The invention provides a method for constructing an industrial park atmosphere pollution characteristic online monitoring system, particularly a method for constructing an online monitoring system for industrial park emission including atmosphere characteristic pollution factors, such as VOCs, inorganic gas and odor substances, and relates to the technical field of industrial park atmosphere environment online monitoring. The method for constructing the industrial park atmosphere pollution characteristic online monitoring system comprises the steps: A, selecting a monitoring site; B, determining a monitoring factor; C, screening a pollutant monitoring instrument; D, establishing an atmosphere automatic monitoring system; and E, constructing an information management system. According to the method for constructing the industrial park atmosphere pollution characteristic online monitoring system, a mutually complementary atmosphere pollution early-warning and monitoring system is obtained by screening automatic monitoring instruments, which are used for optimally controlling pollutants and are integrated with a chromatography, a sensor, a mass spectrometry, an optical technology and so on, on the basis of atmosphere characteristic pollution analysis from three levels of the park, the boundary and sensitive points; online real-time control of industrial park atmosphere characteristic pollution unorganized emission, industrial park boundary and factory boundaries is realized, so that the atmosphere pollution is converted from manual prevention to technical prevention; and therefore, a novel environment management mode is established.