The utility model belongs to the technical field of
ethylene glycol preparation, and particularly relates to an esterification purge gas treatment device in a process of preparing
ethylene glycol from synthesis gas, which comprises an MN
recovery tower, a gas mixer, a
tail gas heater, a
tail gas reactor, a cooler and a
tail gas absorption
tower,
tower top outlet gas of the MN
recovery tower and purge gas from PSA
desorption gas of a hydrogenation unit enter a gas mixer, are mixed in the gas mixer, then enter a tail
gas heater to be heated and then enter a tail gas reactor to react, an outlet of the tail gas reactor is connected with an inlet of a cooler, an outlet of the cooler is connected with a tail gas absorption tower, and an outlet of the tail gas absorption tower is connected with an outlet of the MN
recovery tower. The tail gas absorption tower is connected with a spray water inlet
pipe and a
waste gas discharge pipe; and the tail gas reactor is a fixed tubular reactor. According to the device,
nitrogen oxide which cannot be directly discharged in esterification purge gas can react to generate harmless gas such as
nitrogen and
nitrogen dioxide, environmental
pollution is avoided, the device can adapt to the shutdown working condition of an esterification
system, air does not need to be supplemented to the MN recovery tower, and the technological operation risk is reduced.