This invention discloses a magnetic photothermal
composite film based on a
porphyrin-based
covalent organic framework, its preparation method, and its application. The
composite film uses three-dimensional porous
nickel foam as a magnetic substrate. Active sites are introduced through surface
amination, followed by in-situ condensation of 5,10,15,20-
tetra(4-aminophenyl)
porphyrin and 1,4-phenylenedialdehyde at
room temperature, growing a
porphyrin-based
covalent organic framework layer on the surface and pore walls of the
nickel foam framework. This layer simultaneously provides
photothermal conversion function and a micro / nano roughened structure. The film is then impregnated with a
hexane solution of
polydimethylsiloxane and cured to form a hydrophobic sealing layer. The resulting
composite film has a
water contact angle of 152.9° and exhibits superhydrophobic self-cleaning properties. Utilizing the ferromagnetic properties of the
nickel foam substrate, the composite film exhibits magnetic responsiveness and can move directionally under the guidance of an external
magnetic field. Under one solar
irradiation, the surface temperature rises to above 72.6°C within 120 seconds, and the temperature rise curves essentially overlap after five light-cooling cycles. Based on its
photothermal conversion capability, the membrane can adsorb high-
viscosity crude oil within 110 seconds and de-ice within 90 seconds under standard simulated
sunlight irradiation. The preparation process of this invention is mild and can be used for solar-driven removal and photothermal de-
icing of high-
viscosity oils.