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2606 results about "Sulphate salt" patented technology

Animal litter, process for preparing animal litter and method of removal of animal waste

An animal litter, process for preparing the animal litter, and a method for removal of animal waste using the animal litter are provided. The animal litter generally includes at least one sorbent and a sulfate such as sodium bisulfate. The animal litter is in the form of discrete plural particles which tend to agglomerate when wetted.
Owner:KENT CONSUMER BRANDS AMERICAS LLC

Animal Litter, Process For Preparing Animal Litter And Method Of Removal Of Animal Waste

An animal litter, process for preparing the animal litter, and a method for removal of animal waste using the animal litter are provided. The animal litter generally includes at least one sorbent and a sulfate such as sodium bisulfate. The animal litter is in the form of discrete plural particles which tend to agglomerate when wetted.
Owner:KENT CONSUMER BRANDS AMERICAS LLC

Low-carbon near zero emission process of industrial waste water

A low-carbon near zero emission process of industrial waste water, comprising: S1: entering industrial waste water into a pre-oxidation system to improve biodegradability of organics; S2: after treatment in the pre-oxidation unit, entering the waste water into an anaerobic biological treatment system, sodium chloride and sulfate is deeply removed and carbon sources in the waste water can be used to remove the sulfate and nitrate; S3: entering water output from the anaerobic biological treatment system into a membrane concentration system and membrane concentrated solution enters a nano-filtration salt fractionation system for salt fractionation; and S4: refluxing nano-filtration concentrate solution generated by the nano-filtration salt fractionation system to the anaerobic biologic treatment system for biological desulfurization, or synthesizing the nano-filtration concentrate solution to be sodium persulfate by electro chemical methods, and refluxing proportionately to a waste water pre-oxidation system for use in-situ.
Owner:SHANXI UNIV

Acid-resistant sulfate reducing bacteria and application thereof

The invention relates to acid-resistant sulfate reducing bacteria and application thereof, and belongs to the technical field of microorganisms. The acid-resistant sulfate reducing bacterium disclosed by the invention is Desulfovibrio desulfuricans QY411, and is preserved in the Guangdong Microbial Culture Collection Center on March 14, 2024, and the preservation number of the acid-resistant sulfate reducing bacterium is GDMCC No: 64412. The acid-resistant sulfate reducing bacterium provided by the invention can survive in an environment with the pH value of 4, and can be applied to ecological reconstruction of acid tailings and waste dump soil, the pH values of mining wasteland soil and surface water after ecological reconstruction are remarkably increased, the concentration of SO4 < 2-> in the soil is remarkably reduced, the acidification process in the mining wasteland soil is effectively inhibited, and the acid-resistant sulfate reducing bacterium has the advantages of being safe and reliable. Therefore, the acidification process in the mining wasteland is effectively controlled. Meanwhile, soil heavy metal pollution is reduced, and vegetation growth is recovered.
Owner:SOUTH CHINA NORMAL UNIV

Silver powder with high twin crystal ratio and preparation method and application thereof

The invention discloses silver powder with a high twin crystal ratio and a preparation method and application of the silver powder with the high twin crystal ratio. The preparation method comprises the following steps that S1, a carboxylic acid coordination agent is added into a silver source solution, and a silver precursor solution is obtained; sequentially adding a dispersing agent and an initiator into the reducing agent solution to obtain a reaction base solution; s2, a silver precursor solution is added into the reaction base solution for an oxidation-reduction reaction, then curing is conducted, and mixed mother liquor is obtained; s3, the mixed mother liquor is filtered, washed, dispersed and dried, and then the silver powder with the high twin crystal proportion is obtained; the initiator comprises one or more of sulfate, carbonate and nitrate; through the synergistic effect of the initiator and the carboxylic acid coordination agent, the silver ion release rate and the crystal nucleus preferential growth direction are regulated and controlled, the rapid feeding and curing technology is combined, the low supersaturation environment is constructed, the silver powder is induced to grow in the specific direction, and the twin crystal proportion is remarkably increased.
Owner:WUHAN INSTITUTE OF MARINE ELECTRIC PROPULSION (THE 712TH RESEARCH INSTITUTE OF CHINA STATE SHIPBUILDING CORP LTD) +1

Animal Litter, Process For Preparing Animal Litter And Method Of Removal Of Animal Waste

An animal litter, process for preparing the animal litter, and a method for removal of animal waste using the animal litter are provided. The animal litter generally includes at least one sorbent and a sulfate such as sodium bisulfate. The animal litter is in the form of discrete plural particles which tend to agglomerate when wetted.
Owner:KENT CONSUMER BRANDS AMERICAS LLC

Method and equipment for producing Li2CO3 based on coordinated roasting of lepidolite and spodumene

The invention provides a method and equipment for producing Li2CO3 based on coordinated roasting of lepidolite and spodumene. The method for producing Li2CO3 based on coordinated roasting of lepidolite and spodumene comprises the steps that S1, ore pretreatment is conducted, specifically, lepidolite and spodumene with the particle size smaller than 5 mm are evenly mixed according to the mass ratio of 1: (1-3), and the mixed ore is finely ground till the particle size is smaller than 75 microns; s2, additive mixing, wherein a composite additive is added into the mixed ore obtained after fine grinding and evenly mixed with the ore, and the composite additive is composed of fluoride, sulfate and a fluxing agent; and S3, coordinated roasting, wherein the mixed materials are fed into a rotary kiln to be roasted. According to the method for producing Li2CO3 based on coordinated roasting of the lepidolite and the spodumene, the lepidolite and the spodumene are roasted in a coordinated mode, the structural and chemical property differences of the lepidolite and the spodumene are utilized, advantage complementation is achieved, the overall extraction rate of lithium is increased, compared with a single lithium extraction technology, the lithium recovery rate can be increased by 10%-20%, and the waste residue generation amount is reduced.
Owner:FENGXIN JIULING LITHIUM IND CO LTD

Method for preparing iron oxide yellow by leaching iron ore tailings through advanced oxidation technology

The invention relates to the technical field of iron ore tailing resource utilization, in particular to a method for preparing iron oxide yellow by leaching iron ore tailings through an advanced oxidation technology, which comprises the following steps: adding a required amount of iron ore tailing powder into a persulfate solution, stirring to react, adding a reducing agent, boiling, filtering, adding alkali liquor to adjust the pH value, and filtering, thereby obtaining the iron oxide yellow. Pure liquid containing ferrous ions is obtained; taking part of the pure solution containing ferrous ions, and adding a potassium hydroxide solution to obtain an iron oxide yellow seed crystal solution; adding a pure solution containing ferrous ions into the iron oxide yellow seed crystal solution, adding an alkali solution to adjust the pH value, reacting, and separating and drying a product to obtain the iron oxide yellow. According to the method, the persulfate is adopted to leach iron from the iron ore tailings, and the iron oxide yellow is prepared from the leachate; harmless treatment of the iron ore tailings and value-added utilization of valuable resources are achieved, the raw material source of the iron oxide yellow industry is widened, and a wider prospect is provided for development of iron oxide yellow.
Owner:XINJIANG UNIVERSITY

Composite activator for lithium slag as well as preparation method and application of composite activator

The invention belongs to the technical field of lithium slag resource utilization, and discloses a composite exciting agent for lithium slag as well as a preparation method and application of the composite exciting agent. The composite activator comprises the following components in parts by weight: 10-20 parts of an alkali activator, 10-20 parts of a sulfate activator, 15-30 parts of activated aluminum, 1-8 parts of a nano filler and 3-10 parts of a dispersant. An alkali activator and a sulfate activator are used as main materials, the advantages of the alkali activator and the sulfate activator are integrated, the alkaline environment promotes release of active silica-alumina species, the sulfate activator reacts with active aluminum to generate ettringite and other gel products, meanwhile, the active aluminum supplements aluminum ions, gel generation is promoted, and the gel is formed. The nano filler can fill pores and promote generation of C-S-H gel, and the dispersing agent can effectively disperse the active excitation component and the lithium slag.
Owner:SHANDONG RONGYAN HENGCHANG ENVIRONMENTAL PROTECTION TECHNOLOGY CO LTD

Efficient water-absorbing and salt-resistant modified water-retaining agent and preparation process thereof

The invention discloses a preparation process of an efficient water-absorbing and salt-resistant modified water-retaining agent, which specifically comprises the following steps: (1) mixing alkali liquor, an acrylic polymeric monomer and water to obtain a water-phase solution A; and (2) uniformly mixing the water-phase solution A with a cross-linking agent and a salt-resistant modified monomer, then adding an initiator, and carrying out polymerization reaction, the preparation method of the modified salt-tolerant monomer comprises the following steps: polymerizing a humate solution and starch hydrogel under the initiation of persulfate to obtain the salt-tolerant modified monomer. In the copolymerization reaction of the existing humic acid-based water-retaining agent, the starch hydrogel participates in the polymerization of the acrylamide, the acrylic acid and the modified monomer and has a synergistic effect with the functional group of the modified monomer in the raw materials, so that the comprehensive performance of the water-retaining agent is improved, and the molecular structure of the polymer provides good supporting force and mechanical strength.
Owner:XINJIANG HAMI SANTANGHU ENERGY DEV & CONSTR CO LTD +1

Concrete crack self-repairing material based on microorganism immobilization and preparation method thereof

The invention discloses a concrete crack self-repairing material based on microorganism immobilization and a preparation method of the concrete crack self-repairing material, and belongs to the crossing field of microorganism materials and civil engineering. The material is prepared from peptone, sodium lactate, volcanic rock, bacillus pasteurii and other raw materials through the steps of culture medium preparation, carrier modification, microorganism immobilization, microcapsule and gel protection layer formation and the like, the prepared volcanic rock-chitosan carrier provides an inhabiting environment for microorganisms, and the survival rate of the microorganisms in a high-alkali environment is increased to 70%. When the concrete cracks and the alkaline environment triggers the protective layer to disintegrate, the bacillus pasteurii and the desulfurization vibrio are subjected to a reduction reaction with sulfate through urealysis, and calcium carbonate and calcium sulfide are generated to fill cracks. The 28-day repair rate of the material is larger than or equal to 99%, the maximum crack repair width reaches 1.2 mm, the compressive strength recovery rate is larger than or equal to 85%, excellent durability and environment friendliness are achieved, and the concrete crack repair problem is effectively solved.
Owner:FUJIAN YONGQIANG SOIL

Freeze-thaw-resistant sulfate composite modifier and application thereof in water-stable base

The invention relates to the technical field of building material modification, in particular to an anti-freeze thawing-sulfate composite modifier and application thereof in a water-stable base layer. In road engineering, a water-stable base layer often faces the problems of freeze-thaw cycle and sulfate erosion damage. The key point of the technical scheme of the invention is as follows: on the basis of the mass of cement, a composite modifier is composed of the following components in percentage by mass: 2%-5% of sodium sulfate, 0.02%-0.05% of sodium gluconate, 0.4%-0.6% of polypropylene fiber, 0.1%-0.2% of steel fiber, 1%-3% of butadiene styrene rubber emulsion, 0.05%-0.5% of sodium carboxymethyl cellulose, 0.05%-0.1% of triethanolamine, 0.1%-0.5% of naphthalene water reducer, 0.005%-0.02% of air entraining agent, 8%-10% of silica fume and the like. The composite modifier is mainly used for the water-stabilized base, can effectively improve the freeze-thaw resistance and sulfate erosion resistance of the water-stabilized base, and prolongs the service life of a road.
Owner:CHINA ROAD & BRIDGE

Method for removing and recycling fluorine ions by promoting calcium fluoride precipitation through sulfate doping

The invention relates to the technical field of environmental science and engineering, and discloses a method for removing and recycling fluorine ions by promoting calcium fluoride precipitation through sulfate doping, and the method comprises the following steps: S1, preparing sodium fluoride solutions of sulfate with different concentrations, and analyzing the influence of different sulfate concentrations on calcium fluoride precipitation; s2, respectively adding calcium chloride solutions into the prepared sodium fluoride solutions of the sulfates with different concentrations; s3, the two solutions are subjected to a reaction within a set time, filtering is conducted after the reaction is conducted for a period of time, and the fluorine ion removal reaction is completed. By changing the concentration of sulfate in the sodium fluoride solution, the effect of the sulfate in calcium fluoride precipitation and the influence of the sulfate on the fluorine ion removal efficiency are researched; the positive effect and the action mechanism of the low-concentration sulfate in the calcium fluoride precipitation process are defined, and the problems that the influence of the sulfate in the high-fluoride wastewater on calcium fluoride precipitation is ignored, the calcium fluoride purity is low and the recovery difficulty is large are finally solved.
Owner:GUILIN UNIVERSITY OF TECHNOLOGY

A layered metal hydroxide composite catalytic material, its preparation method and application

The present invention discloses a layered metal hydroxide composite catalytic material, its preparation method and application. The composite catalytic material comprises a carrier carbon nanotube and a metal hydroxide loaded on the carbon nanotube, and the metal is iron, cobalt and nickel. Preparation method: (1) Dissolve nickel salt, cobalt salt, iron salt and urea in an alcohol solution, stir evenly, then add carbon nanotubes, and continue to stir evenly to obtain a mixed solution; (2) Carry out a solvothermal synthesis reaction on the mixed solution obtained in step (1), filter, wash and dry after the reaction is completed to obtain the layered metal hydroxide composite catalytic material. The carbon nanotubes are introduced into the layered metal hydroxide in this composite catalytic material, reducing the precipitation of metal ions, avoiding the aggregation of hydroxides, improving the stability and catalytic activity of the catalytic material, and being used for activating persulfate to degrade organic pollutants, realizing the efficient activation of persulfate so as to improve the degradation rate of pollutants.
Owner:NANJING NORMAL UNIVERSITY

Filling cementing material as well as preparation method and application thereof

PendingCN120607375AMaterial fill-upSlagFly ash
The invention relates to a filling cementing material as well as a preparation method and application thereof. The filling cementing material comprises blast furnace slag powder, fly ash, superfine tailing micropowder, an alkaline activator and a sulfate activator, the specific surface area of the superfine tailing micro powder is 600 to 800 m < 2 > / kg. The technical problem to be solved is how to provide the filling cementing material, the performance of the tailing micropowder can be activated to enhance the bonding effect of the filling cementing material, and the mechanical strength and the cementing effect of the filling cementing material are enhanced through the synergistic effect of the superfine tailing micropowder and other raw materials, so that not only is the industrial solid waste of the tailing treated, but also the economic benefit is improved. And cement is avoided, so that carbon reduction and environmental protection are facilitated.
Owner:BEIJING HUASHENG CHUANGYUAN ENVIRONMENTAL TECH CO LTD +2

Advanced wastewater treatment method based on adsorbent

The invention relates to the technical field of water pollution control and treatment, and particularly discloses a method for deeply treating wastewater based on an adsorbent, which comprises the following steps of: firstly, introducing a mixed gas of carbon dioxide and air into fly ash water washing liquid, and removing calcium ions in the water washing liquid in a calcium carbonate precipitation form in a continuous introducing process; interference of calcium ions on adsorption and electrodialysis processes in the subsequent treatment process is avoided, heavy metals in the water washing liquid are accurately adsorbed and removed while the iron-sulfur loaded magnetic mesoporous biochar is used for activating efficient oxidation of persulfate, finally, electrodialysis treatment is performed on the water washing liquid by using a self-made bipolar membrane, chlorine in water is taken out, and the heavy metals in the water washing liquid are removed. And the washing liquid can meet the requirement of wastewater discharge.
Owner:NANTONG LEER ENVIRONMENTAL TECH CO LTD

A low-temperature resistant and early-strength type alkali-free liquid accelerator and its preparation method

The present invention discloses a low-temperature resistant and early-strength type alkali-free liquid accelerating agent and its preparation method, belonging to the technical field of alkali-free liquid accelerating agents. The composition includes 12-15 parts of aluminum sulfate, 2-5 parts of sodium thiocyanate embedded by β-cyclodextrin, 5-8 parts of calcium hydroxide deactivator, 3-5 parts of fiber, 5-10 parts of hydrophilic polymer substance, 3-5 parts of cationic surfactant, 6-10 parts of polyaluminum chloride, and 2-3 parts of air-entraining agent. The low-temperature resistant and early-strength type alkali-free liquid accelerating agent of the present invention can improve the frost resistance of sulfate alkali-free accelerating agents, reduce the viscosity of cement slurry, promote the hydration reaction of C3S, shorten the setting time of concrete, and improve the later strength of concrete.
Owner:SICHUAN YU CONCRETE BUILDING MATERIALS CO LTD

Method and device for treating peroxymonosulfate water excited by alkali-reinforced copper-based material

The invention provides a water treatment method and device using an alkali-reinforced copper-based material to excite peroxymonosulfate, and relates to the technical field of wastewater treatment.The method comprises the steps that an alkali agent, the copper-based material and peroxymonosulfate are added into water to be treated; the alkaline agent is sodium hydroxide and / or potassium hydroxide; the copper-based material is copper oxide and / or copper sulfide. The method provided by the invention has the advantages of excellent pollutant treatment effect, mild reaction conditions, simple process flow, environmental protection, energy saving, easy recovery and recycling and the like, and realizes the purposes of small dosage of the oxidant and the catalyst, high utilization rate of the oxidant, small dissolution amount of metal ions and up-to-standard pH of effluent.
Owner:CHINESE RES ACAD OF ENVIRONMENTAL SCI

Method for preparing sponge iron from laterite-nickel ore hydrometallurgy tailings

The invention relates to a method for preparing sponge iron from laterite-nickel ore hydrometallurgy tailings, which comprises the following steps: (1) carrying out acid leaching on laterite-nickel ore hydrometallurgy tailings to obtain leached residues without at least part of CaSO4; (2) oxidizing and roasting the leaching residues obtained in the step (1), so that at least part of sulfate is discharged as sulfur-containing gas; performing hydrogen reduction to obtain a reduced material; and (3) the reduction material in the step (2) is sequentially subjected to ore grinding and magnetic separation, and the sponge iron with the Fe content being 90 wt% or above and the S content being 0.01 wt% or below is obtained. According to the method, iron resources in the laterite-nickel ore hydrometallurgy tailings are recycled, desulfurization and reduction are carried out step by step, the desulfurization efficiency is improved, the reduction temperature is reduced, and the sponge iron with the Fe content being 90 wt% or above and the S content being 0.01 wt% or below is obtained.
Owner:JINGMEN GEM NEW MATERIAL CO LTD

Sulfate and chloride ion erosion resistant offshore wind power tower high-strength grouting material and preparation method thereof

The invention discloses a sulfate and chloride ion erosion resistant offshore wind power tower high-strength grouting material and a preparation method thereof. The grouting material comprises Portland cement, fine aggregate, ricinoleic acid modified nano zinc oxide, an anion erosion resistant agent, an expansion component, composite fibers and an additive. Wherein the anti-anion erosion agent comprises mineral powder, barium salt, lithium silicate, a calcium formate early strength agent and silica fume; the preparation method comprises the following steps: firstly, mixing and stirring the cement, the expansion component and the fine aggregate to obtain powder A; mixing and stirring ricinoleic acid modified nano zinc oxide, an anti-anion erosion agent and an additive to obtain powder B; mixing and stirring the powder A and the powder B, adjusting the water-cement ratio, adding the composite fiber, and stirring. The grouting material is good in fluidity, high in strength and excellent in fatigue resistance, can effectively prevent permeation of sulfate and chloride ions, and has high durability.
Owner:江苏博拓新型建筑材料股份有限公司

Method for degrading chloramphenicol by activating peroxymonosulfate based on nano-catalyst derived from bimetallic organic framework

The invention provides an efficient chloramphenicol degradation method based on Co-Cu-carbon composite nano-catalyst activated peroxymonosulfate, which comprises the following steps: regulating the Co / Cu molar ratio in a bimetal organic framework precursor, and performing pyrolysis to prepare the Co-Cu-carbon composite catalyst with an optimized pore structure, graphitization degree and metal dispersity; peroxymonosulfate is activated by utilizing the synergistic effect of Co / Co and Cu / Cu redox pairs to generate sulfate free radicals, hydroxyl free radicals, singlet oxygen and superoxide free radicals, and direct oxidative degradation of chloramphenicol is promoted by taking a catalyst as an electron transfer bridge; the method realizes rapid and efficient removal of chloramphenicol, high mineralization rate, excellent cycle stability and strong anti-interference capability, and solves the technical problems of low removal efficiency, high cost and easy secondary pollution in the prior art.
Owner:连云港市环境监测监控中心(连云港市海洋生态环境监测中心)

Treatment process for crystallizing a metal sulfate

A treatment process for crystallizing a metal sulfate involving pre-treating a feedstock comprising calcium, magnesium, and / or lithium impurities, the pre-treating involving pre-leaching the feedstock in the presence of a lixiviant, selectively extracting a first portion of any of the impurities from the feedstock, and forming a leached solution comprising an uncrystallized metal sulfate and any remaining impurities; and / or refining the leached solution and removing a second portion of any of the remaining impurities; and crystallizing the uncrystallized metal sulfate from the leached solution to form a crystallized metal sulfate. So processed, the crystallized metal sulfate may be battery-grade or electroplating-grade.
Owner:HATCH LTD

Preparation of two-component biochar composite material and application of two-component biochar composite material in activating persulfate to remove antibiotics in wastewater

The invention discloses preparation of a two-component biochar composite material and application of the two-component biochar composite material to removal of antibiotics in wastewater by activating persulfate, and relates to a preparation method of the two-component biochar composite material. The invention aims to solve the problems that the existing biochar material has few surface active sites and limited catalytic ability to antibiotics in wastewater. The method comprises the following steps: 1, shearing, crushing, washing and drying a biomass material, and sieving after drying to obtain fine biomass material powder; 2, mixing and grinding the fine biomass material powder, metal salt and a pore-forming agent; and 3, placing the mixture in a tubular furnace, and carrying out pyrolysis in an inert atmosphere to obtain the bi-component biochar composite material. The bi-component biochar is synthesized through one-step pyrolysis, the preparation method is simple, operability is high, and the biochar is used for activating persulfate to remove antibiotics in wastewater.
Owner:INNER MONGOLIA UNIV OF SCI & TECH

Catalyst of oxygen vacancy defect carbon nitride anchored iron atom cluster as well as preparation method and application of catalyst

The invention provides an oxygen vacancy defect carbon nitride anchored iron atom cluster catalyst and a preparation method and application thereof, and belongs to the technical field of catalysts. Iron atoms are anchored in a carbon nitride (Ov-C3N4) structure containing oxygen vacancy defects in a cluster form, and Fe-Ov-C defect bonds are formed between the oxygen vacancy defects in C3N4 and iron atom clusters to stabilize the iron atom clusters, so that the problem of thermodynamic instability of the catalyst is solved while higher atom utilization efficiency is obtained; the Fe-Ov-C defect bond atoms can reasonably regulate and control the electronic structure of the center of an iron cluster d band, so that the catalytic activity and the cycling stability are greatly enhanced; besides, iron atom clusters and persulfate act to cause O-O bond breakage, non-free radical singlet oxygen is formed, and the problem that the catalytic efficiency is sharply reduced due to free radical annihilation in a complex water environment can be effectively solved.
Owner:湖南工商大学

Sulfate-erosion-resistant metakaolin-slag-based geopolymer concrete and preparation method thereof

The invention discloses sulfate-erosion-resistant metakaolin-slag-based geopolymer concrete, belongs to the technical field of concrete, and aims to solve the problems that the corrosion resistance of traditional silicate concrete is ineffective and the adaptability of conventional alkali-activated concrete is insufficient in a special environment. The concrete comprises the following components in parts by weight: 60-90 parts of a cementing material, 120-170 parts of aggregate, 15-30 parts of a composite activator, 2-8 parts of a function regulator and the like, the cementing material is prepared from nano TiO2 / KH-550 composite modified metakaolin, slag and silica fume-coal gangue powder-HAP composite powder; the aggregate comprises modified limestone macadam (soaked and dried by a sodium dihydrogen phosphate solution) and river sand; the composite exciting agent comprises water glass, sodium hydroxide, sodium pyrophosphate, propylene glycol and the like; the function regulator comprises superfine fly ash, a naphthalene water reducer, HPMC (Hydroxy Propyl Methyl Cellulose) and boric acid. Through the synergistic effect of the components, the sulfate corrosion resistance, the mechanical property and the environmental adaptation performance of the concrete are improved, and the concrete is suitable for engineering construction under the service environment of high-concentration sulfate and the like.
Owner:绵竹市铸诚混凝土有限公司

Water quality monitoring device and monitoring method thereof

The invention discloses a water quality monitoring device and a monitoring method thereof, belongs to the technical field of water quality monitoring, and solves the problems that trace hydrogen sulfide generated by sulfate reducing bacteria in a deposited layer at the bottom of a water tank which is not cleaned for a long time in a low-oxygen environment reacts with a platinum membrane electrode of a residual chlorine sensor to generate a platinum sulfide covering layer; and the electrode reading is continuously virtually high and drifts slowly. Comprising an optical transmitting module, an optical receiving module, a spectrum separation module, a signal conditioning module, a lock-in amplification module, a spectrum feature extraction module and a hydrogen sulfide recognition engine. Residual chlorine is monitored in a non-contact mode, deep ultraviolet pulse light is emitted to penetrate through a water body, a reflection spectrum is received, second derivative spectral characteristics are extracted through multichannel signal processing, and multivariable regression compensation is executed to calculate a real residual chlorine value after hydrogen sulfide interference characteristics are recognized. Meanwhile, the drift trend is quantified based on the double-time-constant integral, graded early warning is triggered, industrial standard signals are finally output, and the problem of electrode contact pollution is avoided in the whole process.
Owner:SHAOXING KEQIAO ENVIRONMENTAL TECH SERVICE CO LTD

Ni-coated NiS2-coated MoSx / NF composite catalyst and preparation method and application thereof

The invention belongs to the technical field of environmental catalytic materials and pollutant control, and particularly relates to a Ni-coated NiS < 2 >-coated MoS < x > / NF composite catalyst and a preparation method and application thereof. According to the preparation method of the Ni-coated NiS2-coated MoSx / NF composite catalyst provided by the invention, the Ni-coated NiS2-coated MoSx / NF composite catalyst with a self-supported metal / crystalline / amorphous heterojunction is constructed by virtue of a collaborative strategy of directional self-assembly and internal Ni source and water dispersion, and meanwhile, the activation efficiency of peroxymonosulfate (PMS) can be remarkably improved by combining an Ni-Mo bimetal active center, so that the activation efficiency of the Ni-coated NiS2-coated MoSx / NF composite catalyst is improved. The problems that an existing catalyst is limited in active site and poor in structural stability are solved, the excellent capacity of activating PMS to remove antibiotics is shown, therefore, efficient degradation of antibiotic pollutants is achieved, and the catalyst has wide application prospects in antibiotic wastewater treatment.
Owner:HENAN INST OF ENG

High-impermeability concrete material and preparation method thereof

The invention discloses a high-impermeability concrete material and a preparation method thereof, and belongs to the technical field of concrete materials, and the high-impermeability concrete material specifically comprises the following components in parts by weight: 80-100 parts of stones, 40-60 parts of quartz sand, 25-35 parts of cement, 8-12 parts of an impermeability reinforcing material, 3-5 parts of sodium carboxymethyl cellulose, 1.5-1.8 parts of an additive and 25-30 parts of water. The Portland pozzolana cement concrete is reinforced through mutual cooperation of sodium carboxymethyl cellulose and an anti-permeability reinforcing material, so that the compressive strength and the water permeability resistance of the cement concrete are effectively improved, the corrosion resistance of chloride ions and sulfate is improved, and the service life of the cement concrete in a high-ion environment is prolonged.
Owner:JIANGSU XINDI WATERPROOF MATERIAL CO LTD

Solid waste-based low-carbon gel material and preparation method thereof

ActiveCN121063892ASlurryNanocrystal
The invention discloses a solid waste-based low-carbon gel material and a preparation method thereof. The material comprises the following components in percentage by mass: 40%-60% of high-activity slag, 20%-35% of tower bottom ash subjected to stage treatment, 3%-8% of a pH sensitive composite exciting agent, 0.5%-2% of nano C-S-H seed crystal, 0.1%-1% of modified cellulose nanocrystals and 15%-25% of water, and the water-solid ratio is controlled to be 0.15-0.28. The preparation method comprises the steps of tower bottom ash grading pretreatment, nano C-S-H seed crystal preparation and dispersion, pH sensitive composite exciting agent preparation, mixing and slurry preparation. Sulfate release is optimized through staged treatment, alkalinity is dynamically regulated and controlled through a pH sensitive exciting agent, ordered hydration and a multi-stage pore structure are induced through nano C-S-H seed crystals and modified cellulose nanocrystals, and the compressive strength, the impermeability and the low expansion rate are remarkably improved. Industrial solid waste is effectively utilized, energy consumption and carbon emission are reduced, the problems of non-uniform hydration and expansion cracking are solved, and the method is suitable for the fields of green buildings and resource recycling.
Owner:POLYMER ECOLOGICAL TECHNOLOGY (JIANGSU) CO LTD

Low-carbon super sulfate cement and preparation method thereof

PendingCN120247433ASlagPhysical chemistry
The invention relates to the technical field of cementing materials, and discloses low-carbon super-sulfate cement and a preparation method thereof.The low-carbon super-sulfate cement is prepared from, by weight, 80%-85% of blast furnace slag, 1%-5% of carbide slag and 10%-15% of desulfurized gypsum, the carbide slag serves as an alkali activator to destroy the slag structure and promote decomposition of a slag glass network body, and the desulfurized gypsum serves as an alkali activator to destroy the slag glass network body; the low-carbon super-sulfate cement prepared by the method has good early strength and later strength, and the carbon emission of the super-sulfate cement is reduced as the ettringite, the C-(A)-S-H gel and other hydration products are generated. And secondly, resource utilization of the industrial solid waste is combined with preparation of the cementing material, so that the risks of stockpiling and pollution of the industrial solid waste are effectively reduced, and comprehensive utilization of the industrial solid waste is promoted.
Owner:XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY