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5135 results about "Ammonium molybdate" patented technology

Ammonium molybdate can refer to: Ammonium orthomolybdate, (NH₄)₂MoO₄ Ammonium heptamolybdate, (NH₄)₆Mo₇O₂₄, usually encountered as the tetrahydrate

Liquid silicon fertilizer and technique for producing the same

The invention relates to a liquid silicon fertilizer and a production technique thereof, and belongs to the technical field of fertilizer. The liquid silicon fertilizer is characterized in that raw materials comprise soluble silicon, urea, trace elements, chelate and fulvic acid, which are prepared into the balanced compound fertilizer. The production technique comprises the following steps: 1, dissolving solid potassium metasilicate; 2, dissolving sulfate of the trace elements in water, and adding EDTA into the mixture to obtain the chelate of the EDTA trace elements; and adding boric acid, ammonium molybdate, the urea and the fulvic acid into the mixture after cooling and filtration; and 3, blending the chelate into the mixture to obtain the liquid silicon fertilizer. The production technique is characterized in that (1) the production technique uses water glass and the fulvic acid chelate, has better buffer action for alkali, and can effectively improve stability of SiO3; and (2) the trace elements are chelated twice by using the EDTA and the fulvic acid to form chelated metal ions, so as to prevent silicic acid radicals and the metal ions reacting to form silicate difficult to be dissolved in water, and influence utilization rate of silicon element. The production technique uses the liquid potassium metasilicate and large amount of elements, trace elements and organic substances to establish a balanced compound system, and can effectively improve utilization rate of the silicon element and various nutrient elements for the crops.
Owner:于春开

Composite smoke denitration catalyst capable of oxidizing zero-valence mercury

The invention provides a composite smoke denitration catalyst capable of oxidizing zero-valence mercury. The catalyst is composite oxide V2O5-CeO2-WO3/TiO2 or V2O5-CeO2-MoO3/TiO2 based on TiO2 as a carrier, wherein the weight proportion is as follows: the weight percent of TiO2 is 75-100, the weight percent of V is 1-1.5, the weight percent of Ce is 1-5, and the weight percent of W or Mo is 7.5-8.5. The preparation method comprises the following steps: depositing Ce(OH)3 on nano TiO2; dipping ammonium vanadate/ammonium molybdate; and drying and roasting so as to obtain the catalyst; or dipping a commercial SCR (selective catalytic reduction) catalyst in a cerous nitrate aqueous solution, and then drying and roasting. The catalyst provided by the invention maintains the denitraiton efficiency of the original SCR catalyst and simultaneously the oxidation rate of zero-valence mercury is obviously improved, and divalent mercury ions are captured in subsequent dedusting equipment and wet desulphurization system; and the application temperature range of the catalyst is wide, the combination control of emission amounts of nitrogen oxides and mercury in smoke of a fuel coal power plant can be achieved on the promise that the smoke purification facility of the fuel coal power plant is not added.
Owner:GUODIAN SCI & TECH RES INST

Plant nutrient liquid fertilizer

InactiveCN102701861AImprove stress resistanceSolve the problem of lack of nutrientsFertilizer mixturesSucrosePhosphate
The invention relates to a plant nutrient liquid fertilizer. In order to solve the problem of over fertilization, the plant nutrient liquid fertilizer is prepared from the following raw materials in proportion by weight: aqua brassin 12-36, gibberellin 1-4, indoleacetic acid 30-80, abscisic acid 10-20, naphthaleneacetic acid 50-90, salicylic acid 80-180, vitamin C 1-3, cane sugar 40-100, chitin 20-80, 0.05-0.2 percent triacontanol 400-1,000, hydrolyzed protein 2-5, potassium dihydrogen phosphate 300-400, thiourea 40-120, cobalt chloride 5-12, borax 50-100, sodium silicate 30-55, urea 300-500, ammonium molybdate 50-80, copper sulfate 30-65, zinc sulfate 120-200, magnesium sulfate 100-150, calcium chloride 50-120, manganese sulfate 40-80 and water in the amount of 3-8 times the total amount of all the raw materials or water in the amount capable of dissolving all the raw materials, wherein the water is de-ionized water or micro cluster water; and the preparation method is that all the materials are prepared into aqueous solution. The plant nutrient liquid fertilizer has the advantages of favorably solving the problems of over fertilization and shortage of nutrient elements in soil, obviously improving the plant adverse resistance, improving the photosynthesis and the accumulation efficiency of nutritive materials and improving the yield and the quality.
Owner:魏玉芳

Functional bioorganic and semi-organic fertilizers and preparation method thereof

The invention discloses a functional bioorganic fertilizer and a semi-organic fertilizer and a preparation method thereof. The method comprises the following steps of: adding microzyme into livestock manure to perform anaerobic and aerobic fermentation; deodorizing, drying and crushing (after biogas slurry of residues after fermentation in a methane tank is separated, the biogas dregs are dried and crushed); adding a certain amount of humic acid, amino acid, borax, ammonium molybdate and zinc sulfate, or also adding nitrogen, phosphor and kalium inorganic nutrients; automatically blending materials by using a computer according to a proportion; after uniformly stirring, granulating by using a granulator, and drying, cooling and screening the grains; and coating a synergist and nitrogen-fixing, phosphorous-dissolving and potassium-releasing composite bacteria on qualified grains to prepare the functional bioorganic and semi-organic fertilizers. The product has the functions of preserving moisture and fertility, resisting drought, coldness, plant diseases and insect pests and the like, improves the soil structure, promoting the proliferation of beneficial microorganisms in soil, jointly participating substance circulation of a soil ecosystem and the like, has quick response and long effect, is mainly used as a base fertilizer for crops to save time and manpower, can realize waste recycling, protects ecological environment, integrates land utilization, land nourishment and land protection, and ensures constant soil productivity.
Owner:杨泉胜

Preparation method of few-layer MoS2/graphene electrochemical storage lithium composite electrode

ActiveCN102683648AGood dispersionHigh electrochemical lithium storage specific capacityCell electrodesActive agentOrganosolv
The invention relates to a preparation method of a few-layer MoS2/graphene electrochemical storage lithium composite electrode. The preparation method comprises the following steps of: ultrasonically dispersing graphene oxide in de-ionized water; adding octaalkyl trimethyl ammonium bromide cationic surfactant, then adding ammonium thiomolybdate and dropwise adding hydrazine hydrate with stirring; performing reflow reaction at 95 DEG C to reduce the ammonium thiomolybdate and graphene oxide into MoS2 and graphene at the same time respectively; centrifugally collecting a solid product; washing with de-ionized water; drying; thermally treating in a nitrogen/hydrogen mixed atmosphere to obtain the few-layer (two to four layers) MoS2/graphene composite nanomaterial; mixing the few-layer MoS2 and graphene composite nanomaterial and acetylene black as well as polyvinylidene fluoride into paste; and coating on a copper foil for rolling. The method provided by the invention has a simple process, and an organic solvent is not consumed. The few-layer MoS2/graphene composite material is used as the electrochemical storage lithium composite electrode and has high electrochemical storage lithium specific capacity, superior circulation performance and superior high-power charging and discharging characteristic.
Owner:ZHEJIANG UNIV

Water culture nutrient solution prescription of lettuce and preparation method of water culture nutrient solution prescription

The invention discloses a water culture nutrient solution prescription of a lettuce and a preparation method of the water culture nutrient solution prescription, and belongs to the technical field of plant soilless culture of the agricultural science. The nutrient solution prescription of the lettuce comprises the following components: a fertilizer A composed of 584.23g/T of calcium nitrate, 421.34g/T of potassium nitrate and 47.8g/T of ammonium nitrate; a fertilizer B composed of 182.4g/T of monopotassium phosphate and, 256.23g/T of magnesium sulfate; a fertilizer C composed of 16.8g/T of FeEDTA (Ethylene Diamine Tetraacetic Acid), 3g/T of boric acid, 2g/T of manganese sulfate, 0.25g/T of zinc sulfate, 0.85g/T of copper sulfate, and 0.38g/T of ammonium molybdate; hormone composed of 0.1g/T indolebutyric acid of or 0.1g/T of naphthylacetic acid; a bactericide composed of 15g/T of carbendazim; and nutrient solution pH (Potential Of Hydrogen) adjusting acid composed of 200ml/T of phosphoric acid or 150g/T of citric acid. The prescription is nutritionally balanced, so that the demand of the lettuce to nutrition can be met, the amount of used nutrient elements is decreased at the same time, the output of the lettuce is increased, and the fertilizers are saved; and the prescription effectively decreases the contents of nitrates in the lettuce under the water culture, improves the quality of the lettuce, enables the simplification of the complicated processes in preparation based on the demand of the actual operation, and is suitable for being used for meeting the requirements of industrialization production.
Owner:NORTHWEST A & F UNIV

High-quality strawberry planting dedicated slow-release compound fertilizer

The invention relates to the compound fertilizer field, and particularly relates to a high-quality strawberry planting dedicated slow-release compound fertilizer. The fertilizer is prepared from the following raw materials in parts by weight: 10-15 parts of a 1250-2000 mesh diatomite, 4-5 parts of borax, 2-3 parts of ammonium molybdate heptahydrate, 10-12 parts of sodium humate, 20-25 parts of urea, 18-22 parts of potassium nitrate, 25-28 parts of organic compost, 2-4 parts of fish meal, 1-3 parts of sesame leaves, 8-10 parts of alfalfa meal, 15-18 parts of corn distiller grains, 2-4 parts of brine, 8-10 parts of an erythromycin fungi residue, 1-2 parts of an EM microbial agent, 4-6 parts of a fern root residue, 1-3 parts of nano silver, 1-2 parts of a semen ginkgo powder, 4-6 parts of 1,6-hexanediol diacrylate, 10-12 parts of an acrylic resin dispersion liquid, 1-2 parts of isocyanate, 1-2 parts of calcium stearoyl lactate, 2-4 parts of zinc gluconate, 6-8 parts of table vinegar, and 4-5 parts of an auxiliary agent. The compound fertilizer has multiple nutrients, is low in production cost and good in slow-release effect, allows double coating to be formed on the nutrients by utilizing diatomite and a coating agent in the process, also contains various trace elements, has no toxicity and no pollution, and is excellent in quality of planted strawberry and obvious in yield and income increasing effects.
Owner:ANHUI SUNSON CHEM

Corrugated metal pipe (CMP) grade flame-retardant smoke-suppressing polyvinyl chloride cable sheath material and preparation method thereof

The invention provides a corrugated metal pipe (CMP) grade flame-retardant smoke-suppressing polyvinyl chloride cable sheath material and a preparation method thereof and belongs to the technical field of material. The invention solves the problem that in the prior art, the flame-retardant and smoke-suppressing effects and the mechanical property and the physical property of the cable sheath material are all good. The raw materials thereof comprise the following components in parts by weight: 100 parts of polyvinyl chloride, 5-15 parts of common plasticizer, 20-50 parts of flame-retardant plasticizer, 40-100 parts of fire retardant, 20-50 parts of smoke-suppressing agent, 5-10 parts of stabilizer, 40-80 parts of toughening modification agent and 1-5 parts of promoter; wherein the smoke-suppressing agent comprises ammonium octamolybdate, zinc molybdate and zinc borate which are compounded according to the proportion of 1:1 to 3:1 to 3 and coated by aluminium hydroxide the grain size of which is 1-5mu m according to the proportion of 1:1 to 3. The CMP grade flame-retardant smoke-suppressing polyvinyl chloride cable sheath material has the advantages of good flame-retardant and smoke-suppressing effect, mechanical property and physical property.
Owner:江西一舟数据技术有限公司

Method for recycling vanadium and molybdenum from waste petroleum catalyst

The invention relates to a method for recycling vanadium and molybdenum from a waste petroleum catalyst, and belongs to the technical field of petrochemical industry. The method comprises air-burning and ball-removing, ball-milling, soda roasting-water leaching, aluminum removing, molybdenum precipitating and enriching molybdenum by ion exchange. The method specifically comprises the following steps: firstly, igniting sticky oil in the waste catalyst in air to burn carbon and oils in the waste catalyst; then, oxidizing the vanadium and nickel in the forms of porphyrin compounds in the waste catalyst into vanadium oxide and nickel oxide, converting most of the molybdenum into molybdenum oxide, wherein the waste catalyst subjected to air-burning and oil-removing is more beneficial for crushing, and the crushed waste catalyst and a certain proportion of sodium carbonate are mixed, and are roasted at a high temperature; leaching roasted materials by hot water, dissolving sodium salts of the vanadium and the molybdenum into water to obtain a solution, filtering the solution, introducing the filtered solution into a leaching solution, introducing a little aluminum into the leaching solution, regulating the pH value of the solution to remove aluminum; regulating the pH value of the solution to 8-9, adding ammonium chloride, precipitating and separating out the vanadium in the form of ammonium vanadate; and concentrating vanadium-precipitated solution by adopting an ion exchange process and enriching an ammonium molybdate solution.
Owner:刘楚玲

Method for separating tungsten and molybdenum

The invention relates to a method for separating tungsten and molybdenum. The method comprises the following steps: (1) adding acid into a tungsten-molybdenum mixed solution and adjusting pH value to obtain mixed sediment of tungsten acid and molybdenum acid; (2) adding hydrogen peroxide and acid into the mixed sediment to form peroxide tungsten acid and peroxide molybdenum acid; (3) heating an obtained mixed solution, adding tungsten powder, reacting and filtering to obtain tungsten acid sediment and a molybdenum-containing acid solution; (4) calcining the prepared tungsten acid to prepare tungsten trioxide or dissolving by using ammonium hydroxide to obtain an ammonium tungstate solution and then evaporating and crystallizing to prepare APT; (5) extracting the molybdenum in the obtained molybdenum-containing acid solution by using an extraction agent/ion exchange resin; and (6) reversely extracting molybdenum-containing organic phase/resin by using ammonium hydroxide to obtain the ammonium molybdate solution, and carrying out acid precipitation to obtain ammonium tetramolybdate. The production process of tungsten-molybdenum products is taken into account in the method, so that the separated tungsten acid or molybdenum can be directly used for preparing the products thereof; the separation effect is excellent; the operation process is simple and is liable to control; the industrial popularization and application are liable to implement.
Owner:CENT SOUTH UNIV

Method for reclaiming metals from molybdenum-containing waste catalyst

ActiveCN102051483APrevents the problem of easy leachingSolve pollutionProcess efficiency improvementFiltrationImpurity
The invention discloses a method for reclaiming metals from a molybdenum-containing waste catalyst, which comprises the following steps of: mixing the waste catalyst and a magnesium-containing compound, roasting, degreasing, removing carbon, then crushing, mixing the powder and sodium carbonate, roasting the mixture, and leaching the roasted materials by using aqueous solution, wherein ammonium salt or aqueous ammonia is added in the aqueous solution leaching step, the molybdenum in the waste catalyst enters the solution in a form of sodium molybdate or ammonium molybdate, the impurities such as silicon, phosphorus and the like entering the aqueous solution form sediment, and the sediment is kept in solid residue in a filtration step; and after the solid is separated, performing acidification, extraction, re-extraction and the like to reclaim the molybdenum and other metals. The method solves the pollution problem caused by sulfur dioxide in the discharged gas in the roasting, degreasing and carbon removal processes; and the salts formed by the reclaimed sulfur and magnesium can play a role in removing impurities in the subsequent steps so as to save the consumption of chemical reagents in the metal reclaiming process and reduce the cost. In addition, the method reduces the operation steps, reduces equipment, improves the operation effect, and also can improve the molybdenum yield.
Owner:CHINA PETROLEUM & CHEM CORP +1
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