86 results about "Phosphate minerals" patented technology

Methods of increasing the rate of separating hydrophobic and hydrophilic particles by flotation have been developed. They are based on using appropriate reagents to enhance the hydrophobicity of the particles to be floated, so that they can be more readily collected by the air bubbles used in flotation. The hydrophobicity-enhancing reagents include low HLB surfactants, naturally occurring lipids, modified lipids, and hydrophobic polymers. These methods can greatly increase the rate of flotation for the particles that are usually difficult to float, such as ultrafine particles, coarse particles, middlings, and the particles that do not readily float in the water containing large amounts of ions derived from the particles. In addition, new collectors for the flotation of phosphate minerals are disclosed.

The invention relates to a phosphorite reverse flotation process which comprises the following steps: after carrying out ore crushing, ore grinding and size mixing on phosphorite, enabling the obtained product to enter the reverse flotation process, wherein ore pulp obtained after size mixing is added with sulfuric acid or phosphoric acid to form a regulator and an inhibitor and then is added with micromolecule organic acid to form a combined inhibitor for inhibiting phosphate minerals; carrying out reverse flotation to separate out carbonate minerals by using fatty acids or fatty acid soaps as a collecting agent so as to obtain high-grade low-magnesium phosphate concentrates. The phosphorite reverse flotation process has the following advantage that the micromolecule organic acid inhibitor is adopted to implement effective separation of collophanite and dolomite, so that the grade of the phosphate concentrates is improved, the grade of tailings is reduced and the recovery rate can be improved. Meanwhile, application of phosphoric acid and derivatives thereof to phosphorite reverse flotation is replaced, so that phosphorus resources are saved, service time of phosphate rock resources is prolonged and the defects in the prior art are overcome.

The invention relates to an anti-microbial and deodorizing coating additive and a preparation method thereof. The anti-microbial and deodorizing coating additive is composed of an inorganic oxide and a phosphate mineral carrier which wrapping the inorganic oxide, wherein a weight ratio of the inorganic oxide to the phosphate mineral carrier is 1:2. The anti-microbial and deodorizing coating additive can be used for preparing a coating in a manner of being mixed with resin, pigment filling materials and solvents. The coating can be coated on surfaces of metal, plastic, walls or woodwares and can form a uniform paint film coating through drying and curing. The coating can decompose various indoor harmful gas or harmful substances and can purify indoor air so that an anti-microbial and deodorizing effect is achieved. The resin, which has a gluing effect, can be selected from a water-based system or an oil-based system. The solvent can be selected according to whether the water-based system or the oil-based system is selected. The solvent can be selected from, in an individual manner or a blended manner, alcohols, esters, ketones, ethers, organic acids and the like. The coating additive is simple in the preparation method and is suitable for being large-range popularized and applied.

The invention relates to a silica-calcia low-grade collophanite positive and inverse floatation process, which comprises the steps: 1 silica-calcia low-grade collophanite ores are broken up and grinded to enable phosphate minerals and gangue mineral monomers to dissociate, then are added with water to mix size, enter positive and inverse floatation, get rid of impurities in ores, and improve grade of phosphorite. Compared with the prior art, the silica-calcia low-grade collophanite positive and inverse floatation process has the advantages that the content of only one kind of gangue minerals can be reduced by adopting direct floatation and single inverse floatation, can reduce the contents of silicate minerals, carbonate minerals and iron and aluminum silicate minerals, can obtain low magnesium low power half oxide low silicon phosphate concentrate by adopting the silica-calcia low-grade collophanite positive and inverse floatation process, successfully achieves mineral processing enrichment of collophane calcium collophanite, and can improve use rate of phosphorus resource. The silica-calcia low-grade collophanite positive and inverse floatation process overcomes the defects that an existing floatation process can not be applied for mineral processing of silica-calcia collophanite which is high in content of high power half oxides.

The subject invention concerns a composite comprising an organic fluid-swellable matrix, such as collagen, and mineral phase, such as calcium carbonate or phosphate mineral phase, for use as a biomimetic of bone. In another aspect, the subject invention concerns a process for making a composite involving the inclusion of acidic polymers to a supersaturated mineralizing solution, in order to induce an amorphous liquid-phase precursor to the inorganic mineral, which is then absorbed (pulled by capillary action) into the interstices of the organic matrix, and subsequently mineralizes via solidification and crystallization of the precursor phase. The present invention further concerns a method of treating a patient suffering from a bone defect by applying a biomimetic composite to the bone defect site.

The present invention relates to a phosphate mineral depressing agent, its application in back-flotation of phosphorus ore and its preparation method, in which the phosphate mineral depressing agent is a derivative of phosphoric acid, pyrophosphoric acid or tetraphosphoric acid. The back-flotation operation for removing carbonate mineral from raw ore containing phosphate mineral or intermediate product uses the derivative of phosphoric acid as depressing agent of phosphate mineral. The preparation method of the phosphoric acid derivative includes the following steps: in wet phosphoric acid, adding phosphorus pentoxide, its added quantity is 200-400% of wet phosphoric acid quantity, heating and stirring so as to obtain the invented phosphoric acid derivative.

The invention discloses a heavy metal polluted soil solidification and repairing composite compound and a solidification and repairing method. The composite compound comprises the following componentsin percentage by mass: 20-40% of quicklime and 60-80% of an iron-based biochar modified phosphate mineral, wherein the iron-based biochar modified phosphate mineral is obtained by uniformly mixing and drying an iron salt and biomass, further mixing the mixture with a phosphate mineral uniformly and performing co-pyrolysis. The method for solidifying and repairing heavy metal polluted oil by usingthe composite compound comprises the following steps: firstly, uniformly mixing the iron-based biochar modified phosphorate mineral with quicklime so as to obtain the heavy metal polluted soil solidification and repairing composite compound; applying the composite compound into heavy metal polluted soil, adding water, and performing uniform stirring; and performing maintenance of the best standards, so as to complete solidification repairing on the heavy metal polluted soil. By adopting the heavy metal polluted soil solidification and repairing composite compound, secondary dissolution of heavy metals can be greatly avoided, and the long-term stability of solidification of the heavy metal polluted soil can be greatly enhanced.

The invention relates to the technical field of beneficiation, in particular to an extremely low content magnetite beneficiation method and system for associated phosphate minerals. The method provided by the invention comprises the step of carrying out multi-stage sorting, namely finely grinding raw ore, carrying out dry separation on ore fines, carrying out superfine crushing by adopting a high-pressure grinding roller, then carrying out dry separation on middlings, and carrying out dry separation by adopting a V-shaped powder selecting machine and a dynamic powder selecting machine, so thatiron core concentrate and tailings are separated, the next wet type grinding and separation treatment capacity is reduced, grinding and separation energy consumption is reduced, water resource is saved, wetting tailing amount is reduced, and beneficiation cost is effectively reduced.

The invention discloses a method for producing a high-quality active ecological organic raw material from livestock and poultry manure. First, a Chinese herbal medicine is added to livestock and poultry feedstuffs; the feedstuffs with the Chinese herbal medicine are digested and absorbed by livestock and poultries, and an additive composed of an azotobacteria flora, potassium mineral powder and phosphate mineral powder is added to the obtained livestock and poultry manure; the mixture is well mixed by stirring, and is placed in a plastic basket; the plastic basket is sealed by using a plasticfilm, and anaerobic fermentation is carried out; the manure is stored for 25-45 days, odor and harmful gas in the manure are removed, roundworm eggs and pathogen are killed, crude protein in the livestock and poultry manure are decomposed into amino acid, and part of crude fiber and starch is decomposed into monosaccharide, such that the active ecological livestock-and-poultry-manure organic raw material used for producing a high-quality high-efficiency organic fertilizer is obtained.

A method is provided for making inexpensive synthetic inorganic resins that are stable, mix easily with water and may be conveniently diluted to form an easy-to-use paste for commercial applications. The method uses environmentally friendly techniques to provide improved efficiencies in the commercial production of these resins. The resins are produced by the partial reaction of phosphoric acid with sparsely-soluble oxides, or sparsely-soluble oxide minerals, that are added to the phosphoric acid under controlled conditions. In certain specific embodiments, methods are provided for modifying synthetic inorganic resins so as to produce rapid-setting phosphate cements and ceramics having high flexural strength. Unique synthetic inorganic resin formulations are also disclosed. These formulations are phosphate-mineral based, non-volatile, tend to be non-flammable, do not contain any hazardous inorganic or organic compounds, and are chemically stable at relatively high temperatures, yet they are less expensive than most commercially available organic synthetic polymeric resins.

The invention discloses a manganese-magnesium low-grade phosphate flotation process. The process comprises the steps that firstly, manganese-magnesium low-grade phosphate ores are crushed and ground to enable manganese-magnesium minerals, phosphate minerals and other minerals to be subjected to monomer separation; secondly, a pH modifier is added into ore pulp to enable the pH value of the ore pulp to be greater than or equal to 11.6; and thirdly, an inhibitor and an obverse floatation collecting agent are added, and floatation is carried out after stirring and pulp conditioning. The adopted floatation process is a technological process including the rough concentration step, the concentration step and the scavenging step. Obtained ingroove products are flotation tailings. Obtained foam products are finished phosphate concentrate products with low MnO2 content, low MgO content and low SiO2 content, and the finished phosphate concentrate products are obtained finally through concentration, filtration and drying. According to the process, floatation is carried out directly under the alkali condition, dextrin and NO-2 are used in cooperation to reduce the content of silicate minerals, carbonate minerals and manganese minerals so as to obtain low-magnesium, low-manganese and low-silicon phosphate concentrates, so that mineral processing and enrichment of magnesium low-grade phosphate ores are realized successfully, and the utilization rate of phosphorus resources is increased.

The invention relates to a high-fertility and low-alkaline cementing material for vegetation concrete and a preparation method thereof. The high-fertility and low-alkaline cementing material for vegetation concrete comprises phosphate minerals, re-fired magnesia, borax, limestone powder, active aluminum powder, silicate clinker and expanded perlite. Through the synergistic action of the components, the cost of the cementing material is greatly reduced while an excellent growth space is provided for plant roots, and the resource utilization of industrial waste is facilitated.

A process for the recovery of lithium from minerals rich in lithium and phosphate, the process comprising passing an ore containing one or more minerals rich in lithium and phosphate to an acid leach step thereby producing a pregnant leach solution, subjecting the pregnant leach solution to a series of process steps by which one or more impurity elements are removed, and recovering lithium as a lithium containing salt product, wherein the series of process steps by which one or more impurity elements are removed includes a low pH impurity removal step conducted at an elevated temperature for the precipitation of one or more impurities.

The invention discloses a beneficiation method for producing low-phosphorous molybdenum concentrate by utilizing ultrasonic waves. The beneficiation method comprises the following steps: (1) carrying out ultrasonic treatment: carrying out ultrasonic dispersing and cleaning on medium-grade and high-grade high-phosphorous molybdenum concentrate obtained by flotation for 3-20 minutes at ultrasonic frequency of 28-80KHz and ultrasonic strength of 200-400W, simultaneously adding a phosphate mineral inhibitor with amount of 1500-7000g/t to carry out dispersion inhibition on phosphor-containing minerals; (2) carrying out primary flotation; (3) carrying out flotation scavenging; and (4) carrying out flotation concentration. According to the beneficiation method, by utilizing ultrasonic means and adding the efficient phosphor inhibitor, phosphor content in a molybdenum concentrate product generated by flotation is reduced to be below the standard, so that qualified low-phosphorous molybdenum concentrate is obtained. According to the method, a chemical phosphorus removal process of a beneficiation plant is cancelled, production cost and generation of waste liquor are reduced, and economic benefits and environmental benefits are remarkable.

The invention relates to a calcium-magnesium collophane ore reverse flotation collector and a preparation method thereof. The calcium-magnesium collophane ore reverse flotation collector is prepared and obtained in the modes that saturated fatty acid serves as a reaction raw material, chlorosulfonic acid is selected as a sulfonating agent to conduct sulfonating reaction, and then a sulfonating product is subjected to bleaching and neutralization reaction. The calcium-magnesium collophane ore reverse flotation collector and the preparation method thereof have the following beneficial effects that (1) according to the collector, a sulfonic group with the extremely strong polarity is selected to serve as a polar group of the collector, so that separation performance of the collector over phosphate minerals and carbonate minerals is improved; the saturated fatty acid is selected as a non-polar group of the collector, so that collecting performance of the collector over carbonate minerals is improved; and the product raw material source is widespread, the price is low, and certain cost price superiority and wide industrialization superiority are achieved; and (2) the preparation process of the calcium-magnesium collophane ore reverse flotation collector is simple, easy to operate and low in production cost, industrialized production is easy to realize, meanwhile, no three-waste discharge exists in production, and environment friendliness and non-pollution are achieved.

The invention discloses a non-sulfide mineral flotation collector and application of the non-sulfide mineral flotation collector, and belongs to the technical field of mineral flotation collectors. The non-sulfide mineral flotation collector is prepared from carboxyl phenylphosphonic acid and salt thereof and has the advantages of being good in water solubility in normal temperature, easy to disperse, high in collection capability, good in selectivity and the like, and is mainly used for flotation and separation of valuable mineral in ilmenite, scheelite, wolframite, rutile, cassiterite, fluorite, rare earth ore, bauxite, manganese carbonate ore or phosphate minerals. The collector is low in cost, safe, environmentally friendly, high in flotation recycling rate and suitable for large-scaleindustrial application.

The present invention relates to a method for pre-processing experimental samples of the core flow in oxygen-sensitive oil and gas reservoirs. For the unconventional oil and gas resources formed in the reducing environment, the oxygen-poor environmental deposition products such as organic matters, pyrite, phosphate minerals, and the like are considered, and the concept of oxygen-sensitive oil andgas reservoirs is innovatively proposed; and in the process of oil and gas exploitation, some of the well fluids have certain oxidizing properties, and the influence of oxidizing substances in the well working fluid are not considered. According to the method for pre-processing samples provided by the present invention, the damage of the samples from the oxidizing substances and the influence of the oxidizing substances on the experimental data during the experiment can be avoided, and the accuracy of the experimental result can be ensured.