to the sum of the weights of the oil-phase active substance and the pentaerythritol tetra(ethylhexanoate) is 1:3-10; and the ratio of the sum of the weights of the lipopeptide, the glycerol, the oil-phase active substance and the pentaerythritol tetra(ethylhexanoate) to the weight of the water is 1:1-4. The emulsion is prepared by using sodium bacillomycin, glycerol and pentaerythritol tetra(ethylhexanoate), can effectively inhibit the diffusion of the oil-phase active substance at the interface of the emulsion, reduce the oxidative degradation of the oil-phase active substance, and greatly prolong the effective action time of the oil-phase active substance in the emulsion.

The invention discloses an antistatic PET dust-free film and a preparation method thereof, and relates to the technical field of high polymer materials. When the antistatic PET dust-free film is prepared, firstly, 6-bromohexanoic acid reacts with 4-imidazole-1-butyric acid, and then is subjected to ion exchange with potassium hexafluorophosphate to prepare diacid imidazole hexafluorophosphate ionic liquid; the preparation method comprises the following steps: enabling montmorillonite to react with tetraethoxysilane, 3-aminopropyltriethoxysilane and dodecyl triethoxysilane, so as to obtain modified montmorillonite; carrying out copolycondensation on terephthalic acid, the diacid imidazole hexafluorophosphate ionic liquid, ethylene glycol and the modified montmorillonite to prepare a modified polyester master batch; and carrying out melt blending on the modified polyester master batch and a chain extender, and carrying out blow molding to obtain the antistatic PET dust-free film. The prepared antistatic PET dust-free film has the advantages of being antistatic, flame-retardant, super-hydrophobic and low in dust adhesion rate.

The invention belongs to the technical field of organic synthesis, and particularly relates to an asymmetric phenanthroline compound as well as a preparation method and application thereof. Compared with the original symmetric ligand compound, the asymmetric phenanthroline compound provided by the invention has the advantage that the extraction performance and selectivity of americium are improved. In addition, the asymmetric phenanthroline compound provided by the invention is stable in structure, has good acid resistance and radiation resistance, can be suitable for high-acidity post-treatment waste liquid, improves the fat solubility of the phenanthroline ligand, is easy to split phases, does not need to use 2-bromohexanoic acid and other synergistic extractants, and reduces the introduction of secondary wastes in the post-treatment process.

A composition comprising: i) from 2% to 5% by weight of an aqueous solution comprising a hydrophilic active ingredient; ii) from 1% to 2% by weight of methyl glucose sesquistearate; iii) from 10% to 12% by weight of a polyglycerol-3 ester of a fatty acid; iv) at least 83% by weight of an ester oil selected from the group consisting of cetyl ethylhexanoate, isopropyl isostearate, and ethylhexyl palmitate; and wherein all weight percentages are based on the total weight of the composition; and wherein the sum of i), ii), iii) and iv) does not exceed 100% by weight. A method for dispersing a hydrophilic active ingredient in an oil. A cosmetic or dermatological pharmaceutical formulation comprising the initial composition. The invention also relates to a cosmetic or dermatological pharmaceutical formulation. A method of cosmetic, non-therapeutic treatment and / or care of skin, hair, nails and / or mucous membranes of a subject comprising topical application of a cosmetically effective amount of the composition.

The invention belongs to the technical field of cosmetics, and particularly relates to a slow-release permeation-enhancing composition based on a water-in-oil system as well as a preparation method and application of the slow-release permeation-enhancing composition. The slow-release permeation-enhancing type composition is prepared from the following components in parts by weight: 1 to 6 parts of polydimethylsiloxane PEG-10 / 15 cross-linked polymer, 0.1 to 2 parts of PEG-10 polydimethylsiloxane, 2 to 15 parts of polydimethylsiloxane, 2 to 15 parts of glycerol tri (ethylhexoic acid) ester and 0.01 to 2 parts of squalane. The sustained-release permeation-promoting composition has excellent wrapping capacity on active ingredients, oxidation and decomposition of the active ingredients are reduced, and therefore the activity retention rate of the active ingredients is remarkably increased. Moreover, the composition formed by the specific compound components has unique molecular structure and physical properties, and a wrapping system of the composition can effectively control the release rate of the active components, so that the durability and effectiveness of the application effect of the composition are improved, and the permeation promoting effect of the composition is further enhanced.

An antifungal composition including a first essential oil, and a second essential oil, where the composition is configured to reduce disease onset, pathogen spread, or a combination thereof. Further, an antifungal compound including one or more aroma compounds selected from 4-(4-hydroxyphenyl)-2-butanone, furaneol, ethyl methylphenylglycidate, ethyl hexanoate, ethyl butanoate, beta-ionone, alpha-ionone, (R)-(+)-limonene, (S)-(-)-limonene, cis-3-Hexen-1-ol, nerol, linalool, 2-heptanone, alpha-terpineol, beta-damascenone, β-caryophyllene, ethyl 2-methylbutanoate, β-myrcene, gamma-octalactone, alpha-humulene, nerolidol, (E,E)-2,4-decadienal, (E,E)-α-farnesene, vanillin, phenylethyl acetate, citral, 3-methylbutan-1-ol, or a combination thereof.

The invention relates to the technical field of surface treatment, in particular to a bio-based degradable cable material and a preparation method thereof. The bio-based degradable cable material is prepared from 55 to 65 parts of matrix resin mixed by poly L-lactic acid and poly-3-hydroxybutyrate-3-hydroxyhexanoate, 4 to 6 parts of dianhydride modified castor oil polyol, 10 to 15 parts of polypentamethylene diamine adipate, 5 to 8 parts of nano reinforcing filler, 6 to 10 parts of bio-based plasticizer, 0.5 to 1.0 part of antioxidant and 8 to 12 parts of environment-friendly flame retardant. A dynamic ester bond cross-linked network formed by the reaction of a dynamic ester bond cross-linking agent dianhydride modified castor oil polyol only undergoes ester bond breakage at a high temperature exceeding a normal working range to release stress, and the temperature returns to normal and can be recombined; the semi-interpenetrating network reinforced phase poly (pentamethylene diamine adipate) and the matrix resin form an interpenetrating structure in a molecular chain interpenetrating manner, a stable heat-resistant skeleton is constructed, high-temperature deformation is effectively inhibited, the overall degradability of the material is ensured by the bio-based structure, and the balance of heat resistance and degradability is realized.

The application provides a Torulopsis glbrata TS-73 and application thereof in fermented fruit juice, and belongs to the technical field of microbial fermentation.The application adopts a composite mutagenesis method combining ARTP mutagenesis and ultraviolet mutagenesis to obtain a Torulopsis glbrata TS-73 capable of high yield of ethyl hexanoate;when the application is used for preparing fermented cherry juice and raspberry juice, the content of ethyl hexanoate in the cherry juice and the raspberry juice is increased by 44.01% and 54.19% respectively compared with the original strain Torulopsis glbrata G4.The Torulopsis glbrata TS-73 has the advantages of increasing the content of aroma substance ethyl hexanoate and stable performance.

The invention discloses a method for rapidly enriching pit mud high-yield caproic acid functional flora and application, and belongs to the technical field of baijiu brewing microorganisms. According to the method, the aged pit mud which is screened through tests and has better quality is used as seed mud, and the selected high-quality pit mud is subjected to step-by-step amplification culture by adopting a specific culture medium. The obtained bacterial community is a caproic acid producing bacterial community (85%) with the caproic acid producing clostridium as the main body, and the bacterial community can produce more than 10 g / L of caproic acid and less than 2 g / L of butyric acid. The mixed flora obtained by the method disclosed by the invention can be used for culturing and repairing the pit mud, increasing the caproic acid-producing main flora in the pit mud, promoting the pit mud to be aged, preventing the pit mud from being aged and hardened, and effectively improving the quality of raw wine at the same time. And the mixed flora can also be used for fermenting the byproduct yellow water of the Luzhou-flavor liquor to produce caproic acid at high yield, and can be further used for producing high-quality flavoring liquor.

The invention discloses composite ester-based hydraulic oil and a preparation method thereof, and belongs to the technical field of hydraulic oil preparation. The hydraulic oil based on the complex ester comprises the following components: pentaerythritol synthetic ester, polysebacic acid glycol ester, a viscosity-temperature performance regulator, an ash-free antioxidant, a bio-based anti-wear agent and a nano modifier. Wherein the pentaerythritol synthetic ester is a mixed ester obtained by carrying out a reaction on a mixture of 2-ethylhexanoic acid, 3, 5-dimethylhexanoic acid and 4-methyloctanoic acid and pentaerythritol, and the pentaerythritol synthetic ester is a mixture of 2-ethylhexanoic acid, 3, 5-dimethylhexanoic acid and 4-methyloctanoic acid; the viscosity-temperature performance regulator is a grafted copolymer obtained by grafting poly (N-isopropylacrylamide) to a poly (ethylene sebacate) molecular chain through an ester exchange reaction. The product prepared by the method disclosed by the invention can effectively solve the contradiction between the environmental protection performance and the comprehensive performance of the traditional hydraulic oil through the synergistic effect of the components, has the characteristics of high biodegradation rate and good oxidation resistance and hydrolytic stability, and can keep excellent performance in both low-temperature and high-temperature environments.

The invention relates to the technical field of comprehensive treatment of agricultural pests, and particularly provides a bactrocera cucurbitae double-trapping type attractant based on optimal matching of host and intestinal bacteria volatile matters and application of the bactrocera cucurbitae double-trapping type attractant. The attractant comprises an active component and a synergistic component, the active component is derived from balsam pear and towel gourd volatile matters and bactrocera cucurbitae intestinal bacterial metabolites, and comprises 2-methyl ethyl valerate, propyl hexanoate, ethyl hexadienoate, heptanal, benzyl alcohol, 3-methyl acetic acid-1-butanol, indole and 1-undecanol; and the synergistic component is myzobenzoic ketone. Active components are quickly released in the early stage of application, so that the attraction efficiency is remarkably improved; the synergistic component prolongs the trapping lasting period through the slow release effect, and the long-term trapping effect is ensured. All the components of the attractant provided by the invention are biological sources or environment-friendly chemical substances, the attractant meets the requirement of green prevention and control, can efficiently attract male and female adults at the same time, makes up the limitation that a traditional sex attractant only induces male adults or a food attractant only induces female adults, and is beneficial to more comprehensive control of population quantity.

The application relates to the technical field of chemical synthesis, in particular to a synthesis method of a key intermediate of pentconazole, which comprises the following steps: S1, Witting-Horner reaction of 2,4-dichlorobenzophenone and (diethoxy) phosphoethyl acetate under the action of a strong base to generate 3-(2,4-dichlorophenyl)-2-en-hexanoic acid ethyl ester; S2, Prilezhaev epoxidation reaction of 3-(2,4-dichlorophenyl)-2-en-hexanoic acid ethyl ester and meta-chloro peroxybenzoic acid to generate 3-(2,4-dichlorophenyl)-2,3-epoxy-hexanoic acid ethyl ester; and S3, base hydrolysis and acidification of 3-(2,4-dichlorophenyl)-2,3-epoxy-hexanoic acid ethyl ester to obtain a key intermediate 2-(2,4-dichlorophenyl) pentanal of pentconazole. The application has the effects of higher reaction yield, lower toxicity of reaction raw materials and more gentle reaction conditions.

This invention discloses a method for preparing high-quality bio-based 1,9-nonanediol, comprising the following steps: transesterification, precipitation, fatty acid methyl ester refining, ozone oxidation pyrolysis, solvent recovery, esterification, dimethyl azelaate refining, and hydrogenation to obtain high-quality bio-based 1,9-nonanediol. This invention achieves gradient and full-component utilization of vegetable oil raw materials: the oil-based portion of triglycerides is used to produce high-quality bio-based 1,9-nonanediol, while simultaneously producing byproducts such as methyl palmitate, methyl stearate, propionic acid, hexanoic acid, and nonanoic acid; the glycerol-based portion of triglycerides is used as a byproduct of glycerol production. This invention utilizes esterification to reconstruct the products of ozone oxidation pyrolysis, converting the high-boiling-point monomethyl azelaate into the low-boiling-point dimethyl azelaate, achieving efficient separation from saturated fatty acid methyl esters. The dimethyl azelaate, as a raw material, is then hydrogenated to obtain high-quality nonanediol, significantly reducing production costs.

The invention discloses a production method of high-grade flavoring liquor of Luzhou-flavor liquor, and relates to the field of liquor brewing. Aiming at the problems of insufficient substrate conversion, easy unbalance of flavor and easy rancidification of fermentation in the traditional double-round fermentation process, the technical scheme of combining double-round fermentation of 15-20% of fermented grains at the bottom of a cellar, mother grain acidity / starch double-index screening, precise regulation and control of sterile air in three-round fermentation / feeding before entering the cellar, and segmented distillation and graded storage is adopted. The process can improve the fermented grain conversion efficiency and stabilize the acidity of a fermentation system; the content of characteristic flavor substances such as ethyl hexanoate is greatly increased, and the flavor ratio is balanced; the sensory quality of raw wine is improved, and the cellar aroma and the ester aroma are stronger. The technological parameter range is feasible through experimental verification, the technical effect is obviously superior to that of a traditional technology, and the method is suitable for producing high-quality Luzhou-flavor liquor.

The present application relates to the technical field of surface treatment, in particular to a kind of biobased degradable cable material and preparation method thereof.Biobased degradable cable material includes 55-65 parts of poly-L-lactic acid and poly-3-hydroxybutyric acid-3-hydroxyhexanoate mixed matrix resin, 4-6 parts of dianhydride modified castor oil polyol, 10-15 parts of polyaminoval, 5-8 parts of nano enhanced filler, 6-10 parts of biobased plasticizer, 0.5-1.0 parts of antioxidant, 8-12 parts of environmentally friendly flame retardant.Dynamic ester bond crosslinking agent dianhydride modified castor oil polyol reaction forms dynamic ester bond crosslinking network, ester bond breakage occurs at high temperature beyond normal working range to release stress, temperature returns to normal and can recombine again;Semi-interpenetrating network enhanced phase polyaminoval forms interpenetrating structure with matrix resin in molecular chain interlacing mode, constructs stable heat-resistant skeleton, effectively inhibits high-temperature deformation, and its biobased structure ensures the overall degradability of the material, realizes the balance of heat resistance and degradability.

To provide a method for producing 6-hydroxyhexanoic acid (6-HHA) with increased production efficiency through a bioprocess.SOLUTION: A method for producing 6-hydroxyhexanoic acid comprises culturing a bacterium belonging to the genus Shewanella in a medium containing adipic acid under metabolically controlled conditions, where the bacterium has a carboxylic acid reductase and an aldehyde reductase.SELECTED DRAWING: None

The invention discloses Leishan fish sauce sour essence as well as a preparation method and application thereof. The leishan fish sauce acid essence is prepared from ethyl acetate, absolute ethyl alcohol, ethyl isovalerate, ethyl hexanoate, isoamyl alcohol, furfuryl alcohol, ethyl lactate, ethyl caprylate, acetic acid, diethyl succinate, methyl salicylate, ethyl benzoate, ethyl laurate, hexanoic acid, phenethyl alcohol, 4-methyl guaiacol, ethyl myristate, ethyl palmitate, ethyl oleate, capsicum oleoresin, ethyl phenylacetate and ginger oil. And lactic acid, glycerol triacetate, ocimene, ethyl isovalerate, ethyl butyrate, anethole and phenylacetaldehyde. The Leishan fish sauce sour essence disclosed by the invention is soft and harmonious in overall fragrance, natural and vivid, still has stable flavor characteristics at high temperature, can make up the problem of flavor deficiency in sour soup products, realizes accurate reproduction and controllable release of composite fragrance, improves the standardization level of products, and effectively improves the preference degree of consumers.

The present invention belongs to the technical field of daily chemical industry, and specifically relates to an emulsion and a preparation method thereof. The emulsion provided by the present invention comprises an emulsifier, glycerol, an oil-phase active substance, pentaerythrityl tetra(ethylhexanoate) and water; wherein the emulsifier is a lipopeptide; the weight percentage of the lipopeptide relative to glycerol is not less than 3%; the weight ratio of the oil-phase active substance to pentaerythrityl tetra(ethylhexanoate) is 1:(3 to 13); the ratio of the total weight of the lipopeptide and glycerol to the total weight of the oil-phase active substance and pentaerythrityl tetra(ethylhexanoate) is 1:(3 to 10); and the ratio of the total weight of the lipopeptide, glycerol, oil-phase active substance and pentaerythrityl tetra(ethylhexanoate) to the weight of water is 1:(1 to 4). By compounding sodium surfactin with glycerol and pentaerythrityl tetra(ethylhexanoate), the emulsion can effectively inhibit the diffusion of the oil-phase active substance at an emulsion interface, reduce the oxidative degradation of the oil-phase active substance, and greatly prolong the effective action time of the oil-phase active substance in the emulsion.

The application belongs to the technical field of biological medicine, and particularly relates to a lactobacillus paracasei and application thereof. The lactobacillus paracasei ZY101 is preserved in the China General Microbiological Culture Collection Center, has a preservation number of CGMCC No. 32360, a preservation date of October 25, 2024, and an address of No. 3, Beichen West Road, Chaoyang District, Beijing. Compared with a commercial bacillus acidophilus, the apricot vinegar prepared by using the lactobacillus paracasei ZY101 has new substances including linalool, alpha-farnesene, 2-phenylacetic acid ethyl ester and geranylgeraniol, and further promotes the aroma of the apricot vinegar. Compared with the commercial bacillus acidophilus, the existing substances are obviously improved, and specifically include ethyl acetate, isoamyl acetate, ethyl octanoate, ethyl hexanoate, acetoin, methyl palmitate, gamma-deca-lactone, ethyl dodecanoate, delta-deca-lactone, trans-nerolidol and dihydro-beta-ionone.

This invention relates to the field of ethyl hexanoate processing technology, specifically to an automated continuous esterification equipment and method for natural ethyl hexanoate. It includes a reaction vessel, with a distillation column at the top. A primary condenser is connected to the top of the distillation column. The lower shell-side outlet of the primary condenser is connected to two parallel flow control lines. One flow control line connects to the upper end of the distillation column via a return pipe, and the other flow control line connects to a product recovery tank. The upper shell-side outlet of the primary condenser connects to a secondary condenser, and the shell-side outlet of the secondary condenser connects to a buffer tank, which is connected to a vacuum pump. A gas phase anti-impact structure is provided at the connection between the reaction vessel and the distillation column. This invention effectively improves the conversion rate and esterification quality of the ester through continuous esterification. The gas phase anti-impact structure effectively reduces the direct impact of the gas phase on the distillation column wall, significantly improving the gas phase control effect and the adaptability to the distillation process.

This invention provides a method for the resource utilization of yellow water fermentation liquid and its application. The method includes the following steps: (1) pretreating the yellow water fermentation liquid to obtain acidic yellow water fermentation liquid; (2) subjecting the acidic yellow water fermentation liquid obtained in step (1) to a chromatography column adsorption, washing, and elution process to obtain a high-concentration eluent; (3) subjecting the high-concentration eluent obtained in step (2) to an esterification reaction to obtain a high-ester flavored liquor; the chromatography column contains macroporous adsorption resin; the eluent used for elution includes ethanol; and the high-concentration eluent is an ethanol solution of hexanoic acid. In this invention, the method not only solves the problem of yellow water discharge, a byproduct of brewing, but also enables recycling and reuse to obtain a high-concentration ethyl hexanoate flavored liquor, improving the quality of liquor, avoiding resource waste, and the process is simple and low-cost.

The invention discloses a moisturizing and repairing spray raw material capable of improving a spray effect and a preparation method of the moisturizing and repairing spray raw material. The moisturizing and repairing spray raw material is prepared from the following raw materials: glycerol tri (ethylhexoic acid) ester, glyceryl stearate citrate, stearyl alcohol polyether-21, cetyl alcohol palmitate, allantoin, sodium hyaluronate, panthenol, PCA sodium and water. According to the specific formula, the facial cleanser is prepared from the following raw materials: 58 to 68 percent of glycerol tri (ethylhexoic acid) ester, 13 to 23 percent of glyceryl stearate citrate, 2 to 12 percent of stearyl alcohol polyether-21, 2 to 12 percent of cetyl alcohol palmitate, 0.1 to 0.5 percent of allantoin, 0.01 to 0.2 percent of sodium hyaluronate, 0.01 to 1 percent of panthenol, 0.1 to 1.5 percent of sodium PCA and 1 to 4 percent of water. The light synthetic ester is used as a main body, the water-soluble moisturizing and repairing component is wrapped in the oil-based emulsified particles, the balance of a water phase system of a basic formula is not changed after the water-based emulsified particles are added for spraying, the viscosity fluctuation in winter caused by excessive water phase is avoided, meanwhile, the oil-based particles can carry functional components to be attached to the skin surface and slowly released, and the moisturizing and repairing effect is good. The long-term effect of moisturizing and repairing is improved.

The present application belongs to the technical field of fermented fruit juice, and particularly relates to a method for preparing high-quality probiotic fermented strawberry juice based on magnetic field assistance. The present application first uses Lactobacillus plantarum CTCF-LP-1 to perform static fermentation on the strawberry juice to be fermented in a fermentation device for more than 24 hours, and then places the fermentation device in a static magnetic field. The static magnetic field reduces the generation of organic acid components by Lactobacillus plantarum during the fermentation process of the strawberry juice, reduces the acidity, and improves the fermentation quality of the strawberry juice. The magnetic field strength of the static magnetic field is 1.0-2.5 mT, and the fermentation time in the static magnetic field is 0.5-1.5 h. After the static fermentation and the magnetic field treatment, the content of malic acid, isocitric acid, glutaconic acid and other organic acid components in the fermented strawberry juice is significantly reduced, while the content of alcohol and ester components such as n-octanol, 2-phenylethanol, methyl benzoate, 3-hexyl hexanoate and butyl valerate is increased, the types of aroma components are more abundant, and the taste and quality of the strawberry juice are significantly improved.

The application provides use of zanamivir in preparation of a medicine for treating or preventing preeclampsia, and a corresponding medicine and treatment method; zanamivir can effectively improve high blood pressure, proteinuria, creatinine, neuraminidase and sialic acid elevation symptoms of preeclampsia, increase NO level, and improve pregnancy outcome. Zanamivir and hydroxyprogesterone caproate in combination show better effects.

The application provides a palladium ion extractant material and a preparation method thereof, and the pyridine-oxadiazole ligand is used as the extractant, most Pd 2+ in the aqueous phase can be extracted into the organic phase in a short time, and has a very high extraction rate; selective extraction separation of Pd 2+ under acidic conditions can be realized, the applicable range of acidity is wide, and excellent extraction capacity is achieved in the range of 0.2-4M nitric acid concentration; the extractant has excellent selectivity to Pd 2+ in the aqueous phase containing various metal ions; the pyridine-oxadiazole extractant has a good application prospect in the separation and recovery of Pd 2+ in high-level radioactive waste; the m-nitro-trifluorotoluene is used as a diluent of the extraction system, has good solubility to the organic ligand and the extractant, and the 2-bromohexanoic acid can increase the lipophilicity of the extractant.

This invention belongs to the field of organic agriculture, specifically a biological agent for promoting wheat photosynthesis and its preparation method. Addressing the problems of existing biological agents having relatively simple components, low absorption and utilization efficiency by wheat ears, and a tendency to reduce nitrate reductase activity, nitrogen utilization, and chlorophyll content in wheat leaves, the following solution is proposed: the biological agent comprises the following raw materials in parts by weight: 50-65 parts of yield-enhancing amine, 15-20 parts of choline chloride, 10-15 parts of diethylaminoethanol hexanoate, 5-10 parts of brassinolide, 3-5 parts of p-chlorophenoxyacetic acid, 1-3 parts of calcium diphenylureasulfonate, 2-5 parts of trace agents, and 2-4 parts of ethylene glycol styraldehyde. The biological agent of this invention can promote better photosynthesis in wheat, enhance nitrate reductase activity, and improve nitrogen utilization.

The presently disclosed subject matter provides an approach to address the needs for microscale control in shaping the spacial geometry and microarchitecture of 3D collagen hydrogels. For example, the disclosed subject matter provides for compositions, methods, and systems employing N-sulfosuccinimidyl-6-(4′-azido-2′-nitro-phenylamino)hexanoate (“sulfo-SANPAH”), to prevent detachment of the hydrogel from the anchoring substrate due to cell-mediated contraction.