The invention belongs to the technical field of preparation of organic light-emitting materials, and particularly relates to polyspirofluorene containing a hole transport group on a
side chain and a preparation method and the application thereof. The
side chain of the polyspirofluorene contains the hole transport group, so that the HOMO
energy level of the polyspirofluorene can be increased, the hole injection barrier can be reduced, and achievement of the balance of hole injection and
electron injection is facilitated; in addition, the polyspirofluorene light-emitting material has relativelygood
solubility, and after the polyspirofluorene light-emitting material is dissolved by a common
organic solvent, a film can be formed through
spin coating,
inkjet printing or printing and a light-emitting layer of a light-emitting
diode is prepared; when the light-emitting layer based on the
polymer is used for preparing a light-emitting device, the addition of a
hole transport layer is not required, so that a preparation technology of the device is simpler; the polyspirofluorene light-emitting material is applied to a single-layer electroluminescent device, the maximum current efficiency (LEmax) thereof is 0.67cd / A, the maximum luminance (Lmax) of the device is 3484cd / m<2>, and the turn-on
voltage (Von) of the device is only 2.7v.