Stabilized curing agent for heavy metal contaminated soil or solid waste treatment and treatment method

A technology for polluted soil and solid waste, applied in the restoration of polluted soil, chemical instruments and methods, soil conditioning materials, etc. problem, to solve the effect of large environmental impact, high-efficiency long-term stabilization effect, and good stabilization and curing effect

Active Publication Date: 2015-01-28
GUIZHOU MEIRUITE ENVIRONMENTAL PROTECTION TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the traditional stabilization and curing technology has disadvantages such as the treatment effect and the treatment agent are greatly affected by the environment, the long-term effect of harmless stability is poor, and the amount of agent addition is difficult to control.
For example, changes in soil acidity and alkalinity will cause the reaction of heavy metal compounds after treatment, leading to re-dissolution, excessive addition will also lead to the formation of easily soluble compl...

Method used

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  • Stabilized curing agent for heavy metal contaminated soil or solid waste treatment and treatment method
  • Stabilized curing agent for heavy metal contaminated soil or solid waste treatment and treatment method
  • Stabilized curing agent for heavy metal contaminated soil or solid waste treatment and treatment method

Examples

Experimental program
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Effect test

Embodiment 1

[0033] The stabilizing curing agent of this embodiment includes the following components in parts by weight: 10 parts of magnesium oxide, 5 parts of calcium polysulfide, and 2 parts of bentonite activated by hydrochloric acid.

[0034] The governance object of the present embodiment is soil A, and the governance method comprises the following steps:

[0035] (1) Detect the content and leaching toxicity of heavy metals in soil A, the test results are as follows figure 1 Shown in soil A;

[0036] (2) Take each component of the stabilizing curing agent, mix it uniformly and prepare it as a stabilizing curing agent, then carry out a stabilizing curing agent addition experiment according to the detection results of step (1), thereby determining the stability of the stabilizing curing agent add scale;

[0037] (3) Add the stabilizing and curing agent to soil A according to the addition ratio determined in step (2), stir and mix evenly, and keep the water content between 25% and 40...

Embodiment 2

[0042] The stabilizing curing agent in this embodiment includes the following components in parts by weight: 7 parts of magnesium hydroxide, 3 parts of calcium sulfide, and 1 part of silicon dioxide activated by hydrochloric acid.

[0043] The treatment method is the same as the step in Example 1, except that the treatment object of this example is the original soil C of a certain groundwater sludge incineration ash in Shimen, Hunan, and the detection results of heavy metal content and leaching toxicity in soil C are as follows: figure 2 Shown in middle soil C; after the treatment, the final test results are as follows figure 2 Middle soil D is shown.

Embodiment 3

[0045] The stabilizing curing agent of this embodiment includes the following components in parts by weight: 5 parts of a mixture of magnesium oxide and magnesium carbonate, 1 part of a mixture of calcium polysulfide and potassium sulfide, and 3 parts of kaolin activated by hydrochloric acid.

[0046] The control method is the same as the step in Example 1, except that the control object of this embodiment is the bottom mud E in a certain place in Shandong, and the content of hexavalent chromium in the bottom mud E and the detection results of leaching toxicity are as follows: image 3 Shown in the middle soil E; after the treatment, the final test results are as follows image 3 Middle soil F is shown.

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PUM

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Abstract

The invention discloses a stabilized curing agent for heavy metal contaminated soil or solid waste treatment and a treatment method. The stabilized curing agent comprises the following components in parts by weight: 5 to 10 parts of a magnesium-based compound, 1 to 5 parts of a sulfur-based compound and 1 to 3 parts of an activated silicon-based compound. The treatment method comprises the following steps of sampling inspection, experimental determination of adding proportion, mixing, backfill maintenance, sealing up for safekeeping and the like. The stabilized curing agent disclosed by the invention has an efficient long-term stabilizing effect on various heavy metals such as arsenic, mercury, hexavalent chromium, lead, cadmium, nickel, tin and cyanide, the repeated acid and alkali leaching experiments prove that the stabilized and cured harmful heavy metals cannot be dissolved out again, and the defects that in the traditional technology, the treatment effect and treatment agents are greatly affected by the environment, the long-term efficacy of harmless stabilization is poor, the medicament adding amount is difficult to control and the re-dissolution of harmful heavy metals is easily caused by the high alkalinity of cement solidification and the like are overcome.

Description

technical field [0001] The invention relates to the technical field of heavy metal pollution treatment, in particular to a stabilizing and curing agent for heavy metal polluted soil or solid waste treatment and a treatment method. Background technique [0002] Heavy metals and their derivatives have the characteristics of persistence, easy migration, bioaccumulation, and biotoxicity. They are important environmental toxic and harmful substances, which pose a huge threat to human health and the ecological environment. The heavy metals referred to by these threats mainly refer to Hg, Cd, Pb, Cr and metalloid As which are significantly toxic to crops and human and animal organisms, and also include toxic pollutants such as Zn, Cu, Co, Ni, Sn. As a large amount of industrial wastewater in the city flows into the river and the dust settles in the atmosphere, many heavy metals contained in it enter the soil along with the sewage sludge. For example, the mining of metal mines, the...

Claims

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Application Information

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IPC IPC(8): C09K17/06C09K17/02B09C1/08A62D3/33C09K103/00A62D101/43
CPCA62D3/33A62D2101/43B09C1/08C09K17/02C09K17/06C09K2103/00
Inventor 李森王良栋李璐
Owner GUIZHOU MEIRUITE ENVIRONMENTAL PROTECTION TECH
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