The invention relates to the technical field of jun porcelain glaze, in particular to jun porcelain sky blue glaze and a preparation method thereof. Frit is prepared from the following raw materials in parts by weight: feldspar, quartz, fluorite, talc, wollastonite and a phosphorus compound. The glaze slip is prepared from the following raw materials in parts by weight: frit, clay, ferric oxide, strontium carbonate, copper oxide, titanium oxide, cobalt oxide, manganese oxide and hydroxypropyl methyl cellulose; through quartz, fluorite, talc and a phosphorus compound, glaze pinhole defects areeliminated, glaze gloss is increased, finished product quality is improved, and glaze gloss is increased. The amounts of feldspar and quartz are reasonably configured, and a good middle layer is formed between the glaze layer and the green body so that the green body and the glaze are tightly combined; the thermal stress between the blank and the glaze is uniform, the stress between the blank andthe glaze is weakened, and the mechanical strength of the Jun porcelain is improved; through high-temperature 'reducing flame' and twice low-temperature 'oxidizing flame' calcination, colored metal generates different reactions at different temperatures to display different colors so that the sky blue glaze is variable in color.