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93results about How to "Increase HOMO level" patented technology

Fused ring compound as well as preparation method and application thereof

The invention discloses a fused ring compound comprising a structure shown as a formula (I) or (II). According to the fused ring compound, by controlling effective conjugation of aromatic rings and heterocyclic rings, the electron transport performance is balanced while the hole performance is improved. The compound has high triplet state energy level and glass transition temperature, is difficultin crystallization of material molecules, and is capable of ensuring high-efficiency transfer of energy to a guest material while serving as a host material of a luminous layer. The substituent groupof the fused ring compound is adjusted, the electron and hole transport performances are further improved, the singlet state and triplet state energy level difference is reduced, the compound area ofthe carrier is widened, and triplet state exciton annihilation is avoided. The invention further discloses an organic electroluminescence device. At least one functional layer contains the fused ringcompound, and the fused ring compound serves as the host material of the luminous layer and is matched with the energy level of an adjacent carrier transport layer. The luminous efficiency of the device is improved, and the driving voltage of the device is reduced.
Owner:NINGBO LUMILAN NEW MATERIAL CO LTD

Fused ring compound as well as preparation method and purpose thereof

The invention discloses a fused ring compound, which has a structure shown as a formula (I) or a formula (II). The effective conjugation of aromatic rings and heterocyclic rings is controlled in the fused ring compound; the hole performance is improved; meanwhile, the electronic transmission performance is favorably balanced; the compound has high triplet state energy level and glass transition temperature; material molecules cannot easily crystallize; when the fused ring compound is used as a luminescent layer host material, the efficient transfer of energy to guest materials can be guaranteed. The substituent group of the fused ring compound is regulated, so that the electron and hole transmission performance is further improved; the singlet state and triplet state energy level difference is reduced; the compound region of carriers is expanded; the triplet state exciton annihilation is prevented. The invention also discloses an organic electroluminescence device; at least one function layer contains the fused ring compound; the fused ring compound is used as the host material of the luminescent layer and is matched with the adjacent carrier transmission layer energy level; the luminous efficiency of the device is improved; meanwhile, the driving voltage of the device is reduced.
Owner:NINGBO LUMILAN NEW MATERIAL CO LTD

Lithium ion battery electrolyte with consideration to water removal, acid reduction and improvement of high-voltage performance

The invention discloses lithium ion battery electrolyte with consideration to water removal, acid reduction and improvement of high-voltage performance, and relates to lithium ion batteries. The lithium ion battery electrolyte with the consideration to the water removal, the acid reduction and the improvement of the high-voltage performance comprises, by weight, 5.0%-18.0% of lithium salt, 83.0%-94.0% of non-aqueous organic solvents, 0.1%-5.0% of silazane additives and 0.1%-5.0% of other functional additives. The lithium ion battery electrolyte has the advantages of simple preparation process,low cost, easiness in implementation and good market prospect.
Owner:XIAMEN UNIV

9,9'- connected host material based on 4,4'-difluorene structure and application thereof

A 9,9'- connected host material based on a 4,4'-difluorene structure and an application thereof. The invention discloses a host material which has high triplet state and HOMO energy level and has excellent performance. According to the host material, 4,4'- connected difluorene structure is used as a molecular skeleton, and a substituent group is connected at 9,9'- site. Diphenylamine element Dn with hole transport performance can be connected, and An element with electron-transport performance also can be connected, wherein the An element contains an oxygen-phosphorus element and a sulfur-oxygen element; and in addition to the oxygen-phosphorus element and the sulfur-oxygen element, a special spiral structure also can be formed. A synthetic method of the host material is simple and practicable, and the host material is suitable for wide application. An organic electroluminescence blue phosphorescent luminescent device made of the host material has high efficiency, high brightness, low extinction efficiency and electroluminescence performance of low starting voltage, and can widely be applied in the field of organic electroluminescence.
Owner:WUHAN UNIV

Organic electroluminescence device

The invention provides an organic electroluminescence device and relates to the technical field of organic electroluminescence. According to the invention, compounds shown as chemical formula I and IIare applied to the organic electroluminescence device, are jointly used as a hole transport layer of the device and are adaptively combined with each other, so that heat stability and carrier transport property of the material are effectively promoted, compounding probability of carrier is promoted, driving voltage of device is effectively reduced, luminous efficiency of device is increased, service life of device is prolonged and the problems of low heat stability of material, short service life and low luminous efficiency of the organic electroluminescence device are effectively solved.
Owner:CHANGCHUN HYPERIONS TECH CO LTD

Trifluoreneamine compound, trifluoreneamine polymer luminescent material and preparation methods and application thereof

The invention discloses a trifluoreneamine compound, a trifluoreneamine polymer luminescent material and preparation methods and application thereof. The material takes trifluoreneamine as a framework; the bipolarity and the illuminant color of the luminescent material can be regulated and controlled by changing the chemical structure of a side chain of the trifluoreneamine polymer luminescent material; and the chemical structure of the material is shown in the specifications. The preparation method comprises the following steps of: performing a series of simple reactions on fluorene serving as an initial reaction raw material; and performing a Suzuki coupling reaction under the catalysis of palladium and performing double-boric acid ester alternative copolymerization on fluorene to obtain a target polymer, namely the luminescent material. The material is easy to synthesize, is convenient to purify, has higher solubility, film forming property, and film form stability and high photoluminescence and electrofluorescence efficiencies, and is applied to a polymer electroluminescent diode luminous layer.
Owner:SOUTH CHINA UNIV OF TECH +1

Cathode injection material, and manufacturing method and application thereof

The invention discloses a cathode injection material, and a manufacturing method and an application thereof. The cathode injection material comprises nano-titanium dioxide and a cesium salt doped mutually. The manufacturing method comprises the following steps of: preparing a nano-titanium dioxide solution and a cesium salt solution respectively; mixing a nano-titanium dioxide solution dispersion system with the cesium salt solution to obtain a mixed solution; and coating the mixed solution onto a conductive substrate in a spinning way, and heating and drying to obtain the cathode injection material. The cathode injection material disclosed by the invention has the advantages of low cost, capability of effectively enhancing the input and the transmission of charges, increase in the LUMO energy level of a cathode when applied to an organic electroluminescent device, matching with the energy level of an organic electroluminescent structure, reduction in a potential barrier between the cathode injection material and the organic electroluminescent structure, more suitability for electron injection, increase in the electron injection efficiency, preferable increase in the light extraction capability of the organic electroluminescent device, high luminance and long service life. The manufacturing method of the cathode injection material has a simple procedure and high production efficiency.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +1

Condensed ring-containing triarylamine compound and organic light-emitting device thereof

The invention provides a condensed ring-containing triarylamine compound and an organic light-emitting device thereof, and relates to the technical field of organic photoelectric materials. The condensed ring-containing triarylamine compound has excellent hole transport performance, has the advantages of high luminous efficiency and low driving voltage, is a good hole transport material, and can improve the luminous efficiency of an organic light-emitting device, prolong the service life of the organic light-emitting device and reduce the driving voltage of the device; and the condensed ring-containing triarylamine compound provided by the invention is applied to the organic light-emitting device as a covering layer material, so that the light extraction efficiency can be improved, the light-emitting efficiency of the organic light-emitting device is improved, and meanwhile, the service life of the device can be prolonged. The triarylamine organic compound is simple to synthesize and easy to operate, and can be widely applied to the fields of panel display, lighting sources, organic solar cells, organic photoreceptors or organic thin film transistors and the like.
Owner:CHANGCHUN HYPERIONS TECH CO LTD

Non-aqueous electrolyte and lithium ion battery

The invention provides a non-aqueous electrolyte and a lithium ion battery. The non-aqueous electrolyte comprises a solvent, an electrolyte lithium salt and a functional additive, wherein the functional additive comprises 4,4'-dipinacol borate diphenyl sulfone, dipyridyl carbonate and lithium difluorophosphate. When the electrolyte provided by the invention is applied to a lithium ion battery of ahigh-nickel ternary material / graphite system, the impedance of the lithium ion battery can be remarkably reduced, the power performance of the lithium ion battery can be improved, gas production of the lithium ion battery in circulation and storage processes can be remarkably inhibited, and the rate capability, the normal-temperature cycle performance, the high-temperature cycle performance, thehigh-temperature storage performance and the safety performance of the lithium ion battery are remarkably improved.
Owner:DONGGUAN DONGYANG SOLAR SCI RES & DEV CO LTD

Fused ring compound as well as preparation method and application thereof

The invention discloses a fused ring compound. The fused ring compound has the structure as shown in a formula (I) or a formula (II). The fused ring compound is favorable for balancing electronic transmission property while improving the cavitation performance by controlling effective conjugation of an aromatic ring and a heterocyclic ring; and the compound has high three linear energy level and vitreous transition temperature, the material molecules are not liable to crystallization, and the compound serving as a main body material of a light-emitting layer can guarantee that the energy is efficiently transmitted to an object material. The substituent group of the fusing ring compound is adjusted, so that the transmission performance of electrons and cavities is further improved, single linear and three linear energy level difference is reduced, the composite area of a current carrier is widened and three linear exciton annihilation is avoided. The invention also discloses an organicelectroluminescence device; at least one functional layer comprises the fused ring compound; the fused ring compound serves as the main body material of the light-emitting layer and is matched with the energy level of the adjacent current carrier transmission layer; and the driving voltage of the device is reduced while the light-emitting efficiency of the device is improved.
Owner:NINGBO LUMILAN NEW MATERIAL CO LTD

Electrolyte-containing nitrile ethyl amine and lithium secondary battery

ActiveCN104681868AInhibition of irreversible oxidation reactionsImprove oxidation resistanceSecondary cellsHigh temperature storageOrganic solvent
The invention discloses electrolyte-containing nitrile ethyl amine and a lithium secondary battery. The electrolyte comprises electrolyte lithium salt, nitrile ethyl amine, a non-water organic solvent and an additive, wherein the concentration of the electrolyte lithium salt in electrolyte is 0.5-2mol / L; the nitrile ethyl amine is 0.1%-20% (in percentage by weight) of the electrolyte; the used amount of the additive is 0.1-10.0% of the weight of the organic solvent. The nitrile ethyl molecular structure comprises more than one pair of bisnitrile functional groups and can be complexed with transitional metal ions, is added by a small amount to effectively inhibit irreversible oxidation reaction of the organic solvent on a positive surface, so that the oxidization resistance of the electrolyte is improved; the nitrile ethyl molecular structure contains a Louis alkaline amine radical, and can be used for effectively stabilizing physical and chemical properties of the electrolyte through the complexing between the amine and free trace HF and PF5 in the electrolyte. With the technical characteristics, the nitrile ethyl amine is beneficial to improving the circulating performances of the battery under high voltage, so that a gas inflation rate of the battery under a high-temperature storage environment is reduced, and a capacity recovery rate is increased.
Owner:GUANGZHOU TINCI MATERIALS TECH

Cavity-transferring material and its preparation method

This invention relates to a hole mobile material TPA-BN-TPA used in organic electroluminescent devices and method for making same, comprising: in the argon gas atmosphere, dissolve the dinaphthalenediboracic acid and 4-bromobenzene-diphenylamine in organic solvent; add in palladium catalyst and catalyst promoter and reflux by heating; extract with organic solvent, dry the organic phase with magnesium sulfate, remove the solvent and obtain the final product. This invention has a simple process, and the produced material is characterized of good solubility, easy to form imperforate dense optically transparent film, which can efficiently realize hole injection. The further element result shows that this compound is a hole mobile material with good combination property, therefore, it can be used in producing high efficient electroluminescent devices.
Owner:INST OF CHEM CHINESE ACAD OF SCI

Polyspirofluorene containing hole transport group on side chain and preparation method and application thereof

The invention belongs to the technical field of preparation of organic light-emitting materials, and particularly relates to polyspirofluorene containing a hole transport group on a side chain and a preparation method and the application thereof. The side chain of the polyspirofluorene contains the hole transport group, so that the HOMO energy level of the polyspirofluorene can be increased, the hole injection barrier can be reduced, and achievement of the balance of hole injection and electron injection is facilitated; in addition, the polyspirofluorene light-emitting material has relativelygood solubility, and after the polyspirofluorene light-emitting material is dissolved by a common organic solvent, a film can be formed through spin coating, inkjet printing or printing and a light-emitting layer of a light-emitting diode is prepared; when the light-emitting layer based on the polymer is used for preparing a light-emitting device, the addition of a hole transport layer is not required, so that a preparation technology of the device is simpler; the polyspirofluorene light-emitting material is applied to a single-layer electroluminescent device, the maximum current efficiency (LEmax) thereof is 0.67cd / A, the maximum luminance (Lmax) of the device is 3484cd / m<2>, and the turn-on voltage (Von) of the device is only 2.7v.
Owner:SOUTH CHINA UNIV OF TECH

Organic electroluminescent device and preparation method thereof

An organic electroluminescent device comprises an anode, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, an electron injection layer, and a cathode, all of which are sequentially stacked. The cathode layer is composed of a film layer, a zinc compound doped layer, and a metal sulfide layer. The film layer is made of at least one material selected from an indium tin oxide target, an aluminum zinc oxide target, and an indium zinc oxide target. The zinc compound doped layer includes a zinc compound and a hole injection material doped in the zinc compound, wherein the zinc compound includes at least one selected from zinc oxide, zinc sulfide, zinc selenide, and zinc chloride. The metal sulfide layer includes at least one material selected from zinc sulfide, cadmium sulfide, magnesium sulfate and copper sulfide. The organic electroluminescent device has high luminous efficiency. The invention further provides a method for preparing the organic electroluminescent device.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +2

Lithium ion battery electrolyte containing unsaturated bond silane additive and lithium ion battery

The invention discloses a lithium ion battery electrolyte containing an unsaturated bond silane additive, which comprises an electrolyte lithium salt, a non-aqueous organic solvent and a film-forming additive, and the film-forming additive comprises an unsaturated bond-containing silane additive with a structure shown in a formula (I). The invention further discloses a lithium ion battery. The lithium ion battery comprises a positive plate, an isolating membrane, a negative plate and the lithium ion battery electrolyte containing the unsaturated bond silane additive. According to the invention, the formula of the electrolyte is optimized, all the components have a synergistic effect, the advantages of the components can be exerted, the defects of the components can be mutually inhibited, and the cycle performance of the lithium ion battery and the capacity retention rate after high-temperature storage are remarkably improved.
Owner:SHANSHAN ADVANCED MATERIALS QUZHOU CO LTD

Compound with ketone as core, preparation method and application of compound

The invention discloses a compound with ketone as the core, a preparation method and application of the compound. The compound has small delta Est, reverse interstitial leaping of energy is facilitated, and the compound has a high triplet state energy level (T1) and appropriate HOMO and LUMO energy levels, and is suitable for being used as a main material of a luminescent layer of an organic electroluminescence device; and in addition, the compound has the strong group rigidity, and has the characteristics of difficult crystallization and difficult aggregation among molecules and good film formation. The compound is applied to an OLED device as an organic electroluminescence functional layer material, the current efficiency, the power efficiency and the external quantum efficiency of the device are all greatly improved, and meanwhile, the service life of the device is obviously prolonged.
Owner:JIANGSU SUNERA TECH CO LTD

Dibenzo-heterocyclic compound and preparation method and applications thereof

The invention discloses a dibenzo-heterocyclic compound, which has a structure represented by the formula (I). The LUMO energy level of the dibenzo-heterocyclic compound is low, the dibenzo-heterocyclic compound can be well matched with an electron transport material, and the electron injection and transportation are promoted. The dibenzo-heterocyclic compound has a good hole transport performance, is capable of balancing the ratio of electrons / holes in a luminous layer when being used as a luminous layer material, increases the compounding probability, and improves the luminous efficiency. Due to the spatial configuration of the dibenzo-heterocyclic compound, molecule stacking is avoided, the generation of high energy exciton generated by energy transmission between molecules is prevented, annihilation of exciton is inhibited, and the roll-off is inhibited. At the same time, the dibenzo-heterocyclic compound has good thermal stability and is capable of efficiently and stably emittingblue light. The invention also discloses an organic electroluminescent device, at least one functional layer of the device comprises the dibenzo-heterocyclic compound, and the blue light device has the advantages of high blue light luminous efficiency and low work voltage.
Owner:NINGBO LUMILAN NEW MATERIAL CO LTD +1

1,1-bis(4'-aminophenyl)cyclohexane group-containing hole transport material, preparation method and applications thereof

The present invention discloses a 1,1-bis(4'-aminophenyl)cyclohexane group-containing hole transport material, a preparation method and applications thereof, and belongs to the technical field of perovskite solar cells, wherein the 1,1-bis(4'-aminophenyl)cyclohexane group-containing hole transport material has a structure represented by a formula 1, R is represented by a formula 2 or formula 3 or formula 4 or formula 5 or formula 6 or formula 7 or formula 8 or formula 9 or formula 10. The invention further discloses a preparation method and applications of the hole transport material. According to the present invention, the hole transport material is easy to prepare and refine, has characteristics of high yield and good solubility, is easily dissolved in common organic solvents, has high HOMO energy level, can be well matched to the energy level of the perovskite material, further has characteristics of high hole mobility, high glass transition temperature and high thermal stability, and easily forms the good amorphous film.
Owner:VALIANT CO LTD

Thickened triphenyl compound as well as preparation method and application thereof

The invention discloses a thickened triphenyl compound as well as a preparation method and application thereof. The thickened triphenyl compound has a structure shown as a formula (I). The parent nucleus of the thickened triphenyl compound is thickened triphenyl. Since the three benzene rings are non-coplanar, the thermal stability of molecules is improved. In addition, the non-coplanar structureof the thickened triphenyl can avoid molecular stacking, exciton generation is facilitated, and the luminous efficiency of the material is improved. By setting R1 and R2 substituent groups, the compound shown as the formula (I) has high overall structural rigidity, the thermal stability of the molecules can be improved, and the service life of the material is prolonged. The invention furthermore discloses an organic electroluminescence device. At least one functional layer contains the previous thickened triphenyl compound. The thickened triphenyl compound serves as a host material or a guestmaterial of the luminescent layer, the stability is high, and the luminous efficiency of the device is high.
Owner:NINGBO LUMILAN NEW MATERIAL CO LTD +1

Compounds, organic light-emitting device comprising same, display panel and display device

The invention provides compounds, an organic light-emitting device comprising the same, a display panel and a display device. The compounds have a structure represented by a formula I. The organic light-emitting device comprises an anode, a cathode and an organic thin film layer located between the anode and the cathode, and the organic thin film layer comprises a light-emitting layer and furthercomprises one or a combination of at least two of a hole transport layer, an electron blocking layer and a light-emitting auxiliary layer; at least one of the hole transport layer, the electron blocking layer and the light-emitting auxiliary layer contains at least one of the compounds. The compounds provided by the invention have a relatively shallow HOMO energy level, a relatively shallow LUMO energy level and a relatively high triplet state energy level, have the advantages of proper hole mobility, high Tg, large molecular torque, difficult crystallization and good thermal stability, can beused in the hole transport layer, the electron blocking layer and / or the light-emitting auxiliary layer of the organic light-emitting device, reduces the working voltage of the device, improves the light-emitting efficiency of the device and prolongs the service life of the device.
Owner:WUHAN TIANMA MICRO ELECTRONICS CO LTD

Novel compound and organic light-emitting element comprising same

A compound of the present invention has: an HOMO energy level facilitating hole injection; a high LUMO energy level capable of blocking electrons; and excellent hole transport characteristics. When applied to a hole injection layer or a hole transport layer of an organic light emitting device, the compound enables the organic light emitting device to have stability and durability resulted from excellent low voltages, high efficiency, and high Tg.
Owner:DONGJIN SEMICHEM CO LTD

Terpolymer and preparation method of electric storage device thereof

The invention provides a terpolymer and an electric storage device prepared by using the terpolymer as an organic layer. The prepared electric storage device is low in turn-on voltage, high in switchcurrent ratio, rapid in response, capable of performing repeated cyclic reading and writing, and excellent in performance. The terpolymer is simple in synthesis method and stable in electric storage device preparation process, has ternary electric storage performance, can realize industrial production, and has a good application prospect in the field of information storage.
Owner:HEILONGJIANG UNIV

Heterocyclic compound, synthetic method thereof and organic light-emitting diode containing compound

The invention relates to a heterocyclic compound, a synthetic method thereof and an organic light-emitting diode containing the compound. The structural formula of the heterocyclic compound is as shown in the figure I in the specification. According to the heterocyclic compound, the disubstituted pyridino-heterocyclic compound is obtained by introducing oxygen and a sulfur heterocyclic ring such as benzofuran and benzothiophene into a material, the HOMO energy level of the material is improved by the plane structures, the charge transfer efficiency is improved, and the thermodynamic stability of the material is improved; and meanwhile, the triplet-state energy level accords with the exciton binding requirement by virtue of special ortho-substitution connection, and the heterocyclic compound is applied to the organic light-emitting diode, so that the organic light-emitting diode (OLED) has the advantages of being high in efficiency, low in operating voltage and long in service life.
Owner:SHAANXI LIGHTE OPTOELECTRONICS MATERIAL CO LTD

Novel hole injection and hole transport compound and organic light-emitting element comprising same

A hole injection and hole transport compound according to the present invention has a HOMO energy level facilitating hole injection, high LUMO energy level capable of blocking electrons, a superb hole transport characteristic, and when applied to a hole injection layer or hole transport layer of an organic light-emitting element, can impart stability and extended lifespan thereto due to superbly low voltage, high efficiency and high Tg.
Owner:DONGJIN SEMICHEM CO LTD

Blue-ray metal complex and organic electroluminescent device thereof

The invention provides a blue-ray metal complex shown as the formula I and an organic electroluminescent device containing the blue-ray metal complex. By means of introduction of an alkoxy group to a complexing N atom para-position, HOMO (highest occupied molecular orbital) energy level of the complex is effectively increased, and hole injection barrier is lowered. Compared with the prior art, the organic electroluminescent device based on the blue-ray metal complex has the advantages of low driving voltage and high power efficiency.
Owner:CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI

Quantum dot light-emitting diode and preparation method thereof

The invention provides a quantum dot light-emitting diode. The quantum dot light-emitting diode comprises an anode and a cathode which are oppositely arranged, a quantum dot light-emitting layer arranged between the anode and the cathode, and a hole function lamination layer arranged between the anode and the quantum dot light-emitting layer, wherein the hole function lamination layer comprises ahole injection layer, a hole transport layer arranged on the hole injection layer and an interface layer arranged between the hole injection layer and the hole transport layer, the hole injection layer is arranged adjacent to the anode, and the material of the hole injection layer contains a transition metal oxide; the hole transport layer is arranged adjacent to the quantum dot light-emitting layer, and the material of the hole transport layer contains an organic hole transport material; and the interface layer is made of a graphene material.
Owner:TCL CORPORATION

Polysilafluorene luminescent material with hole transmission groups, and preparation and application thereof

The invention belongs to the technical field of organic luminescent materials, and discloses a polysilafluorene luminescent material with hole transmission groups, and preparation and application thereof. The structural general formula of the luminescent material is disclosed as Formula (I), wherein the hole refers to a hole transmission group. The preparation method comprises the following steps: carrying out reaction on 2,2'-diiodo-4,4'-dibromobiphenyl, butyl lithium and silicon tetrachloride to obtain 9,9'-dichlorosilafluorene; carrying out reaction bromine-atom-containing carbazole or triarylamine and butyl lithium or metal magnesium to obtain corresponding organic lithium or a Grignard reagent, and adding the organic lithium or Grignard reagent into the 9,9'-dichlorosilafluorene solution to react, thereby obtaining a 2,7-dibromosilafluorene monomer of which the side group is provided with carbazole or triphenylamine; and finally, carrying out polymerization reaction on the monomer to obtain the polysilafluorene luminescent material with hole transmission groups. The luminescent material can be used in the fields of electroluminescence, photovoltaic batteries, nonlinear optics and transduction.
Owner:SOUTH CHINA UNIV OF TECH

Thiophene-carbazole core four-arm hole transport material as well as preparation method and application thereof

ActiveCN111153896AInhibition of interfacial electron recombinationThe synthetic route is simpleOrganic chemistrySolid-state devicesBoronic acidElectron recombination
The invention discloses a thiophene-carbazole core four-arm hole transport material as well as a preparation method and application thereof; thiophene-carbazole is taken as a core, so that the HOMO energy level and LUMO energy level of the material are remarkably higher than those of mixed halogen perovskite, electrons can be prevented from jumping to a hole transport layer from a perovskite layer, and an interface electron recombination phenomenon is effectively inhibited. The preparation method comprises the following steps: carrying out a coupling reaction on p-iodoanisole and p-bromoaniline to generate an intermediate (5); carrying out substitution reaction on the intermediate (5) and bis(pinacolato)diboron to generate an intermediate (6); carrying out coupling reaction on the intermediate (6) and 2,3-dibromothiophene to generate an intermediate (7); carrying out bromination reaction on the intermediate (7) to generate an intermediate (8); carrying out coupling reaction on the intermediate (6) and 3,6-dibromocarbazole to generate an intermediate (9); and carrying out coupling reaction on the intermediate (9) and the intermediate (8) to generate a final product CZ-1. When the hole transport material provided by the invention is used for a perovskite solar cell, a cell device has relatively high photoelectric conversion efficiency.
Owner:HUAIYIN INSTITUTE OF TECHNOLOGY

Thiophene pyrroledione based co-polymer material, and preparation method and application thereof

InactiveCN103159928AEasy to modify photophysical propertiesConducive to delocalizationOrganic chemistrySolid-state devicesPolar structureElectron delocalization
The invention belongs to the field of solar cells, and discloses a thiophene pyrroledione based co-polymer material, and a preparation method and an application thereof. The co-polymer has the following structural formula (I). In the formula, both R1 and R2 represent a C1-C20 alkyl group and n is an integer ranging from 10 to 100. In the thiophene pyrroledione based co-polymer material provided by the invention, 2,7-carbazole has good hole transport properties, excellent chemical stability and easily modified photophysical properties; thiophene pyrroledione has a simple, symmetrical and polar structure and is beneficial to electron delocalization when the thiophene pyrroledione is polymerized with other monomers; and the thiophene pyrroledionehas relatively strong electron-withdrawing effect that results in reduction of an HOMO energy level and a LUMO energy level, thereby facilitating the increase of an open-circuit voltage. The performance can improve energy conversion efficiency of solar energy, so that the problem of low efficiency of polymer solar cells is solved.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +1

Indacenodifuranyl organic solar cell donor materials, and preparation method and application thereof

The invention discloses indacenodifuranyl organic solar cell donor materials, and a preparation method and an application thereof, wherein the structural formula of the IDF-based polymers is shown inthe specification, wherein R is n-hexyl, n-octyl, other groups defined in the specification, or other alkane and aromatic hydrocarbons, and n is 8-50. Besides, the series of designed and synthesized polymers PIDFCx have relatively high conjugation degree, relatively high HOMO energy level, relatively good light capturing capability and electrochemical performance; polymers PIDFC2C4 and PIDFC8 of which the side chains are isooctyl and n-octyl are taken as examples, the corresponding cell obtains relatively good photoelectric conversion efficiency under the condition of no post-treatment.
Owner:HENAN UNIVERSITY
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