4334 results about "Sulphate salt" patented technology

The invention provides a self-leveling rapid repair mortar based on a steel slag solid waste cementing material and a preparation method thereof, the self-leveling rapid repair mortar comprises the following components in parts by mass: 100 parts of a self-leveling rapid repair mortar cementing material: 20-32 parts of steel slag powder, 20-30 parts of slag powder, 10-23 parts of raw ash, 10-15 parts of desulfurized gypsum, 5-8 parts of silica fume, and 8-25 parts of rapid hardening sulphoaluminate cement; the fine aggregate comprises 50 parts of quartz sand and 50 parts of steel slag aggregate; 0.3 to 0.7 part of a polyether defoaming agent, 0.05 to 0.25 part of lithium carbonate and 6 to 12 parts of a polycarboxylic acid water reducing agent; and 25-28 parts of water. According to the self-leveling rapid repair mortar based on the steel slag solid waste cementing material, on the basis of an alkali excitation synergistic sulfate excitation mechanism, the solid waste materials such as the steel slag powder, the slag powder, the raw ash and the desulfurized gypsum are utilized, and through proportioning optimization, the self-leveling rapid repair mortar which can open traffic within 2 hours and has the compressive strength gt within 28 days is prepared; the bonding strength is gt; the self-leveling mortar for rapidly repairing the cement concrete pavement has the advantages of self-leveling, no shrinkage of later strength and excellent durability.

A forest fire retardant composition contains a retardant compound that includes a phosphate salt. The phosphate salt may include diammonium phosphate, diammonium orthophosphate, monoammonium phosphate, monoammonium orthophosphate, monosodium phosphate, disodium phosphate, disodium phosphate hydrate, sodium ammonium phosphate, sodium ammonium phosphate hydrate, sodium tripolyphosphate, trisodium phosphate, or dipotassium phosphate, and combinations thereof. The forest fire retardant composition may include an ammonium source. The composition may be in the form of a dry concentrate, a liquid concentrate, or a final diluted product. The final diluted product is effective in suppressing, retarding, and controlling forest fires while exhibiting corrosion resistance and low toxicity.

The invention discloses a sulfur-manganese composite autotrophic denitrification filler as well as a preparation method and application thereof, and belongs to the technical field of environmental functional materials and polluted water treatment. The sulfur-manganese composite autotrophic denitrification filler contains manganese salt, a sulfur-based component and a cement-based component, the manganese salt comprises one or more of manganese carbonate, calcium manganese ore and rhodochrosite; the sulfur-based component comprises sulfur and sulfur manganese ore; the cement-based component comprises cement, fly ash pottery sand, silica fume, blast furnace slag and metakaolin; the cement comprises one or more of Portland cement, iron aluminate cement and sulphoaluminate cement. The nitrogen removal efficiency of the sulfur-manganese composite autotrophic denitrification filler is superior to that of a sulfur autotrophic denitrification system, the sulfate concentration and nitrite nitrogen accumulation in effluent are remarkably reduced, the service life of the filler is prolonged, and the efficient utilization rate of the material is improved.

A forest fire retardant composition contains a retardant compound that includes a phosphate salt. The phosphate salt may include diammonium phosphate, diammonium orthophosphate, monoammonium phosphate, monoammonium orthophosphate, monosodium phosphate, disodium phosphate, disodium phosphate hydrate, sodium ammonium phosphate, sodium ammonium phosphate hydrate, sodium tripolyphosphate, trisodium phosphate, or dipotassium phosphate, and combinations thereof. The forest fire retardant composition may include an ammonium source. The composition may be in the form of a dry concentrate, a liquid concentrate, or a final diluted product. The final diluted product is effective in suppressing, retarding, and controlling forest fires while exhibiting corrosion resistance and low toxicity.

The invention discloses a cobalt-loaded covalent organic framework material as well as a preparation method and application thereof, and belongs to the technical field of catalyst preparation. The cobalt-loaded covalent organic framework material is prepared by taking a carbonized covalent organic framework as a matrix and cobalt nitrate hexahydrate as a cobalt source, reducing by using a sodium borohydride methanol solution, and introducing transition metal cobalt into the framework through room-temperature impregnation and thermal reduction processes. In the material, active components comprise Co0 and Co < 2 + > which are uniformly distributed on a carrier. Moreover, the metal cobalt is stably loaded in a carbon skeleton through the bonding effect of heteroatoms such as nitrogen and carbon, so that the stability, the catalytic activity and the durability of the metal cobalt are effectively improved, the dissolution risk of the metal cobalt is reduced, the hidden danger of environmental pollution is reduced, and efficient catalytic activity is shown in the aspect of catalyzing and activating peroxymonosulfate to degrade organic pollutants; and good recycling stability is achieved.

The present invention relates methods for treating thyroid cancer, renal cell carcinoma or hepatocellar carcinoma comprising orally administering to a patient in need of such therapy a therapeutic amount of cabozantinib lauryl sulfate salt, preferably in a capsule form. The method allows the administration of the therapeutic amount of cabozantinib lauryl sulfate salt in a fed state or a fasted state and the administration does not exhibit a food effect.

The present invention relates methods for treating thyroid cancer, renal cell carcinoma or hepatocellar carcinoma comprising orally administering to a patient in need of such therapy a therapeutic amount of cabozantinib lauryl sulfate salt, preferably in a capsule form. The method allows the administration of the therapeutic amount of cabozantinib lauryl sulfate salt in a fed state or a fasted state and the administration does not exhibit a food effect.

The presently claimed invention is directed to a bleaching medium comprising at least one phenalenone which is capable of generating singlet oxygen, at least one persulfate salt, at least one alkalizing agent and at least one hydrogen peroxide source and methods for bleaching hair by using the bleaching medium.

The invention discloses a carbon-coated sodium ferrous sulfate phosphate positive electrode material as well as a preparation method and application thereof. The carbon-coated sodium ferrous sulfate phosphate positive electrode material is square flaky particles formed by coating sodium ferrous sulfate phosphate with a conductive carbon material and irregular aggregates of the square flaky particles. The molecular formula of the sodium ferrous sulfate phosphate is Na (6-2x + y) Fex( SO4) (3-y) (PO4) y, x is more than 0 and less than 3, and y is more than 0 and less than or equal to 0.5. The invention also discloses a preparation method and application of the carbon-coated sodium ferrous sulfate phosphate positive electrode material. The positive electrode material has the advantages of phosphate and sulfate positive electrode materials, the voltage platform is high, the conductivity is excellent, the air stability is good, and the assembled battery has excellent chemical sodium storage performance, high discharge specific capacity, highly reversible charge-discharge reaction and good cycle performance. The method is simple in process, high in feasibility, low in raw material cost and easy to realize industrial production through a solution system.

The invention provides a power transmission and transformation project reinforced concrete corrosivity evaluation method and system, and relates to the technical field of civil engineering durability evaluation.The method comprises the steps that temperature data of a project location and the total volume, the water content and the pore volume of reinforced concrete are collected, and a freeze-thaw failure index formula is constructed; the product type is judged according to the measured sulfate concentration, different sulfate erosion index formulas are constructed in combination with related data, and the magnesium ion concentration is independently considered in the marine environment; constructing a chlorine salt erosion index formula according to the chloride ion concentration; extracting data from the research report to construct a carbonization erosion index formula; and giving a weight to each erosion type to establish a comprehensive corrosivity evaluation index formula, and judging the erosion degree according to a result. By means of the method, various erosion factors can be comprehensively considered, the erosion degree can be effectively judged according to the evaluation result, and a key basis and scientific guidance are provided for durability guarantee, protective measure making and maintenance decision making of the reinforced concrete structure of the power transmission and transformation project.

The invention relates to the technical field of carbon monoxide oxidation catalysts, and discloses a sulfur-tolerant noble metal-based CO oxidation catalyst as well as a preparation method and application thereof. The preparation method of the catalyst comprises the following steps: dipping a carrier in an aqueous solution containing a noble metal precursor and an auxiliary agent precursor, and then drying and roasting to obtain a catalyst matrix; carrying out pre-reduction treatment on the catalyst matrix in a hydrogen-containing atmosphere to obtain a catalyst intermediate; carrying out induced activation on the catalyst intermediate in an atmosphere containing CO and H2S; wherein the carrier is at least one of titanium dioxide, cerium dioxide, aluminum oxide and zirconium dioxide, and the metal element in the auxiliary agent precursor is at least one of Fe, Co and Ni. The catalyst prepared by the method provided by the invention can realize the high-selectivity oxidation process of H2S species, inhibits the adsorption of S species and the formation process of sulfate, and realizes the high-conversion-rate oxidation reaction of carbon monoxide in the presence of H2S.

The invention discloses a treatment process for acid mine wastewater and a combined reactor thereof, and relates to the technical field of water treatment. The method specifically comprises the following steps: oxidizing the mine acid wastewater through an aerobic reactor; adjusting the pH value to 2.8 by using KOH in a first neutralization reactor, and further adjusting the pH value to 4.5 by using KOH in a second neutralization reactor; the wastewater enters a pretreatment reactor, H2S is introduced for treatment, and the treated wastewater continuously enters two anaerobic reactors for reaction. According to the method, an aerobic-anaerobic combined reactor containing iron oxidizing bacteria and sulfate reducing bacteria is adopted for treating the mine acid wastewater, on one hand, AMD can be effectively treated, on the other hand, heavy metal can be selectively precipitated, and Schwertmannite and metal sulfide with utilization value are obtained. The method not only realizes the economic value of effectively utilizing the wastewater, but also realizes the target of environmental treatment, and has better economic value.

The present invention belongs to the field of pharmaceutical chemistry, and relates to different sulfate crystal forms of an amide compound, namely, 1-(3-cyano-5-methylthiophene-2-yl)-N-(6-methoxy-1H-benzo[d]imidazol-2-yl)-2,5-dimethyl-1H-pyrrole-3-carboxamide, a pharmaceutical composition containing the crystal form, and uses thereof. The chemical stability and crystal stability of the sulfate crystal form are both better than those of the free base crystal form.

An animal litter, process for preparing the animal litter, and a method for removal of animal waste using the animal litter are provided. The animal litter generally includes at least one sorbent and a sulfate such as sodium bisulfate. The animal litter is in the form of discrete plural particles which tend to agglomerate when wetted.

The invention provides a concrete admixture with sulfate corrosion resistance and rust resistance functions. The concrete admixture is prepared from the following raw materials in parts by weight: 50-65 parts of fly ash, 8-12 parts of barium carbonate, 8-12 parts of barium hydroxide, 8-12 parts of mineral powder, 5-8 parts of modified hydrotalcite or hydrotalcite, 1-3 parts of nano silicon dioxide and 1-3 parts of calcium nitrite. Nano silicon dioxide is adopted as a compact component, the porosity of the material is reduced, the compactness of concrete is improved, sulfate in the environment is inhibited from being transmitted into the concrete, meanwhile, hydrotalcite is modified by polymaleic acid serving as a scale inhibition component, and the scale inhibition effect is improved through the dual effects of high adsorbability and slow release of the scale inhibition component of hydrotalcite. The preparation method has the advantages that generation of ettringite and gypsum in a sulfate radical environment is inhibited, calcium nitrite is added as a corrosion-inhibiting component, a protective film is formed on the surface of a reinforcing steel bar, the corrosion phenomenon of the reinforcing steel bar in a concrete structure is inhibited, and finally, the concrete admixture with sulfate corrosion resistance and corrosion-inhibiting functions is formed through compounding.

The invention discloses a solid waste-based cementitious material, which comprises the following raw materials based on 100% of the total mass percentage: 10% to 35% of pretreated pyrite tailing powder, 30% to 50% of granulated blast furnace slag powder, 15% to 30% of steel slag powder, and the remainder being gypsum powder. The invention heats the pyrite tailing at 300°C and ultrafinely grinds the pyrite tailing to cause an oxidation reaction of pyrite and pyrrhotite contained therein to generate sulfate minerals, thereby reducing the proportion of sulfide compounds in the tailing and reducing the risk of expansion and cracking of a hardened body of the solid waste-based cementitious material in the later stage. Moreover, the sulfate generated by oxidation and the gypsum contained in the pyrite tailing react with the steel slag and slag in the solid waste-based cementitious material to generate hydrated calcium silicate gel and calcium sulfonite, thereby improving the strength of the solid waste-based cementitious material.

An animal litter, process for preparing the animal litter, and a method for removal of animal waste using the animal litter are provided. The animal litter generally includes at least one sorbent and a sulfate such as sodium bisulfate. The animal litter is in the form of discrete plural particles which tend to agglomerate when wetted.

A low-carbon near zero emission process of industrial waste water, comprising: S1: entering industrial waste water into a pre-oxidation system to improve biodegradability of organics; S2: after treatment in the pre-oxidation unit, entering the waste water into an anaerobic biological treatment system, sodium chloride and sulfate is deeply removed and carbon sources in the waste water can be used to remove the sulfate and nitrate; S3: entering water output from the anaerobic biological treatment system into a membrane concentration system and membrane concentrated solution enters a nano-filtration salt fractionation system for salt fractionation; and S4: refluxing nano-filtration concentrate solution generated by the nano-filtration salt fractionation system to the anaerobic biologic treatment system for biological desulfurization, or synthesizing the nano-filtration concentrate solution to be sodium persulfate by electro chemical methods, and refluxing proportionately to a waste water pre-oxidation system for use in-situ.

The invention relates to acid-resistant sulfate reducing bacteria and application thereof, and belongs to the technical field of microorganisms. The acid-resistant sulfate reducing bacterium disclosed by the invention is Desulfovibrio desulfuricans QY411, and is preserved in the Guangdong Microbial Culture Collection Center on March 14, 2024, and the preservation number of the acid-resistant sulfate reducing bacterium is GDMCC No: 64412. The acid-resistant sulfate reducing bacterium provided by the invention can survive in an environment with the pH value of 4, and can be applied to ecological reconstruction of acid tailings and waste dump soil, the pH values of mining wasteland soil and surface water after ecological reconstruction are remarkably increased, the concentration of SO4 < 2-> in the soil is remarkably reduced, the acidification process in the mining wasteland soil is effectively inhibited, and the acid-resistant sulfate reducing bacterium has the advantages of being safe and reliable. Therefore, the acidification process in the mining wasteland is effectively controlled. Meanwhile, soil heavy metal pollution is reduced, and vegetation growth is recovered.

The invention provides a method for preparing a lithium slag-based molecular sieve by melting lithium slag with assistance of eutectic salt, and relates to the technical field of molecular sieves. The method comprises the following steps: carrying out acid pickling pretreatment on a lithium slag raw material to obtain pretreated lithium slag; co-grinding and uniformly mixing the pretreated lithium slag and eutectic salt, and reacting at 200-350 DEG C for 2-6 hours to obtain eutectic lithium slag; carrying out aging treatment and crystallization treatment on the eutectic lithium slag, carrying out solid-liquid separation, washing the solid to be neutral, and drying to obtain a lithium slag-based molecular sieve; wherein the eutectic salt comprises an alkali solvent and an auxiliary salt, the alkali solvent is sodium hydroxide, and the auxiliary salt is at least one of chlorine salt, villiaumite, carbonate, sulfate and nitrate; the molar ratio of the alkali flux to the auxiliary salt is (4-19): 1. According to the method, the eutectic salt system is introduced in the lithium slag alkali fusion stage, meanwhile, the molar ratio of the alkali flux to the auxiliary salt in the eutectic salt is controlled to be (4-19): 1, the alkali fusion reaction temperature is reduced, the reaction of the lithium slag and alkali is promoted, the molecular sieve yield is increased, the product morphology can be regulated and controlled, and a specific molecular sieve can be formed in a guiding mode.

The invention discloses a method for degrading dioxin in fly ash and stabilizing heavy metals, which comprises the following steps: carrying out water washing treatment on the fly ash, and carrying out solid-liquid separation to obtain water washing slag; mixing the washed slag with water, adding zero-valent iron and sulfite, carrying out hydrothermal treatment, and carrying out solid-liquid separation to obtain hydrothermal slag and hydrothermal liquid; according to the method for degradation of dioxin in fly ash and stabilization of heavy metal in cooperation with degradation of dioxin in fly ash, under the combined action of zero-valent iron, chlorite and a hydrothermal environment, efficient degradation of dioxin in fly ash can be rapidly achieved under the lower reaction condition, stabilization of heavy metal in fly ash can be synchronously achieved, and the method is suitable for industrial production. The method has the advantages of being low in cost, mild in reaction condition, high in treatment efficiency, good in treatment effect, environmentally friendly and the like, can effectively solve the problems existing in the prior art, provides powerful support for harmless treatment and resource utilization of the waste incineration fly ash, and has wide engineering application prospects.

The invention belongs to the technical field of environment-friendly materials, and particularly relates to an MIL-88A-WS2 composite material and a preparation method and application thereof. The preparation method comprises the following steps: mixing WS2 taking a 1T phase as a main phase and MIL-88A in a solvent, then carrying out a hydrothermal reaction, in the hydrothermal reaction process, loading the WS2 taking the 1T phase as the main phase on the MIL-88A, forming a Fe < 2 + > / Fe < 3 + > and W < 4 + > / W < 6 + > circulating channel, covalent bonds and ionic bonds between the WS2 taking the 1T phase as the main phase and the MIL-88A, and meanwhile, forming a hollow structure by the MIL-88A, so as to obtain the MIL-88A-WS2 composite material. The MIL-88A-WS2 composite material obtained by the method provided by the invention has many active sites and strong conductivity, and can act together with an oxidizing agent peroxymonosulfate to realize degradation of phenolic pollutants.

The invention discloses a treatment method of tantalum-niobium smelting wastewater, and relates to the technical field of tantalum-niobium smelting, and the treatment method specifically comprises the following steps: step 1, wastewater collection and primary treatment; step 2, physicochemical reaction and precipitation; step 3, biological treatment; and step 4, MBR membrane pool treatment. According to the treatment method of the tantalum-niobium smelting wastewater, uniform distribution of the coagulant or the precipitant in the precipitation tank can be ensured by intermittently adding the coagulant or the precipitant, and over-high or over-low local concentration caused by one-time large-amount adding is avoided, so that the coagulation effect is improved, impurities such as suspended solids, part of organic matters and sulfate in the wastewater are more effectively removed, and the treatment effect is improved. The input amount of the coagulant or the precipitator can be flexibly adjusted according to the water quality change and the treatment requirement in the sedimentation tank, so that the treatment process is more accurate and efficient; by accurately controlling the input amount of the coagulant or the precipitant, waste caused by excessive addition can be avoided, and the consumption of chemical agents is reduced.

The invention discloses silver powder with a high twin crystal ratio and a preparation method and application of the silver powder with the high twin crystal ratio. The preparation method comprises the following steps that S1, a carboxylic acid coordination agent is added into a silver source solution, and a silver precursor solution is obtained; sequentially adding a dispersing agent and an initiator into the reducing agent solution to obtain a reaction base solution; s2, a silver precursor solution is added into the reaction base solution for an oxidation-reduction reaction, then curing is conducted, and mixed mother liquor is obtained; s3, the mixed mother liquor is filtered, washed, dispersed and dried, and then the silver powder with the high twin crystal proportion is obtained; the initiator comprises one or more of sulfate, carbonate and nitrate; through the synergistic effect of the initiator and the carboxylic acid coordination agent, the silver ion release rate and the crystal nucleus preferential growth direction are regulated and controlled, the rapid feeding and curing technology is combined, the low supersaturation environment is constructed, the silver powder is induced to grow in the specific direction, and the twin crystal proportion is remarkably increased.

The invention provides a superfine light-weight high-strength filler and a preparation method thereof, and belongs to the technical field of fillers. The filler is prepared from the following components in parts by weight: 30 to 100 parts of quartz sand, 1 to 10 parts of cullet, 1 to 15 parts of Al2O3, 7 to 15 parts of Li2O, 2 to 8 parts of P2O5, 1 to 12 parts of ZrO2, 3 to 6 parts of composite nucleating agent, 5 to 10 parts of carbonate, 10 to 20 parts of feldspar and 2 to 5 parts of sulfate. The preparation method comprises the following steps: mixing the quartz sand, the cullet, the Al2O3, the Li2O, the P2O5, the ZrO2 and the composite nucleating agent, melting at a high temperature to obtain a base material, nucleating and crystallizing at different temperatures, grinding, adding the carbonate, the feldspar and the sulfate, adding the binder, granulating, and sintering to obtain the product. The lightweight high-strength filler has the characteristics of sound absorption, noise reduction, fire prevention, flame retardance, light mass density, high compressive strength, low water absorption, ecological environmental protection and the like, and is suitable for lime, gypsum and cement-based products; particularly, the high-temperature-resistant and high-strength dry-mixed mortar has a good application prospect in dry-mixed mortar products, such as ceramic tile adhesives, light plastering and self-leveling, as well as acoustic boards, sound insulation barriers, heat insulation boards and fireproof board products.

An animal litter, process for preparing the animal litter, and a method for removal of animal waste using the animal litter are provided. The animal litter generally includes at least one sorbent and a sulfate such as sodium bisulfate. The animal litter is in the form of discrete plural particles which tend to agglomerate when wetted.

The invention relates to a method for preparing high-quality ammonium sulfate by using sodium-ammonium-containing sulfate solid waste, which comprises the following steps: partially dissolving the sodium-ammonium-containing sulfate solid waste and carrying out solid-liquid separation to obtain a first dissolved solution and a first solid phase; the first dissolving solution is subjected to first evaporative crystallization and solid-liquid separation, and an ammonium sulfate product and a first mother solution are obtained; wherein the temperature of partial dissolution is 5-10 DEG C; efficient separation and recovery of ammonium sulfate and sodium sulfate resources in sulfate solid waste containing sodium and ammonium are achieved, the purity of an ammonium sulfate product obtained after first evaporative crystallization is preferably as high as 98.6% or above, the appearance color is white, the water content is preferably as low as 1.3% or below, and the recovery rate is high. The recovery rate is preferably up to 98.00% or above, the purity of the sodium sulfate product is up to 98.5% or above, the amount of sodium hydroxide required to be consumed is as low as 0.93% or below, and the method is simple in technological process, mild in condition and easy to industrialize.

Methods, systems and devices for PFAS destruction including oxidatively pretreating an aqueous foam fractionate solution including PFAS to form a pretreated solution by mixing the aqueous foam fractionate solution with a persulfate and an acid or a base to increase or decrease the pH and oxidizing the aqueous foam fractionate solution and then subjecting the pretreated solution to UV photolysis, such as by directing UV light onto the pretreated aqueous foam fractionate solution at 222 nm, 254 nm and / or 185 nm. Oxidizing the foam fraction may include subjecting the aqueous foam fractionate solution to an increased temperature and pressure for a period of time sufficient for thermal oxidation or subjecting the aqueous foam fractionate solution to ozone oxidation.

To provide a water-soluble chelating polymer that can rapidly trap a trace amount of heavy-metal ions to reduce the amount of heavy-metal ions to a ppm level or lower in a short time.Use a water-soluble chelating polymer comprising an anionic polymer having a carboxy group, a sulfonate group and / or a sulfate group bonded through an ionic bond to a chelating functional group having a cationic functional group, wherein the water-soluble chelating polymer contains 0.2 to 6 mmol / g of the chelating functional group and has a weight-average molecular weight in the range of 30,000 to 1,000,000.

The invention discloses a high-entropy layered double hydroxide with a strong strain effect and a preparation method of the high-entropy layered double hydroxide. The preparation method comprises the following steps: firstly, preparing ferric salt, cobalt salt, nickel salt, copper salt and zinc salt into a mixed aqueous solution of five metal salts; preparing sodium hydroxide and sodium carbonate into an alkali source aqueous solution; then mixing and stirring the mixed aqueous solution of the five metal salts and the alkali source aqueous solution to gradually form yellowish-brown precipitates, then transferring the yellowish-brown precipitates into a polytetrafluoroethylene reaction kettle, and further reacting in a drying oven; and finally, carrying out centrifugal separation, deionized water and absolute ethyl alcohol washing and freeze drying on the fully reacted precipitate to obtain brown powdery solid, namely the high-entropy layered double hydroxide. The high-entropy layered double hydroxide can be used for advanced oxidation catalytic degradation of tetracycline antibiotic wastewater, the strong strain effect of the high-entropy layered double hydroxide enhances the benefit of activating peroxymonosulfate to generate active free radicals, the efficiency of degrading water pollutants is improved, and the high-entropy layered double hydroxide has good application prospects.