408 results about "Methanol water" patented technology

The invention provides a PVDF (Polyvinylidene Fluoride) nanofiltration membrane constructed on the basis of microwave-enhanced bridging interfacial polymerization as well as a preparation method and application of the PVDF nanofiltration membrane. The method comprises the following steps: reacting PVDF powder with an organic alkali to prepare a modified film-forming solution, blade-coating the modified film-forming solution on a non-woven fabric supporting layer, placing the non-woven fabric supporting layer in an ethanol-water or methanol-water coagulating bath, and preparing a PVDF supporting film by virtue of assistance of an ice template; weighing the functionalized nano material and an amino silane coupling agent, performing ultrasonic dispersion, and adding a catalyst for reaction to obtain dispersion liquid; immersing a PVDF support membrane into the dispersion liquid to obtain a modified membrane; immersing the modified membrane into an aqueous solution containing an amine monomer and an organic solution containing an acyl chloride monomer, and carrying out microwave radiation. The interface reaction rate and selectivity are enhanced through the microwave excitation effect, and meanwhile, the hydrophilicity and reaction activity of the PVDF base membrane are cooperatively regulated and controlled, so that the separation efficiency and the anti-pollution capacity of the membrane are remarkably improved. The obtained PVDF nanofiltration membrane has high flux, high selectivity and excellent structural stability, and is suitable for efficient purification and resource recovery application in a complex water system.

The present application relates to hydrogen production technology field, especially to a kind of methanol hydrogen production method, comprising the following steps: S10: methanol water is heated and vaporized to obtain methanol water vapor;S20: methanol reforming reaction obtains hydrogen mixture gas;S30: after cooling treatment to hydrogen mixture gas, through water washing tower absorption unreacted methanol water, then, adjust the relative humidity and temperature of hydrogen mixture gas;S40: hydrogen mixture gas is input into carbon dioxide absorption tower to remove carbon dioxide;S50: after removing carbon dioxide, product hydrogen is obtained and input hydrogen tank storage to supply user end.The above-mentioned methanol hydrogen production method, by methanol water vapor reforming hydrogen treatment, obtains hydrogen mixture gas.Again, hydrogen mixture gas is purified to obtain product hydrogen with very low carbon monoxide content, with raw material easy to transport, the hydrogen purity of output is high, equipment construction cost is low, and energy consumption is low and the like advantages, reach the purpose of expanding hydrogen application range.

The invention relates to a detection method for determining isotope abundance of a 15N or 18O labeled nitrate sample by using an organic mass spectrum. The detection method comprises the following steps: (1) dissolving the 15N or 18O labeled nitrate sample in a methanol aqueous solution; (2) taking the supernatant, filtering with a filter membrane, and diluting with a methanol aqueous solution to obtain a solution to be detected; and (3) detecting the solution to be detected by using a high-resolution liquid chromatograph-mass spectrometer, selecting a mass spectrum in a peak appearance time window, recording relative mass spectrum signal intensities with mass-to-charge ratios of 61.988 and 62.985, and calculating to obtain the 15N isotope abundance. Or recording the relative mass spectrum signal intensities with the mass-to-charge ratios of 61.988, 63.993, 65.997 and 68.001, and calculating to obtain the abundance of the < 18 > O isotope. Compared with the prior art, the method has the advantages that the sample pretreatment time is greatly shortened, the economic cost is low, and the test result is accurate.

The invention relates to a methanol internal combustion engine high-temperature fuel cell hybrid power system based on double-path waste heat gradient utilization. The invention relates to the technical field of internal combustion engine waste heat recovery and new energy power system integration. The system comprises a fuel tank, a first pump body, a heat exchanger, a methanol internal combustion engine, a turbine, a gas compressor, an air compressor, a reformer, a high-temperature proton exchange membrane fuel cell, an evaporator and a second pump body. A methanol-water vapor mixture generated by heat exchange of a mixed solution of methanol and water and a high-temperature fuel cell stack coolant in a heat exchanger is introduced into a reforming reactor and is subjected to catalytic reforming to produce hydrogen by utilizing waste heat of high-temperature tail gas of an engine, and the produced hydrogen is directly supplied to an anode of a high-temperature fuel cell. Through a double-path methanol distribution strategy, collaborative design of internal combustion engine waste heat recovery, electric pile heat management and reforming hydrogen production is realized, and the comprehensive energy efficiency of the system is improved.

The invention discloses a combined phenol-primary polyamidoamine phenol-amine resin nonionic demulsifier and a preparation method thereof.The preparation method comprises the steps that phenol M and primary polyamidoamine are mixed, a formaldehyde solution is dropwise added, a reaction product is diluted with methyl alcohol, and phenol M-primary polyamidoamine resin slurry is obtained; the preparation method comprises the following steps: mixing organic phenol N and formaldehyde, reacting under the catalysis of sodium hydroxide, and diluting a product with methanol to obtain phenol N phenolic resin slurry; dropwise adding the phenol N phenolic resin slurry into the phenol M-primary polyamidoamine resin slurry, reacting, refluxing to remove methanol and water to obtain combined phenol-primary polyamidoamine resin, and polymerizing the combined phenol (M-N)-primary polyamidoamine resin with epoxypropane and ethylene oxide in sequence under the catalysis of alkali metal hydroxide to generate R-PO-EO diblock demulsifier polyether. And cross-linking with a cross-linking agent to obtain the finished demulsifier. The demulsifier prepared by the invention has the characteristics of high dehydration speed and high final dehydration rate for thick oil emulsion in the Bohai Sea region, and especially can effectively reduce an emulsion layer of output crude oil for thick oil output liquid in a high-water-content exploitation period.

The invention relates to the technical field of hydrogen production catalysts, in particular to a preparation method of a supported methanol steam reforming hydrogen production catalyst. Comprising the following steps: S1, dissolving copper salt, adding indium oxide, heating in a water bath to evaporate water, drying, and carbonizing to obtain a Cu / In2O3 catalyst; s2, adding the Cu / In2O3 catalyst and tris (hydroxymethyl) aminomethane into water, then adding dopamine hydrochloride for reaction, and performing centrifugal washing and drying to obtain a precipitate; and S3, grinding and carbonizing the precipitate to obtain the nitrogen-doped carbon modified Cu / In2O3 catalyst. After the surface of the Cu / In2O3 catalyst is modified by carbon, strong electron interaction exists between carbon and metal copper, metal Cu electrons are promoted to be transferred to nitrogen-doped carbon, and the formed Cu < + > species enhance the catalytic activity for catalyzing methanol steam reforming hydrogen production and the selectivity for hydrogen.

The invention is suitable for the technical field of fuel cells, and provides a methanol reforming fuel cell rapid cold start system and a control method, the system comprises: a methanol reforming hydrogen production reactor, the methanol reforming hydrogen production reactor comprises a combustion chamber, a reforming chamber and a heat exchanger, and the combustion chamber is provided with an electrical bar; the high-temperature proton exchange membrane fuel cell is connected with the methanol reforming hydrogen production reactor, and an electric heating sheet is arranged on the high-temperature proton exchange membrane fuel cell; the air pump is connected with the reforming chamber and is used for introducing air to promote the reduction-state catalyst in the reforming chamber to perform oxidation exothermic reaction; a methanol water storage tank; and the control module is used for regulating and controlling the quantity of fuel entering the methanol reforming hydrogen production reactor module, air entering the methanol reforming hydrogen production reactor module and the high-temperature proton exchange membrane fuel cell module and controlling the starting of the electric heating bar and the electric heating sheet. According to the invention, the starting time of the methanol reforming fuel cell system within hectowatt level can be shortened to be within 10min, so that the system can quickly enter a power generation state.

The invention belongs to the technical field of fuel cells, and particularly relates to a high-temperature methanol reforming fuel cell system for realizing carbon cycle and an operation process. The system comprises an electric pile, a methanol steam reforming hydrogen production reactor, a carbon dioxide hydrogenation methanol production reactor and an electrolyzed water module, hydrogen prepared by the methanol steam reforming hydrogen production reactor enters an anode of the galvanic pile through a pipeline, a cathode of the galvanic pile is supplied by an air pump, and the hydrogen and oxygen are subjected to electrochemical reaction in the galvanic pile to realize external power supply; liquid water recovered from the electric pile tail gas is introduced into the water electrolysis module, and water electrolysis is performed to generate hydrogen; carbon dioxide in the stack tail gas and hydrogen generated by the water electrolysis module enter the carbon dioxide hydrogenation methanol preparation reactor through the gas inlet pipeline to prepare methanol. According to the invention, the circulation of carbon in the high-temperature methanol fuel cell system is realized, the emission of carbon dioxide is reduced, the circulation of hydrogen and oxygen is realized, and the energy utilization efficiency of the system is jointly improved through the circulation of carbon, hydrogen and oxygen.

The invention discloses a photovoltaic and thermochemical coupled full-spectrum solar hydrogen production system. The system comprises a concentrating and frequency dividing subsystem, a photovoltaic electrolysis subsystem and a photo-thermal methanol reforming subsystem, the light condensation and frequency division subsystem is used for carrying out focusing and frequency division on the incident full-spectrum sunlight, and then the full-spectrum sunlight enters the photovoltaic electrolysis subsystem and the photo-thermal methanol reforming subsystem; the waveband sunlight matched with the photovoltaic band gap is focused and incident into the photovoltaic electrolysis subsystem to be converted into electric energy, and then water electrolysis for hydrogen production is driven; and the sunlight of the rest wave band is focused and incident to the photo-thermal methanol cracking subsystem to be converted into heat energy, so that the methanol / water reaction solution is driven to perform methanol reforming thermal chemical reaction for hydrogen production. And the photovoltaic electrolysis subsystem is connected with the photo-thermal methanol reforming subsystem, and is used for recycling waste heat generated in the photovoltaic power generation process for preheating a reaction solution and cooling a photovoltaic device at the same time. According to the invention, efficient conversion from full-spectrum solar energy to hydrogen energy is realized.

The invention discloses a noble metal-based catalyst as well as a preparation method and application thereof, and belongs to the technical field of methanol steam reforming hydrogen production and catalysts. The noble metal-based catalyst comprises a carrier, an auxiliary agent metal and an active metal, the carrier comprises CeO2, and the shape of the carrier is in a rod shape; the active metal comprises Pt; the auxiliary agent metal comprises In2O3; the active sites of the noble metal-based catalyst comprise Pt < 2 + > and Pt < delta + >, the Pt < 2 + > is higher than 85%, and the Pt < delta + > is lower than 15%. According to the invention, the ratio of CO in the product is effectively reduced.

The invention relates to a modular methanol reforming hydrogen production system, and belongs to the technical field of new energy of methanol reforming hydrogen production. The hydrogen production system comprises a control system, an air inlet module, a methanol supply module, a plurality of methanol reforming hydrogen production modules, a reformed gas main pipeline and a tail gas main pipeline, wherein the methanol reforming hydrogen production module comprises a methanol reformer, a tail gas heat exchanger, a methanol evaporator, a methanol aqueous solution sub-feeding pump, a methanol aqueous solution sub-pipeline, a reformed gas sub-pipeline and a tail gas sub-pipeline; the methanol reformer comprises a vaporizing chamber, an oxidizing chamber and a reforming chamber; an outlet of high-temperature tail gas generated by the oxidizing chamber is connected with the tail gas heat exchanger and the methanol evaporator; and the methanol aqueous solution main storage tank is sequentially connected with the methanol evaporator, the tail gas heat exchanger and the reforming chamber through a methanol aqueous solution feeding pump. The methanol reforming hydrogen production system adopts a modular design, is simple in equipment, high in expansibility, quick to start and adjustable in hydrogen production amount, and realizes instant production and instant use of hydrogen energy and hydrogen.

The invention discloses a sialic acid molecular imprinting extraction method, and belongs to the technical field of separation and purification. The invention discloses a sialic acid molecular imprinting extraction method which comprises the following steps: dissolving a sialic acid standard substance and a functional monomer in a binary pore-foaming agent-ionic liquid, adding a cross-linking agent and an initiator, polymerizing under ultraviolet light to prepare a high-molecular polymer, and washing off the sialic acid standard substance to prepare a molecular imprinting polymer; specifically adsorbing sialic acid in the fermentation liquor by using the molecularly imprinted polymer; performing graded elution on sialic acid by using a methanol-water mixed solution and a methanol-acetic acid mixed solution; and performing rotary evaporation concentration, anti-solvent crystallization, separation and drying on the bird's nest acid eluent. Tests show that the sialic acid purity is greater than or equal to 99%, and can meet the requirements of the sialic acid in the fields of food, health care, medicine, cosmetics and the like. According to the method, sialic acid can be efficiently separated and extracted from sialic acid fermentation liquor, the product yield is increased, the extraction procedures are reduced, and the production cost and the discharge amount of three wastes are reduced.

The acid removal system comprises a shift gas washing tower, a medium-pressure flash tower, a CO2 desorption tower, an H2S concentration tower, an N2 gas stripping tower, a thermal regeneration tower, a methanol-water separation tower and a tail gas washing tower which are sequentially communicated through a first pipeline, the lower end of the shift gas washing tower is communicated with a shift gas pipe which is communicated with the top of the medium-pressure flash tower through a second pipeline, and the top of the shift gas washing tower is communicated with a PSA hydrogen production device through a third pipeline; the CO2 desorption tower is sequentially communicated with the compressor and the urea production part through a fourth pipeline; the comprehensive automation level of the acid removal device can be improved, and the operation labor intensity is reduced; the operation stability of the acid removal device is improved, and the standard deviation of each key process parameter is reduced.

The invention relates to the technical field of radiation refrigeration films, and discloses a porous polyvinylidene fluoride based composite radiation refrigeration film and a preparation method thereof. The method comprises the following steps: firstly, carrying out melt blending on PVDF, NaCl and ZnO nanoparticles and forming a film, then dissolving out NaCl through water washing, and constructing a continuous three-dimensional porous structure in a PVDF matrix; and immersing the obtained porous PVDF / ZnO membrane material into a methanol aqueous solution containing 2-methylimidazole, so that ZnO is subjected to a coordination reaction at the pore wall and is converted into the ZIF-8 nanocrystal in situ. In the thin film prepared by the steps, the micron-sized salt-induced pore structure, the nano-sized ZIF-8 particles and the interface of the ZIF-8 particles jointly form a multi-stage scattering network, so that the scattering ability of the thin film in the solar spectrum range of 0.25-2.5 microns can be remarkably enhanced, the high infrared emission performance of the PVDF matrix in an atmospheric window of 8-13 microns is maintained, and the thin film has high solar reflectivity and high infrared emissivity, and can be used for preparing the solar film. An excellent radiation refrigeration effect can be achieved, and the heat-dissipating material is suitable for being applied to building outer surfaces, equipment heat dissipation, individual heat management and the like.

The invention relates to a modular methanol reforming and high-temperature membrane fuel cell coupled heat and power cogeneration system, which comprises a modular methanol reforming hydrogen production system, a modular high-temperature membrane fuel cell power generation system and an electric control system, and is characterized in that the modular methanol reforming hydrogen production system comprises a methanol reforming hydrogen production module, a methanol aqueous solution main pipeline and a tail gas main pipeline; the number of the methanol reforming hydrogen production modules is multiple, the methanol aqueous solution main pipeline is connected with the methanol reforming hydrogen production modules, and the methanol reforming hydrogen production modules convey obtained reformed hydrogen to the high-temperature fuel stack module; the high-temperature membrane fuel cell power generation module supplies power according to electric energy generated by reforming hydrogen; the electric control system is connected with the methanol reforming hydrogen production module, a temperature alarm value and a starting temperature value are set, the methanol reforming hydrogen production module is closed when the actual temperature of the methanol reforming hydrogen production module exceeds the temperature alarm value, the methanol reforming hydrogen production module is restarted when the actual temperature is lower than the corresponding starting temperature value, and the power supply cost can be reduced.

The invention belongs to the technical field of teenager depression marker detection, and particularly relates to a teenager depression marker detection kit and a teenager depression marker detection method, the kit comprises an extraction liquid, an internal standard substance, a quality control substance and a mobile phase additive, the internal standard substance comprises a stable isotope labeled metabolic marker, the quality control substance comprises a standard metabolic marker, and the mobile phase additive comprises a mobile phase. The detection method comprises the following steps: S1, dissolving an internal standard substance by using a methanol-containing aqueous solution to prepare an internal standard stock solution; s2, methanol is added into the internal standard stock solution for dilution, uniform mixing is performed, and an extraction working solution is prepared; s3, taking a quality control product / sample, adding an extraction working solution, carrying out oscillation incubation, centrifuging, and taking supernate as a to-be-detected sample; s4, the sample to be detected is detected through a liquid chromatograph-mass spectrometer, various biomarkers related to depression in the body of the teenager can be rapidly and accurately detected, and an objective and reliable basis is provided for early diagnosis and illness state evaluation of the depression of the teenager.

The invention discloses a method for determining chemical components in a medicine for treating vitiligo and a method for establishing a fingerprint spectrum. Comprising the following steps: S1, preparing a to-be-detected solution and a reference substance solution: grinding Bailing tablets, dissolving the Bailing tablets in a solvent, and extracting to prepare the to-be-detected solution; dissolving a paeoniflorin reference substance in a solvent to prepare a reference substance solution; wherein the extraction solvent is a methanol-water mixed solution; s2, respectively obtaining chromatograms of the to-be-detected solution and the reference substance solution under the same detection conditions by adopting ultra-high performance liquid chromatography, and carrying out qualitative analysis and / or quantitative analysis on chemical components in the chromatograms of the to-be-detected solution; wherein the detection conditions are as follows: the wavelength of a detector is 201 + / -2nm; the elution conditions are as follows: acetonitrile is used as a phase A, water is used as a phase B, and elution is performed through a gradient elution procedure. According to the method, the chemical components in the medicine for treating the leucoderma can be accurately determined, so that the establishment of the fingerprint spectrum database of the medicine for treating the leucoderma can be better realized.

The invention discloses a marine methanol single fuel supply temperature control system, and belongs to the field of methanol fuel temperature control. A marine methanol single fuel supply temperature control system comprises a water ethylene glycol pump, a methanol water ethylene glycol heat exchanger, an electric heater, a water ethylene glycol cylinder sleeve water heat exchanger and a three-way temperature adjusting valve, and the input end of the water ethylene glycol pump is communicated with the output end of the methanol water ethylene glycol heat exchanger; electric heating and waste heat of main engine cylinder sleeve water are used as heat sources, water glycol is used as a closed circulating medium, the heat sources are switched through a three-way temperature adjusting valve, before an engine or a generator is started, electric heating is used as a temporary heat source, and methanol fuel is heated to the required temperature through heat exchange of the water glycol; and after the engine or the generator is started, electric heating is stopped, the waste heat of the cylinder sleeve water is used as a heat source, additional energy consumption does not need to be increased, the energy utilization rate is increased, and the ship operation cost is reduced.

The invention discloses a methanol water reforming hydrogen production method, and relates to the technical field of hydrogen energy preparation, and the method comprises the following steps: 1) catalytic reforming reaction; and 2) separation and purification. The preparation method comprises the following steps: performing nitrogen doping modification on activated carbon by a hydrothermal method to prepare an N-AC carrier; then Co is preferentially anchored to the carrier at low temperature by utilizing the steric hindrance effect of a cobalt-ammonia complex, and a highly dispersed CoxOy active center is formed through thermal decomposition; and finally, co-dipping Cu and Zn precursors, precipitating and reducing to form a Cu-Zn active center, and constructing a Cu-Zn-CoxOy / N-AC bifunctional concerted catalytic system which is used for hydrogen production by reforming methanol and water. After methanol and desalted water are mixed and gasified, the mixture is introduced into a reforming reactor loaded with a Cu-Zn-CoxOy / N-AC catalyst for reaction, generated reformed gas is subjected to cooling and gas-liquid separation and then is purified through a CO adsorption bed and a pressure swing adsorption system, and high-purity hydrogen is obtained.

The invention relates to a BYD (1, 4-butynediol) rectification process and system, and solves the problems of high energy consumption and high steam and circulating water consumption in the existing BYD rectification process. The rectification process comprises the following steps: preheating a mixed solution containing 1, 4-butynediol, methanol, water and formaldehyde from an ethynylation reactor through a feed preheater, feeding the preheated mixed solution into a stripping tower for stripping, and leading out tower kettle liquid of a tower kettle of the stripping tower through a liquid phase outlet, feeding into the feed preheater, carrying out indirect heat exchange with the mixed solution, and further cooling by a stripping tower kettle discharge cooler to obtain a BYD product; a gas phase at the top of the stripping tower is led out through a gas phase outlet, is firstly fed into a compressor for pressurizing and heating, then is fed into a stripping tower reboiler for heat exchange and heat energy recovery, then enters a stripping tower reflux tank, and is fed into an alcohol tower for rectification through a reflux pump. The method has the advantages of simple process, energy saving, consumption reduction, low operation cost, effective recovery of tower top heat energy, saving of a large amount of cooling water, and high product concentration.

The invention belongs to the field of liquid chromatography-mass spectrometry detection, and discloses a liquid chromatography-mass spectrometry detection method for trace target objects in seawater, which comprises the following steps: firstly, configuring and precisely calibrating parameters such as flow velocity, column temperature, ion source voltage and the like for a liquid chromatography system, a chromatographic column, an automatic sampler and a tandem mass spectrometer; then, a methanol-water (containing 0.1% formic acid) system is adopted to implement linear gradient elution, polar difference component separation is considered, and analysis duration is compressed; a sample is subjected to solid-phase extraction, purification and concentration, then is automatically injected, is subjected to chromatographic separation and then enters an electrospray ion source; a mass spectrum end selects a dynamic multi-reaction monitoring (dMRM) mode, characteristic ion pairs are collected in a preset time window, and selective scanning and baseline noise suppression are achieved; and finally, utilizing retention time matching and internal standard correction to obtain a pg.L <-1 > magnitude quantitative result.

The utility model discloses a hydrogen production and power generation coupling system based on methanol concentration difference, which relates to the technical field of methanol electrolysis hydrogen production and comprises a methanol electrolysis hydrogen production reactor, a methanol water supply unit, a direct methanol fuel cell and an energy storage cell, the methanol water supply unit provides methanol water required by hydrogen production for the methanol electrolysis hydrogen production reactor, and a water outlet of the methanol electrolysis hydrogen production reactor is communicated with a water inlet of the direct methanol fuel cell, so that low-concentration methanol water output by the methanol electrolysis hydrogen production reactor is input into the direct methanol fuel cell for power generation; the direct methanol fuel cell, the energy storage cell and the methanol electrolysis hydrogen production reactor are sequentially in circuit connection. According to the methanol electrolysis hydrogen production reactor, the high-concentration methanol aqueous solution is used for electrolysis hydrogen production, the output low-concentration methanol aqueous solution serves as a raw material for power generation of the direct methanol fuel cell, the direct methanol fuel cell generates power and then supplies the power for hydrogen production of the methanol electrolysis hydrogen production reactor, an external power source is not needed for power supply, and the system efficiency is high.

The application discloses a kind of ruthenium grafting manganese aluminum hydrotalcite and catalytic method for C02 hydrogenation preparation formic acid, belong to catalyst technical field, in the application, under the optimized reaction condition, with methanol:water mixture as solvent (5:1), total pressure is 60bar, 60 DEG C, reaction 24 hours, with temperature controller to be heated to the temperature required for reactor.When the temperature inside the reactor reaches the specified temperature, start stirring at a fixed stirring speed (200-800 revolutions / min), after the required reaction time, stop stirring and heating, and allow the reactor to cool to room temperature. The hydrogenation products were analyzed by high performance liquid chromatography, the conversion number (TON) of formic acid reached more than 8000; RuMnAl-LDH was prepared by coprecipitation method, and RuMnAl hydrotalcite catalyst was obtained by heating and activation in a muffle furnace. The preparation process is simple, and the raw materials are easy to obtain. The RuMnAl-LDH catalyst prepared by the application has good catalytic activity and stability in the catalytic hydrogenation of formic acid to formic acid reaction, and has wide application prospect.

The invention belongs to the technical field of methanol hydrogen production, and discloses a process for catalytic heating coupling methanol hydrogen production. The process comprises the following steps: S1, providing a methanol cracking hydrogen production system; and S2, carrying out methanol steam reforming hydrogen production treatment based on a methanol cracking hydrogen production system. And S3, carrying out pressure swing adsorption treatment on the methanol decomposition gas prepared in S2 to obtain desorbed gas and purified hydrogen. S4, purified hydrogen flows through a product gas buffer tank with a filter element and then is fed into a gas using section. And S5, feeding the desorbed gas into a catalytic oxidation reactor for recovery treatment, and supplying released heat energy to a methanol cracking hydrogen production system for use. According to the invention, the organic combination of catalytic oxidation and methanol cracking hydrogen production is realized, the problems that the existing methanol hydrogen production process needs to discharge combustible tail gas and is unsafe and not environment-friendly are solved, extra fuel is not needed in the whole hydrogen production process, and only methanol needs to be provided; the method has the remarkable advantage of zero consumption of natural gas, diesel oil, coal and other fuels.

The application discloses a preparation method and application of a low-Cu-loading high-activity methanol reforming hydrogen production catalyst. The catalyst takes Al2O3 as a carrier, Cu as an active component, and Ce as an additive, is synthesized by a coprecipitation method in one step, and realizes the synergistic effect of the active metal, the additive and the carrier by precisely controlling the Cu loading to be 5-15%, the Ce doping amount to be 1-5%, and combining specific precipitation, calcination and reduction processes; the dispersion degree and the low-temperature catalytic performance of Cu are improved by using the redox electron regulation formed by CeO2 and Al2O3 and the strong metal carrier interaction. Without doping of noble metals, the raw material cost is reduced, meanwhile, the catalyst has excellent mechanical strength, the long-period reaction performance does not attenuate for 300 hours, is suitable for a fixed-bed reforming reactor, can be efficiently applied to a methanol steam reforming hydrogen production reaction, and has remarkable industrial application value.

The utility model discloses an anti-corrosion control system for a low-temperature methanol washing process, which comprises an alkali liquor adding tank used for storing and preparing alkali liquor with the concentration of 2%; the alkali liquor filling pump is connected to the alkali liquor dosing tank and is used for conveying the prepared 2% alkali liquor to an ammonia washing tower and a methanol-water separation tower in the production system; the alkali liquor dosing tank liquid level meter is arranged on the alkali liquor dosing tank and is used for monitoring the liquid level in the alkali liquor dosing tank in real time and sending out an alarm and interlocking protection signal; the DCS control system is used for automatically controlling the supplement amount of alkali liquor according to preset program setting and ensuring safe operation, the alkali liquor filling pump and the alkali liquor dosing tank liquid level meter are both connected with the DCS control system, 1-2% of alkali liquor is supplemented through online continuous operation, the PH value of condensate of the methanol-water separation tower and the ammonia washing tower is controlled to be 7-8, and therefore the problem of equipment corrosion is solved.

The application discloses a cold-heat-electricity-hydrogen-carbon co-production system and method based on cross-critical carbon dioxide energy storage, and the method is as follows: carbon dioxide is compressed by a carbon dioxide compressor set and then enters an expander set to work and generate electricity; heat energy generated in the carbon dioxide compression process provides heat for a methanol water vapor reforming hydrogen production process and a methanol cracking hydrogen production process through a first heat exchanger and a second heat exchanger respectively; a solar power generation unit generates electricity to provide electric energy for the carbon dioxide compressor set, a methanol water vapor reforming hydrogen production reactor and a methanol cracking hydrogen production reactor; carbon dioxide generated in the methanol water vapor reforming hydrogen production is input into the carbon dioxide compressor set; carbon monoxide generated in the methanol cracking hydrogen production is combusted to generate high-temperature flue gas, and the high-temperature flue gas provides heat for the expansion of compressed carbon dioxide in the expander set; the carbon dioxide compression provides heat energy for a hydrogen production reaction of methanol, and solar power generation provides electric energy for the hydrogen production of methanol, so that the system energy consumption is reduced, and carbon monoxide is consumed in the system.

The application discloses a kind of oxygen vacancy promotes methanol carbon-carbon coupling ethane production method, comprising the following steps: synthesizing H2Ti4O9;The obtained H2Ti4O9 is stripped into colloidal sheet, obtains two-dimensional TiO2 nanosheet;Hydrogenation treatment obtains the TiO2 nanosheet with oxygen vacancy;The TiO2 nanosheet with oxygen vacancy is dissolved in methanol / water solution, drop into H2PtCl6 solution, solution is in vacuum state, then it is irradiated with arc lamp while stirring N1 hour, obtain brown white precipitate, after washing vacuum drying catalyst is obtained;Methanol / water solution is placed into reactor, catalyst is uniformly dispersed in methanol / water solution, when reaction, first the reactor is evacuated to remove air, then xenon lamp is opened to carry out illumination, after reaction, obtain ethane.The application uses the TiO2 nanosheet with oxygen vacancy as catalyst to produce ethane, and a large number of oxygen vacancies increase a large number of methanol dissociation sites, thereby reducing the distance between adjacent methoxyl groups, and then promoting coupling to generate ethane.

The present application relates to the technical fields of chemical synthesis, and discloses a kind of aviation kerosene production process and equipment, production process includes: carbon source gas, hydrogen, circulating gas is sent into main reactor reaction and obtains including hydrocarbon, methanol, CO, water and unreacted gas mixed component a;Mixed component a is sent into cascade reactor and is prepared to obtain including aviation kerosene component, light hydrocarbon component and water mixed component b, wherein light hydrocarbon component includes one or more of C2-C7 light hydrocarbon;Mixed component b is fractionally condensed to collect liquid phase and gas phase, and liquid phase is carried out three-phase separation to obtain aviation kerosene component, light hydrocarbon component and water respectively, aviation kerosene component is hydrotreated, fractionation to obtain aviation kerosene.The present application realizes the step-by-step control of reaction path in carbon source hydrogenation process through the synergistic effect of main reactor and cascade reactor, improves the selectivity of aviation kerosene target product, so that the obtained product meets the 3# aviation kerosene standard requirements in key indicators such as distillation range distribution, aromatic content and low temperature performance.

The invention discloses a crystal form and a preparation method of Alalistrum hydrochloride, the crystal form comprises a crystal form Form3, a crystal form 4 and a crystal form Form11, Alalistrum hydrochloride solids Form3 (methanol-water composite solvate), Form4 (hydrate) and Form11 can be obtained by mixing and dissolving Alalistrum hydrochloride solids and an organic solvent, and then adopting the modes of crystallization, crystal mush and volatilizing, and the Alalistrum hydrochloride solids Form3 (methanol-water composite solvate), Form4 (hydrate) and Form11 can be obtained by using the crystal form of Alalistrum hydrochloride and the preparation method of the crystal form of Alalistrum hydrochloride and the preparation method of the crystal form of Alalistrum hydrochloride. The preparation method disclosed by the invention is simple in process, strong in operability, high in yield, high in purity and good in crystallinity, and the crystal form disclosed by the invention is high in solubility, few in residual solvent and good in solid property and meets the medicinal development standard.