The invention discloses a high-generating-efficiency solar cell based on an electrochromic device and a making method of the solar cell. Improvement is conducted on the structure of the electrochromic device and a making technology, therefore, the electrochromic device has the self-power supply advantage, and the high-generating-efficiency solar cell based on the electrochromic device is made, wherein the solar cell is extremely high in photovoltaic energy conversion efficiency, the service life is prolonged, and the cold resistance is good. The method is simple and easy to operate, and industrial production is easy. At room temperature, a 1,000 W simulated sunlight source xenon lamp (Oriel 91192, USA) and a Keithly 2400source meter are used, the photovoltaic energy conversion efficiency is measured to range from 8.28% to 10.58% on the condition that the irradiation intensity is 100 W/cm<2>, and the irradiation area of the cell is 0.25 cm<2>, and after circulation is conducted 5,000 times, the photovoltaic energy conversion efficiency is measured to range from 8.01% to 10.56%.