The invention belongs to the field of environmental
pollution remediation and
inorganic materials and particularly relates to a
sulfur modified porous
iron oxide catalyst, a preparation method therefor and application of the
sulfur modified porous
iron oxide catalyst. A main ingredient of the porous
iron oxide catalyst is iron
oxide, and a
sulfide of iron coexists. The preparation method comprises the steps: dissolving
oxalic acid in water so as to prepare an
oxalic acid solution, carrying out heating in water bath, and carrying out stirring while carrying out heating until the
oxalic acid is completely dissolved; and adding a
sulfur compound solution into the oxalic acid solution, carrying out uniform mixing, then, dropwise adding a
ferrous salt solution into the mixture, continuing to carry out stirring until the reaction is thorough, then, carrying out ice bath immediately so as to obtain a yellow suspension, carrying out filtrating, then, carrying out
drying treatment so as to obtain a yellow sulfur-modified
ferrous oxalate precursor, and then, carrying out
calcination, thereby obtaining the sulfur modified porous
iron oxide catalyst. The sulfur modified porous
iron oxide catalyst can be used for effectively activating
hydrogen peroxide and
persulfate in
sewage water with the pH value of 3-10 and efficiently removing toxic or
refractory organic pollutants from the water.