The invention relates to a self-supported 
titanium nitride / 
graphene combined 
electrode and a preparation method of the self-supported 
titanium nitride / 
graphene combined 
electrode. The preparation method comprises the steps that (1) 
titanium foil is soaked with acid liquid, ultrasonic 
processing is conducted on the 
titanium foil, the 
titanium foil is taken out, washed by deionized water, and soaked with a 
hydrogen peroxide solution, the temperature of the solution is increased to 60DEG C-95DEG C from the 
room temperature under the normal pressure through heating, the temperature is kept for 10-60 minutes, and the 
titanium foil is taken out and dried after an reaction ends; (2) the titanium foil is placed into a tubular 
atmosphere furnace, 
ammonia is fed into the tubular 
atmosphere furnace to conduct 
nitrogen treatment on the titanium foil, and 
titanium nitride is formed on the surface of the titanium foil; (3) a layer of 
graphene is formed on the surface of the 
titanium nitride in a deposition mode through a dipping-pull method or a 
drop casting method, and the graphene and the 
titanium nitride are placed into a 
drying oven at the temperature 
ranging from 60DEG C to 100DEG C to be dried, so that the self-supported titanium 
nitride / graphene combined 
electrode is obtained. Compared with the prior art, a graphene / titanium nitride three-dimensional network is directly formed on the surface of flexible 
metal foil so that the self-supported electrode can be formed. The combined electrode is low in cost, high in 
porosity ratio and good in catalytic activity and electrical 
conductivity, and has the broad application prospect.