533 results about "P phosphate" patented technology

The present invention belongs to the technical field of battery materials, and particularly relates to a composite phosphate-based positive electrode material, and a preparation method therefor and the use thereof. The composite phosphate-based positive electrode material comprises a phosphate-based active core, wherein the outer surface of the phosphate-based active core is sequentially coated with a carbon coating layer, a nitrogen-doped carbon coating layer and a nitrogen-phosphorus co-doped carbon coating layer from inside to outside, wherein the carbon coating layer can improve the electronic and ionic conductivity of the composite positive electrode material, and optimize the particle size and morphology of the composite positive electrode material. The nitrogen-doped carbon coating layer improves the consistency and integrity of coating; and nitrogen-atom-doped carbon further enhances the electronic conductivity and lithium-ion diffusion of the carbon coating layer. Electron-rich clouds of P and N atoms in the nitrogen-phosphorus co-doped carbon coating layer can provide a rich conductive network, mutual contact is formed among different particles to form a series network, thus promoting the interfacial electron transport of the composite material during a charging and discharging process, and improving the cycling and rate performance of the composite phosphate-based positive electrode material during the charging and discharging process.

The invention relates to a betaine phosphate-containing feed additive for improving net energy level and a preparation method and application thereof, and belongs to the technical field of feed additives, the preparation method comprises the following steps: preparing composite betaine phosphate, preparing composite zinc methionine, and mixing; the preparation of the composite betaine phosphate comprises the following steps: preparing a betaine phosphate crude product, preparing a composite silicon dioxide carrier, and crystallizing; the preparation of the compound zinc methionine comprises the following steps: preparing an activated silicon dioxide carrier, adsorbing starch and adsorbing the zinc methionine; in the step of mixing, the compound betaine phosphate and the compound zinc methionine are mixed and then stirred at room temperature, and the betaine phosphate-containing feed additive capable of improving the net energy level is obtained. The feed additive prepared by the invention has a strong effect of improving the net energy level of broiler chickens, is not easy to have the problems of bonding and clustering, and is good in storage resistance.

The application specifically discloses a phosphate-based positive electrode material and a preparation method and application thereof. The phosphate-based positive electrode material comprises base particles and a carbon coating layer coated on the surface of the base particles; the chemical formula of the base particles is Li x M y PO4, 0.96≤x≤1.08, 0.96≤y≤1, M comprises at least one of Fe and Mn; wherein, the M site is doped with a first metal element, the first metal element comprises at least one of Ti, V, Cr, Co, Ni, Nb, Mo and W; and / or, the Li site is doped with a second metal element, the second metal element comprises at least one of Mg and Zr; the carbon coating layer comprises a carbon material, and the degree of disorder I D / I G of the carbon material is ≤1.2. The application has the advantages of improving the electrochemical performance of the phosphate-based positive electrode material and reducing the ion elution rate thereof.

The present invention discloses a method for detecting MPL in a sample and its related applications, relating to the field of biological detection. The adsorbent includes aluminum phosphate or a product obtained by mixing aluminum hydroxide and a phosphate solution, which can effectively adsorb free MPL in the sample, thereby achieving effective separation of free MPL and MPL bound to liposomes in the sample. By detecting the difference in MPL content in the sample before and after adsorption, the proportion of free MPL and MPL bound to liposomes in the sample can be determined. This method has the advantages of being easy to implement, low cost, and high efficiency. It does not require expensive reagents and instruments, and can quickly and accurately calculate the encapsulation rate of MPL in liposomes, providing a new approach for quality control of adjuvants or vaccines containing MPL.

Disclosed is a phosphate e precursor, which has a chemical formula of LixMy(PO4)(x+y) / 2Az·wH2O, where M is a transition metal element selected from one or more of Fe, Ti, V, Cr, Ni, Co, Mn, Al, Nb, Y, Zr, Sb, Mo, Sn, and Ce, A is one or more of F, OH, CO32−, C2O42−, and O2−; and 0.5≥x<1.2, 0.5<y≥1, 0≥z≥1, and 0.1≥w<8. The phosphate precursor has good uniformity, contains crystal water, and exhibits excellent structural stability, and can be used to prepare olivine-type phosphate cathode material through sintering at a low temperature of 260° C.-600° C.; and the phosphate precursor is blended with a carbon source and is subjected to heat treatment to obtain carbon-contained cathode material, which has good electrochemical properties.

The invention discloses a bone cement composition and application thereof, and relates to the technical field of bone cement. The bone cement composition comprises a solid phase component and a liquid phase component, wherein the solid phase component comprises 60-75 parts of composite calcium phosphate, 10-20 parts of strontium glass powder, 8-12 parts of a reinforcing agent and 3-7 parts of a solidification reaction regulator; the liquid phase component comprises 20-30 parts of a phosphate buffer solution, 3-8 parts of a sodium citrate solution, 5-15 parts of an anti-inflammatory agent and 1-5 parts of a hyaluronic acid solution. The preparation method comprises the following steps: reacting 1, 10-phenanthrene-2, 9-dicarboxylic acid with 2-aminomethyl furan to obtain an intermediate 1, and reacting the intermediate 1 with poly (ethylene glycol) maleimide to prepare the reinforcing agent. The prepared bone cement composition has good mechanical properties, self-repairing performance and anti-inflammatory performance, and has a good application prospect in the field of bone repairing.

The invention discloses bioactive gel for accelerating wound healing. The gel is prepared from the following raw materials in percentage by weight: 0.8%-1% of bomer 980, 5%-5.5% of glycerol, 15%-20% of white vaseline, 51.7%-55% of phosphate buffer, 1.8%-2% of nano royal jelly acid, 2%-3% of recombinant III type human collagen, 0.4%-0.5% of sodium hyaluronate, 1%-3% of sodium alginate, 20%-25% of polyethylene glycol-400, 1.5%-3% of dopamine-methacrylamide copolymer, 0.5%-0.8% of nano silver and 0.3%-0.5% of phenoxyethanol. The nano royal jelly acid and the nano silver have a synergistic antibacterial effect, so that the inhibition effect on drug-resistant bacteria such as MRSA and pseudomonas aeruginosa is remarkably improved, and meanwhile, the wound epithelization can be accelerated and scar formation can be reduced through the dual effects of the recombinant III type collagen and the acetylated sodium hyaluronate. The defects that a traditional dressing is narrow in antibacterial spectrum, single in repairing effect, poor in environmental adaptability and the like are overcome, and the dressing is particularly suitable for complicated wounds such as diabetic foot ulcer and second-degree burn.

According to the cell fixing liquid, phenol oxidase is used for catalyzing phenol to be oxidized into a quinone structure, the quinone structure reacts with protein amido to form light covalent immobilization, cell immobilization is achieved, a stable hydration environment and membrane protection are provided through the ionic liquid solvent choline dihydrogen phosphate, a phosphate-free buffer system is provided, and cell immobilization is achieved. Therefore, a novel cell fixing liquid is obtained, the cell structure integrity required by cell imaging analysis is effectively reserved, meanwhile, cell staining fluorescence signal interference is avoided, and therefore the accuracy of cell counting and cell imaging analysis is ensured.

The invention discloses injectable hydrogel for alveolar bone repair, the injectable hydrogel comprises a first component and a second component, the first component comprises 4-carboxyl-3-fluorophenylboronic acid modified carboxymethyl chitosan CMCS-FPBA and beta-tricalcium phosphate, and the second component comprises oxidized dextran, PPS-HA nano-micelle and curcumin. The invention also discloses a preparation method and application of the injectable hydrogel. The injectable hydrogel disclosed by the invention has the effects of resisting oxidation, resisting inflammation and promoting bone tissue regeneration, is high in biocompatibility, can be customized in a personalized manner, and can be used for repairing alveolar bones.

The invention provides a method for detecting vitamin B6 related substances in a multivitamin preparation, and belongs to the field of analytical chemistry. According to the method, a high performance liquid chromatograph is adopted, and chromatographic conditions are as follows: an octadecyl silane bonded silica gel chromatographic column is adopted, a mobile phase is a phosphate buffered solution (containing sodium hexanesulfonate)-acetonitrile, and a mobile phase A and a mobile phase B are performed according to a gradient procedure; the flow velocity is 0.8 to 1.2 mL / min; the column temperature is 28-40 DEG C, the detection wavelength is 320-340nm, and the sample size is 20-50mu L. The detection method has the advantages of high sensitivity and good linear relationship, and is suitable for analysis and content determination of vitamin B6 related substances in various vitamin preparations.

The invention relates to the technical field of new energy, in particular to a multi-stage compound positive electrode material as well as a preparation method and application thereof, and the compound positive electrode material comprises a phosphate spherical material, phosphate single particles and a ternary material which are compounded in a three-stage mixing manner; the phosphate spherical material is formed by aggregating primary particles, the particle size distribution consistency ((D90-D10) / D50) is 1.2-2.0, the closed pore porosity in the spherical material is less than or equal to 5vol.%, and the phosphate single particles are obtained by crushing and dissociating the phosphate spherical material. Phosphate spherical materials and single particles are prepared through hydro-thermal synthesis, the phosphate spherical materials are formed by agglomeration of nano-particles and have good rate capability and nitrogen-containing pores (with excellent thermal resistance), and the single particles are ternary materials for gap filling and thermal resistance. The advantages of a ternary material and a phosphate material are coordinated, and the energy density, the thermal safety and the service life of the battery are optimized.

The invention relates to the technical field of pavement patching materials, in particular to a pavement patching material with high early strength and toughness and a preparation method thereof. The repairing material is formed by compounding phosphate-based powder A, magnesium oxide-based powder B, a composite retarder C and a fiber material D, the phosphate-based powder comprises phosphate and disodium hydrogen phosphate dodecahydrate; the magnesium oxide-based powder B comprises dead burned magnesium oxide, superfine powder, industrial solid waste powder, cellulose ether and wollastonite whiskers; the composite retarder C comprises borax and nitrite; the fiber material D comprises reinforced fibers. The preparation method is the preparation method of the pavement patching material. The pavement patching material slurry has high early strength, the construction time can be remarkably shortened, and it is guaranteed that a repaired pavement has excellent mechanical performance and durability; according to the preparation method, materials can be prepared respectively, and standardized production, transportation and storage are facilitated; only water needs to be added for preparation on a construction site, and construction is convenient.

The invention belongs to the technical field of anti-rust coatings, and provides an anti-rust coating composition as well as a preparation method and application thereof. The preparation method comprises the following steps: firstly, preparing a BiVO4 composite material with high thermal stability and an oxygen vacancy structure by adopting a hydrothermal method so as to enhance the thermal stress resistance and mechanical strength of the BiVO4 composite material; secondly, a phosphonitrile chloride polymer compound is prepared through an absolute ethyl alcohol dispersion polymerization method, so that the chemical corrosion resistance and the thermal stability of the coating are improved; then, phosphate reinforced glass ceramic is prepared, and the mechanical performance and the high temperature resistance of the coating are improved; finally, the functional materials are mixed with the modified resin and the phosphate coupling agent, the mixture is evenly dispersed through a three-roller grinding machine, the anti-corrosion coating composition is prepared, the coating shows excellent thermal stress resistance under the high-temperature condition, cracking, falling and corrosion of the coating can be effectively inhibited, the service life of the high-temperature transportation pipeline is prolonged, and the anti-corrosion performance of the high-temperature transportation pipeline is improved. The method is suitable for the high-temperature pipeline field.

A negative electrode material for secondary battery use includes silicon-containing particles and coating layers covering at least part of the surfaces of the silicon-containing particles. The silicon-containing particles each include an ion conductive phase and silicon phases dispersed in the ion conductive phase. The coating layers contain at least one phosphate compound selected from the group consisting of a phosphate compound, a polyphosphate compound, and a metaphosphate compound, each of which contains an anion represented by general formula (1):In general formula (1), A represents an organic group or an oxygen atom.

The invention relates to the technical field of battery materials, and provides a phosphate positive electrode material and a preparation method and application thereof. The phosphate positive electrode material provided by the invention comprises a plurality of composite particles, and each composite particle comprises a lithium-containing phosphate core and a carbon shell layer; in the composite particles, the number of primary particles with the particle size of 150-2000 nm accounts for not less than 80%; the phosphate positive electrode material comprises the following raw materials: a lithium source, an iron source and an iron-based dispersant; wherein the lithium source comprises lithium carbonate; the iron source comprises iron phosphate; the iron-based dispersing agent comprises an iron-polyamine complex. The phosphate positive electrode material provided by the invention has proper grain composition, so that the lithium ion diffusion path can be remarkably shortened, the interface impedance is reduced, and the rate capability of the battery is effectively improved; and the compaction density of the pole piece can be improved, so that the energy density of the battery is improved.

The invention relates to the technical field of medical materials, in particular to a composite root canal filling agent premixed with a calcium silicate-niobium compound as well as a preparation method and application of the composite root canal filling agent. The composite root canal filling agent comprises (a) a calcium silicate compound, (b) a phosphate compound, (c) a calcium compound, (d) a niobium compound, (e) a radiation-resistant material, (f) a water-miscible non-aqueous phase solvent and (g) an organic matter, the total mass of the component (a), the component (b), the component (c), the component (d), the component (e) and the component (g) accounts for 60-95% of the total mass of the filling agent, and the total mass of the component (a), the component (b), the component (c), the component (d), the component (e) and the component (g) accounts for 20-30% of the total mass of the filling agent. And the component (f) accounts for 5-40% of the total mass of the filling agent. The filling agent is fast in solidification, good in biological activity, excellent in antibacterial performance and convenient to popularize and apply.

Provided is an optical filter, including an absorbing glass substrate composed of phosphate-based glass or fluorophosphate-based glass; a bonding layer with a single layer structure; and a resin layer, wherein the resin layer is provided on the absorbing glass substrate through the bonding layer, wherein the bonding layer includes a Si atom and one or more selected from a Ti atom, a Zr atom, and an Al atom; or an optical filter, including an absorbing glass substrate composed of phosphate-based glass or fluorophosphate-based glass; and a resin layer, wherein the resin layer includes a Si atom and one or more selected from a Ti atom, a Zr atom, and an Al atom, and is provided on the absorbing glass substrate.

[Problem] To provide a Sm-Fe-N-based magnetic powder that has good heat resistance in an atmospheric environment (that is, good oxidation resistance when the temperature has been raised in the atmosphere) and that, when held in an atmospheric environment, is capable of maintaining good magnetic properties as compared to conventional, typical powders that are surface-treated by phosphate coating. [Solution] Provided is a fatty acid-coated Sm-Fe-N-based magnetic powder that is composed of particles having a structure in which one or more fatty acid molecules having 12-20 carbon atoms per molecule are adhered to the surface of Sm-Fe-N-based magnetic particles, wherein, when C content (mass%) in the powder is denoted as [% C], and a cumulative 50% particle diameter (μm) of the powder in a volume-based particle size distribution by a dry laser diffraction scattering method is denoted as [D50], an adhesion amount index Ci defined by formula (1) is 0.5-50.0 mass%･μm.　(1): Ci = [% C] × [D50]

A sodium iron phosphate pyrophosphate positive-electrode material and a preparation method thereof, a battery, and an energy storage device are provided. A molar ratio A of sodium element to iron element in the sodium iron phosphate pyrophosphate positive-electrode material of embodiments of the disclosure satisfies 1.36≤A≤1.45.

A positive electrode material and a preparation method therefor, a positive electrode, and a battery are provided. The positive electrode material includes an iron-based phosphate material. The iron-based phosphate material includes a first active material and a second active material. A chemical formula of the first active material is Na4Fe3(PO4)2P2O7. A chemical formula of the second active material is Na2FeP2O7. A mass fraction of the first active material in the iron-based phosphate material is a1. A mass fraction of the second active material in the iron-based phosphate material is a2. a1 and a2 satisfy: 0<a2 / a1≤0.2.

The invention discloses a Pickering emulsion for embedding beta-carotene as well as a preparation method and application of the Pickering emulsion. The Pickering emulsion is obtained by embedding beta-carotene in an emulsifying agent; the emulsifier is a suspension prepared according to the following method: S1, extracting freeze-dried water extraction residues of pterocarya palustris by using an alkaline solution to obtain a filtrate; s2, adjusting the pH value of the filtrate to 6.8-7.3, and centrifuging to obtain a precipitate; s3, dispersing the precipitate in a phosphate buffer solution, performing hydration and shearing treatment, and then performing ultrasonic treatment. The Pickering emulsion disclosed by the invention has a higher BC retention rate after being stored for a short time under low-temperature, dark and low-oxygen conditions; the Pickering emulsion disclosed by the invention still has very high biological accessibility after being subjected to simulated in-vitro digestion, so that the Pickering emulsion stabilized by suspension liquid has very large potential in the aspect of conveying bioactive substances, and theoretical support is provided for practical application of the Pickering emulsion.

The present compositions and methods relate to thermostabilization of phytase with phosphate and increasing the recovery of phytase during the production of heat-treated food or animal feed pellets that contain phytase.

An active material of the positive electrode comprises secondary particles (2). Each of the secondary particles (2) comprises primary particles (1). Each of the primary particles (1) comprises an olivine-type phosphate compound. A portion of the surface of the secondary particle (2) has a depression (3). At the depression (3), the surface of the secondary particle (2) is concave. A cross-section of the secondary particle (2) satisfies the relationship "0.41 ≤ Sa / Ca ≤ 0.95". "Sa" represents the area of ​​the cross-section of the secondary particle (2). "Ca" represents the area of ​​the smallest circumcircle of the cross-section of the secondary particle (2).

The invention relates to a method for detecting genotoxic impurities of rupatadine fumarate, which is characterized in that a phosphate buffer solution is matched with acetonitrile, a high performance liquid chromatography method is adopted, a chromatographic column is a silica gel bonded octadecylsilane column, a gradient program is adopted for elution, and the content of the rupatadine fumarate genotoxic impurities in the rupatadine fumarate genotoxic impurities in the rupatadine fumarate genotoxic impurities is detected. Effective separation between rupatadine fumarate and genotoxic impurities and between genotoxic impurities can be achieved, accurate quantitative analysis can be achieved, and the quality of drugs can be effectively controlled.

The invention belongs to the technical field of battery materials, and particularly relates to a method for determining iron phosphide in a phosphate positive electrode material, the positive electrode material and application. Comprising the following steps: preparing standard solutions of a series of phosphate positive electrode materials with different iron phosphide contents; respectively collecting and purifying magnetic substances in the standard solutions, and adding a quimocilidone reagent to determine the corresponding quinoline phosphomolybdate precipitate; drawing a standard curve according to the mass of the iron phosphide and the mass of the quinoline phosphomolybdate precipitate in the standard solutions with different iron phosphide contents; preparing a to-be-detected solution, collecting and purifying magnetic substances in the to-be-detected solution, adding a quinmolybdenum citronone reagent to determine the mass of the quinoline phosphomolybdate precipitate, and calculating the content of iron phosphide in the to-be-detected phosphate positive electrode material. By means of the method, the content of trace iron phosphide in the phosphate positive electrode material can be efficiently, accurately and quantitatively analyzed, the content of iron phosphide in the phosphate positive electrode material can be quantitatively regulated and reduced, and the electrochemical performance of the phosphate positive electrode material is improved.

To provide formulations of protein molecules comprising iduronate 2-sulfatase.SOLUTION: Certain embodiments provide a pharmaceutical composition comprising a protein molecule comprising an ERT enzyme-Fc fusion polypeptide and a modified Fc polypeptide, a buffer, an isotonicity agent, a surfactant, and a stabilizer, wherein the pH of the pharmaceutical composition is about 5.5 to 7.0, and further provide methods of use thereof. In certain embodiments, the buffer is selected from the group consisting of phosphate buffer, acetate buffer, arginine buffer, and histidine buffer. In certain embodiments, the phosphate buffer is a sodium phosphate buffer or a potassium phosphate buffer.SELECTED DRAWING: None

The present invention discloses a phosphate detection method using a colorimetric method and electrochemical test paper, which belongs to the field of environmental monitoring. Specifically, the phosphate content in the water body is first semi-quantitatively detected by standard colorimetric test paper, and then the electrochemical test paper with a paper base is used to select cyclic voltammetry or square wave pulse voltammetry according to the colorimetric result to detect the phosphate concentration in the water body; when the phosphate content calculated as phosphorus in the colorimetric result is higher than 5 mg / L, the water sample is diluted by half and then detected by cyclic voltammetry; when the phosphate content calculated as phosphorus in the colorimetric result is within the range of 0.5 to 5 mg / L, cyclic voltammetry is used for detection; when the phosphate content calculated as phosphorus in the colorimetric result is lower than 0.5 mg / L, square wave pulse voltammetry is used for detection. The detection process of the present invention does not require the addition of other reagents, has a wide and accurate detection concentration range, and can achieve simple and fast in-situ detection of phosphate.

The present application provides a detection method and quality control method for related substances in dextromethorphan oral solution, which comprises the following steps: dissolving dextromethorphan oral solution in a solvent to obtain a test solution; and performing high performance liquid chromatography detection on the test solution; the mobile phase used in the high performance liquid chromatography detection comprises mobile phase A and mobile phase B, the mobile phase A comprises a phosphate solution, the mobile phase B comprises acetonitrile, and the concentration of the phosphate solution is 0.1 mM-10 mM. The detection method has good linear relationship between dextromethorphan and related substances, good accuracy and sensitivity, strong specificity, high stability, good separation degree and good reproducibility, and is suitable for wide application.

The invention relates to a pyridoxal phosphate (PLP) synthesis method based on cascade biological catalysis and capable of realizing ATP autonomous regeneration. The method comprises the following steps: constructing engineering bacteria for co-expressing pyridoxal phosphate kinase (PdxK) and polyphosphate kinase (PPK) to prepare a whole-cell catalyst or a crude enzyme solution; under the condition that ATP does not need to be exogenously added, pyridoxal, ADP and polyphosphate serve as substrates, cascade reaction is carried out under the action of a catalyst, ATP is regenerated in situ, and PLP synthesis is driven. A wild enzyme system is adopted, and the yield of PLP exceeds 95% within 4 hours of reaction; after PdxK mutation optimization, the reaction time is shortened to about 2 hours, and conversion can be completed. According to the invention, a polyphosphate-driven ATP regeneration system is coupled with PLP biosynthesis, so that the cofactor cost is remarkably reduced, a feasible technical path is provided for industrial biological manufacturing of PLP, and the application of polyphosphate in cyclic regeneration of cofactors is expanded.

The invention discloses a stage targeting scallop adductor non-phosphorus water-retaining agent containing antifreeze glycopeptide and application, and relates to the technical field of food additives. The antifreeze glycopeptide-containing stage targeting scallop adductor phosphorus-free water-retaining agent consists of an agent A and an agent B, and does not contain phosphate additives, the agent A is permeable anti-freezing liquid and is prepared from the following components in percentage by mass: 5.0 percent to 9.0 percent of trehalose, 3.0 percent to 5.0 percent of sorbitol, 0.8 percent to 1.5 percent of sodium citrate, 0.4 percent to 1.0 percent of compound amino acid, 0.01 percent to 0.1 percent of high-activity anti-freezing glycopeptide, 0.01 percent to 0.05 percent of vitamin C, 0.01 percent to 0.05 percent of rosemary extract and the balance of water. According to the antifreeze glycopeptide-containing phase-targeting scallop adductor non-phosphorus water-retaining agent and the application thereof, ice crystal damage and protein denaturation are inhibited from the source, and cell-level protection of scallop adductors is realized. Through detection, the unfreezing loss rate of the treated scallop adductor is as low as about 2.12%, the cooking loss rate is as low as about 10.63%, and the water retention capacity is close to that of a commercially available phosphate water retention agent and is remarkably superior to that of an existing non-phosphorus water retention agent.