The invention relates to an efficient environment-friendly concrete preservative, which comprises the following components in portion by weight: 10 to 18 portions of various benzoic acids and boric acids, 20 to 40 portions of silica fume, 20 to 35 portions of alkalis; 35 to 50 portions of ethanolamine, and 15 to 20 portions of active components. The preservative can be widely applied to various building materials, especially to concrete and cement, and is reliable in rust prevention and corrosion resistance and good in environmental indexes. The preservative has the advantages of containing no mineral oil, containing no nitrite, chromate and the like harmful to human body, adapting to compressive strength (50 MPa in general) of actual requirements, improving strength, durability and heat resistance and meeting the requirements for high-performance concrete, along with no toxicity, no stimulation, no pollution, good construction performance, high dimensional stability, less shrinkage and no cracking in the hardening process.