88 results about "Iron carbonate" patented technology

The invention relates to a new technology for sorting a lean red magnetite ore containing iron carbonate, which is characterized by comprising the following steps of: enriching and discarding tailings by adopting a 'technology for stage grinding and strong magnetic discarding tailings', thereby obtaining a mixed magnetic concentrate; sorting the mixed magnetic concentrate by adopting an 'open-circuit reverse flotation technology with one-stage roughing, one-stage fining and two-stage scavenging', thereby obtaining a high-grade hematite and magnetite concentrate; adopting a 'close-circuit centrifuge technology with one-stage roughing and one-stage fining' for sorting a high iron carbonate ore enriched in mine obtained by adopting the 'open-circuit reverse flotation technology', thereby obtaining a siderite concentrate; feeding the centrifuge tailings into a weak magnetic machine and sorting; and recycling fine fraction magnetic concentrates. The new technology provided by the inventionhas the advantages that the lean hematite and magnetite ore containing iron carbonate is sorted by adopting a 'combined sorting process flow with stage grinding, strong magnetic discarding tailings, reverse flotation-centrifuge', so that the sorting indexes of the whole iron grade of the obtained comprehensive concentrate being more than 65% and the metal recovery rate being more than 65% are achieved and the maximization of utilization benefit of iron ore resources is realized.

Methods for improving surface roughness of an environmental barrier coating including providing a component having a plasma sprayed environmental barrier coating; applying a slurry to the environmental barrier coating of the component, the slurry being a transition layer slurry or an outer layer slurry; drying the environmental barrier coating having the applied slurry; and sintering the component to produce a component having an improved surface roughness where the slurry includes a solvent; a primary transition material, or a primary outer material; and a slurry sintering aid selected from iron oxide, gallium oxide, aluminum oxide, nickel oxide, titanium oxide, boron oxide, alkaline earth oxides, carbonyl iron, iron metal, aluminum metal, boron, nickel metal, iron hydroxide, gallium hydroxide, aluminum hydroxide, nickel hydroxide, titanium hydroxide, alkaline earth hydroxides, iron carbonate, gallium carbonate, aluminum carbonate, nickel carbonate, boron carbonate, alkaline earth carbonates, iron oxalate, gallium oxalate, aluminum oxalate, nickel oxalate, titanium oxalate, solvent soluble iron salts, solvent soluble gallium salts, solvent soluble aluminum salts, solvent soluble nickel salts, solvent titanium salts, solvent soluble boron salts, and solvent soluble alkaline earth salts.

The invention discloses a Fe2O3 micro-nano porous sphere, a preparation method thereof and uses thereof. The porous sphere is formed by Fe2O3 nanoparticles having a nanometer mesoporous alpha-Fe2O3 phase structure therebetween, wherein the diameter of the sphere is 500-5000nm, the specific surface area of the sphere is 15-25m<2>/g, particle sizes of the particles are 20-60nm, and pore diameters of mesopores are 2-50nm. The method comprises the following steps: mixing ferric chloride hexahydrate, ascorbic acid, urea and water, and uniformly stirring them to obtain a mixed liquid; reacting the mixed liquid under conditions that the temperature is 140-180DEG C and the pressure is a self-generated pressure for at least 4h to obtain an intermediate product; separating, washing and drying the intermediate product to obtain porous iron carbonate; and annealing the porous iron carbonate at 450-550DEG C for at least 4h, and naturally cooling the porous iron carbonate to room temperature to prepare the Fe2O3 micro-nano porous sphere. The Fe2O3 micro-nano porous sphere can be placed in water polluted by organic dyes to photocatalytically degrade under visible light, or in water polluted by potassium dichromate to adsorb.

The invention relates to a technique for processing high-iron-carbonate mixed ore. The technique for processing the high-iron-carbonate mixed ore is characterized in that the stage grinding technique and the weak magnetic-strong magnetic-centrifugal machine technique are adopted, and separate grinding and separate screening are carried out on the high-iron-carbonate mixed ore. The technique for processing the high-iron-carbonate mixed ore has the advantages that the weak magnetic technique, the strong magnetic technique and the centrifugal machine technique are allocated flexibly and reasonably according to specific screening indexes of work to recover iron carbonate and hematite in raw ore, environmental pollution is light, the technological process is simple, and qualified iron ore concentrate which has the iron grade of more than 65% after sintering and is capable of meeting smelting requirements can be obtained.

The invention relates to a dispersed flotation separation method for carbonate-containing iron ore. The reverse flotation is directly carried out on carbonate-containing mixed magnetic separation iron ore concentrate, i.e. the rough concentration, the scavenging and the selection separation. Particularly, a roughing separation method comprises the following steps of: adjusting the mixed magnetic separation iron ore concentrate into ore pulp with the weight concentration of 20-40%, adding 200-1000g/t of dispersing agent-salinized water glass, adding 1200-2400g/t of inhibitor-starch, adding 400-1000g/t of activating agent-lime, and adding 600-1400g/t of collecting agent-KS-III. As the dispersing agent is added, the covering phenomenon among minerals can be eliminated or weakened, so that the ore pulp is under the stable dispersing status, the influence of the iron carbonate to the flotation can be weakened or reduced, and the iron ore concentrate of which the Fe grade is larger than 66% and the recovery rate is 65%-75% can be finally obtained. The method is simple in technological process and lower in cost.

This invention relates to a kind of anode material and method used for reducing preparation of lithium iron phosphate by vacuum carbon. It uses cheap phosphate, iron compound and lithium compound as raw material, compound of cheap heavy metal as adulteration modifying agent, cheap and abundant activated carbon, acetylene black and graphite as reducing agent. Dealing with it using ball milling techniques and makes solid-phase chemical reaction under the vacuum condition, then get the anode material adulterating lithium iron phosphate which contains carbon. Lithium iron phosphate compounded in this invention has a stable performance, physical chemistry of products has a good homogeneity and consistency and a high productivity; lithium iron phosphate produced in this invention has a high tap density and electric specific votume, good discharging capability of high-current, stable electrochemistry circulation capability, and low local action, besides, it is easy to control content of tantalum adulterated. The tap density of lithium iron phosphate produced by this method is 1.63-2.04g/cu cm, the highest discharging specific votume is 161.3mAh/g.

The invention belongs to the technical field of lean hematite processing, in particular to a lean hematite processing technology which comprises the steps of stage grinding, coarse-fine separation, coarse fraction gravity separation, fine-fraction magnetic separation and centrifuge beneficiation. The lean hematite processing technology disclosed by the invention adopts centrifuge beneficiation to replace reverse flotation beneficiation in the original technology, so that the whole production technological flow is optimized and becomes shorter, and the loss of fine fraction high-grade hematite particles in tailings is reduced; besides, the technological course is more adaptive to properties of the hematite, so that the influence of over-high content of iron carbonate over reverse flotation in the original technological course is effectively solved; and furthermore, due to the adoption of centrifuge beneficiation, reagents does not need to be used and hematite pulp does not need to be heated, so that expenses of reagents and coal are effectively saved and the hematite processing cost is reduced.

The invention discloses a heat-insulation fireproof coating applied to a pre-buried pipe of a vacuum cast aluminium alloy casting. The heat-insulation fireproof coating is prepared from the following components in parts by weight: 20-30 parts of sepiolite powder, 4-6 parts of cationic starch, 4-6 parts of expanded graphite, 1.5-3 parts of chloroplatinic acid, 1-3 parts of industrial alkali, 4-6 parts of modified clay, 4-6 parts of aluminium oxide, 4-6 parts of silicon carbide, 4-6 parts of sodium carboxymethylcellulose, 30-50 parts of deionized water, 1-3 parts of mullite, 1-3 parts of shell, 4-6 parts of sea mud, 1-3 parts of potassium titanate whiskers, 1-3 parts of silicon nitride, 1-3 parts of boron nitride, 1-3 parts of iron carbonate, 1-3 parts of titanium dioxide whiskers, 1-3 parts of magnesium carbonate, 1-3 parts of zinc oxide, 4-6 parts of calcined kaolin, 1-3 parts of white alum and 4-6 parts of kyanite powder. By improving the preparation of the conventional fireproof mud, a pre-buried copper pipe or stainless steel pipe is coated with a layer of fireproof coating with specific thickness; and the effects of insulating heat, preventing softening and preventing a liquid aluminum accommodation copper pipe from entering a pipeline can be implemented.

The invention relates to a method for recycling magnetic tailings by adopting preselection-calcination-magnetic levitation processes. The method comprises the following steps of supplying a first period of weak magnetism to the magnetic tailings of which the iron grade is 9 to 13% and the content of iron carbonate is more than 3%, supplying a first period of strong magnetism to the magnetic tail,performing spiral chute reselecting operation of one coarseness and one fineness on one strong concentrate, merging fine spiral tailings and coarse spiral tailings and one strong tailing into primarytailings, and merging fine spiral concentrate and first magnetic concentrate into primary concentrate; condensing, filtering and roasting the primary concentrate so as to obtain roasted ore; performing closed circuit grinding on the roasted ore, supplying a second period of weak magnetism to overflow products of which the -0.046mm content is 83% to 90%, performing reverse flotation of one coarseness and one fineness and three sweep on second magnetic concentrate, wherein the reverse flotation concentrate is final concentrate of which the grade is more than 65%, and merging the tailings of a centrifugal machine and second magnetic tailings and the primary tailings into final tailings of which the grade is 7% to 10%. The method has the advantages that (1) preselection is performed without grinding; (2) magnetic separation is combined with reverse flotation, the regrinding particle size is coarse, and the yield is increased.

Methods for improving surface roughness of an environmental barrier coating involving providing a component having a plasma sprayed environmental barrier coating; applying a slurry to the environmental barrier coating of the component, the slurry being a transition layer slurry or an outer layer slurry; drying the environmental barrier coating having the applied slurry; and sintering the component to produce a component having an improved surface roughness wherein the slurry includes water; a primary transition material, or a primary outer material; and a slurry sintering aid selected from iron oxide, gallium oxide, aluminum oxide, nickel oxide, titanium oxide, boron oxide, alkaline earth oxides, carbonyl iron, iron metal, aluminum metal, boron, nickel metal, iron hydroxide, gallium hydroxide, aluminum hydroxide, nickel hydroxide, titanium hydroxide, alkaline earth hydroxides, iron carbonate, gallium carbonate, aluminum carbonate, nickel carbonate, boron carbonate, alkaline earth carbonates, iron oxalate, gallium oxalate, aluminum oxalate, nickel oxalate, titanium oxalate, water soluble iron salts, water soluble gallium salts, water soluble aluminum salts, water soluble nickel salts, water titanium salts, water soluble boron salts, and water soluble alkaline earth salts.

The present invention relates to the simple production process of zinc citrate, zinc lactate, ferrous citrate and ferrous lactate oral liquid, and features that the zinc citrate, zinc lactate, ferrous citrate and ferrous lactate oral liquid is produced through the direct chemical reaction between organic acid and zinc carbonate or ferric carbonate while adding protect CO2 gas to prevent ferrous ion from being oxidized. The present invention can produce cheap zinc replenishing and iron replenishing oral liquid easy to be absorbed by human body and with high stability, high purity and no side effect.

The invention discloses a completion fluid pH value buffer agent which is a mixed liquid of a first buffer liquid system and a second buffer liquid system, wherein the pH value of the mixed liquid is9.85-10.45; the first buffer liquid system is a mixed solution of an ammonium chloride solution and ammonia water; the pH value of the first buffer liquid system is 9.15-10.35; the second buffer liquid system is a mixed solution of sodium carbonate and sodium bicarbonate; the pH value of the second buffer liquid system is 9.0-10.5. The completion fluid pH value buffer agent is high in efficiency in removing hydrogen sulfide and the like and inhibiting iron scale and is capable of effectively preventing sleeve damage and cracks caused by hydrogen brittleness and hydrogen induced brittleness; inaddition, due to addition of the completion fluid pH value buffer agent, a completion fluid is constantly maintained under an alkali condition, corrosion products, namely ferric hydroxide and iron carbonate, have very low solubility, a metallic surface is solidly covered by a small amount of generated ferric hydroxide and iron carbonate, further corrosion of a metal can be prevented, and a stablecompletion fluid system can be maintained.

Some embodiments of the invention include cementitious iron carbonate binder precursor compositions that includes powdered iron or steel, a first powdered additive including silica, a second powdered additive including calcium carbonate, at least one powdered clay, and a fibrous and/or woven additive. In some embodiments of the invention, the precursor composition includes an alumina additive. In some further embodiments, the powdered clay includes kaolinite clay and/or metakaolin clay. In some further embodiments, the precursor composition includes an organic reducing agent such as oxalic acid. Some embodiments include up to about 60% by weight of powdered iron or steel, up to about 20% by weight of the first powdered additive, up to about 8% by weight of the second powdered additive, up to about 10% by weight of at least one powdered clay, and up to about 2% by weight of an organic acid.

A novel non-toxic IR tracer composition is provided herein which, when incorporated into an IR tracer projectile which is then fired, generates a dim visibility IR trace. Such IR tracer composition is a non-toxic, metallic-boron-containing, IR tracer composition comprising: from about 20 to about 30% by weight, or from about 45 to about 60% by weight, of at least one of potassium chlorate or sodium nitrate; from about 5 to about 16% by weight of a metallic fuel which consists of metallic boron; optionally, from about 15 to about 25% by weight, or from about 40 to about 50% by weight, of a non-metallic fuel which consists of sodium salicylate; from about 5 to about 20% by weight of a retardant which consists either of iron carbonate, or magnesium carbonate or calcium carbonate; from about 5 to about 15% by weight of a first binder which consists of calcium resinate; and up to about 7.5% by weight of a second synthetic resin binder which consists either of a copolymer of hexafluoropropylene and vinylidene fluoride or cellulose acetate butyrate, wherein the total percentage of such ingredients add up to 100%. A novel IR tracer projectile containing such IR tracer composition for generating a dim visibility IR trace is also provided.

The invention discloses a CO2 gasification method of waste textile fabrics. The method mainly comprises that with the waste textile fabrics as a gasification object, CO2 as a gasification gas, and iron carbonate, calcium carbonate, potassium carbonate, sodium carbonate or a mixture thereof as a catalyst, and at a certain temperature, a reaction is carried out to generate synthetic gases CO and H2. The splitting decomposition temperature of the waste textile fabrics is 300-400 DEG C, the gasification temperature is 800-1000 DEG C, the reaction conditions are easy to obtain, and the reaction temperature can be further reduced by adding the catalyst; and emissions of the waste textile fabrics and greenhouse gases can be effectively reduced, and a climate deterioration process is alleviated.

The invention relates to a flocculation desliming and acidic flotation method for iron carbonate ore fine-grained products. The flocculation desliming and acidic flotation method includes feeding selected materials of ground crude ores into a primary fineness classification cyclone to be subjected to classification operation, and is characterized in that settle sand of the primary fineness classification cyclone is graded in a gravity concentration procedure, split flow of the primary fineness classification cyclone is fed into a secondary fineness classification cyclone to be subjected to grading operation, settled sand of the secondary fineness classification cyclone is subjected to acidic direct flotation operation, spilt flow of the secondary fineness classification cyclone is fed into a titling narrow flowing classifier to be subjected to desliming classification operation, coarse-grained products, which have the desliming classification larger than 19 micrometers, of the tilting narrow flowing classifier and rough concentrates A which are obtained by means of acidic direct flotation are combined with one another and then are subjected to acidic reverse flotation grading operation, and concentrates and tailings which are obtained by means of acidic reverse flotation are graded by means of a rougher acidic reverse flotation process, a cleaner acidic reverse flotation process and two scavenging acidic reverse flotation processes. Owing to the processes, the flocculation desliming and acidic flotation method has the advantage that ore dressing technical indexes of the iron carbonate ore ground fine-grained products are greatly improved.

The invention relates to a method for preparing hematite powder pellets. The method comprises the steps of proportioning, mixing, pelletizing and roasting, and is characterized in that: iron carbonate ore powder in weight ratio of 5-15 percent, which is subjected to damp-mill pretreatment, is added during proportioning of hematite powder and bentonite. The method comprises the following specific steps of: I, performing damp-mill pretreatment on the iron carbonate ore powder: filtering the iron carbonate ore powder with water content of not more than 8.5 percent or drying in a rotary drum dryer to keep the water content of the iron carbonate ore powder not more than 6.5 percent, and feeding the iron carbonate ore powder into a damp mill to perform the damp-mill pretreatment; II, proportioning: proportioning the iron carbonate ore powder, the hematite powder and the bentonite in the following percentage by weight: 5-15 percent of iron carbonate ore powder, 83.5-93 percent of hematite powder and 0.5-2 percent of bentonite; III, pelletizing: uniformly mixing the components, adding the components into a pan pelletizer and replenishing water for pelletizing to produce pellets; and IV, roasting: distributing and roasting on a chain grate machine-rotary kiln to obtain finished product pellets. The hematite powder pellets prepared by using the method disclosed by the invention has the advantages of low preheating combustion temperature and high strength.

The invention discloses a method for preparing red iron oxide with sludge produced in neodymium-iron-boron waste recovery. According to the invention, a raw material which is a sludge waste produced during a neodymium-iron-boron waste recovery process is subjected to acid dissolution, oxidation, precipitation, filtration and firing, such that red iron oxide is obtained. According to the invention, the sludge is soaked for 1-4h with 10-35% hydrochloric acid under stirring and under a temperature of 40-80 DEG C, wherein a final pH value is controlled at 1-7; divalent iron is oxidized into trivalent iron with potassium chlorate, wherein a dose of potassium chlorate is 1-10% of the weight of dry sludge; the temperature is quickly increased to 50-100 DEG C by heating; ammonium bicarbonate is used for precipitation, wherein the addition amount of ammonium bicarbonate satisfies that the pH value of the solution reaches 7-14; and iron carbonate is fired in a firing kiln with a temperature of 200-800 DEG C. with the method provided by the invention, valuable elements can be completely recycled, mineral resources can be saved, ecological environment can be protected, and more importantly red iron oxide with extremely high purity can be recovered from waste sludge.

The invention relates to a separation technology for hematite containing iron carbonate. The separation technology comprises the step that iron ores with the hematite distribution rate being higher than 40% are fed into first-stage closed circuit grinding operation. The separation technology is characterized by further comprises the steps of first-stage weak-magnetic and strong-magnetic operation,thickness grading operation, gravity separation operation, secondary-grading grinding operation, second-stage weak-magnetic and strong-magnetic operation and reverse flotation operation, wherein primary-grading overflow products and middling regrinding products are treated through first-stage weak-magnetic and strong-magnetic operation, first-stage weak-magnetic and strong-magnetic mixed concentrates are treated through thickness grading operation, coarse grain products subjected to thickness grading operation are treated through gravity separation operation, gravity separation operation tailings are treated through secondary-grading grinding operation, fine grain products subjected to thickness grading operation are treated through second-stage weak-magnetic and strong-magnetic operation, second-stage weak-magnetic and strong-magnetic mixed concentrates are treated through reverse flotation operation, and reverse flotation operation middlings are treated through table separation operation. The separation technology has the advantages that first-stage strong magnetic tailing discarding after rough grinding is enhanced, the middling circulation volume is decreased, the technological process is simplified, and the production cost is saved.

The invention discloses a process for sorting iron-carbonate-containing low-grade iron ore concentrate. The process is characterized in that the iron-carbonate-containing low-grade iron ore concentrate is fed into a centrifugal machine for two sections of sorting work including roughing and scavenging and a section of grinding and grading work, so that grade of the iron ore concentrate is effectively increased and can reach above 67%, and the iron-carbonate-containing iron ore concentrate after sorting completely meets requirements of ironmaking production; the process adopting the centrifugal machine is free of environmental pollution and simple and easy to operate. The process has the advantages that the iron-carbonate-containing low-grade iron ore concentrate is fed into the centrifugal machine for the two sections of sorting work including roughing and scavenging and a section of grinding and grading work, so that the grade of the iron ore concentrate is effectively increased and can reach above 67%, a sorting index that metal recovery rate is 70% is realized, the iron-carbonate-containing iron ore concentrate after sorting completely meets the requirements of ironmaking production; the process adopting the centrifugal machine is free of environmental pollution and simple and easy to operate.

Some embodiments of the invention include a method of producing iron carbonate binder compositions including providing a plurality of binder precursors including a powdered iron or steel, a first powdered additive comprising silica, a second powdered additive including calcium carbonate, and a powdered clay. The method includes mixing the plurality of binder precursors and a water additive to form an uncured product, and feeding at least a portion of the uncured product into a curing chamber. The curing chamber is fluidly coupled to a CO₂ source so that some CO₂ from the CO₂ source reacts with the uncured product to form a cured iron carbonate containing product and at least one reaction byproduct, where at least some byproduct can be fed from the curing chamber to the CO₂ source for use as a fuel by the CO₂ source.